1067 results about "Carbon quantum dots" patented technology

The invention discloses a synthesis method of amphiphilic quantum dots and application of the amphiphilic quantum dots in nano oil displacement, and belongs to the field of nano oil displacement. The synthesis method comprises the following steps: heating a mixture containing a carbon source and a nitrogen source in an air atmosphere for reaction, and centrifuging, filtering and drying a reaction product to obtain the amphiphilic quantum dots, the carbon source is selected from at least one of glucose, mannose, citric acid, lignin, chitosan and starch; the nitrogen source is selected from at least one of alkylamine, and the carbon chain length of the alkylamine is C6 to C12. The synthesis method is simple, heating of a high-pressure reaction kettle is not needed, the technological process is simple, and the method is suitable for large-scale industrial production; the series of amphiphilic carbon quantum dots show better solubility and higher absolute fluorescence quantum yield in water and various organic solvents.

The invention discloses a metal-doped carbon quantum dot as well as preparation and application of the metal-doped carbon quantum dot in a nano antibacterial agent, citric acid, urea and tea polyphenol are taken as precursors, metal salt is added, carbon dot synthesis and metal ion doping are synchronously completed in one step through a hydrothermal method, and the metal-doped carbon quantum dot is prepared; the surfaces of the metal-doped carbon quantum dots are negatively charged, and the metal-doped carbon quantum dots have peroxidase-like activity and catalase-like activity at the same time; the metal ions adopt any one of Fe < 3 + >, Cu < 2 + > and Ce < 3 + >; the metal-doped carbon quantum dots are in a sphere-like shape. The metal-doped carbon quantum dots prepared by the preparation method disclosed by the invention have peroxidase-like activity and catalase-like activity at the same time through precise doping of metal ions, and the two activities have a synergistic effect in an oral periodontitis microenvironment, so that a good antibacterial effect is achieved.

The invention relates to a carbon quantum dot for strengthening and promoting growth of microalgae and application thereof. In the process of preparing the carbon quantum dots by a conventional hydrothermal method, a precursor mixture is subjected to acidification modification in advance, the pH value is adjusted to 2 by using nitric acid, and then a hydrothermal reaction is performed, so that the prepared carbon quantum dots have the capability of promoting the growth of microalgae. However, if other acids are adopted or pH adjustment is not in place, the effect cannot be achieved, and even the inhibition effect can be achieved. The obtained product is good in effect and stable in performance, no special reaction device needs to be additionally arranged in the acidification modification process, and the method has the advantages that operation is easy and convenient, raw materials are easy to obtain, and the process can be quantified; the method is simple and convenient in process operation, has universality and is easy for industrial production.

The invention discloses an MOF-CQD enzyme-sensitive FRET hydrogel diagnosis and treatment probe as well as a preparation method and application thereof, and belongs to the technical field of biomedical detection and treatment. The probe takes a carboxyl carbon quantum dot (CQD) as a donor and a metal organic framework (MOF) as an acceptor, and the donor and the acceptor are connected through a replaceable enzyme response polypeptide bridge; when the fluorescence is complete, FRET is generated to quench the CQD fluorescence, the FRET is interrupted after the target enzyme cuts off the peptide bridge, and the blue / red fluorescence ratio is changed to realize nanomole-level quantitative detection and has self-correction capability. The probe is packaged in a four-arm PEG transparent hydrogel which does not need a photoinitiator and can be quickly self-crosslinked, and can be prepared into a film, a tooth socket and the like for POCT (point-of-care testing) of parts such as an oral cavity / skin and the like. After detection, the MOF is activated by illumination of 630-660 nm to generate active singlet oxygen, so that local antibacterial or anti-tumor treatment is realized, and a diagnosis and treatment integrated scheme is constructed.

The invention provides a nitrogen-doped biomass-based fluorescent carbon quantum dot, a preparation method and application, and relates to the technical field of carbon nanomaterials, the method comprises the following steps: mixing a biomass material and deionized water under an ultrasonic condition, adding a nitrogen source, and carrying out ultrasonic dispersion to obtain a uniformly dispersed to-be-reacted solution; reacting the to-be-reacted solution at a preset temperature for a preset time to obtain a mixed product solution; and filtering and dialyzing the mixed product solution to obtain the nitrogen-doped biomass-based fluorescent carbon quantum dot solution. The nitrogen-doped biomass-based fluorescent carbon quantum dot prepared by the method shows a stable fluorescent effect and good water solubility, the free radical clearance rate can reach 90% or above, and the antibacterial rate can reach 99% or above. The method can be used in the fields of drug sustained release, bioimaging and the like.

