360 results about "Non solvent" patented technology

The invention provides an alkaline electrolytic water hydrogen production diaphragm based on zirconium oxide modification, the alkaline electrolytic water hydrogen production diaphragm comprises a support layer and a hydrophilic modified coating on the support layer, the hydrophilic modified coating is obtained by coating the support layer with a casting liquid prepared from modified zirconium oxide particles, a film-forming polymer and an organic solvent and then carrying out non-solvent induced phase inversion, the modified zirconium oxide particles are prepared by adding micron-sized zirconium oxide and alkali liquor into a ball mill for ball milling, and the particle size of the zirconium oxide subjected to ball milling treatment is 20-100nm. According to the method, the structure of the micron-sized zirconium oxide particles is regulated and controlled by combining a ball milling-alkali etching synchronous process. Through combination of ball milling treatment and alkali etching treatment, the dispersion degree and the reaction opportunity of the zirconium oxide powder can be effectively improved, and the efficiency of the etching process is remarkably improved. The obtained modified zirconium oxide particles endow the diaphragm with excellent hydrophilicity, alkali resistance and OH <-> ion conduction performance, and the diaphragm has excellent performance when being used as an alkaline electrolytic water hydrogen production diaphragm.

The invention discloses an alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer and a preparation method of the alkaline electrolytic water hydrogen production diaphragm. The diaphragm comprises a supporting base net and a hydrophilic gas insulation coating which is arranged on the supporting base net and contains a hydroxyl ion transfer carrier, the method comprises the steps that a supporting base net is pretreated; the preparation method comprises the following steps: dissolving a polymer binder, a pore-foaming agent, a hydroxyl ion transfer carrier and a hydrophilic metal oxide in an organic solvent according to a mass ratio to obtain hydrophilic slurry; uniformly coating two sides of a supporting base net with the hydrophilic slurry, and then carrying out non-solvent induced phase conversion to obtain the alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer; polar groups such as hydroxyl, amino and carboxyl are introduced into a traditional composite diaphragm to construct a hydrogen bond network, so that hydroxyl ions can be transmitted in a jumping manner along the dynamic hydrogen bond network in the diaphragm to promote transmission of the hydroxyl ions, the performance of the diaphragm can be improved, the materials are cheap and easy to obtain, the preparation process is simple and convenient, and industrial expanded production is facilitated.

The invention relates to a preparation method of a radiation refrigeration coating with super-hydrophobic performance. According to the method, hydrophobic modified nano-particles and nano-particles with high reflectivity and high emissivity are blended in an adhesive solution, an adhesive is separated out to form a micron-sized aggregate through a non-solvent induced phase separation technology, and meanwhile, various nano-particles are uniformly coated on the surface of the aggregate, so that a stable suspension system is prepared. The radiation refrigeration coating has excellent radiation refrigeration performance, excellent super-hydrophobicity and good durability, the preparation process is simple, the radiation refrigeration coating is suitable for large-scale industrial application of outdoor scenes such as building outer walls, and a new technical solution is provided for developing efficient and lasting radiation refrigeration materials.

The present invention relates to a novel method for synthesizing olefin covalent organic framework foams, and polyimide, imine, hydrazone or Ketoenamine covalent organic frameworks (COFs). The method is a green synthetic strategy, including: under non-solvent condition, performing condensation reaction of a methyl-containing monomer and an aldehyde monomer with participation of acid anhydride or carboxylic acid compound to prepare olefin COFs; performing condensation reaction of a multihead acid anhydride or a multihead carboxylic acid monomer and an amino monomer with participation of acid anhydride or carboxylic acid compound to prepare amide COFs; and performing condensation reaction of the aldehyde monomer and the amino monomer with participation of acid anhydride, imidazole or carboxylic acid compound to prepare imine COFs. The COFs obtained by using the method have large specific surface area, regular and adjustable porous structure, and high crystallinity. The method effectively avoids use of organic solvent and risk of high pressure in the reaction process, and is suitable for large-scale preparation of COF materials.

