5985 results about "High polymer" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention discloses a multi-layer controllable degradation coating composition as well as a preparation method and application thereof, and belongs to the field of biodegradable high polymer materials and coating compositions. The coating composition comprises an outer protective layer and an inner functional layer, and the inner functional layer is arranged between a substrate and the outer protective layer and comprises a plurality of microcapsules. The key innovation lies in that the microcapsule encapsulates an enzyme capable of catalytically degrading the outer protective layer and is configured to be released after a predetermined delay time. The pH buffer system is integrated in the inner functional layer, and an optimal catalytic microenvironment is created for released enzyme, so that the outer protective layer is actively and quickly degraded, and programmable time-controlled removal is realized. The problem that the degradation rate of an existing biodegradable material is passive and uncontrollable is solved, and the coating has a remarkable application value in the field of seed coating or fertilizer controlled release by endowing the coating with a unique two-stage degradation characteristic.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention relates to the technical field of high polymer materials, and particularly provides a self-repairing type UV curing alumite color layer coating and a preparation method thereof. The water-based ink is prepared from, by weight, 30-50 parts of polyurethane acrylic resin, 10-25 parts of modified acrylic oligomer containing dynamic covalent bonds, 2-5 parts of photoinitiator, 3-8 parts of hydrophobic modified nano filler and 1-3 parts of cross-linking agent, and the dynamic covalent bonds are selected from at least one of hydrazide bonds, boric acid ester bonds and Diels-Alder bonds. By introducing a gradient energy collaborative network of dynamic covalent bonds and quadruple hydrogen bonds, rapid self-repairing of the coating at normal temperature and thermal triggering recombination of deep damage are achieved, and meanwhile through the micro-phase separation design of the hydrophobic core-shell filler and the graft modified silicon carbide nanowires, the hydrolysis resistance is improved.

The invention relates to the technical field of high polymer material processing, in particular to an insulation board extrusion molding control method and system.The method comprises the steps that 1, multi-dimensional parameters are collected in real time, at least three detection sections are arranged on an outlet section of a die head of an extruding machine in the material flowing direction, and each section synchronously collects the following data; 2, evaluating the rheological state of the melt in real time; 3, dynamically reconstructing a temperature field, dividing the die cavity into an axial independent temperature control section and a circumferential heating unit, and dynamically adjusting the power of the heating unit according to a state judgment result in the step 2; 4, pressure-rotating speed cooperative compensation is carried out; and 5, closed-loop verification is carried out, the density uniformity of the formed plate is detected after the adjustment instruction is executed, and if the density range exceeds the limit, the step 2 is executed again. By accurately controlling the temperature and the concentration of the foaming agent, the feasibility of high-proportion mixing of the reclaimed material is optimized, the quality fluctuation caused by temperature and viscosity fluctuation is reduced, and green manufacturing, energy conservation and consumption reduction are promoted.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The invention provides a high polymer material performance prediction method based on deep learning, and relates to the technical field of material performance prediction.The method comprises the specific steps that variable parameters influencing high polymer material performance are determined, multiple sets of samples are prepared and subjected to a tensile test and an accelerated aging test, and initial and final tensile performance parameters are obtained; and constructing and training an initial performance prediction model and an aging performance prediction model based on a deep learning network model, inputting related parameters into the models to obtain performance parameters, generating an environment severe coefficient through data processing, calculating a performance evaluation index in combination with a tensile performance parameter variation, and comparing the performance evaluation index with a preset threshold value to evaluate the material performance. According to the method, the performance change of the aged material can be accurately predicted, the performance evolution can be reflected, the prediction result is closer to reality, the material performance can be comprehensively evaluated, and an effective reference and a scientific basis are provided for long-term use, selection and application of the material.

The invention provides a PHA dispersion emulsion as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The invention aims to solve the technical problem that the prior art cannot simultaneously meet the requirements of the polyhydroxyalkanoate water dispersion system on extremely low temperature natural film-forming property, excellent comprehensive performance after film formation and long-term storage stability. The method is characterized in that a polyhydroxyalkanoate polymer with specific molecular weight and polydispersity index range, a coalescing agent 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate with a specific chemical structure and a specific type of aliphatic polyisocyanate cross-linking agent compatible with water dispersion are strictly limited and combined. Through the synergistic effect generated by the unique ternary combination, the minimum film forming temperature of the prepared emulsion can be reduced to 6-10 DEG C, a film can be naturally formed without hot pressing, and the formed film has excellent mechanical property, water resistance and adhesive force and has excellent storage stability of at least one year.

