750 results about "P-Phenylenediamine" patented technology

The invention relates to the technical field of lithium ion battery diaphragm preparation, in particular to modified aramid diaphragm coating slurry, a battery diaphragm and a preparation method thereof.The preparation method of the modified aramid diaphragm coating slurry comprises the steps that under protection of inert gas, a cosolvent is dissolved into a polymerization solvent, and a solvent-cosolvent mixed system is obtained; adding p-phenylenediamine into the solvent-cosolvent mixed system, and dissolving to obtain a mixed solution; adding paraphthaloyl chloride into the mixed solution in batches, controlling the temperature of the system, and carrying out polymerization reaction, so as to obtain the modified aramid diaphragm coating slurry after the polymerization reaction is finished, in the preparation method, a third monomer is also added to participate in the polymerization reaction, and the third monomer is at least one of an amine third monomer and an acyl chloride third monomer. The modified aramid diaphragm coating slurry can be used for preparing a battery diaphragm with heat resistance and air permeability, and the process is simple.

The invention discloses a polyrotaxane covalent organic framework material capable of regulating interlayer spacing through cyclodextrin and application of the polyrotaxane covalent organic framework material, and belongs to the technical field of biological medicine. The polyrotaalkylated covalent organic framework material is obtained by taking a cyclodextrin aromatic multi-amino inclusion compound and a (multi-aldehyde bipyridine) ruthenium (II) complex as structural units and carrying out copolymerization; the cyclodextrin aromatic polyamine inclusion compound is a beta-cyclodextrin p-phenylenediamine inclusion compound with a hydroxyl group or without a hydroxyl group; the (multi-aldehyde dipyridyl) ruthenium (II) complex is tris (4, 4 '-diformaldehyde-2, 2'-dipyridyl) ruthenium (II). The interlayer spacing of the polyrotaxane covalent organic framework material is greatly increased by utilizing a cavity of gamma-cyclodextrin, and meanwhile, the material has excellent photo-thermal and photodynamic activity, is positively charged, and can better adsorb negatively charged bacteria; and the hydrogel is good in biocompatibility and free of toxic and side effects, and has an excellent treatment effect on wounds infected with staphylococcus aureus.

The invention relates to a carbon plate for sports shoes. From a sole to the top, the carbon plate sequentially comprises a first fiber layer, a second fiber layer and a third fiber layer, the second layer is a fiber layer made of 0-degree unidirectional polyimide fiber cloth; the third layer is an arch reinforcing sheet made of a poly-p-phenylene terephthamide material; the carbon fiber unidirectional belts adopted by at least two carbon fiber layers are symmetrically arranged in the forward direction and the reverse direction, and the other carbon fiber layer is made of 90-degree carbon fiber unidirectional belt materials. The carbon fiber plate has the advantages that the reinforcing piece is arranged at the foot arch, the structural strength of the carbon fiber plate at the weak position of the foot arch can be improved, in addition, the protruding reinforcing ribs can further improve the rigidity of the foot arch, and therefore the structural strength of the whole carbon plate is improved, and the problem that the service life is damaged due to excessive bending of the carbon plate is solved.

The invention relates to the field of cables, and discloses a modified polyvinyl chloride composite material for cables and a preparation method thereof.The composite material comprises low-density polyethylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, nitrile rubber, modified graphene oxide, modified nano calcium carbonate and auxiliaries; the modified graphene oxide is prepared by reacting acylating chlorination of graphene oxide with an anti-aging derivative, the anti-aging derivative is prepared by reducing a benzoxazole-containing intermediate generated by a reaction of 2-amino-4-bromophenol and 4-cyanobenzaldehyde to obtain an aminated benzoxazole-containing intermediate, then the aminated benzoxazole-containing intermediate reacts with p-phenylenediamine, and then the product reacts with 3-(3, 4-dichlorophenyl)-1, 2, 3-triazole-3-one to obtain the anti-aging graphene oxide. 2, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride is subjected to a reaction to prepare the product. And the modified nano calcium carbonate is prepared by reacting phosphonitrilic chloride trimer with an amino silane coupling agent and 2-amino benzoxazole-5-borate and then grafting on the surface of the nano calcium carbonate. The composite material prepared by the invention has excellent flame retardance, heat resistance and long-acting oxidation resistance.

