5372 results about "Thermal reaction" patented technology

The present invention provides a method and device for controlling the heat-affected zone of a perovskite battery laser processing, the method comprising: performing multi-source data collection and calibration processing on the perovskite battery stack structure to obtain a calibration data set including temperature distribution, surface morphology and electrical characteristics; based on the calibration data set, comprehensively analyzing the area where ion thermosensitive reactions are generated to obtain the risk zoning result of the heat-affected zone; based on the risk distribution result of the heat-affected zone, differentially configuring the energy output and movement path of the laser etching to obtain a control instruction set for local etching; according to the control instruction set, executing the laser etching process to obtain an etching control scheme for managing the heat-affected zone. The method monitors and identifies heat-sensitive areas in real time based on the collection and analysis of multi-source data, controls the temperature distribution and local thermal stress during laser processing, reduces thermal damage by accurately adjusting the laser power and scanning path, and improves the long-term stability of the perovskite battery.

The invention provides a degradable environment-friendly packaging material and a preparation process thereof, and belongs to the technical field of packaging materials. The preparation method comprises the following steps: preparing the modified nano montmorillonite; preparing a composite antibacterial additive; preparing a barrier additive; and preparing the degradable environment-friendly packaging material. The preparation method comprises the following steps: by taking methacrylic acid (2-dimethylaminoethyl) ester and acrylic acid as raw materials, modifying nano-montmorillonite under the initiation of benzoyl peroxide, performing quaternary ammonium salinization, and performing in-situ synthesis of nano-zinc oxide on the surface of the quaternary ammonium salinized montmorillonite through a hydrothermal reaction to prepare the composite antibacterial additive. When the composite antibacterial additive is added into polylactic acid to prepare a packaging material, the growth of various microorganisms such as bacteria and fungi can be effectively inhibited, the packaging material is endowed with strong antibacterial protection capability, and the composite antibacterial additive has a more lasting antibacterial effect so as to prolong the antibacterial validity period of the packaging material.

The invention relates to the technical field of inorganic nonmetal ceramic materials, in particular to a ceramic tile and a preparation method thereof. The ceramic tile comprises the following raw materials: 40-50 parts of waste residues, 1-5 parts of barium carbonate, 5-8 parts of feldspar powder, 0.5-3 parts of zinc oxide, 2-7 parts of pigment, 15-20 parts of modified kaolin and 1-5 parts of water. The preparation process of the modified kaolin comprises the following steps: (1) adding kaolin into deionized water, then adding octadecyl bis (hydroxyethyl) methyl ammonium chloride, stirring, filtering and drying to obtain pretreated kaolin; and (2) adding the kaolin pretreated in the step (1) into deionized water, then adding cellulose and manganous nitrate, carrying out heating reaction, and then filtering, washing and drying to obtain the modified kaolin. Cellulose is carbonized on the surface of kaolin through a hydrothermal carbonization reaction, the heat conduction efficiency of the ceramic tile is reduced, the hybridization degree of the surface structure of kaolin is further improved by adding manganous nitrate, and the strength of the ceramic tile is improved.

The invention discloses a CoFeCuMn LDH nanosheet, a confinement catalytic membrane and a preparation method of the CoFeCuMn LDH nanosheet. The preparation method of the CoFeCuMn LDH nanosheet comprises the steps that A1, cobalt salt, ferric salt, copper salt and manganese salt are dissolved in pure water according to a preset proportion to prepare a first solution, sodium hydroxide is dissolved in pure water to prepare a second solution, and sodium carbonate is dissolved in pure water to prepare a third solution; a2, adding the first solution and the second solution into the third solution, and stirring to obtain a mixed solution; a3, carrying out hydrothermal reaction on the mixed solution; a4, centrifugally washing the product obtained in the step A3 to obtain a precipitate; and A5, the sediment is dried, and the CoFeCuMn LDH nanosheet is obtained. According to the CoFeCuMn LDH nanosheet, the confinement catalytic membrane and the preparation methods of the CoFeCuMn LDH nanosheet and the confinement catalytic membrane, the degradation efficiency and the degradation rate of new pollutants are remarkably improved.