The invention discloses a preparation method of a photo-thermal super-hydrophobic coating with excellent anti-icing / deicing performance in a low-temperature and high-relative-humidity environment, which comprises the following steps of: firstly, growing photo-thermal Cu-MOF (Metal Organic Framework) nano particles on the surfaces of fibrous clay mineral nano particles with low heat conductivity coefficient in situ to construct composite photo-thermal particles with a two-stage nano / nano structure; the preparation method comprises the following steps: preparing nano-particles, then carrying out low surface energy modification on the nano-particles, introducing a low-heat-conductivity-coefficient binder, inducing the binder to generate phase separation through a non-solvent to form a micron-scale binder / low-surface-energy nano-particle aggregate, and finally, spraying to construct the photo-thermal super-hydrophobic coating with a three-level micro / nano / nano structure. The three-level micro / nano / nano structure of the coating simultaneously endows the coating with excellent photo-thermal performance in a low-temperature and high-relative-humidity environment and Cassie-Baxter state stability of liquid drops on the surface of the coating, so that the coating has excellent passive anti-icing / frosting and active deicing / defrosting performance in the environment. The low heat conduction characteristic of the coating further inhibits heat exchange between the base material and water drops, so that the passive anti-icing / frosting performance of the coating is further improved. In addition, the invention also has the advantages of simple preparation method, large-area preparation and the like, and lays a solid foundation for the practical application of the photo-thermal super-hydrophobic anti-icing coating.

The invention provides a preparation method of a composite double-layer microporous membrane, and belongs to the technical field of separation membrane preparation, different lower-layer and upper-layer membrane casting solutions are prepared respectively, the separation membrane is prepared at one time by adopting a double-scraper casting and coating method, the upper layer is thermally induced phase separation, and the lower layer is thermally induced phase separation or non-solvent induced phase separation; the double-layer liquid membrane is subjected to pre-phase splitting and pore opening in a constant-temperature and constant-humidity environment, and enters a gel bath at a certain temperature after pre-phase splitting, and a microporous membrane with a certain membrane structure is formed under the action of RTIPS and NIPS. According to the invention, a co-coating method is adopted, and VIPS, RTIPS and NIPS are used for adjusting the pore structure of the membrane, so that the microporous membrane meeting different filtering requirements is prepared; the prepared membrane product is high in flux and high in yield; the preparation process is simple and conditions are mild: the microporous membrane prepared by the method is simple in process, mild in conditions and suitable for industrial production; and the membrane structures of the upper and lower membranes can be freely adjusted.

The invention provides a preparation method of a quick-dissolution reverse osmosis basement membrane, the reverse osmosis basement membrane prepared by the preparation method and application, and relates to the technical field of reverse osmosis basement membrane preparation. The preparation method comprises the following steps: mixing a pre-casting membrane solution containing polysulfone and a solution containing an amphiphilic block copolymer to obtain a casting membrane solution; coating the surface of a base material with the casting film solution to obtain the base material with a wet film layer; immersing the base material with the wet film layer into a coagulating bath, and obtaining a base film with a modified polysulfone layer through a non-solvent induced phase transformation method; sequentially contacting the base membrane with the modified polysulfone layer with a water-phase monomer solution containing m-phenylenediamine and an oil-phase monomer solution containing trimesoyl chloride, and curing to form a polyamide layer, so as to obtain the reverse osmosis base membrane capable of being quickly dissolved out. The TOC dissolution amount of the reverse osmosis membrane material can be effectively reduced, the TOC dissolution process is accelerated, it is ensured that the membrane can rapidly reach the preset water quality standard in the initial use stage, and the performance stability of the membrane is improved.

The invention provides a porous fiber membrane with a multistage pore channel structure and a preparation method thereof.The preparation method comprises the steps that soluble polymers are dissolved in corresponding solvents, then dispersed EVOH nanofibers are added, and a mixed solution of the polymer solution and the EVOH nanofibers is obtained; injecting the mixed solution into a rotationally stirred non-solvent coagulating bath containing a cross-linking agent at a certain rate by using an injector, performing phase separation on the mixed solution, forming porous fibers under the action of centrifugal force, and dispersing the porous fibers in a non-solvent to obtain a porous fiber dispersion liquid; and finally, coating the porous fiber dispersion liquid on a non-woven base material, performing auxiliary film formation under the action of negative pressure, and drying to obtain the porous fiber film with the multilevel pore channel structure. The prepared porous fiber membrane with the hierarchical porous channel structure not only has micron-sized porous channels, but also has nano-sized porous channels with different sizes on the surfaces of the porous fibers forming the membrane channels, shows higher loading capacity and lower mass transfer resistance, and is suitable for the field of adsorption separation.