The invention relates to a preparation method and application of polysaccharide-based fluorescent carbon quantum dots with adjustable emission wavelength, and belongs to the technical field of preparation of fluorescent carbon nanomaterials. Polysaccharide is respectively mixed with different nitrogen dopants o-phenylenediamine, m-phenylenediamine and p-phenylenediamine, then the mixture is subjected to a hydrothermal reaction to respectively prepare blue, green and yellow green fluorescent carbon quantum dots, and then the blue, green and yellow green fluorescent carbon quantum dots are applied to nitrite detection. The carbon quantum dots with different emission wavelengths and different colors are obtained by adjusting the types of the nitrogen doping agents, the problems that the emission wavelengths of the carbon quantum dots cannot be adjusted and the range is narrow are solved, and reference is provided for subsequent design and opening of the generator-based multicolor fluorescent carbon quantum dots. Meanwhile, the biological polysaccharide is used as a raw material, deionized water is used as a solvent, the whole technological process is easy to operate and low in cost, and the method has far-reaching significance on further high-value utilization of biomass resources and promotion of sustainable utilization of the biomass resources.

The invention provides a core material for a vacuum insulation panel, the vacuum insulation panel and a preparation method and application of the vacuum insulation panel. The core material for the vacuum insulation panel comprises aramid fibers and a binding material, and the aramid fibers comprise at least one of poly (m-phenylene isophthalamide) fibers, poly (p-phenylene terephthalamide) fibers and heterocyclic aramid fibers; the length of the aramid fiber ranges from 1 mm to 10 mm. The vacuum insulation panel comprises a core material for the vacuum insulation panel and a barrier film material, and the barrier film material wraps the core material for the vacuum insulation panel. In the process of preparing the vacuum insulated panel and the process of cutting and producing the core material for the vacuum insulated panel, dust and fine fibers are not generated, and environmental pollution and health risks are avoided.

The invention discloses a p-phenylenediamine compound as well as a preparation method and application thereof, and the compound is obtained by carrying out hydrogenation reaction on 2, 4-diaminodiphenylamine and ketone in the presence of a catalyst. Compared with the current mainstream anti-aging agent 6PPD, the compound provided by the invention has good anti-dynamic / static ozone protection performance, good anti-dynamic fatigue performance and anti-emigration discoloration performance; the tire added with the compound provided by the invention does not generate toxic residues of p-benzoquinone structural substances in the use process, is more green and environment-friendly, is an ideal substitute of the anti-aging agent 6PPD, and has good economic and social benefits and wide market prospects.

The invention discloses a production process of a modified p-phenylenediamine rubber anti-aging agent, which comprises the following steps: S1, catalyzing a ring-closure reaction through lipase, and accurately controlling pH by combining a phosphate buffer solution, so that the bonding efficiency of 6PPD and tea polyphenol is remarkably improved, and the release amount of aniline is effectively reduced; s2, carrying out spray drying to obtain EP-TP powder to control the particle morphology; s3, increasing the load rate of the anti-aging agent and effectively inhibiting the migration rate of the anti-aging agent through the pore diameter physical confinement of mesoporous silica and an amination gas phase modification technology, and ensuring uniform dispersion of anti-aging agent particles through the synergistic effect of staged load reaction and a polyethylene glycol dispersant; and S4, the particle morphology is cooperatively controlled through vacuum microwave drying, the dispersion requirement of the rubber mixing technology is met, and the interface bonding strength is improved by combining the staged loading reaction with a polyethylene glycol dispersing agent.

The invention relates to the field of cable materials, and discloses a flame-retardant anti-aging cable material and a preparation method thereof.The flame-retardant anti-aging cable material is prepared from, by weight, 45-70 parts of nitrile rubber, 20-40 parts of natural rubber, 7-12 parts of modified carbon nanotubes, 5-10 parts of composite filler, 3-5 parts of nano-zinc oxide, 2-4 parts of stearic acid, 1-3 parts of sulfur and 0.1-0.5 part of accelerant; the modified carbon nano tube is prepared by modifying a flame retardant and p-phenylenediamine on the surface of a carbon nano tube through a chemical reaction; the composite filler is prepared by taking a titanium dioxide nanosheet as a carrier and growing silicon dioxide nanoparticles in situ, and the cable material is endowed with excellent mechanical properties, flame retardance and ageing resistance by adding the modified carbon nanotubes and the composite filler.