The invention provides a method for preparing carbon quantum dot reinforced subcritical artificial humic acid and applying the carbon quantum dot reinforced subcritical artificial humic acid to a rice field, which comprises the following steps: collecting organic wastes, and drying, grinding and sieving the organic wastes to obtain pretreated raw materials; the preparation method comprises the following steps: mixing pretreated raw materials with water, reacting in a hydrothermal carbonization system at 200-280 DEG C for 1-3 hours, modifying through acid-base pretreatment, adjusting a reaction medium or an additive, and naturally cooling to obtain a natural substance subjected to hydrothermal carbonization; carrying out solid-liquid separation on the natural substance subjected to hydrothermal carbonization by using a 100-mesh coarse filter screen to obtain solid-phase hydrothermal carbon and liquid-phase artificial humic acid; carrying out purification treatment on the liquid-phase artificial humic acid for 48 hours by using a dialysis bag to obtain carbon quantum dots and characterizing the carbon quantum dots; the carbon quantum dot reinforced subcritical artificial humic acid is applied to a rice field, and is additionally applied in a fertilization period. Compared with a traditional composting technology, the scheme has the advantages that the carbon conversion rate is increased by 2-3 times, the soil fertility can be improved, and the rice yield is increased.

The invention discloses a fluorescent composite nano material as well as a preparation method and application thereof, and belongs to the technical field of fluorescent materials. The fluorescent composite nano-material provided by the invention comprises carbon quantum dots with carboxyl modified surfaces and fluorescent nano-particles with amino modified surfaces, wherein the mass ratio of the carbon quantum dots to the fluorescent nano-particles is (0.8-3): 1; the carbon quantum dots of which the surfaces are modified with carboxyl groups are connected with the fluorescent nanoparticles of which the surfaces are modified with amino groups through amido bonds formed by dehydration condensation of carboxyl groups and amino groups; the molecular formula of the fluorescent nanoparticles is Cs2NaYCl6: Yb < 3 + > / Eu < 3 + >, the molar concentration of doped Yb < 3 + > is 15-25%, and the molar concentration of doped Eu < 3 + > is 8-12%. The fluorescent composite nanomaterial provided by the invention has the advantages of uniform particle size and high fluorescence emission intensity, has good fluorescence stability, and can be applied to the fields of humidity detection, fluorescence imaging and the like.

The invention discloses a polypropylene-based thermoplastic cable shielding material and a preparation method thereof, and the polypropylene-based thermoplastic cable shielding material comprises the following components in parts by weight: 100 parts of polypropylene resin, 10-40 parts of a modified elastomer, 2-6 parts of an amino silane functionalized carbon quantum dot compatilizer, 15-25 parts of carboxylated carbon black, 0.2-0.7 part of an antioxidant, and 0.2-2 parts of a lubricant, the modified elastomer is a mixture of a polypropylene soluble substance and a polyolefin elastomer. The modified elastomer used in the invention has good compatibility with a polypropylene matrix, and can significantly improve the toughness of the matrix and reduce physical defects of an interface; meanwhile, the amino silane functionalized carbon quantum dot compatilizer used in the invention can reduce and uniformly disperse the phase size, can also improve the dispersity of the carbon black, has conductivity and can reduce the content of the carbon black, and the cable shielding material with high conductivity and an ultra-smooth surface can be obtained.

The invention discloses a silk protein-MXene composite film and a preparation method thereof. The silk protein-MXene composite film sequentially comprises a conductive surface layer, a porous response layer and a supporting bottom layer from top to bottom, the invention relates to the technical field of composite films. According to the fibroin-MXene composite film and the preparation method thereof, a three-layer gradient structure is formed by the conductive surface layer, the porous response layer and the supporting bottom layer, good conductivity and electromagnetic shielding effectiveness are ensured by utilizing oriented arrangement of MXene of the conductive surface layer, gallic acid and MXene form a hydrogen bond network, and nitrogen-doped carbon quantum dots coat the surface of MXene to form a physical barrier, so that the electromagnetic shielding effect is improved, and the electromagnetic shielding effect is improved. Through double oxidation resistance of gallic acid and nitrogen-doped carbon quantum dots, a sponge body structure formed by the porous response layer is matched to endow the composite film with high-sensitivity response to external stimulation, the supporting bottom layer is crosslinked by hexamethylene diisocyanate and enhanced by nanocellulose, the tensile strength is improved, and the tensile strength of the composite film is improved. And the contradiction between the mechanical property and the conductivity of the traditional composite film is effectively solved.