The invention discloses a polyether-ether-ketone-based composite material with low reflection and high electromagnetic shielding effectiveness and a preparation method of the polyether-ether-ketone-based composite material, and belongs to the technical field of electromagnetic shielding materials. The problems that an existing electromagnetic shielding material is high in reflection coefficient, insufficient in shielding effectiveness, poor in high temperature resistance and corrosion resistance and difficult to adapt to severe environment service are solved. The composite material is composed of a porous conductive substrate and an asymmetric conductive layer. Wherein the porous conductive substrate is formed by blending a soluble ketimine type polyether-ether-ketone solution and a conductive filler suspension and then carrying out non-solvent induced phase separation and acidification reduction reaction, the electric conductivity is 2.8 * 10 <-4 >-0.1839 S / cm, and the porosity is 80%-90%; the asymmetric conductive layer is plated on the surface of one side of the porous conductive substrate, and the asymmetric conductive layer is made of nickel-phosphorus alloy. The composite material significantly reduces the electromagnetic wave reflection coefficient through an absorption-reflection-reabsorption mechanism, has high electromagnetic shielding effectiveness and excellent high temperature resistance and corrosion resistance, and is suitable for serving in a severe environment.

The invention discloses a mixed matrix membrane for efficient oxygen and nitrogen separation and a preparation method and application thereof. The mixed matrix membrane comprises a polymer continuous phase and an MOF filler uniformly dispersed in the polymer continuous phase, the MOF filler can separate nitrogen and oxygen, and the surface of the MOF filler is modified by the silane coupling agent, so that the MOF filler is well compatible with a polymer, and the oxygen-nitrogen separation effect is improved. The polymer solution and the MOF filler dispersion liquid are mixed, the mixed matrix membrane is prepared through the non-solvent induced phase separation method, and the method has the advantages of being simple in reaction condition, high in efficiency, easy to amplify and the like and has wide engineering prospects.

The present invention discloses a preparation method of a photothermal super-hydrophobic coating with excellent anti-icing / de-icing performance under a low temperature and high relative humidity environment, first by in situ growth of photothermal Cu-MOF nanoparticles on the surface of low thermal conductivity fibrous clay mineral nanoparticles, constructing a two-level nano- / nano-structured composite photothermal particle, which is then subjected to low surface energy modification and introduced into a low thermal conductivity binder, and a binder is induced to phase separate to form a micron-scale binder / low surface energy nanoparticle aggregate by a non-solvent, and finally a photothermal super-hydrophobic coating with a three-level micro- / nano- / nano-structure is constructed by spraying. The three-level micro- / nano- / nano-structure of the coating simultaneously gives the coating excellent photothermal performance and the Cassie-Baxter state stability of the droplet on the coating surface under a low temperature and high relative humidity environment, so that it has excellent passive anti-icing / frosting and active de-icing / defrosting performance in this environment. The low thermal conductivity of the coating further suppresses the heat exchange between the substrate-water droplets, so that the passive anti-icing / frosting performance of the coating is further improved. In addition, the present invention has the advantages of simple preparation method and large-area preparation, laying a solid foundation for the practical application of photothermal superhydrophobic anti-icing coatings.

The application belongs to the technical field of membrane separation materials, and discloses an ultrahydrophilic oil-water separation membrane, a preparation method and application thereof, and comprises the following steps: 2-(2-bromoisobutyryloxy)ethyl methacrylate monomers are prepared from 2-hydroxyethyl methacrylate and 2-bromoisobutyryl bromide, and a polymer with an atom transfer radical polymerization initiator is prepared through a free radical polymerization reaction; the polymer with the atom transfer radical polymerization initiator and polyacrylonitrile are dissolved into a solvent, and a PAN / P(AN-g-BIEM) blended membrane is prepared through a non-solvent induced phase separation method; and a hydrophilic polymer brush is grafted to the surface of the PAN / P(AN-g-BIEM) blended membrane to obtain the ultrahydrophilic oil-water separation membrane; the ultrahydrophilic oil-water separation membrane prepared by the application has a high separation flux, excellent oil-water separation efficiency and separation performance for different oil-in-water emulsions.