The invention discloses an immunoregulation hydrogel as well as a preparation method and application thereof, and relates to the technical field of medical materials, amino-derived cationic polysaccharide, carboxyl-derived anionic polysaccharide and dopa-modified protein biopolymer materials are used as biological matrix materials, spermidine is used as a bioactive functional component, and the immunoregulation hydrogel is prepared by a one-step method. The preparation method comprises the following steps: by taking a benzaldehyde-terminated high polymer material as a cross-linking agent, forming a first layer of dynamic reversible cross-linked network structure through Schiff base reaction; then calcium ions are introduced, and the calcium ions and carboxylate radicals are complexed and cross-linked to form a second layer of static irreversible cross-linked network structure which can be used for an ESD (Electro-Static Discharge) operation. By adopting a step-by-step cross-linking mode, the first-step cross-linked single-network hydrogel has injectability, self-repairability, tissue adhesiveness and an immune regulation function, and the second-step cross-linking further ensures stable and lasting performance, so that the problems that a submucosal injection material is easy to disperse, short in lasting time and poor in stability are solved. The immunoregulation function effect of the wound repair material is poor.

The invention discloses a low-temperature-resistant PVC / SEBS modified material and a preparation method thereof, and belongs to the technical field of high polymer materials. The PVC / SEBS modified material comprises the following raw materials in parts by weight: 80-100 parts of PVC, 20-40 parts of SEBS, 5-20 parts of a plasticizer, 6-10 parts of a cold-resistant agent, 2-4 parts of a flame retardant, 5-8 parts of an anti-aging agent, 2-3 parts of a stabilizer and 3-5 parts of a lubricant. The PVC / SEBS modified material prepared by the invention has excellent cold resistance.

The invention belongs to the technical field of flame-retardant macromolecules, and particularly relates to intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) carrying out a reaction on diethanol amine and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; and (2) carrying out condensation polymerization on the intermediate A and phenylphosphonic acid to prepare the phosphate-terminated polyester flame retardant (PEF). And (3) carrying out epoxidation on 4, 4 '-biphenol to prepare the liquid crystal epoxy precursor LEP. And (4) mixing PEF, LEP and 3, 3 '-dithiodipropionic acid, and heating and curing to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardance and efficient recoverability, and is a high polymer material with great potential.

The invention provides a preparation method of an h-BN / PI high-temperature-resistant anticorrosive coating, and relates to the technical field of polymer composites.The preparation method of the h-BN / PI high-temperature-resistant anticorrosive coating comprises the steps that under the protection of inert atmosphere, aromatic diamine containing impurity element five-membered rings and aromatic dianhydride containing ether bonds are taken and subjected to a polymerization reaction in a polar aprotic solvent, and the h-BN / PI high-temperature-resistant anticorrosive coating is obtained. A polyamide acid solution is obtained; performing ultrasonic-assisted liquid phase stripping on the micron-sized hexagonal boron nitride to obtain single-layer hexagonal boron nitride; adding the single-layer hexagonal boron nitride into the polyamide acid solution for multiple times, and uniformly stirring to obtain a hexagonal boron nitride / polyimide composite solution; and coating the hexagonal boron nitride / polyimide composite liquid on a to-be-coated surface, and carrying out gradient heating curing to obtain the h-BN / PI high-temperature-resistant anticorrosive coating. The h-BN / PI high-temperature-resistant anticorrosive coating based on interaction of multiple hydrogen bonds has relatively good high temperature resistance, relatively good resistance mechanical property and excellent corrosion resistance.