The invention relates to the technical field of metal materials, and discloses a preparation method of high-purity vanadium, which comprises the following steps: step 1, controlling the purity, granularity and content of raw materials for preparing a vanadium-aluminum intermediate alloy; 2, carrying out an aluminothermic reaction in a vacuum aluminothermic smelting furnace; thirdly, a plate ingot is smelted in a vacuum electron beam horizontal furnace for the first time; fourthly, the plate ingot is smelted in the vacuum electron beam horizontal furnace for the second time; and 5, smelting the high-purity vanadium ingot in a vacuum electron beam ingot pulling furnace. According to the method, traditional slag formers such as CaO are not used, so that alloy components are more stable in the smelting process, component fluctuation caused by the reaction of the slag formers and main reactants is reduced, the reaction temperature and degree are controlled by controlling the addition amount of the Al2O3 cooling material, energy is saved, and the smelting cost is reduced; the beneficial effects that a CaO slag former does not need to be used, and introduction of impurities is avoided are achieved.

The invention discloses a 0.6 / 1kV cross-linked polyethylene cable and a preparation method thereof, and relates to the technical field of cross-linked polyethylene cables, the 0.6 / 1kV cross-linked polyethylene cable comprises a wire core, a cross-linked polyethylene bottom layer, a protective outer layer and a composite protective layer, and the composite protective layer is prepared by mixing expanded graphite and a thermal response hard generator; when the thermal response hard generating agent is heated and is at the heating reaction temperature, a solid hard object used for improving the hardness of the composite protection layer is generated, and after the expanded graphite is heated to expand and the thermal response hard generating agent is heated to generate the solid hard object, it can be guaranteed that the composite protection layer has the good hardness, and the service life of the composite protection layer is prolonged. When the composite protective layer is impacted in the heating process, the composite protective layer can still resist impact by using a solid hard object generated by heating, so that the situation that the impact resistance of the composite protective layer is seriously reduced after the expanded graphite is heated and expanded is avoided; therefore, the cross-linked polyethylene bottom layer and the wire cores in the cross-linked polyethylene bottom layer can still be well protected after the composite protection layer is impacted in the heating process.

The invention belongs to the technical field of synthesis of magnesium hydroxide flame retardants, and provides a synthesis method and flame-retardant application of hexagonal flaky magnesium hydroxide, and the synthesis method comprises the following steps: step 1, dissolving a mineralizer, a crystal form control agent and magnesium chloride in water in proportion; step 2, putting a certain amount of the mixed solution into a high-pressure reaction kettle for hydrothermal reaction; step 3, after the reaction is finished, taking out the cooled solution from the high-pressure reaction kettle, and filtering and separating out a white product; 4, drying the sample, and grinding to obtain pure magnesium hydroxide powder; through reasonable process design and optimization, the prepared magnesium hydroxide not only has regular morphology and better dispersity, but also has excellent performance in the field of flame retardance of high polymer materials, meets the requirement of environmental protection, has the production advantages of low cost and high efficiency, and is suitable for industrial production. The method not only can effectively improve the overall utilization rate of salt lake resources, but also has remarkable economic and application values, and has wide industrial application prospects.

The invention relates to a carbon quantum dot for strengthening and promoting growth of microalgae and application thereof. In the process of preparing the carbon quantum dots by a conventional hydrothermal method, a precursor mixture is subjected to acidification modification in advance, the pH value is adjusted to 2 by using nitric acid, and then a hydrothermal reaction is performed, so that the prepared carbon quantum dots have the capability of promoting the growth of microalgae. However, if other acids are adopted or pH adjustment is not in place, the effect cannot be achieved, and even the inhibition effect can be achieved. The obtained product is good in effect and stable in performance, no special reaction device needs to be additionally arranged in the acidification modification process, and the method has the advantages that operation is easy and convenient, raw materials are easy to obtain, and the process can be quantified; the method is simple and convenient in process operation, has universality and is easy for industrial production.

