The invention relates to a preparation process of 
continuous casting slab high-temperature 
oxidation resistant coatings, which is characterized in that less than 120 meshes of 
powder, reductant containing carbon, inorganic binders, surfactants, 
suspending agents and the like with the compositions such as 25-55 wt% SiO2, 10-20 wt% Al203, 11-23 wt% MgO and the like are respectively grinded and mixed evenly, then water is used to be mixed and stirred sufficiently evenly, and finally the density of the coatings are adjusted within 1200-1500 kg / m3. The coatings can not only be sprayed onto 
continuous casting slabs at normal temperature, but also be sprayed onto high-temperature 
casting slabs, form continuous whole protective 
coating layers under the action of high temperature, effectively reduce 
temperature drop of the 
casting slabs and oxidation burning loss in even heating process of a 
heating furnace without changing original performance of matrixes, and effectively decrease 
dilution of alloying elements on the surfaces of the 
casting slabs. After the casting slabs are out of the 
heating furnace, natural spalling capability of the 
coating layers is strong, and oxidation matrixes of the casting slabs are smooth. Raw materials of the 
oxidation resistant coatings are easy to be obtained, and the coatings have low cost and simple preparation process and are adaptable to 
oxidation resistance for various steels when being heated at 700-1300 DEG C /  2-8 hours.