The invention discloses a para-aramid (PPTA) fiber as well as a preparation method and application thereof, belongs to the technical field of high polymer materials, and solves the problem that a PPTA material in the prior art cannot meet the requirement of an ultrahigh-end application field on material modulus. The invention discloses a preparation method of para-aramid fiber, which comprises the following steps: uniformly dispersing a covalent organic framework material in concentrated sulfuric acid at room temperature to obtain a sulfuric acid solution of the covalent organic framework material; dissolving poly (p-phenylene terephthalamide) in a sulfuric acid solution of a covalent organic framework material to obtain spinning slurry; filtering, defoaming and spinning the spinning slurry in sequence; and carrying out purification operation to obtain the para-aramid fiber. According to the preparation method provided by the invention, the condensed state of a PPTA molecular chain is regulated and controlled by adding the COFs structural material, and intermolecular microdefects of the PPTA molecular chain are reduced, so that the strength and modulus of the para-aramid fiber are improved, and the application field of the para-aramid fiber is expanded.

The invention relates to the technical field of battery electrodes, in particular to a zinc pole piece coated with a sulfonic COF membrane, a preparation method of the zinc pole piece and an aqueous zinc battery, and the preparation method comprises the following steps: dissolving 2, 4, 6-triformyl phloroglucinol and p-phenylenediamine-2, 5-disulfonic acid in an organic solvent to obtain a mixed solution; and putting the zinc foil into the mixed solution, carrying out sealed standing at normal temperature, taking out the zinc foil coated with the sulfonic group COF film, and washing and drying the zinc foil to obtain the zinc pole piece coated with the sulfonic group COF film. The prepared zinc pole piece coated with the sulfonic COF film has good corrosion resistance and dendritic crystal inhibition capacity, and when the zinc pole piece is used as a negative electrode of a water-based zinc battery, the cycle performance of the water-based zinc battery can be improved, and the cycle life of the water-based zinc battery can be prolonged; the problems that a zinc negative electrode of an existing water-based zinc battery is prone to generating dendritic crystal and corrosion passivation side reactions in the battery circulation process, so that the use performance of the water-based zinc battery is reduced, and the service life is greatly shortened are solved.

The invention relates to the technical field of heat dissipation materials, and discloses a graphite cooling fin of a multi-layer composite structure and a manufacturing process of the graphite cooling fin of the multi-layer composite structure. 15 to 25 parts of artificial graphite powder; 3 to 8 parts of an aniline-p-phenylenediamine copolymer; 2 to 6 parts of antimony oxide nano particles; 2 to 5 parts of urea; 1 to 3 parts of polyvinylpyrrolidone; the preparation method comprises the following steps: carrying out heat treatment on the artificial graphite film, and then carrying out mechanical pulverization; mixing the graphite oxide with an ethanol or water mixed solvent containing ammonia water; mixing the raw materials; performing vacuum defoamation and then coating on a base material; and performing carbonization treatment on the graphene film crude product, and performing lamination calendering treatment to form a final product. According to the technical scheme, the antimony oxide nano particles are adopted to synergistically adjust the heat conductivity, the effect of remarkably improving the transverse heat conductivity of the film body is achieved, the heat conductivity is enhanced, and material embrittlement caused by overfilling is avoided.

The invention relates to the technical field of aramid fibers, in particular to a heterocyclic aramid fiber and a preparation method thereof.The preparation method comprises the steps that S1, p-phenylenediamine, benzimidazole diamine and terephthaloyl chloride are subjected to a polymerization reaction in an amide solvent, and a polymer stock solution is obtained; s2, the polymer stock solution is subjected to spinning through a spinning nozzle, coagulating bath forming, drafting bath, alkali washing, water bath, drying, hot drafting, oiling and winding into a barrel, and the heterocyclic aramid fiber is obtained. In the step S1, the polymerization reaction temperature is-10 DEG C to 0 DEG C. According to the heterocyclic aramid fiber prepared by the preparation method, the problems of broken filaments, doubled filaments, sticky filaments, broken filaments and the like are obviously improved, the mechanical property is improved, the irregularity is reduced, and the product quality is excellent. The tensile strength of the heterocyclic aramid fiber is 30 to 37 cN / dtex, the elongation at break of the heterocyclic aramid fiber is 3.0 to 4.0 percent, and the elastic modulus of the heterocyclic aramid fiber is 950 to 1150 cN / dtex.