The invention discloses a preparation method and application of a carbon dioxide gas capture functional molecule modified nanogold catalyst. The preparation method comprises the following steps: synthesizing a modified molecule with a carbon dioxide gas capturing function through a chemical reaction; adding the modified molecules into an organic solvent, and uniformly mixing to obtain a solution; then adding a nanogold colloidal solution into the solution, uniformly stirring, and carrying out oil bath heating reaction; and after the reaction is completed, cooling to room temperature, carrying out suction filtration on the reaction liquid, respectively washing with ethanol and deionized water, and carrying out vacuum drying on the product to obtain the carbon dioxide gas capture functional molecule modified nanogold catalyst. In the electrocatalytic carbon dioxide reduction reaction process of the obtained catalyst, modification molecules are connected with the nanogold catalyst through chemical bonds, active sites of the nanogold catalyst are exposed, and meanwhile, an interface environment beneficial to the carbon dioxide reduction reaction can be provided; therefore, high activity, high selectivity and high stability of the molecular modified nanogold catalyst are realized.

The invention belongs to the technical field of environment-friendly materials, and particularly relates to an MIL-88A-WS2 composite material and a preparation method and application thereof. The preparation method comprises the following steps: mixing WS2 taking a 1T phase as a main phase and MIL-88A in a solvent, then carrying out a hydrothermal reaction, in the hydrothermal reaction process, loading the WS2 taking the 1T phase as the main phase on the MIL-88A, forming a Fe < 2 + > / Fe < 3 + > and W < 4 + > / W < 6 + > circulating channel, covalent bonds and ionic bonds between the WS2 taking the 1T phase as the main phase and the MIL-88A, and meanwhile, forming a hollow structure by the MIL-88A, so as to obtain the MIL-88A-WS2 composite material. The MIL-88A-WS2 composite material obtained by the method provided by the invention has many active sites and strong conductivity, and can act together with an oxidizing agent peroxymonosulfate to realize degradation of phenolic pollutants.

The invention belongs to the field of material preparation and chemical engineering, and particularly relates to an N-doped modified MOFs (Metal-Organic Frameworks) derived core-shell nanoreactor as well as a preparation method and application thereof. The preparation method comprises the following steps: taking cobalt as a node metal, synthesizing an N-doped modified MOFs material with an organic ligand and a nitrogen source through a hydrothermal reaction, then coating the surface of the material with porous silicon dioxide, and preparing the N-doped modified MOFs derived core-shell nanoreactor through a two-step calcination method. The MOFs derived core-shell nanoreactor prepared by the invention has a large specific surface area, a rich pore structure and excellent catalytic activity and stability, and is high in catalytic activity, good in recycling stability and suitable for large-scale popularization and application when being used as a catalyst for alpha, beta-unsaturated aldehyde transfer hydrogenation.

The invention discloses a method for preparing a waste gas purification catalyst from red mud and electrolytic manganese residues, a product and application thereof, and belongs to the field of solid waste resource utilization. According to the method, the preparation process is simple, efficient resource utilization of the red mud and the electrolytic manganese residues can be achieved through reasonable burdening, hydrothermal reaction and pyrolysis carbonization processes, and no other waste liquid or secondary solid waste is generated in the preparation process. The prepared waste gas purification catalyst is excellent in catalytic performance and can be used for quickly converting harmful gas of 1, 2-dichlorobenzene.

The invention discloses a compound molecular sieve ozone catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: mixing molecular sieve powder with a low silica-alumina ratio and a salt solution of an active component, heating and stirring the mixed solution to evaporate the solvent, washing, drying, calcining and grinding the residual solid to obtain the compound molecular sieve ozone catalyst. Active component loaded hydrophilic molecular sieve powder is obtained; the preparation method comprises the following steps: mixing all-silicon molecular sieve powder and an NH4F aqueous solution, carrying out a hydrothermal reaction, and after the reaction is finished, washing, drying, calcining and grinding an obtained solid material to obtain fluorinated modified hydrophobic molecular sieve powder; mixing the active component loaded hydrophilic molecular sieve powder, the fluorinated modified hydrophobic molecular sieve powder, an inorganic binder and a pore forming agent, and granulating to obtain spherical catalyst particles; and drying and calcining the spherical catalyst particles to obtain the compound molecular sieve ozone catalyst. The ozone catalyst provided by the invention improves the removal rate of refractory organics in reclaimed water.