The invention discloses a polyvinylidene fluoride (PVDF) super-hydrophobic membrane and a preparation method thereof.The preparation method comprises the steps that firstly, methyl sodium silicate, perfluorodecyl triethoxysilane (PFDTES) and tetraethoxysilane (TEOS) serve as catalysts / reactants, fluorinated hydrophobic modification is conducted on hydrophilic silicon dioxide (SiO2) nanoparticles, a nanoparticle non-solvent composite spraying synergistic phase inversion method is provided, and the polyvinylidene fluoride (PVDF) super-hydrophobic membrane is prepared. F-SiO2 is successfully introduced into the surface of the membrane, a multi-scale micro-nano structure is formed on the surface of the membrane, and the hydrophobicity and the surface roughness of the membrane are greatly improved. The prepared membrane is applied to vacuum membrane distillation testing, the flux and the salt rejection rate are very excellent, the maximum salt rejection rate reaches 99.99%, the flux is kept at 18.21 kg.m <-2 >. H <-1 > or above, the performance of the super-hydrophobic membrane is superior to that of a base membrane and a membrane prepared through a traditional non-solvent induced phase separation method, and the super-hydrophobic membrane has good anti-pollution performance and is very good in recovery effect after being washed with water.

Disclosed in the present invention are a super-hydrophobic polylactic acid film having long-lasting self-cleaning performance and a preparation method therefor, belonging to the technical field of materials. The method comprises: by using polylactic acid as a main material, polymerized rosin as a pore-foaming agent and toluene as an extraction agent, performing non-solvent induced phase separation to prepare a polylactic acid porous film; and then soaking same in a hydrophobic substance solution so as to obtain the super-hydrophobic polylactic acid film. The super-hydrophobic polylactic acid film obtained in the present invention has an initial water contact angle reaching 150 degrees or above, and has super-hydrophobicity and a remarkable self-cleaning effect. In addition, after a plurality of times of rubbing, 94% or above of the water contact angle of the film can be kept and the self-cleaning property is still remarkable. Therefore, said film has wide application prospects in the fields such as self-cleaning, fluid drag reduction, oil-water separation and icing and corrosion prevention.

The invention relates to a poly (ether) sulfuryl block copolymer integrated nanofiltration membrane and a preparation method and application thereof, and belongs to the technical field of high polymer materials, and the preparation method comprises the following steps: adding an additive with reaction active sites into a membrane casting solution, adding another substance capable of carrying out a cross-linking reaction with the additive in the membrane casting solution into a coagulating bath, and carrying out a cross-linking reaction with the additive in the membrane casting solution to obtain the poly (ether) sulfuryl block copolymer integrated nanofiltration membrane. Preparing a flat sheet membrane through a non-solvent induced phase separation technology; the compact hollow fiber nanofiltration membrane is integrally prepared on line by using a double-layer spinning nozzle through dry spraying and wet spinning by taking a membrane casting solution added with a monomer with reaction activity as an inner layer and taking a solution containing another substance capable of being subjected to cross-linking reaction with the monomer with reaction activity in the membrane casting solution as an outer layer. The method disclosed by the invention has the characteristics of simple process, simplicity and convenience in operation, short preparation period and environmental friendliness, and compared with a traditional membrane preparation process, the method is more favorable for preparing the high-flux and high-interception nanofiltration membrane.

The application relates to a preparation method of a hollow fiber membrane composite thermal insulation material, which comprises the following steps: adding 18-22% of polyurethane, 4-8% of polyethylene glycol 2000 and 72-76% of N,N-dimethylacetamide into a spinning reaction kettle to mix, stir and defoam to prepare homogeneous casting solution; based on a non-solvent induced phase separation method, the homogeneous casting solution is coated on the surface of a polyester braided tube through a spinneret by adopting a concentric circle composite spinning technology, is gathered on a spinning wheel after a coagulation bath to form a reinforced polyurethane hollow fiber membrane assembly which is arranged in parallel and obliquely crosses and is mutually bonded, and the fiber membrane assembly is hot-pressed to prepare the hollow fiber membrane composite thermal insulation material under the conditions of a temperature of 60-150 DEG C and a pressure of 120-470 MPa. Since the coating layer and the braided tube are both through porous structures, the prepared composite material has good air permeability.