The invention relates to the field of lithium battery diaphragms, and particularly discloses an aramid diaphragm for a lithium battery and a preparation method of the aramid diaphragm. The aramid diaphragm for the lithium battery comprises aramid slurry and a base membrane, the aramid slurry is coated on two sides of the base membrane to form an aramid coating, and the aramid slurry is prepared from the following raw materials in parts by weight: 20-40 parts of aramid polymer liquid, 5-10 parts of tencel fibrillation slurry, 1-3 parts of titanium aluminum lithium phosphate nanoparticles, 3-5 parts of nano ceramic particles and 8-15 parts of solvent; the aramid polymer liquid is prepared from the following raw materials in parts by weight: 1 to 3 parts of p-phenylenediamine, 60 to 80 parts of polar solvent, 5 to 10 parts of paraphthaloyl chloride, 1 to 3 parts of 3, 4 '-diaminodiphenyl ether, 1 to 3 parts of o-chloro-p-phenylenediamine and 0.5 to 1 part of polyether surfactant; the aramid polymer liquid is combined with the nano ceramic particles and the tencel fibrillation slurry component to form an intercommunicated porous three-dimensional network structure, so that the air permeability, the thermal stability and the porosity of the aramid diaphragm are improved.

The invention relates to preparation and photocatalytic application of a three-component covalent organic framework photocatalyst. The invention aims to solve the problems of low visible light utilization rate, low efficiency of photocatalytic synthesis of hydrogen peroxide and complex synthesis process of a multi-component covalent organic framework material in the synthesis of a high-performance photocatalyst in the prior art. The method comprises the following steps: dispersing two reaction monomers into an organic solvent to form a mixed solution, adding a catalyst into the mixed solution, then adding the third monomer, carrying out ultrasonic dispersion, carrying out a heating reaction for a period of time, cooling to room temperature, and carrying out solid-liquid separation to obtain a solid; and carrying out solid separation, collecting the solid, washing and drying to obtain the three-component covalent organic framework material. The prepared TTBTP-1 three-component covalent organic framework photocatalytic material is high in crystallinity and good in catalytic effect and is superior to a two-component photocatalyst, the preparation method is simple, through the design thought that p-phenylenediamine is adopted as a linker to connect two monomers with different structures, the thought is broadened for the design of a novel COF structure and function, and the application prospect is broad. The method has important research significance.

The invention relates to the technical field of polyurethane coatings, and discloses a preparation method of an antibacterial wear-resistant waterborne polyurethane coating, which comprises the following steps: taking concentrated hydrochloric acid, p-phenylenediamine, sodium nitrite, paraformaldehyde, amino-modified nano silicon dioxide and hexamethylene diisocyanate as raw materials; the preparation method comprises the following steps: taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide as a raw material, carrying out diazotization coupling reaction, substitution reaction, Mannich reaction and addition reaction to prepare modified polyisocyanate, then taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and ((2-aminoethyl) azadiyl) dimethanol as raw materials, carrying out substitution reaction to prepare DOPO-based dihydric alcohol, and carrying out reaction to prepare the DOPO-based dihydric alcohol. Finally, the modified polyisocyanate, DOPO-based dihydric alcohol and polyethylene glycol 400 are used as raw materials, an antibacterial wear-resistant polyurethane emulsion is prepared through a prepolymerization reaction and a chain extension reaction, and the prepared polyurethane coating has good antibacterial, anti-ultraviolet, flame-retardant and wear-resistant properties.

The invention discloses a preparation method and application of a photo-thermal dual-response membrane material, and relates to the field of membrane materials. When the photo-thermal double-response membrane material is prepared, a photo-thermal material firstly reacts with 4-(triethoxysilyl) aniline and then reacts with 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde and p-phenylenediamine, and a modified photo-thermal material is prepared; the preparation method comprises the following steps: sequentially reacting benzaldehyde with 2-hydroxyacetophenone and 3-N, N-dimethylamino methacryloyl chloride to prepare a photo-initiation monomer; the preparation method comprises the following steps: mixing N-isopropylacrylamide, a photo-initiation monomer, N, N '-methylene bisacrylamide and a modified photo-thermal material, combining with a hydrophobic substrate membrane, preparing a membrane, and finishing the surface by using 2-bromo-1-[3, 5-di (tert-butyl)-4-hydroxyphenyl] ethanone, thereby obtaining the photo-thermal dual-response membrane material. The photo-thermal dual-response membrane material prepared by the invention has the characteristics of pollution resistance, easiness in cleaning, durability, antibacterial property, metal ion recovery and low energy consumption.