The invention discloses a method for preparing a catalyst by using red mud and titanium dioxide acidolysis waste residues as well as a product and application thereof. The method comprises the following steps: calcining red mud, adding titanium dioxide acidolysis waste residues and an auxiliary agent, uniformly stirring, adding a desulfurization waste liquid, uniformly stirring, carrying out a hydrothermal reaction, carrying out solid-liquid separation, and calcining to obtain the catalyst material. The preparation process is simple, and efficient resource utilization of the red mud and the titanium dioxide acidolysis waste residues can be achieved. The catalyst prepared through a hydrothermal reaction and a secondary calcination process realizes efficient removal of COD, ammonia nitrogen, total phosphorus and heavy metal pollutants in waste liquid through a photocatalytic function.

The invention relates to a preparation method of monodisperse spherical alumina powder with uniform granularity. The preparation method comprises the following steps: dissolving and stirring an aluminum source, a precipitator and a dispersing agent in ultrapure water to prepare an aluminum oxide precursor solution; transferring the prepared aluminum oxide precursor solution into a hydrothermal reaction kettle, carrying out heating reaction, after the hydrothermal reaction is finished, naturally cooling to room temperature, alternately and respectively washing with ultrapure water and ethanol, and drying to obtain aluminum oxide precursor powder; and sintering the prepared aluminum oxide precursor powder in a muffle furnace in an air atmosphere to obtain the spherical aluminum oxide powder. The hydrothermal method is adopted to react in a high-temperature and high-pressure environment, so that the reaction uniformity is improved, and the spherical aluminum oxide precursor with uniform granularity and consistent morphology is obtained. The bending strength of the obtained ceramic material is remarkably improved, and the highest bending strength reaches 245MPa. The method has wide application prospects in the fields of heat-conducting composite materials, integrated circuit films, substrate materials, 3D printing materials, precision polishing materials and the like.

The invention provides a method for preparing analcime from lithium slag, and belongs to the field of zeolite preparation. The method comprises the following steps: acid pickling and impurity removal: mixing lithium slag with an inorganic acid solution, stirring and reacting at 50-70 DEG C for 0.5-3 hours, and then filtering, washing and drying in sequence to obtain impurity-removed lithium slag; activation: mixing the impurity-removed lithium slag with a NaOH solution, carrying out continuous stirring reaction at 75-95 DEG C for 35-72 hours, and aging for 10-30 minutes to obtain a mixture colloid; and crystallization: carrying out hydrothermal reaction on the mixture colloid at 110-130 DEG C for 24-72 hours, and then sequentially filtering, washing and drying to obtain the analcime crystal material. According to the method, the lithium slag obtained after leaching and lithium extraction of spodumene by a sulfuric acid method is taken as a raw material, and on the basis of not calcining and activating and not additionally adding the raw material, the NaOH concentration, the activation temperature and time during activation and the temperature and time during hydrothermal reaction are controlled, so that the high-purity analcime crystal can be obtained.

The invention discloses preparation of a bionic copper-based MOF nano-enzyme and application of the bionic copper-based MOF nano-enzyme in hydroquinone detection, and the bionic copper-based MOF nano-enzyme is prepared by the following method: dissolving terephthalic acid H2BDC and L-histidine His in N, N-dimethylformamide DMF to obtain a solution A; adding copper chloride CuCl2. 2H2O into the solution A obtained by C1, and stirring to form a uniform mixed solution; carrying out hydrothermal reaction on the mixed solution obtained from C2 for a certain time, centrifuging to obtain a solid precipitate, cleaning the solid precipitate, and drying to obtain the bionic Cu / His-MOF nano-enzyme; the invention also discloses an application of the sensor in hydroquinone detection. The bionic copper-based MOF nano-enzyme has the advantages of being simple and convenient to synthesize, high in substrate affinity, high in catalytic capacity and the like, and meanwhile, a rapid, sensitive and reliable HQ detection method is provided.