The invention relates to a preparation method and application of polysaccharide-based fluorescent carbon quantum dots with adjustable emission wavelength, and belongs to the technical field of preparation of fluorescent carbon nanomaterials. Polysaccharide is respectively mixed with different nitrogen dopants o-phenylenediamine, m-phenylenediamine and p-phenylenediamine, then the mixture is subjected to a hydrothermal reaction to respectively prepare blue, green and yellow green fluorescent carbon quantum dots, and then the blue, green and yellow green fluorescent carbon quantum dots are applied to nitrite detection. The carbon quantum dots with different emission wavelengths and different colors are obtained by adjusting the types of the nitrogen doping agents, the problems that the emission wavelengths of the carbon quantum dots cannot be adjusted and the range is narrow are solved, and reference is provided for subsequent design and opening of the generator-based multicolor fluorescent carbon quantum dots. Meanwhile, the biological polysaccharide is used as a raw material, deionized water is used as a solvent, the whole technological process is easy to operate and low in cost, and the method has far-reaching significance on further high-value utilization of biomass resources and promotion of sustainable utilization of the biomass resources.

The invention relates to a method for improving cadmium stress resistance of rice by using carbon quantum dots (CDs), which solves the technical problem that rice growth is affected due to the fact that rice is deeply poisoned by cadmium in the prior art by spraying the carbon quantum dots on leaf surfaces of the rice or irrigating the carbon quantum dots into root soil of the rice. CDs are used as a leaf surface resistance and control agent to treat cadmium-stressed rice, and it is found that on the premise that growth and development of the rice are not affected, CDs can improve the stress resistance of the rice by promoting photosynthesis of the rice and can stimulate a rice defense system to generate more antioxidant enzymes to cope with oxidative damage caused by Cd stress. Besides, CDs can also reduce the concentration of DTPA-Cd in soil and reduce accumulation of Cd on the overground part so as to further reduce the toxicity of Cd to rice, and meanwhile, the Cd content of the overground part of the rice is reduced so as to be beneficial to reducing accumulation of Cd in grains, so that CDs can be used as a leaf surface resistance and control agent to effectively relieve cadmium toxic rice, thereby promoting growth and development of the rice and improving the yield.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention relates to the technical field of electrode paste, in particular to a preparation method of high-pressure-resistant high-strength graphite enhanced electrode paste, which comprises the following steps: sequentially performing oxidation modification and silane modification on crystalline flake graphite powder, preparing silane modified graphite powder, and synchronously preparing a boron-nitrogen source precursor; coating the aminated carbon quantum dots with silicon to obtain silicon-coated carbon quantum dots; preparing a composite adhesive, a tungsten carbide-aluminum nitride composite reinforced phase and carbon-plated silicon powder; the preparation method comprises the following steps: blending and kneading silane modified graphite powder, a boron-nitrogen source precursor and other components, and pressing under gradient pressure to obtain a green body; and performing segmented roasting on the green body, and cooling to obtain the target electrode paste. According to the invention, crystalline flake graphite oxidation-silane modification is adopted to optimize interfacial compatibility, silicon-coated carbon quantum dots are adopted to reinforce a bonding system, a composite reinforcement phase is adopted to construct a mechanical support network, boron-nitrogen source in-situ doping supplemental reinforcement is adopted, and gradient pressure pressing and segmented roasting are combined to ensure that the structure is compact. The normal-temperature compressive strength, high-temperature mechanical stability and compactness of the electrode paste are improved through the synergistic effect of all links, and the electrode paste can stably adapt to the high-temperature and high-load working conditions.

