4732results about "Paints with biocides" patented technology

The invention relates to a preparation method of a high-durability multifunctional super-hydrophobic coating. According to the method, a mixed solution of an adhesive and hydrophobic modified nanoparticles is subjected to phase separation through non-solvent induction, so that the hydrophobic modified nanoparticles are coated on the outer layers of adhesive particles to form a uniform suspension, and finally, a micro-nano structure dispersed on the surface and inside of a coating can be obtained. After the surface layer is worn, the newly exposed surface still has an excellent micro-nano structure, namely super-hydrophobic performance; on the other hand, the nanotubes (wires) are added into the suspension, so that the mutual connection among the adhesive particles is further enhanced, and finally, the firm super-hydrophobic coating can be obtained. The super-hydrophobic coating provided by the invention has excellent durability, chemical stability, ultraviolet resistance and thermal stability, and functions of photo-thermal, electric heating, antibiosis, easy deicing, high thermal conductivity and the like, is suitable for various base materials, and is easy to realize large-scale preparation.

The invention relates to a preparation method of a graphene oxide loaded nanoparticle functional anticorrosive coating. The preparation method comprises the following steps: (1) preparing a graphene oxide loaded nanoparticle composite material; and (2) preparing the anticorrosive coating, namely weighing dimethylbenzene, n-butyl alcohol and filler according to a ratio, performing ultrasonic treatment, weighing epoxy resin, continuously performing ultrasonic treatment and stirring, dropwise adding a defoaming agent, a flatting agent, a wetting dispersant and a curing agent, stirring, standing, and spraying on the surface of a matrix to serve as the anticorrosive coating. According to the anticorrosive filler prepared by the preparation method, the problem that graphene oxide agglomerates in a coating is solved, nano-particles are introduced to optimize a coating structure, micropores and microcracks in the coating are filled, the compactness of the coating is enhanced, defects in the coating are reduced, and the protective performance of the coating is improved.

A zwitterionic polymer coating with surface grafting crosslinking, its preparation method and application are disclosed, which relate to surface modification of biomedical materials, pipelines and other medical equipment, such as extracorporeal blood circulation devices, artificial blood vessels, catheters, endoscopes and other medical equipment, to provide functions such as anticoagulation and anti-biological adhesion. The disclosure constructs the zwitterionic polymer coating with simple process and excellent performance by simulating the structure of the blood vessel intima, having the surface micro-nano structure similar to the blood vessel intima, extremely low friction coefficient, soft elasticity and super hydrophilicity, realizing zero activation and zero adhesion of blood platelets, further providing the blood circulation effect of “blood undisturbed”, which is beneficial to avoiding the problems of thrombus of artificial blood vessels in vivo, various complications caused by clinical blood extracorporeal circulation and the like, and has great clinical application value.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The invention relates to the technical field of wood corrosion prevention and corrosion resistance treatment, in particular to a preparation process of a coating for improving the antibacterial and corrosion-resistant performance of wood. In order to improve the antibacterial and corrosion-resistant capabilities of the prepared coating, a corrosion-resistant antibacterial agent is prepared and added into the raw materials of the coating, and quaternary ammonium salt, guanidyl and other group structures are introduced into the corrosion-resistant antibacterial agent, so that the antibacterial performance on microorganisms such as fungi is realized; the introduction of fluorine can effectively improve the hydrophobicity of a coating of the paint and reduce the influence of water vapor on antibacterial components in the coating, and the introduction of allyl can enable the corrosion-resistant antibacterial agent to react with butyl acrylate and other raw materials under the action of an initiator to achieve the cross-linking ability, so that the loss of the corrosion-resistant antibacterial agent is effectively avoided, and the service life of the coating is prolonged. The antibacterial activity is kept for a long time.