The invention discloses a synthesis method of phosphorus-containing polysilazane. The synthesis method comprises the following steps: S1, preparing solid methyl hydrogen polysilazane; s2, solid methyl hydrogen polysilazane is dissolved in an organic solvent, phosphate ester is added, the mixture is stirred to be uniform, then a Karst catalyst is added, and a phosphorus-containing polysilazane solution is obtained after a heating reaction. The phosphorus-containing polysilazane solution obtained through combined action of polysilazane and phosphate containing a vinyl structure is applied to an anti-corrosion coating, the anti-corrosion coating with the thin thickness can be obtained, and the adhesive force and the salt spray resistance are excellent. According to the invention, self-made phosphorus-containing polysilazane is adopted, phosphate is connected to polysilazane through chemical modification, the salt spray resistance effect is improved, the storage stability is good, phosphorus liquid passivation treatment is not needed, and the process is green and environment-friendly.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention discloses a method for preparing a catalytic material by synergistically utilizing red mud and electrolytic manganese residues as well as a product and application thereof. The method comprises the following steps: mixing electrolytic manganese residues and red mud, uniformly stirring, adding ammonium chloride, stirring, adding a hydrochloric acid solution, stirring, roasting and grinding. And adding an auxiliary agent, uniformly stirring, adding water, granulating, standing, carrying out hydrothermal reaction, and roasting to obtain the catalytic material. The preparation process is simple, the technological process is brief, the needed core raw materials are only the red mud and the electrolytic manganese residues, and resource utilization of the red mud and the electrolytic manganese residues is efficiently achieved. The prepared catalytic material can quickly adsorb pollutants in waste liquid under the condition of no photocatalysis, and the removal effect on COD (Chemical Oxygen Demand), ammonia nitrogen, total phosphorus and heavy metal mercury can be further remarkably improved under the photocatalysis condition.

The invention relates to a preparation method of H12MDA with low trans-trans isomer content and a catalyst used in the preparation method. The catalyst is a supported catalyst and comprises a silicon-aluminum amorphous carrier and an active component, the silicon-aluminum amorphous carrier has a micropore, mesopore and macropore structure and is prepared by carrying out hydrothermal reaction on raw materials comprising an aluminum source and a silicon source in the presence of a template agent, and the template agent is selected from 4, 4-diaminodiphenyl-methane and 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane. The catalyst is one or a combination of two of 1, 4-diaminodiphenylmethane. The catalyst is long in service life and excellent in stability, the yield of an H12MDA target product can be increased, the content of trans-isomers in the product is reduced, and the preparation process is also simple. The invention also provides a method for preparing H12MDA through MDA catalytic hydrogenation, and the method can improve the yield of the H12MDA product and obviously reduce the content of trans-isomers in the product.

The invention relates to the technical field of composite catalyst materials, in particular to a ferrocobalt bimetal hydroxide / BCN composite material and a preparation method and application thereof.The preparation method comprises the steps that cobalt nitrate and ferric nitrate are used for preparing a metal salt solution, sodium carbonate and sodium hydroxide are used for preparing a precipitant solution, a B-doped carbon nitride BCN material is added into the metal salt solution to form a uniform suspension, and the suspension is dried to obtain the ferrocobalt bimetal hydroxide / BCN composite material; dropwise adding the precipitant solution into the suspension to obtain a precursor solution, performing hydrothermal reaction on the precursor solution, and performing centrifugal impurity removal and drying to construct a heterostructure between layered double hydroxide and BCN in situ to obtain the Co-Fe LDH-coated BCN composite material. Through boron doping and heterostructure construction, the charge separation capacity of graphite carbon nitride is enhanced, the electron migration efficiency is improved through a heterointerface structure, the metal ion release amount and the cycle stability are controlled, and the catalytic performance is remarkably improved.