The invention discloses a high-weather-resistance halogen-free flame-retardant polyamide composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The composite material comprises the following raw materials in parts by weight: 20-60 parts of polyamide resin A, 0-20 parts of polyamide resin B, 10-50 parts of glass fibers, 0.1-2 parts of an ultraviolet absorbent, 0.1-2 parts of a free radical scavenger, 10-20 parts of a halogen-free flame retardant, 1-15 parts of a flame retardant synergist and 0.5-5 parts of a conventional auxiliary agent. The preparation method comprises the following steps: uniformly mixing the polyamide resin A, the polyamide resin B, the ultraviolet absorbent, the free radical scavenger, the flame-retardant synergist and the conventional auxiliary agent in a high-speed mixer according to the proportion to obtain a mixture, then adding the mixture into a double-screw extruder through main feeding, side feeding of the halogen-free flame retardant through a first side feeding and side feeding of the glass fiber through a second side feeding, and carrying out extrusion molding to obtain the flame-retardant polyamide composite material. And carrying out melt blending and extrusion granulation to obtain the high-weather-resistance halogen-free flame-retardant polyamide composite material. The obtained high-weather-resistance halogen-free flame-retardant glass fiber reinforced polyamide composite material is excellent in mechanical property, flame retardance and weather resistance.

The invention discloses a high-strength low-density proppant as well as a preparation method and an in-situ generation method thereof. The proppant is prepared by compounding recycled glass fiber reinforced plastic powder or glass fiber powder with different meshes and recycled glass fiber reinforced plastic powder in different proportions and blending a styrene system / unsaturated polyester resin system in different proportions. The glass fiber reinforced plastic powder as the filler can improve the mechanical properties of the proppant, such as strength and toughness. The matrix is made of polystyrene or unsaturated polyester or other high polymer materials and is low in density. Therefore, the proppant has the characteristics of high strength and low density. The invention discloses a preparation method of a high-strength and low-density proppant, which can produce the high-strength and low-density proppant with uniform particle size distribution on a large scale by adopting a suspension polymerization method, and can efficiently recover a large amount of glass fiber reinforced plastic wastes. The suspension polymerization method is simple to operate, the produced proppant is high in roundness and sphericity, the mining cost of a coal-bed gas well can be reduced, and the yield of coal-bed gas can be increased.

The invention relates to the technical field of high polymer materials, and provides a high-performance PVC spool and an injection molding method thereof.The spool is prepared from, by weight, 100 parts of polyvinyl chloride resin; 5 to 10 parts of nano silicon dioxide; 1 to 5 parts of graphene; 2-4 parts of a heat stabilizer; 3-6 parts of an impact modifier; 0.5-1 part of an ultraviolet light absorber; 0.5 to 1 part of an antioxidant; 1-3 parts of a compatilizer; the nano silicon dioxide is surface-modified nano silicon dioxide, and the graphene is modified graphene. The surface-modified nano silicon dioxide, the modified graphene, the heat stabilizer, the impact modifier, the ultraviolet light absorber, the antioxidant and the compatilizer are mixed according to a specific proportion to prepare the PVC spool, and the problems that when the PVC spool is exposed to an ultraviolet, high-temperature or strong acid and alkali environment, aging is fast, the mechanical property is reduced, and the chemical resistance is insufficient are solved.

The invention relates to a synthesis method and application of a poly (ether) sulfuryl block copolymer based on chain exchange reaction, and belongs to the technical field of high polymer materials, the synthesis method comprises the following preparation steps: S1, taking an organic solvent, adding a poly (ether) sulfuryl material into the organic solvent, heating and stirring until the poly (ether) sulfuryl material is completely dissolved to obtain a mixed system; and S2, adding an amino-containing hydrophilic polymer material with reaction activity into the mixed system prepared in the step S1, and removing the solvent after reaction to obtain the poly (ether) sulfuryl block copolymer. The preparation process is easy to operate, the production period is short, the obtained material is stable in performance, and industrial production is easy.