The invention discloses a fingerprint-resistant coating of a chromium-plated part and a preparation method of the fingerprint-resistant coating, and belongs to the technical field of metal material plating surface treatment. Comprising the following steps: carrying out hydrolysis reaction on an organic siloxane coupling agent to obtain silane coupling agent hydrolysate; mixing and reacting the silane coupling agent hydrolysate, levodopa, an EDC hydrochloride reagent and a DMAP reagent to obtain modified levodopa; soaking the pretreated chromium-plated part in modified levodopa, taking out the pretreated chromium-plated part, soaking the pretreated chromium-plated part in a methacrylate solution, and polymerizing to obtain a polymethacrylate-poly-levodopa-chromium-plated part; and the polymethacrylate-poly-levodopa-chromium-plated part is soaked in a silver salt solution, and the fingerprint-resistant coating of the chromium-plated part is obtained. According to the method, the poly-levodopa adhesion layer is constructed on the surface of the chromium-plated part according to the molecular bionics principle, then the poly-levodopa is further polymerized to generate the polymethacrylate protection layer, and finally the fingerprint resistance of the chromium-plated part is improved through further coordination crosslinking of the silver salt solution.

The present invention relates to the technical field of coatings. Disclosed are a coating composition having mold-proof and antibacterial properties and a preparation method therefor. The coating composition comprises the following raw materials: an acrylic resin emulsion, a curing agent, a coalescing agent, a defoaming agent, and a leveling agent, wherein the acrylic resin emulsion is prepared from an acrylate monomer, a cross-linking agent, and fluorine-containing silicone oil by means of free radical polymerization under the action of an initiator. A gemini-type quaternary ammonium salt functional group in the structure of the cross-linking agent can enable the coating to have good mold-proof and antibacterial effects, the presence of the ether bond can enable the coating to have better adhesive force, and the presence of the fluorine-containing silicone oil can enable a coating film formed by curing the coating to have a super-hydrophobic surface, thereby avoiding surface moisture which promotes bacterial growth and reproduction, and endowing the coating with antifouling and self-cleaning effects. In addition, the silicon-oxygen bond in the silicone oil can effectively enhance the heat resistance of the coating, thereby facilitating further application of the coating in indoor decoration.

The invention belongs to antibacterial materials, and particularly relates to antibacterial modified waterborne polyurethane and a preparation method and application thereof.The preparation method of the antibacterial modified waterborne polyurethane comprises the following steps that polyol and diisocyanate are mixed and subjected to a prepolymerization reaction, and a polyurethane prepolymer is obtained; mixing the polyurethane prepolymer and a chain extender, and carrying out chain extension reaction; in the chain extension reaction, adding the graft and carrying out esterification reaction to obtain a first intermediate; mixing the first intermediate with triethylamine and carrying out neutralization reaction to obtain a second intermediate; and emulsifying the second intermediate in deionized water to obtain the antibacterial modified waterborne polyurethane. Compared with the prior art, the antibacterial waterborne polyurethane has the advantages that the problems of poor intermiscibility, low durability and the like in physical addition and the problems of limited binding objects and weak antibacterial effect in covalent binding in the antibacterial waterborne polyurethane in the prior art are solved. According to the scheme, arginine and chitosan are grafted to a molecular chain of waterborne polyurethane, so that the waterborne polyurethane is endowed with a synergistic antibacterial property.

The invention relates to the technical field of polyurethane films, in particular to a long-acting, stable, flexible, impact-resistant and resistance-reducing protective film and a preparation process thereof. According to the invention, the raw materials such as polyethylene glycol, a modified fluorosilicone monomer, isophorone diisocyanate, hydroxyethyl acrylate, an acrylic antifouling monomer, dodecafluoroheptyl methacrylate and the like are added to prepare the anti-drag coating. Mixing a polyurethane thermoplastic elastomer, aminopropyl polydimethylsiloxane, an antioxidant and an ultraviolet light absorber, and carrying out melt extrusion and blow molding to form a film, so as to obtain a flexible impact-resistant base film; and uniformly coating the surface of the flexible anti-impact base film with the anti-drag coating, and carrying out ultraviolet curing to obtain a finished product. The finished product prepared by the invention has good impact resistance, and can effectively reduce frictional resistance, so that the finished product has wide application prospects in the technical field of polyurethane films.