The invention belongs to the field of new energy materials and devices, and particularly discloses nitrogen self-doped phenolic resin-based hard carbon microspheres and a preparation method and application thereof.The preparation method comprises the following steps that nitrogen-containing phenol monomers, aldehyde monomers and a basic catalyst are mixed according to a certain sequence, and after prepolymerization is conducted at the low temperature, the nitrogen self-doped phenolic resin-based hard carbon microspheres are obtained; carrying out high-temperature hydrothermal reaction to obtain phenolic resin microspheres; and sequentially carrying out low-temperature carbonization treatment and high-temperature carbonization treatment to obtain the nitrogen self-doped phenolic resin-based hard carbon microspheres. Compared with the existing nitrogen-doped resin hard carbon preparation method, the nitrogen-self-doped phenolic resin hard carbon has the advantages that a nitrogen source is introduced into the phenolic resin hard carbon from the source end of the resin, the production process is simplified, and uniform distribution and atomic-scale doping of the nitrogen element are realized. The material is used for sodium ion batteries, has excellent long cycle stability, good rate capability and high specific capacity, and has industrial application prospects.

The invention provides a cerium oxide-loaded mesoporous carbon sphere material and a preparation method and application thereof, and belongs to the technical field of cerium oxide composite material preparation, and the preparation method comprises the following steps: carrying out a hydrothermal reaction on cerium salt under the action of an alkaline mesoporous carbon sphere aqueous solution to obtain a mixed solution; the mass fraction of the mesoporous carbon spheres in the mixed solution is 1-4 wt%, and the concentration of the cerium salt is 0.04-0.06 mol / L; and carrying out centrifugal washing on the obtained mixed solution, and carrying out vacuum drying to obtain the cerium oxide loaded mesoporous carbon sphere material. The mesoporous carbon sphere has a large specific surface area and a uniform pore structure, the pore structure of the mesoporous carbon sphere is very close to the diameter of the short rod type CeO, and the short rod type CeO can be embedded into the pore of the mesoporous carbon sphere due to the size matching, so that tight physical contact is formed; meanwhile, hydroxyl groups on the surfaces of the carbon spheres and oxygen vacancies on the surfaces of the CeO particles can form stable covalent bonds, so that the bonding strength of the cerium oxide-loaded mesoporous carbon spheres is improved, and the service life of the cerium oxide-loaded mesoporous carbon spheres is prolonged.

The invention belongs to the technical field of nano magnetic beads, and relates to a carboxyl nano magnetic bead and application thereof in DNA capture and DNA release. The invention discloses a preparation method of carboxyl nano magnetic beads, which comprises the following steps: dissolving iminodiacetic acid in a sodium hydroxide solution, stirring in an ice bath, dropwise adding a silane coupling agent, carrying out a first heating reaction, cooling in the ice bath, dropwise adding the silane coupling agent again, carrying out a second heating reaction, and cooling in the ice bath to obtain a carboxyl silane coupling agent; and dispersing the ferroferric oxide / silicon dioxide hydroxyl magnetic compound and a carboxyl silane coupling agent in an organic solvent, and stirring for reaction to obtain the carboxyl nano magnetic beads. The carboxyl nano magnetic bead is a nano-scale magnetic bead, is large in specific surface area, good in suspension property and not easy to settle, and has multiple sites for DNA binding; the method can be used for effectively extracting DNA ladders and cfDNA in nucleic acid capture and nucleic acid release.

The invention relates to an alkynyl-modified acyl covalent organic framework (COF) material and application thereof, and relates to the field of preparation of crystalline porous materials and fuel cells. The material is a covalent organic framework material which is synthesized by taking 1, 3, 5-triformyl phloroglucinol and 2, 5-bis (2-propynyloxy) terephthaloyl hydrazine as raw materials through solvothermal reaction under specific conditions, and has relatively high crystallinity. The material has good performance in the aspect of proton conductivity, the highest proton conductivity can reach 6.16163 * 10 <-4 > S / cm, and the mechanical property is enhanced due to introduction of alkynyl. Alkynyl is used as an active functional group, and various chemical reactions can be derived, so that the potential application value of the material is greatly improved.