A photoresist composition including one or more non-solvent alkali-insoluble base materials present in a combined amount of greater than 50 wt%, based on total solids of the photoresist composition; a non-polymeric ionic photoacid generator compound including an anion and an iodonium or sulfonium cation, wherein the anion is represented by Formula (1) as defined herein; and a solvent, wherein the photoresist composition is free of a photoacid generator that generates a photoacid having a higher acidity than a photoacid generated by the non-polymeric ionic photoacid generator compound.

A method for producing a 3D porous sorbent structure may include building a 3D porous green body from a build material including a solvent, an inorganic porous sorbent material, and an organic binder material dissolved in the solvent. The build material is deposited as filaments in a plurality of stacked layers to obtain the 3D porous green body, and at least some of the filaments are spaced apart; inducing phase inversion of the body by exposing it to a non-solvent for the organic binder material. The solidified body is dried to obtain the 3D porous sorbent structure. The build material has 30-70% by weight of the inorganic porous sorbent material and 5-30% by weight of the organic binder material, based on the total weight of the build material, the 3D porous sorbent structure comprising at least a portion of the organic binder material.

The invention discloses a double-layer uniform-hole ultrafiltration membrane with a pH stimulation response active layer and a preparation method of the double-layer uniform-hole ultrafiltration membrane, and relates to an ultrafiltration membrane and a preparation method of the ultrafiltration membrane. The invention aims to solve the problems of Trade-off effect between permeability and selectivity of the existing ultrafiltration membrane, difficulty in membrane pollution cleaning and low utilization rate of a block copolymer in the preparation process of the homogeneous-pore ultrafiltration membrane. The double-layer homogeneous-pore ultrafiltration membrane with the pH stimulation response active layer comprises a polyvinylidene fluoride supporting layer and an active layer taking a PS-b-PMMA (Polymethyl Methacrylate) block copolymer as a main component. The double-layer homogeneous-pore ultrafiltration membrane is synchronously synthesized through a selective solvent-induced non-solvent-induced phase-conducting separation method, the use amount of BCPs is reduced, and the dual purposes of enhancing the mechanical property and reducing the preparation cost are achieved. The finished membrane has the advantages of good permeability, high selectivity, low membrane preparation cost, convenience in membrane pollution cleaning and the like, and can be applied to process upgrading and water quality upgrading and reconstruction of urban water purification plants.

The invention provides a preparation method and application of a PVDF (polyvinylidene fluoride)-based hollow fiber nanofiltration membrane with piezoelectric responsiveness. Specifically, firstly, PVDF, an inorganic pore-foaming agent, a carbon-based conductive material with a piezoelectric property, an organic reactive monomer (TMC) and an organic solvent are prepared into a uniform viscous dispersion liquid according to a certain proportion, then polyamine molecules and water are mixed according to a certain proportion to serve as a core liquid, finally, spinning is conducted through a non-solvent induced phase separation-interfacial polymerization synchronous preparation technology (NIPS-IP), and the PVDF / TMC composite material is obtained. And the PVDF hollow fiber nanofiltration membrane with piezoelectric responsiveness is prepared in one step. The method is simple and convenient to operate, and the prepared nanofiltration membrane is high in beta-PVDF crystal form content (the relative proportion of the beta crystal form is not lower than 90%). In addition, a carbon-based conductive material which can form a continuous phase and has a piezoelectric property is added into the dispersion liquid, so that the content of a beta-PVDF crystal form can be further increased, a continuous path can be formed in the membrane after the dispersion liquid is combined with PVDF, the surface charge density of the membrane is remarkably improved under the driving of nanofiltration pressure, and an internal electric field is generated in a membrane body; the selective separation performance of multivalent / monovalent mixed ions is enhanced through the triple synergistic effect of size screening, surface strong electrostatic interaction and internal electric field strengthening.

The invention provides a preparation method of a high-sensitivity nanofiber composite slub core-spun yarn strain sensor, and belongs to the field of wearable flexible sensors. Comprising the following steps: S1, dissolving polyurethane in a solvent to prepare a spinning solution, preparing a nanofiber / traction filament composite yarn through an electrically-assisted core spinning technology, and endowing traction filaments with deformation by using a stretching device; s2, the composite yarn in the deformation state is placed in a conductive nanoparticle / polymer dilute solution to be soaked; s3, the impregnated composite yarn is impregnated in water, and a nanoparticle / polymer conductive layer is constructed on the surface of the composite yarn through non-solvent induced phase separation; s4, the stretching device is removed, heat treatment is conducted on the composite yarn, and the nanofiber composite slub core-spun yarn sensor is obtained. The sensor has a radial core-shell structure and an axial concave-convex structure, is high in sensitivity, has a stress detection limit as low as 0.01 N, and also has excellent mechanical properties.