The invention discloses a corrosion-resistant stainless steel pipe and a preparation method thereof, and application of the pipe in marine engineering, and belongs to the technical field of stainless steel materials, and is used to solve the technical problem that the corrosion resistance and antifouling performance of stainless steel in the prior art need to be improved; wherein the preparation method of the corrosion-resistant stainless steel pipe comprises: adding epoxy-modified titanium dioxide and 2-aminoethyl methacrylate to anhydrous ethanol, stirring, adding hydrochloric acid aqueous solution, heating, reacting, and obtaining modified titanium dioxide; adding epoxy-modified carbon quantum dots and modified titanium dioxide to the hydrochloric acid aqueous solution, heating, reacting, and ending the reaction, filtering, washing, and drying to obtain epoxy-modified carbon quantum dot grafted modified titanium dioxide; the corrosion-resistant stainless steel pipe prepared by the invention not only has good corrosion resistance and antifouling performance, meets the application of the pipe in marine engineering, but also has good weather resistance and durability, is conducive to prolonging the service life, and reduces the cost of later maintenance.

The invention discloses a polyurethane elastomer for sealing and a preparation method thereof, and relates to the technical field of polymer materials, the polyurethane elastomer comprises polyether polyol, diisocyanate, a catalyst, a cross-linking agent, a stabilizer and a plasticizer; the polyurethane elastomer further comprises additives, the additives specifically comprise functionalized graphene oxide, an ionic liquid toughening agent, self-repairing microcapsules and a carbon quantum dot toughening agent, and the polyurethane elastomer is prepared based on the materials. According to the polyurethane elastomer for sealing and the preparation method thereof, the sealing property, the tensile property, the wear-resisting property and the self-repairing property of the material are remarkably improved. The functionalized graphene oxide, the ionic liquid toughening agent, the self-repairing microcapsule and the carbon quantum dot toughening agent are introduced into the polyurethane, so that the excellent performance of the polyurethane elastomer in high-stress, high-abrasion and damage environments is realized. The polyurethane elastomer not only has lower leakage rate and higher tensile strength, but also can be quickly self-repaired after being worn.

The invention provides an oil field productivity monitoring method using a carbon quantum dot tracer agent, and the method comprises the steps: S100, obtaining the convection term and diffusion term characteristics of an oil field through the injection of the carbon quantum dot tracer agent and an inert tracer agent, and building an oil field monitoring characteristic set; step S200, selecting main characteristics of oil field monitoring from the oil field monitoring characteristic set by using a Spearman correlation coefficient and a random forest tree model method; and S300, inputting the main features into a neural network to monitor the productivity of the oil field, wherein the neural network is a particle swarm optimization-back propagation neural network for Wiener process optimization.

The invention discloses a carbon quantum dot loaded diatom electrocatalyst and a preparation method and application thereof. The preparation method comprises the following steps: dissolving and mixing diethylene triamine pentaacetic acid and salt of metal M1 in water, and performing reflux reaction to obtain a complex solution of the metal M1; adding salt of metal M2 for reflux reaction, filtering after the reaction is finished, and removing a solvent from filtrate to obtain a solid complex of bimetals M1 and M2; drying and calcining to obtain a diatomic electrocatalyst precursor; and carrying out post-treatment and freeze-drying to obtain the diatomic electrocatalyst. The carbon quantum dot loaded bimetallic atom site catalyst is obtained by a preparation strategy of coupling molecular design and quantum dot confinement, and is used for research on deep reduction of carbon dioxide into methane through electro-catalysis. The obtained catalyst has excellent methane production activity on an electro-catalysis carbon dioxide reduction reaction under an alkaline condition and a flow cell configuration, and still has relatively good stability under long-term work.

The present invention belongs to the technical field of batteries. Disclosed are an iron(III) phosphate material, a preparation method therefor, and a use thereof. The iron(III) phosphate material comprises a carbon quantum dot core located internally and an iron(III) phosphate shell formed on the surface of the carbon quantum dot core, and the surface of the iron(III) phosphate shell is provided with a carbon coating layer formed from a carbon-containing dispersing agent. The iron(III) phosphate material is nanoscale iron(III) phosphate and has a uniform crystal size. The preparation method therefor comprises the following steps: mixing a first mixed solution containing a divalent iron salt and carbon quantum dots, a second mixed solution containing a phosphate and a dispersing agent, and an oxidizing agent to undergo a reaction to obtain iron(III) phosphate dihydrate; and annealing and calcining the iron(III) phosphate dihydrate. The iron(III) phosphate material can be further used for preparing a lithium iron phosphate positive electrode material and a battery.