The invention discloses a metal particle Ni supported catalyst based on fly ash. The preparation method comprises the following steps: firstly, carrying out alkali fusion on fly ash to prepare powder; dissolving the powder and Ni (NO3) 2.6 H2O in a mixed solution of distilled water and absolute ethyl alcohol, adding polyethylene glycol, and performing ultrasonic stirring to obtain uniform dispersion liquid; and finally, continuously performing ultrasonic stirring on the dispersion liquid, performing hydrothermal reaction, cooling, performing centrifugal separation, drying, calcining, cooling and grinding to obtain the catalyst. The coal ash derivative zeolite is adopted as a carrier of the catalyst, Ni is loaded on the carrier to improve the specific surface and effective active sites of the carrier, the effective catalytic specific surface area of the catalyst is effectively improved, and the catalytic activity is improved, so that a stable and safe catalyst material for preparing methane through CO2 hydrogenation with high activity and selectivity is obtained; the space time yield of methane is high.

The present invention provides a method for preparing analcime using lithium slag, and belongs to the field of zeolite preparation. The method comprises the following steps: acid washing and impurity removal: mixing the lithium slag with an inorganic acid solution, stirring and reacting at 50-70°C for 0.5-3h, and then filtering, washing, and drying in sequence to obtain the lithium slag after impurity removal; activation: mixing the lithium slag after impurity removal with a NaOH solution, stirring and reacting continuously at 75-95°C for 35-72h, and aging for 10-30 min to obtain a mixture colloid; crystallization: hydrothermally reacting the mixture colloid at 110-130°C for 24-72h, and then filtering, washing, and drying in sequence to obtain analcime crystal material. The method uses lithium slag after lithium extraction by leaching of spodumene sulfuric acid method as raw material, and can obtain high-purity analcime crystals by controlling the NaOH concentration, activation temperature and time during activation, and the temperature and time during hydrothermal reaction without calcination activation and without adding raw materials.

The invention provides a VOCs catalyst as well as a preparation method and application thereof, and belongs to the field of atmosphere prevention and control. The invention provides a VOCs (Volatile Organic Compounds) catalyst. The VOCs catalyst comprises a modified ZSM-5 zeolite molecular sieve and active metal and / or oxide of the active metal loaded on the modified ZSM-5 zeolite molecular sieve, the preparation method of the modified ZSM-5 zeolite molecular sieve comprises the following steps: mixing a ZSM-5 zeolite molecular sieve and an organic alkali solution, and carrying out a hydrothermal reaction to obtain an organic alkali-loaded ZSM-5 zeolite molecular sieve; and roasting the ZSM-5 zeolite molecular sieve loaded with the organic alkali, and removing the organic alkali to obtain the modified ZSM-5 zeolite molecular sieve, the organic alkali solution is a tetrapropylammonium hydroxide solution.

The invention discloses a NiCrAl structured catalyst as well as a preparation method and an application method thereof. The catalyst contains NiCrAl layered double hydroxides (NiCrAl-LDHs) and a metal substrate, the NiCrAl-LDHs vertically grow on the surface of the metal substrate in situ, nickel ions, chromium ions and aluminum ions in the NiCrAl-LDHs structure come from the metal substrate, and the preparation method comprises the following steps: dissolving urea in water to prepare a urea aqueous solution; and putting the metal substrate into the urea aqueous solution, and carrying out hydrothermal reaction to obtain the composite material. The application method of the catalyst comprises the following steps: introducing current into the catalyst in a reaction atmosphere, and driving the catalytic reaction by using Joule heat generated by the current. The NiCrAl structured catalyst provided by the invention has the characteristics of simple preparation method, less chemical reagent dosage, excellent catalytic performance, easiness in batch production and the like, and is very suitable for application of electrothermal catalysis.