The invention belongs to the technical field of synthesis of magnesium hydroxide flame retardants, and provides a synthesis method and flame-retardant application of hexagonal flaky magnesium hydroxide, and the synthesis method comprises the following steps: step 1, dissolving a mineralizer, a crystal form control agent and magnesium chloride in water in proportion; step 2, putting a certain amount of the mixed solution into a high-pressure reaction kettle for hydrothermal reaction; step 3, after the reaction is finished, taking out the cooled solution from the high-pressure reaction kettle, and filtering and separating out a white product; 4, drying the sample, and grinding to obtain pure magnesium hydroxide powder; through reasonable process design and optimization, the prepared magnesium hydroxide not only has regular morphology and better dispersity, but also has excellent performance in the field of flame retardance of high polymer materials, meets the requirement of environmental protection, has the production advantages of low cost and high efficiency, and is suitable for industrial production. The method not only can effectively improve the overall utilization rate of salt lake resources, but also has remarkable economic and application values, and has wide industrial application prospects.

The invention discloses a biodegradable plastic and a preparation method thereof, belongs to the field of bioplastic preparation, and aims to solve the problem that the existing plastic is slow in degradation rate in a marine environment. The biodegradable plastic is prepared from the following components in percentage by weight: 50-80% of a biomass-based high polymer material; 10 to 35% of a degradable toughening agent; 1-5% of a photosensitizer; 2-10% of a microbial inducer; 1-5% of a processing aid; after the biomass degradable plastic is subjected to ultraviolet radiation for 7-15 days in a marine environment, initial cracks with the density being larger than or equal to 20 pieces / cm < 2 > appear on the surface, the initial cracks are broken into degradation units with the particle size being 5-20 mm after being subjected to mechanical impact of sea waves for 30-60 days, and the biological decomposition rate of the degradation units is larger than or equal to 90% within 6-12 months under the action of marine microorganisms; and no micro-plastic particles with the particle size of less than or equal to 1mm exist in the residual product. Through the synergistic effect of the photosensitizer and the microbial inducer, the degradation period in the marine environment is shortened, the degradation efficiency is improved, and the method is remarkably superior to the prior art.

The invention discloses an extrusion process multi-parameter dynamic cooperative control method and system based on deep learning, and belongs to the technical field of high polymer material processing control, the extrusion process multi-parameter dynamic cooperative control method and system based on deep learning comprises the following specific steps: 1, data acquisition and preprocessing, the method comprises the following steps: acquiring multi-source time sequence data in an extrusion production process in real time through a sensor system, and preprocessing the data to form a standardized data set; the multi-source time sequence data comprises equipment operation parameters, process physical parameters and environment parameters. According to the method, the control system is endowed with powerful nonlinear time sequence prediction and multi-parameter collaborative decision-making capabilities through deep fusion of deep learning and reinforcement learning technologies, the quality trend can be accurately predicted, a collaborative control instruction can be given prospectively, and the problems of parameter coupling and control lag are effectively solved.

The invention discloses a polyurethane composite material embedded with a liquid repair network and a preparation method thereof, and belongs to the technical field of high polymer materials, the polyurethane composite material comprises 40-60 parts of a polyurethane prepolymer, 5-20 parts of repair agent carrier particles, 10-30 parts of a liquid repair agent and 0.1-1 part of a dispersant. The composite material provided by the invention solves the problems that a polyurethane material is easy to damage and low in repair efficiency in long-term use. The composite material disclosed by the invention has rapid, efficient and self-adaptive repairing performance under large-scale damage and multiple damage, is suitable for complex environments such as acid-base and high temperature, and has important application prospects in the fields of various industrial equipment, flexible electronic equipment, automobiles, buildings and the like.

The invention relates to the technical field of coal mine safety mining, and discloses a coal mine roadway high-stress area unloading-to-suction danger relieving method which comprises the following steps: step 1, a pressure relief stage: drilling holes in a roadway high-stress area to form a pressure relief channel; 2, a transfer stage, wherein stress is transferred to the deep part of the coal rock mass through the layout of the drill holes; and (3) an energy absorption stage: an energy absorption device is installed in the drill hole, the device comprises an outer steel pipe, an internal high polymer material and a monitoring element, the diameter of the drill hole in the step (1) is 50-150mm, the depth of the drill hole is 5-20m, a one-time hole forming process is adopted for construction, and the drill hole is formed in a high stress concentration area which is 6-20m away from the surface of the roadway and is arranged at intervals in the axial direction of the roadway. By constructing a pressure relief-transfer-energy absorption three-stage synergistic effect system, the whole-process dynamic regulation and control of the surrounding rock stress of the roadway is realized, and the problem that the pressure relief effect is uncontrollable due to the fact that a stress transfer path is not clear in the prior art is effectively solved.