The invention belongs to the field of carbon nanomaterials, and provides a method for preparing a carbon quantum dot material doped with elements such as silicon and aluminum by oxidative depolymerization and stripping of coal gangue. Comprising the steps of screening and matching of coal gangue, oxidative depolymerization stripping, centrifugal dialysis membrane filtration and modification, drying and the like, raw materials and all the steps are specifically set, and the particle size or fluorescence performance of fluorescent carbon dots can be specifically selected and set according to selective oxidative depolymerization stripping conditions. The main particle size of the prepared multi-inorganic-element doped carbon quantum dot material is kept within the range of 1.5-2.0 nm, the structure is stable, the optical performance also meets the requirements, and the material can be further modified and is expected to be applied to the fields of photovoltaic equipment, biological imaging, photocatalytic degradation of organic pollutants or sensing and the like.

The application discloses a cross-linked ETFE composite film with gradient ultraviolet shielding function and a preparation method and application thereof, and belongs to the technical field of ETFE film preparation. The cross-linked ETFE composite film is composed of three layers of a surface layer, a middle layer and a bottom layer. The surface layer material comprises ETFE resin and fluorinated carbon quantum dots; the middle layer material comprises ETFE resin, allyl-containing comonomer A and phenyl-containing comonomer B; and the bottom layer material comprises ETFE resin and CeO2 nanowires. The fluorinated carbon quantum dots have a particle size of 3-5 nm and contain a -C4F9 structure. The comonomer A is an allyl-containing fluorine olefin monomer, and the comonomer B is a phenyl-containing organic fluorinated compound. Through the synergistic effect of the surface layer self-migration fluorinated carbon quantum dots, the middle layer copolymerization modification and the bottom layer CeO2 nanowires, high light transmittance, full-waveband ultraviolet shielding and long-term weather resistance are achieved.

The invention discloses a carbon quantum dot / metal organic framework composite material as well as a preparation method and application thereof, and the method is characterized in that carbon quantum dots derived from waterborne polyurethane are embedded into a zeolite imidazate framework 8 to prepare the carbon quantum dot / metal organic framework composite material. The composite material can be used as a ratio type fluorescent probe for trace detection of tetracycline, a dual-emission fluorescence signal of the probe is derived from tetracycline which quenches blue fluorescence of puCDs at 450 nm through an inner filter effect, and the coordination effect between Zn < 2 + > and tetracycline triggers an aggregation-induced emission effect, so that new fluorescence emission is generated, and the detection sensitivity is improved. The intensity of the two signals changes in proportion to the concentration of tetracycline, the wide linear concentration detection range and the low detection limit are achieved, the probe has the high recovery rate and the large adsorption capacity in detection, the problems that a traditional detection method is insufficient in sensitivity, poor in anti-interference capacity, high in cost and the like are solved, and the application prospect is wide. A new thought is provided for constructing a ratio type fluorescent probe with a removal function.

The invention relates to the technical field of functional board manufacturing, in particular to a damp-proof and wear-resistant composite board and a laminating process thereof. The composite material is prepared from 40-50 parts of dithiocar-bamate modified epoxy resin, 30-40 parts of nano silicon dioxide-carbon quantum dot modified polyurethane, 5-8 parts of a graphene-silane-metal organic framework compound, 2-4 parts of magnetic field oriented silicon carbide whiskers and 1-3 parts of self-repairing microcapsules. The modified epoxy resin is prepared from epoxy chloropropane and mercapto silane through a reaction, the graphene compound is embedded into the ZIF-8 nanoparticles, and the silicon carbide whiskers are directionally arranged through a 0.5-1T magnetic field during lamination; the plate is of a three-layer structure, covalent bonds are formed among layers through a silane coupling agent, and the plate has moisture-proof, wear-resistant and self-repairing functions. The composite material is low in water absorption rate, high in wear resistance frequency, high in microcrack repairing efficiency, high in interlayer bonding strength, capable of being stably used in high and low temperature environments, efficient in preparation process and suitable for the fields of high-end buildings, electronic equipment and the like, and the moisture-proof grade reaches IP67.