The invention belongs to the technical field of adhesive tapes, and particularly relates to a UV protective film for packaging substrate cutting and a preparation method thereof.The UV protective film comprises a PO base material layer, a non-solvent type UV viscosity-reducing adhesive layer and a PET release layer, and the non-solvent type UV viscosity-reducing adhesive layer is located between the PO base material layer and the PET release layer; the non-solvent type UV viscosity-reducing adhesive layer comprises the following components: an acrylate soft monomer, an acrylate hydroxyl monomer, an acrylate hard monomer, an acrylate monomer with a space crosslinking site, n-dodecanethiol, a photoinitiator and a photosensitive multifunctional group acrylate monomer. The non-solvent type UV viscosity-reducing adhesive layer is introduced, so that the preparation process is environment-friendly and free of solvent volatilization, the UV protective adhesive is high in viscosity and excellent in impact resistance before UV irradiation, the adhesive layer is stably attached before cutting, and the UV protective film is stripped at low stress and free of residual adhesive after irradiation.

A manufacturing method of a porous polyimide film, includes: preparing a polyamic acid solution at a concentration of 10 to 30 wt % by dissolving a diamine compound and a dianhydride in a solvent; applying the prepared polyamic acid solution to a substrate to prepare a film and then immersing the same in a non-solvent for 30 minutes to 180 minutes; and taking out the immersed film and thermally curing the same; and a porous polyimide film manufactured thereby.

The present invention discloses a polyethersulfone membrane with low protein adsorption function and its preparation method. The polyethersulfone membrane comprises the following raw materials according to mass percentage: 10-30% of polyethersulfone, 3-15% of amphiphilic copolymer, 2-10% of pore former, 0.5-15% of non-solvent, and 55-75% of solvent. Through a carefully designed formulation and preparation process, the present invention successfully prepares a polyethersulfone membrane with low protein adsorption function. The addition of the amphiphilic copolymer P(PVP-r-PDMS) not only enhances the hydrophilicity and protein adsorption resistance of the membrane, but also realizes the optimization of the membrane structure through the fine regulation of the RTIPS method. Finally, a polyethersulfone hollow fiber membrane with excellent anti-fouling performance and high permeability is obtained, which has broad application prospects in the fields of hemodialysis, drug filtration, food industry, etc.

The invention belongs to the technical field of hydrogel high polymer materials, and particularly relates to a preparation method of high-strength and high-conductivity nano hydrogel and the hydrogel prepared by the preparation method. The preparation method of the hydrogel provided by the invention comprises the following steps: firstly, dissolving polyvinyl alcohol in a good solvent dimethyl sulfoxide of polyvinyl alcohol, and keeping an extended conformation and a staggered network; then, a poor solvent ethyl acetate of polyvinyl alcohol is introduced for non-solvent quenching, so that in-situ phase separation is promoted, polymer chains are drawn close, and interaction between the chains is enhanced; finally, neutral solvent water of polyvinyl alcohol is introduced for solvent replacement, the polymer microphase is evolved into nanofibers, and the polyvinyl alcohol hydrogel with nanoscale pores is formed. The hydrogel prepared by the invention has relatively high fracture stress strain and ionic conductivity, and effectively solves the problems of easy fracture, poor conductivity and the like of the traditional ionic thermoelectric gel.

The invention discloses a hydrophilic modified polysulfone hollow fiber nanofiltration membrane and application thereof, and belongs to the field of polymeric membrane materials. Comprising the following steps: 1) blending a high-molecular film-forming polymer, a hydrophilic auxiliary agent, a pore-foaming agent and an organic solvent to prepare a film casting solution; (2) preparing a hollow fiber base membrane by adopting a non-solvent induced phase separation method; 3, the hollow base membrane is subjected to chemical crosslinking treatment, and the hydrophilic modified polysulfone hollow fiber nanofiltration membrane is obtained.The hydrophilic modified polysulfone hollow fiber nanofiltration membrane has excellent hydrophilic modification, permeation flux, interception performance and long-term thermal stability, and the preparation method is simple, environmentally friendly and low in production cost and has good industrial application prospects.