The invention relates to a recyclable composite water purifying agent and a preparation method thereof, and belongs to the technical field of high polymer materials. The recyclable composite water purifying agent comprises the following components in parts by weight: 12-18 parts of activated carbon, 20-25 parts of diatomite, 15-25 parts of polyaluminum chloride, 6-12 parts of a modified flocculant, 5-10 parts of polyethylene glycol, 1-3 parts of a modified photocatalyst and 250-370 parts of deionized water, the recyclable composite water purifying agent prepared by the invention not only has a good pollutant adsorption effect, but also has an excellent antibacterial effect.

The invention relates to the field of treatment and resource utilization of high-carbon-content materials, in particular to a method for preparing graphene at high temperature through electric pulses. The method comprises the following steps: mixing a non-graphitized carbon material and a conductive carbon material to obtain a mixture; pulse current is applied to the mixture, so that the temperature of the mixture is increased to 2000-3000 DEG C, and the mixture subjected to electric heat treatment is obtained; and carrying out cooling treatment on the mixture subjected to the electric heat treatment to obtain the graphene, wherein the carbon content in the non-graphitized carbon material is greater than or equal to 50wt%; the heating rate is 103-104 DEG C / s. According to the method, the carbon atom conversion rate is remarkably increased, the graphene preparation cost is greatly reduced, and meanwhile, the environmental problem caused by a traditional incineration or landfill mode is solved through high value-added utilization of the high-carbon-content waste. Compared with a traditional graphene preparation method, low-cost, high-quality and green preparation of graphene is achieved, the method is suitable for high-valued treatment of various high polymer materials and industrial waste, and a new technical path is provided for large-scale preparation and application of graphene.

The invention discloses a polycarbonate material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials, and the polycarbonate material is prepared from the following raw materials in parts by weight: 40-80 parts of polycarbonate, 20-60 parts of silicon copolymerized polycarbonate, 0.1-0.5 part of a sulfonate flame retardant, 0.1-0.5 part of a compound flame retardant, 0.3-0.8 part of an anti-dripping agent, 0.1-0.4 part of an antioxidant and 0.2-0.8 part of a lubricant. The compound flame retardant is an organic silicon flame retardant with free radicals of nitrogen and oxygen in structure. The material still has better impact resistance in a low-temperature environment of minus 40 DEG C; the compound flame retardant not only has an efficient flame retardant effect, but also has excellent weather resistance; under the action of a sulfonate flame retardant and a compound flame retardant, the flame retardant can meet the flame retardant requirement of 0.5-0.8 mm ultrathin parts, and is especially suitable for the field of electronic and electrical appliances such as middle-and-high-end notebook computers, electronic book shells and the like.

The invention relates to the field of high polymer materials, in particular to a burnthrough-resistant PC composite material and a preparation method thereof. According to the burnthrough-resistant PC composite material provided by the invention, the bromine flame retardant, the silicon flame retardant and the boron flame retardant are used as one of the components, during combustion, bromine is used for absorbing free radicals, so that the oxidation reaction is slow, heat is reduced, silicon and boron are crosslinked to form a B-Si vitrification protection layer, heat insulation and oxygen insulation are realized, the compactness of a carbon layer is complemented, a sinking carbon layer is formed, and matrix resin is prevented from being combusted; the melt strength of the PC composite material is synergistically improved, burnthrough is prevented, and the PC composite material has excellent burnthrough resistance and meets the requirements of new national standards. The invention further provides a preparation method of the burnthrough-resistant PC composite material, the method is simple in process and high in product benefit, and the technical problem of how to improve the burnthrough resistance of the PC composite material is efficiently solved.