The invention discloses a silicon shell protected magnetic quantum dot nanoprobe, a preparation method, a kit and application. The nanoprobe comprises a nanomaterial and a specific antibody, the nanometer material is of a core-shell structure, and the outer surface of a core is sequentially coated with an interlayer and a protective shell layer outwards. The interlayer comprises a multi-layer laminated structure formed by alternately arranging a plurality of layers of positive electricity interlayers and negative electricity interlayers; the positive electric interlayer is polyethyleneimine, the negative electric interlayer is quantum dots, the quantum dots are CdSe / ZnS or carbon quantum dots, amino groups on the surface of the shell layer and a dialkynyl polyethylene ethanol solution are subjected to general coupling of specific antibodies in a click chemistry mode by taking diyne molecules as connecting arms. The magnetic nanoprobe with the core-shell structure not only has strong magnetic responsiveness and a high fluorescence signal, but also can adapt to a complex environment, after the magnetic nanoprobe is integrated with an immunochromatography test strip, to-be-detected targets including pathogenic bacteria and inflammatory markers can be rapidly captured in a whole blood sample at the same time, and the magnetic nanoprobe has huge application potential in early diagnosis of sepsis.

The invention creatively provides the CQDs modified Cu-based catalyst with high stability. The modified copper-based catalyst is composed of a copper-based catalyst and a proper amount of CQDs dispersed on the surface of the copper-based catalyst, and the weight ratio of the copper-based catalyst to the CQDs is (100: 2)-(100: 20). Wherein the copper-based catalyst is Cu < 2-x > Se, CuO, Cu2O, CuS, Cu2S or Cu3N. According to the CQDs modified Cu-based catalyst, reduction of Cu < + > is avoided by adopting the electron storage performance of the carbon quantum dots, and long-term stability of Cu < + > is achieved. The invention also provides an application of the CQDs modified Cu-based catalyst in an electrochemical reaction. On the basis, the invention further provides a method for efficiently carrying out electrochemical reaction by adopting the CQDs modified Cu-based catalyst, CQDs storage and electron release circulation are realized by adjusting proper pulse time and pulse potential, and the technical problem that the electron storage capacity of CQDs is limited is fundamentally solved.

The invention relates to the technical field of agricultural application of nano materials, and discloses a preparation method and application of a photosynthetic accelerant containing carbon quantum dots. Urea and citric acid are adopted as raw materials, and the nitrogen-carbon molar ratio and hydrothermal reaction parameters are optimized, so that efficient doping of nitrogen and accurate regulation and control of the particle size are achieved, and the photosynthetic accelerant containing the carbon quantum dots is obtained. The nitrogen-doped carbon quantum dot photosynthetic promoter with excellent upconversion performance is successfully synthesized, the promoter has good water solubility and biocompatibility, the photosynthetic efficiency of plants can be greatly improved within the concentration range of 0-100 mg / L, a safe application window is defined, and by establishing foliage spraying and water planting dual-mode application specifications, the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened, and the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened. The problems that current crops are insufficient in solar spectrum utilization and low in light energy conversion efficiency are solved in a targeted manner by utilizing an ultraviolet light-photosynthetically active radiation conversion function mediated by the carbon quantum dots and combining the targeted enrichment permeation characteristic of the carbon quantum dots in chloroplast.

The invention provides a pharmaceutical wastewater treatment process. The pharmaceutical wastewater treatment process comprises the following steps: A1, pretreatment, A2, adsorption treatment, A3, oxidation treatment and A4, filtration treatment. In the step A2, a composite adsorbent comprising the following raw materials: attapulgite, activated carbon, carbon nanotubes, 4-carboxyphenylboronic acid, polyethyleneimine, sodium dithiocarbamate, epoxy resin E-44, deionized water and modified nano zero-valent iron is used, and self-repairing is realized through dynamic chemical bonds such as boric acid ester bonds, imine bonds and thiol-disulfide bonds; the adsorbent can be self-repaired during microscopic damage, so that the service life is prolonged, and relatively high adsorption capacity is kept. In the step A3, a gel microsphere oxidant comprising the following raw materials: hydrogen peroxide, potassium persulfate, copper-iron sulfide, nitrogen-doped carbon quantum dots, sodium alginate powder, sodium polyacrylate and a phosphate buffer solution is used, and efficient degradation is realized through a synergistic mechanism of free radical oxidation, non-free radical oxidation and photocatalysis.

