The invention relates to a doped hexagonal boron nitride nano sheet, a preparation method thereof, a catalyst using the same as the carrier, and applications thereof. The preparation method comprises the following steps: adding a single substance or compound of hetero atoms, a single substance or compound of boron, and a nitrogen compound into water, evenly mixing, drying to remove water; then grinding the solid, placing the powder in a tubular furnace, introducing inert gas into the tubular furnace, heating the tubular furnace to a temperature of 800 to 1200 DEG C by program to carry out reactions, after reactions, cooling to the room temperature; grinding the reaction products, then boiling the grinded products in hot water, filtering when the water is still hot, washing the filter residue by hot water and ethanol, and drying. The doped hexagonal boron nitride nano sheet is taken as the carrier to prepare a catalyst, the active components loaded on the carrier can be one or more of transition metals, and the catalyst is used to catalyze organic reactions. A high temperature pyrolysis method is adopted, and the controllable preparation of nano material is achieved through controlling the ratio of each element in raw materials. The method is simple, the operation is easy, and the yield is high. The doped hexagonal boron nitride nano sheet can be used as the catalyst carrier, and is capable of improving the dispersity and catalytic activity of metal nano particles.