Disclosed in the present invention are a fluorosilicone-modified low-surface-energy antifouling coating and a preparation method therefor. The coating comprises the following components in parts by weight: 11-15 parts of butyl acrylate, 3-4 parts of dodecafluoroheptyl methacrylate, 3-4 parts of vinyl-terminated polydimethylsiloxane, 3-4 parts of 2-hydroxy-4-acryloyloxybenzophenone, 30-38 parts of methyl isobutyl ketone, 0.15-0.25 parts of azobisisobutyronitrile, 0.1-0.2 parts of sodium hydroxide, 2-3 parts of modified titanium dioxide nanoparticles, and 0.5-1.5 parts of 3-aminopropyltriethoxysilane. In the present invention, vinylpentamethyldisiloxane reacts with decamethylcyclopentasiloxane to prepare vinyl-terminated polydimethylsiloxane; a titanium dioxide precursor is mixed with polydopamine nanoparticles for modification to prepare modified titanium dioxide nanoparticles; and then the components above are mixed to prepare the fluorosilicone-modified low-surface-energy antifouling coating. The coating has low surface energy and good adhesion and ultraviolet resistance.

The invention relates to the technical field of plastics, in particular to an antibacterial food packaging bag and a preparation method thereof.The antibacterial food packaging bag is prepared by blending polylactic acid and polypropylene carbonate as a base film raw material, selecting a food-grade ADR chain extender as a chain extender, selecting one of butyl titanate and a titanate coupling agent as a compatibilizer and selecting composite hybrid cellulose as a broad-spectrum antibacterial agent; carrying out extrusion granulation and blow molding to obtain a base film; the preparation method comprises the following steps: taking microcrystalline cellulose-nano zinc oxide hybrid particles as hybrid cellulose, performing epoxidation on the hybrid cellulose by using epoxy chloropropane, and then grafting an amino acid-based Schiff base antibacterial agent by using epoxy-hydroxyl reaction; composite hybrid cellulose and modified castor oil-based waterborne polyurethane are used for preparing a protective coating, the surface of a base membrane is coated with the protective coating, and a green, environment-friendly, durable, antibacterial, hydrophobic and antifouling self-repairing surface is constructed.

The invention relates to the technical field of coatings, and provides an antifouling coating as well as a preparation method and application thereof. The antifouling paint comprises a component A and a component B, wherein the component A comprises fluorosilicone modified acrylic resin, fluorinated paraffin, modified nano attapulgite, a wetting agent, a defoaming agent and a dispersing agent; a modifying agent of the modified nano attapulgite is 2-imidazole-1-ethylamine and 2-(3, 4-cyclohexyl oxide) ethyl triethoxy silane, and a modifying agent of the modified nano attapulgite is 2-imidazole-1-ethylamine and 2-(3, 4-cyclohexyl oxide) ethyl triethoxy silane; and the component B comprises a curing agent and a diluent. The nano attapulgite is modified, so that the dispersity of the nano attapulgite in the coating and the compatibility of the nano attapulgite with resin are improved, the nano attapulgite can be subjected to cross-linking reaction with other network structures to form a more compact cross-linked network, and the mechanical strength and the wear resistance of the coating are further improved.

The invention discloses a double-sterilization-anti-sticking composite cross-linked coating as well as a preparation method and application thereof, and belongs to the technical field of functional polymer materials. The coating comprises the following raw materials in parts by weight: 5-30 parts of a cross-linkable release type multifunctional branched polymer and 30-95 parts of a cross-linkable functional polymer. According to the double-sterilization-anti-adhesion composite cross-linked coating, the advantages of contact sterilization, antibacterial factor release and adhesion resistance can be combined together, on one hand, the super-hydrophilic component can effectively prevent initial adhesion of bacteria and protein, and even if a small amount of bacteria fall into the surface of the coating, the contact sterilization component can effectively kill a small amount of adhesion bacteria; the formation of bacteria and biological membranes is avoided; in addition, the introduction of releasable antibacterial molecules can effectively enhance the antibacterial effect, and the purpose of deeply killing pathogens is achieved.

The invention relates to the technical field of epoxy resin coatings, and discloses an inorganic composite nano anticorrosive coating material and a preparation method thereof. The inorganic composite nano anticorrosive coating material comprises a component A, a component B and a component C, wherein the component C is obtained by mixing a functional modified inorganic composite nano material and aluminum sorbate; the component A is obtained by mixing modified epoxy resin, a defoaming agent and an anti-settling agent, and the component B comprises a polyamide curing agent. The inorganic composite nano anticorrosive coating material disclosed by the invention has excellent toughness, wear resistance, corrosion resistance, antibacterial and antifouling properties and ultraviolet resistance.