The invention discloses an OMTD photoelectric mapping transparent display film with adjustable light transmittance and a preparation method, and belongs to the technical field of transparent display films. The transparent display film comprises an electric control dimming film layer, a fluorescent layer, an adhesive layer and a release material layer, wherein the fluorescent layer comprises the following raw materials in parts by weight: 80-100 parts of polyurethane resin, 2-5 parts of a fluorescent agent, 3-6 parts of a dispersing agent, 4-8 parts of a modified anti-aging agent, 1-10 parts of a curing agent and 200 parts of a solvent; according to the invention, p-phenylenediamine and 4-(diethylamino) salicylaldehyde react to prepare a fluorescent small molecule substance, and then the fluorescent small molecule substance is introduced into a polyurethane chain to finally prepare the fluorescent agent. The prepared transparent display film has excellent fluorescence performance, transparency and anti-aging performance.

The invention discloses a modified heterocyclic aramid fiber and a preparation method thereof, and belongs to the technical field of high-performance organic fibers. The invention discloses a preparation method of a modified heterocyclic aramid fiber, which comprises the following steps: by taking 2-(4-aminophenyl)-5-aminobenzimidazole, p-phenylenediamine, isophthaloyl chloride and paraphthaloyl chloride as raw materials and LiCl as a catalyst, carrying out polymerization reaction in a solvent to obtain a polymer, and then spinning to obtain the modified heterocyclic aramid fiber. The invention also discloses the modified heterocyclic aramid fiber prepared by the method. According to the invention, m-phthaloyl chloride is creatively used for replacing a part of paraphthaloyl chloride and is subjected to nucleophilic reaction with 2-(4-aminophenyl)-5-aminobenzimidazole and p-phenylenediamine, so that the elongation at break of the fiber can be greatly improved under the condition that the breaking strength and other weather resistance of the original fiber are basically unchanged.

The invention relates to the technical field of flame-retardant materials, in particular to a vanillin-derived nitrogen-phosphorus synergistic flame retardant as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out aldehyde-amine condensation reaction on vanillin and p-phenylenediamine to generate a Schiff base intermediate with a characteristic group-C = N-; and carrying out addition reaction on the intermediate and reactive hydrogen connected with a phosphorus atom on 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the vanillin-derived nitrogen-phosphorus synergistic flame retardant. The flame retardant obviously improves the flame retardant grade of the high polymer material under the condition of lower addition amount, does not release toxic and harmful gases in the combustion process, and meets the requirements of greenness and environmental protection. The flame retardant has good compatibility with high polymer materials such as thermoplastic polyurethane and the like. The preparation method of the flame retardant is controllable in reaction process, large-scale production is easy to realize, an innovative and feasible solution is provided for flame retardance of high polymer materials, and the flame retardant is expected to be widely applied to the fields of electronics, automobiles, buildings and the like.

The invention provides a para-aramid fiber and a preparation method thereof.Under the sealed condition, poly-p-phenylene terephthamide resin with the water content lower than 500 ppm and the viscosity of 6.5 dL / g-7. 5 dL / g and concentrated sulfuric acid solid particles are mixed, defoamed and filtered to obtain a spinning solution, then tows are obtained through a dry jet wet spinning method, and finally multi-stage drying is conducted to obtain the para-aramid fiber. The high-strength and high-modulus para-aramid fiber is obtained. The concentrated sulfuric acid solid particles are used as raw materials, the mixing and permeation effects of concentrated sulfuric acid on resin are enhanced, the slurry sandwich phenomenon is reduced, polymer degradation is relieved, a high-quality spinning solution is provided for preparing the high-strength and high-modulus aramid fiber, and the strength and modulus of the para-aramid fiber, especially the modulus, are greatly improved.

The invention discloses a PVC / PU modified material and a preparation method thereof, and belongs to the technical field of high polymer materials. The PVC / PU modified material comprises the following raw materials in parts by weight: 80-100 parts of PVC, 30-40 parts of PU, 10-20 parts of a plasticizer, 4-8 parts of a modified flame-retardant anti-aging agent, 2-4 parts of a stabilizer and 3-5 parts of a lubricant. The preparation method comprises the following steps: carrying out a reaction on cyanuric chloride and N-phenyl p-phenylenediamine to prepare an intermediate 1, carrying out a reaction on the intermediate 1 and 1-amino-10-undecene to prepare an intermediate 2, carrying out a reaction on diphenyl phosphinyl chloride and 1-amino-10-undecene to prepare an intermediate 3, and finally carrying out a reaction on the intermediate 2 and the intermediate 3 to prepare the modified flame-retardant anti-aging agent. The PVC / PU modified material prepared by the invention has excellent anti-aging performance and flame retardant performance.