The invention relates to the technical field of aromatic polyamide high polymers, in particular to a modified poly-p-phenylene terephthamide fiber with high elongation at break and a preparation method of the modified poly-p-phenylene terephthamide fiber. According to the invention, a small amount of 3, 4-difluorobenzene is introduced According to the preparation method, the third monomer containing 4, 4 '-diaminodiphenyl ether and the fourth monomer containing a diaminophenoxy functional group are added, and the molar ratio of the third monomer and the fourth monomer in the total amount of the diamine monomer is controlled, so that the rigid molecular chain structure of the conventional para-aramid fiber is destroyed to a certain extent, the breaking strength of the fiber is maintained, the elongation at break of the polymer fiber is enhanced, and the service life of the polymer fiber is prolonged. The prepared modified poly-p-phenylene terephthamide can still adopt a dry-jet wet spinning process, the cost of a new production line of a factory is saved, the fiber with stable elongation at break index is obtained by optimizing process conditions and parameters, and the elongation at break of the prepared fiber is 3.6% or above.

The invention discloses a flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The flame-retardant ABS composition provided by the invention comprises the following components in parts by mass: 50-80 parts of ABS resin; 8 to 12 parts of styrene-acrylonitrile copolymer; 3 to 5 parts of styrene-acrylonitrile-maleic anhydride terpolymer; 2 to 6 parts of a fluorine-containing maleimide copolymer; 5 to 15 parts of graphite nanosheet modified high rubber powder; 12 to 18 parts of brominated flame retardant; 3-7 parts of a phosphorus-based flame retardant; 0.1-1 part of a processing aid; the phosphorus-based flame retardant is prepared from the following components in parts by mass: 80 to 95 parts of diethyl phosphinate; 0.3 to 3 parts of ethyl butyl phosphinate; 0.1 to 2 parts of ethyl phosphonate; and 5 to 20 parts of melamine polyphosphate. The flame-retardant ABS composition prepared by the invention is good in flame retardant property, good in welding strength and low in cost.

The invention belongs to the field of high polymer material chemistry, and particularly relates to double-network hydrogel based on sodium alginate / gelatin, a preparation method and dressing. A chemical method of grafting modification is adopted, grafting modification is carried out by designing abundant active groups on side chains of gelatin and sodium alginate, and based on traditional gelatin or sodium alginate hydrogel, not only is the thermal stability of gelatin improved, but also the biological activity of sodium alginate is improved, and the antibacterial property is achieved; the finally prepared SD / GelMA dual-network hydrogel wound dressing not only has excellent mechanical properties, but also has very high biocompatibility and antibacterial activity, and has huge application prospects and potential in the aspect of skin wound healing.

The invention discloses a temperature-responsive microcapsule fire extinguishing material as well as a preparation method and application thereof. The temperature-responsive microcapsule fire extinguishing material comprises a core structure and a shell structure, wherein the shell structure coats the core structure; the core structure comprises a fluorine-containing fire extinguishing agent; the shell structure comprises a high polymer material, a nano compound, a surfactant and a curing agent. According to the perfluorohexanone microcapsule fire extinguishing material, intelligent response release is achieved, the explosion temperature range can be precisely regulated and controlled to be 90-130 DEG C according to the applicable scene, it is ensured that the fire extinguishing agent is released at the critical moment, and the problem of too early or too late release is avoided.

The invention relates to the technical field of antibacterial high polymer materials, in particular to an antibacterial nylon material as well as a preparation method and application thereof. The method comprises the following steps: carrying out anion ring-opening copolymerization on a seven-membered ring lysine monomer obtained by ring formation of lysine and a lactam monomer to obtain copolyamide, dissolving the copolyamide, and carrying out complete quaternization reaction by using halogenated hydrocarbon to obtain the antibacterial nylon material. The preparation method provided by the invention effectively avoids the problems of insufficient antibacterial property, obvious mechanical property reduction, poor thermal stability and the like of an antibacterial nylon material prepared by hydrochloric acid protonation in the prior art. Meanwhile, the seven-membered cyclic lysine monomer can be copolymerized without alkylation, the synthesis process is greatly simplified, the production efficiency is high, and the production cost is low. The prepared antibacterial nylon material has the characteristics of lasting and efficient antibacterial performance, high safety, environment friendliness, excellent mechanical property and thermal stability and the like, and can be widely applied to the fields of textiles, daily necessities, packaging materials, panels and the like.