The invention relates to the technical field of high-barrier composite packaging films, and discloses a high-barrier composite packaging film with an antibacterial function, which sequentially comprises a base layer, a nano composite barrier layer, an antibacterial functional layer and an outer protective layer from bottom to top, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier composite packaging film with the antibacterial function, the cellulose nanowhiskers have the characteristics of high strength and high modulus and are mixed with the bio-based polylactic acid, so that the tensile strength and tear resistance of the bio-based polylactic acid can be remarkably improved, and the structural stability of the packaging film in the using process is guaranteed; nano titanium dioxide and nano cellulose aerogel are arranged in the nano composite barrier layer, so that the barrier property of the packaging film on oxygen and ultraviolet rays can be enhanced, and the packaging film also has a certain antibacterial effect; in addition, the nanocellulose aerogel has a loose porous structure, so that gas molecules can be effectively prevented from passing through, and the barrier property is further improved.

The invention relates to the field of coatings, and discloses an outer wall light radiation heat preservation and heat insulation decorative sheet and a preparation method thereof.A radiation refrigeration layer on the surface of the outer wall light radiation heat preservation and heat insulation decorative sheet comprises modified acrylate resin, silicon dioxide, ground calcium carbonate, talcum powder, modified hollow glass beads and auxiliaries; the modified acrylate resin is prepared by copolymerizing perfluorooctyl ethyl acrylate, methyl methacrylate, modified isocyano ethyl methacrylate and vinyltriethoxysilane, and the modified isocyano ethyl methacrylate is prepared by using salicylaldehyde and benzothiazole-2-formaldehyde as well as 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator and using 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator. The preparation method comprises the following steps: reacting amino groups at two ends of 1, 5-naphthylenediamine with DOPO, carrying out nucleophilic addition reaction with DOPO, and grafting with isocyano ethyl methacrylate. The modified hollow glass beads are prepared by using tetrabutyl titanate as a titanium source through a sol-gel method, and the prepared radiation refrigeration layer has the super-amphiphobic self-cleaning effect, the radiation refrigeration effect is good, and meanwhile the flame retardant property and the antibacterial effect are excellent.

The invention provides a gamma-cyclodextrin-based metal organic framework composite material as well as preparation and application thereof. The metal organic framework composite material based on gamma-cyclodextrin comprises chitosan, gamma-CD-MOFs (Metal Organic Frameworks) and an active substance. The preparation method comprises the following steps: by taking chitosan as a film material base material, synthesizing gamma-CD-MOFs by utilizing a hydrothermal method, and then loading cinnamyl aldehyde with antibacterial property, 2-methoxycinnamyl aldehyde with ultraviolet light resistance and curcumin with an antioxidant effect into the gamma-CD-MOFs. And finally, mixing with chitosan with better film-forming property, and spraying on glass or the surfaces of fresh fruits. The gamma-CD-MOFs has the characteristic of slowly releasing bioactive substances, is non-toxic and is a material capable of being applied to food packaging.

The invention provides a flame-retardant antibacterial coating for aluminum products and a preparation method of the flame-retardant antibacterial coating, and belongs to the technical field of coatings. The preparation method comprises the following steps: activating 3-[3-carboxyl allylamido] propyltriethoxysilane coated magnesium powder through EDC and NHS, mixing the magnesium powder with 1-aminopropyl imidazole hexafluorophosphate modified graphene oxide and nickel-doped UiO-66-NH2 for reaction, adding the mixture into epoxy resin, stirring for reaction, adding dimethyl sulfate for reaction, adding a dispersing agent, a flatting agent and a solvent, uniformly mixing, and drying to obtain the graphene-modified nickel-doped graphene composite material. The flame-retardant antibacterial coating for the aluminum product is prepared. The flame-retardant antibacterial coating for the aluminum product, prepared by the preparation method disclosed by the invention, has relatively good mechanical property, flame retardance and antibacterial property, also has a relatively good anti-corrosion effect, is more uniform and compact after being cured, has relatively good performance and has a wide application prospect.