The invention discloses a polyether-ether-ketone bicontinuous porous coating or membrane based on non-solvent induced phase separation and a preparation method thereof.The preparation method comprises the following steps that polyether-ether-ketone is dissolved in a mixed solution of methanesulfonic acid and concentrated sulfuric acid, a solution A is obtained, hydroxide, oxide or salt of metal is added into the solution A, uniform mixing is conducted, and mixed slurry is obtained; the mass ratio of the polyether-ether-ketone to the hydroxide, oxide or salt of the metal is (0.5-4): 1; and coating the surface of a substrate with the mixed slurry, placing the substrate in wet air or water for a set time, carrying out induced phase separation, and cleaning after complete curing. Alkali or metal salt is used as an additive, the starting point and path of components in the phase separation process can be regulated and controlled, then the formation and size of a bicontinuous structure are controlled, and a highly-controllable coating structure is achieved.

The invention relates to the technical field of gas separation materials, in particular to a preparation method of a high-selectivity functionalized ZIF-7-8 mixed matrix membrane. The preparation method comprises the following steps: taking pebax-1657 as a matrix material of a mixed matrix membrane, synthesizing a ZIF-7-8 filling material by virtue of a non-solvent induced crystallization (NSIC) method, then carrying out ionic liquid impregnation on ZIF-7-8, and finally preparing the high-performance mixed matrix membrane in a blending manner, so as to obtain the functional modified ZIF-7-8 mixed matrix membrane material. 1-butyl-3-methylimidazole bis (trifluoromethanesulfonyl) imide salt ([bmim] [Tf2N]) is adopted as an ionic liquid, ZIF-7-8 is subjected to functionalization treatment through a post-synthesis method, and the ionic liquid with high affinity to CO2 is loaded in a nanomaterial pore cage, so that the adsorption capacity of the material to CO2 is improved, and the performance of the membrane material is further optimized; therefore, the purpose of improving the CO2 separation performance of the mixed matrix membrane is achieved.

The invention discloses a polyimide hollow fiber gas separation membrane and a preparation method thereof, and the polyimide hollow fiber gas separation membrane is prepared by reasonably designing a precursor structure and accurately regulating spinning parameters. The prepared polyimide hollow fiber gas separation membrane is compact in surface, free of holes and defects and excellent in mechanical property, and has a high-flux and high-selectivity gas separation effect, especially for hydrogen. Wherein the hollow fiber spinning solution is obtained by mixing a polyimide polymer, a high-boiling-point solvent, a low-boiling-point solvent and a non-solvent, and the polyimide polymer is synthesized by carrying out condensation polymerization on a dianhydride monomer, a diamine monomer containing a benzimidazole group and other diamine monomers. The preparation method provided by the invention is simple, convenient and easy to operate, avoids tedious procedures and additional economic investment brought by subsequent processes (polydimethylsiloxane coating and crosslinking modification), and has a wide application prospect.

The invention provides a hollow ultrafiltration membrane and a preparation method and application thereof.In the preparation method, a non-water-soluble ether compound is adopted as a pore opening agent, in the non-solvent-induced phase separation (NIPS) process, a membrane casting solution enters a coagulating bath for phase separation after being extruded, the ether compound is migrated due to the fact that mass transfer cannot be conducted between the ether compound and water, and the membrane casting solution enters the coagulating bath for phase separation; the ether compound is dissolved out through post-treatment, and the composite structure hollow fiber ultrafiltration membrane with nano-scale open pores in both the inner surface and the outer surface and a sponge body structure in the interior is prepared. In an actual filtering process, pollutants are intercepted for multiple times by virtue of nano-scale open pore channels on the surface of the membrane and an internal sponge body structure, so that the use requirements of high pure water flux and high interception efficiency are met. The retention rate of the obtained hollow ultrafiltration membrane on 50nm silicon dioxide particles is not less than 99%, and the pure water flux is not less than 600L / (m < 2 > hbar) (25 DEG C). And efficient and stable terminal filtering guarantee can be provided for an ultrapure water system.