The invention relates to the technical field of textile materials, and particularly discloses high-strength screen cloth and a preparation method thereof. The high-strength screen cloth is prepared from the following raw materials: caprolactam, p-phenylenediamine, adipic acid, diphenyldicarboxylic acid, a modified monomer, zinc diethyl hypophosphite, divinyl benzene, modified glass fibers, an antioxidant and a lubricant. The preparation method comprises the following steps: preliminarily polymerizing caprolactam, p-phenylenediamine, adipic acid, biphenyldicarboxylic acid and the modified monomer, then adding the modified glass fiber, zinc diethyl hypophosphite and divinyl benzene for continuous reaction to obtain a polyamide copolymer, and finally performing melt spinning and weaving on the polyamide copolymer, the antioxidant and the lubricant to obtain the required high-strength mesh cloth. The high-strength screen cloth prepared by the invention has excellent mechanical properties and aging resistance, is suitable for being applied to the fields with high-performance requirements, such as constructional engineering materials and special protective equipment, and is high in practicability and wide in application prospect.

The present invention relates to the technical field of cosmetics, and in particular to a hair dye composition for preventing hair breakage, hypoallergenic and repairing, and a preparation method and application thereof. The composition is composed of agent A and agent B in a mass ratio of 1:0.8-1.5. The raw materials of agent A are hydrogen peroxide, glycerol, thickener, cetearyl alcohol polyether, sodium stannate, hydroxyethylidene diphosphoric acid and water. The raw materials of agent B are: p-phenylenediamine, sodium sulfite, triethanolamine, urea, Polygonum multiflorum extract, Acorus calamus extract, Nepeta tenuifolia extract, chelating agent, ascorbate, preservative, keratin, trehalose, 4-amino-2-hydroxytoluene, polyquaternium salt, squalane, arbutin, allantoin, bisabolol, emulsifier, polyglutamic acid, octadecyl alcohol, wheat germ oil and water. The hair dye of the present invention has a good hair dyeing effect, and has hypoallergenicity, and also has a good effect of preventing hair breakage and repairing hair quality.

The invention discloses a high-temperature-resistant, heat-insulating and flame-retardant poly (p-phenylene terephthamide) nanofiber composite aerogel as well as a preparation method and application thereof. The composite aerogel is prepared by slowly releasing proton to induce gel through a two-step sol-gel method. Firstly, carboxyl on a PAA molecular chain is introduced to interact with deprotonated amido in an ANF molecular chain, so that a part of a hydrogen bond system is recovered, ANF pre-gel is achieved, then Ti2CCl2 is dispersed into the ANF pre-gel system, the gelation process is further completed through protonic acid, and the ANF / Ti2CCl2 / ANF composite material is obtained. The composite aerogel is obtained through an improved directional freeze-drying technology and a solvent replacement method. The prepared composite aerogel combines the high thermal stability of Ti2CCl2 and the excellent mechanical property of ANF, has excellent flame retardance, high temperature resistance and heat shielding effectiveness, has wide application prospects in the fields of electronic heat dissipation, building energy efficiency, solar energy utilization and the like, and can meet the ever-increasing requirements for efficient thermal regulation and thermal protection.

The invention relates to the field of protective films, and discloses a liquid crystal display light guide plate TPE protective film and a preparation method thereof, the protective film comprises modified SBS, polypropylene, modified nano calcium carbonate, a lubricant and a plasticizer; the modified nano calcium carbonate is prepared by grafting a modified additive on the surface of nano calcium carbonate through chemical reaction and then coordinating with copper ions; the modified additive is prepared by preparing a chlorinated silicon-containing intermediate by using dichlorodiphenyl silane, diethylene glycol and cyanuric chloride as raw materials and then grafting a component I and 3-aminopropyltrimethoxysilane; the component I is prepared from 5-chloromethylthiazole and p-phenylenediamine through a reaction, and the modified SBS is prepared from epoxidized SBS and nano titanium dioxide subjected to amination modification by 3-aminopropyltriethoxysilane through a ring-opening reaction. The film material is endowed with excellent tensile strength, aging resistance and antibacterial and flame-retardant effects.