Disclosed in the present invention are an oxygen-enriched carbon quantum dot composite bismuth oxybromide nanosheet material, and a preparation method therefor and the use thereof. The preparation method comprises: sequentially uniformly dissolving Bi(NO3)3·5H2O and oxygen-enriched carbon quantum dots in a mannitol solution, then adding KBr thereto, stirring the mixture, then subjecting same to a solvothermal reaction, and then subjecting same to washing, suction filtration and drying, so as to obtain an oxygen-enriched carbon quantum dot composite bismuth oxybromide nanosheet material. The preparation method of the present invention is simple, and the bismuth oxybromide nanosheet is more easily and uniformly modified with the oxygen-enriched carbon quantum dots. The oxygen-enriched carbon quantum dots provide more active sites for bismuth oxybromide, thereby overcoming the defects of monomer bismuth oxybromide having a limited visible-light response and few active sites, optimizing the electron transmission performance of monomers, enhancing the light absorption intensity of the material, effectively guiding the charge flow, accelerating the separation and transfer of photo-generated charges, and achieving efficient visible light catalytic activity.

The invention discloses preparation of a phosphate radical modified carbon quantum dot nickel-based catalyst and application of the phosphate radical modified carbon quantum dot nickel-based catalyst in alkaline seawater electrolysis, and belongs to the technical field of hydrogen production through electro-catalysis and seawater electrolysis. The preparation method of the phosphate radical modified carbon quantum dot nickel-based catalyst comprises the following steps: mixing citric acid and urea in water to obtain a carbon quantum dot precursor solution; and mixing the carbon quantum dot precursor solution, phytic acid and a nickel substrate, and reacting to obtain the phosphate radical modified carbon quantum dot nickel-based catalyst. The phosphate radical modified carbon quantum dot nickel-based catalyst is designed by introducing a composite modification layer of carbon quantum dots and phosphate radicals on the surface of a nickel substrate, and the phosphate radical modified carbon quantum dot nickel-based catalyst has an obvious promotion effect on the OER activity through the synergistic effect of PO4 groups and CDs in the phosphate radical modified carbon quantum dot nickel-based catalyst; therefore, the catalyst can show excellent oxygen evolution reaction activity and long-term stability in alkaline seawater containing Br <-> and Cl <->.

The invention relates to the field of manufacturing of multi-color sheath glass, in particular to glass and a preparation method of a multi-color sheath of the glass. The glass base layer comprises glass, a multicolor sheath layer and a surface self-cleaning layer. The surface self-cleaning layer of the glass has a novel composite structure of a nanocrystalline multicolor sheath layer and a quantum dot sensitized self-cleaning layer. The structure effectively solves the problem of color covering of a traditional thick coating. In addition, through cooperative modification of the carbon quantum dots and the graphene quantum dots, the photoresponse range of titanium dioxide is expanded from ultraviolet light to visible light, so that the photocatalytic efficiency of the titanium dioxide is remarkably improved.

The invention discloses a high-transparency self-cleaning antistatic coating and a preparation method thereof. The method comprises the following steps: 1, adding an alcohol solvent, a cosolvent, a catalyst and nitrogen-doped carbon quantum dots into a container, uniformly mixing, adding a silane modifier, reacting, filtering, washing and drying to obtain modified nitrogen-doped carbon quantum dots; and 2, adding an alcohol solvent, a cosolvent, the modified nitrogen-doped carbon quantum dots, a silane coupling agent and an antistatic organosilicon monomer into a container, uniformly mixing, adding a catalyst, filtering, washing, and drying to obtain the nitrogen-doped carbon quantum dot grafted polysiloxane. 3, the polysiloxane containing the nitrogen-doped carbon quantum dots and a flatting agent are dissolved in an organic solvent respectively or in a mixed mode, and after the polysiloxane containing the nitrogen-doped carbon quantum dots and the flatting agent are completely dissolved, the high-transparency wear-resistant self-cleaning antistatic coating is obtained. And 4, coating a substrate with the high-transparency wear-resistant self-cleaning antistatic coating step by step or in one step. The transparent self-cleaning coating prepared by the invention has good wear-resistant and antistatic effects.