The invention discloses a method for detecting L-cysteine in serum based on N, S co-doped carbon nanodots, and belongs to the field of analysis and detection. The method comprises the following steps: (1) preparing carbon dots by taking beta-mercaptoethylamine and p-phenylenediamine as precursors; (2) after Fe < 3 + > is added into the carbon dot solution, a carbon dot fluorescence quenching phenomenon occurs, and a carbon dot-Fe < 3 + > mixed system is obtained; then adding L-cysteine into the carbon dot-Fe < 3 + > mixed system to gradually recover the fluorescence of the system; and (3) constructing a linear relationship between the concentration of the L-cysteine and the fluorescence recovery degree to obtain the quantitative detection model for the L-cysteine in the serum sample. According to the method, the carbon dots are prepared by taking beta-mercaptoethylamine and p-phenylenediamine as precursors for the first time, quantitative detection of L-cysteine is realized, and the method is low in cost, high in sensitivity, suitable for field rapid detection and relatively high in practical value and popularization prospect.

The invention belongs to the technical field of covalent organic framework membrane materials, and provides a covalent organic framework / polyether sulfone mixed matrix membrane as well as a preparation method and application thereof. The method comprises the following steps: mixing polyether sulfone, a solvent and trialdehyde phloroglucinol to obtain a trialdehyde phloroglucinol solution; the glass fiber filter membrane is coated with the trialdehyde phloroglucinol solution, and a trialdehyde phloroglucinol / polyether sulfone membrane is obtained; the method comprises the following steps: mixing p-phenylenediamine, a catalyst and water to obtain a p-phenylenediamine solution; the trialdehyde phloroglucinol / polyether sulfone membrane is soaked in a p-phenylenediamine solution for a reaction, and the covalent organic framework / polyether sulfone mixed matrix membrane is obtained. The preparation method disclosed by the invention is mild in condition, the obtained membrane is uniform and stable, the advantages of high flux of a polymer and strong adsorption and separation of a covalent organic framework on CO2 are fully combined, and the H2 flux and H2 / CO2 selectivity of the covalent organic framework / polyether sulfone mixed matrix membrane are greatly improved.

The invention provides a preparation method and application of a polymer-based covalent organic framework membrane, which comprises the following steps: dividing a reaction container into two chambers by using a polyacrylonitrile porous membrane subjected to alkali treatment, adding a toluene solution of a trialdehyde phloroglucinol monomer into the chamber on one side of the porous membrane polyacrylonitrile, and adding an acetic acid aqueous solution of p-phenylenediamine or a p-phenylenediamine derivative into the other chamber, sealing, and carrying out a heating reaction to obtain the polymer-based covalent organic framework film. The method disclosed by the invention has universality, the prepared covalent organic framework membrane has a regular 1D nano channel, and the ion separation performance of the membrane can be regulated and controlled by adjusting the structure and the charged group of the amino monomer, so that good monovalent and multivalent ion separation performance is realized; the covalent organic framework membrane prepared by the method has good application potential in the fields of ion separation, water quality purification, high value-added ion enrichment and the like.

The invention relates to the technical field of high-molecular compounds, and particularly discloses a preparation method of a late transition metal catalyst for synthesizing hyperbranched polyethylene. The preparation method comprises the following steps: under the protection of inert gas, dissolving p-phenylenediamine into anhydrous alcohol, adding pyridine-2-formaldehyde into a mixed solution, and heating to react to obtain a ligand A; the method comprises the following steps: under the protection of inert gas, dropwise adding an alcoholic solution of a metal precursor into a chlorinated alkane solution dissolved with a ligand A, and then fully reacting at room temperature; and after the reaction is finished, purifying the product to obtain the late transition metal catalyst. The metal precursor is a bivalent Fe salt, a bivalent Co salt and a bivalent Ni salt. According to the synthetic catalyst, the polymerization activity of the late transition metal catalyst can be enhanced, and the synthesis of hyperbranched polyethylene is facilitated. The molecular weight of the hyperbranched polyethylene catalyzed by the catalyst is 1.1-2.6 kg / mol, the molecular weight distribution PDI is less than 2, and the branching degree is more than 100.