The invention discloses a water-based multi-layer degradable self-polishing ship antifouling coating system and a preparation method thereof, and belongs to the field of marine anticorrosion and antifouling materials. The system is composed of a zinc-rich primer, a modified epoxy intermediate paint and a functionalized finish paint. The finish paint takes polyhydroxyalkanoate as a matrix, and integrates a self-stratification modifier capable of forming a silicon-rich top layer during curing and a latent dual-curing system capable of realizing normal-temperature curing through a synergistic effect. According to the present invention, the mixing mechanism of dynamic self-polishing and static fouling release is adopted, and the innovative curing technology is combined, such that the long working life, the excellent mechanical property and the long-acting antifouling ability are achieved. The drawing adhesive force of the system is not lower than 7.9 MPa, and the environment-friendly requirements that the content of volatile organic compounds is smaller than or equal to 50 g / L, and the content of free diisocyanate monomers is smaller than or equal to 0.1 wt% are met.

The invention discloses a thiazolinone acrylic acid silane ester self-polishing antifouling resin and a preparation method and application of the thiazolinone acrylic acid silane ester self-polishing antifouling resin. The preparation method of the thiazolinone acrylic acid silane ester self-polishing antifouling resin mainly comprises the following steps: in a nitrogen environment, adding an initiator, the preparation method comprises the following steps: carrying out random free radical polymerization reaction on thiazolinone methacrylate, methyl methacrylate, ethyl acrylate, triisopropyl silicon-based methacrylate and phenyl dimethyl silicon-based methacrylate by taking azodiisobutyronitrile and benzoyl peroxide as initiators to synthesize the photoinitiator. Wherein the thiazolinone methacrylate monomer is prepared by grafting double bonds on 5-chloro-2-benzothiazolinone and methacryloyl chloride through a substitution reaction, then grafting hydroxyl on the 5-chloro-2-benzothiazolinone and mercaptoethanol through a mercapto-alkene click reaction and finally carrying out a substitution reaction on the 5-chloro-2-benzothiazolinone and methacryloyl chloride. According to the invention, the coating still has good surface self-renewal capability even in a static environment so as to inhibit the adhesion of large fouling organisms.

The invention relates to the field of optical lens coatings, and particularly discloses a preparation method of an antifouling and antibacterial spectacle lens coating. The preparation method of the antifouling and antibacterial spectacle lens coating comprises the following steps: depositing a silicon dioxide substrate on the surface of a lens through plasma enhanced chemical vapor deposition treatment; the preparation method comprises the following steps: dispersing nano-graphene and nano-silver particles in an ethanol solvent, adding a silane coupling agent to form a homogeneous suspension, loading the suspension on the surface of a silicon dioxide substrate through a spin-coating method, and carrying out heat treatment curing to form an antibacterial layer, with the loading amount of nano-silver being less than or equal to 0.5 wt%; and etching the surface of the antibacterial layer by adopting a reactive ion etching method, and then grafting perfluorooctyltriethoxysilane on the etched surface at 80-100 DEG C by adopting a vapor deposition method to form the hydrophobic layer. The preparation method of the antifouling and antibacterial spectacle lens coating has the advantages of being antibacterial, antifouling and high in durability.

The invention relates to the technical field of surface coating materials, in particular to a multifunctional surface coating which comprises the following raw materials: organic silicon modified acrylic resin, an intumescent flame retardant, hollow glass beads, nano titanium dioxide, an auxiliary agent, graphene, silver nanoparticles and flaky zinc powder. The intumescent flame retardant is formed by compounding melamine polyphosphate and pentaerythritol, and the auxiliary agent comprises a dispersing agent, a flatting agent and a plasticizer. By integrating multiple functions of fire prevention, water prevention, heat insulation, self-cleaning and the like into a whole, the complex requirements of different fields of buildings, industry, traffic and the like on material performance can be comprehensively met. In the application of building exterior walls, the fireproof safety, the waterproof sealing performance and the heat insulation performance of buildings can be effectively improved, and energy consumption is reduced; in the aspect of industrial equipment protection, equipment can be protected from being damaged by environmental factors such as high temperature, moisture and corrosion, and the service life of the equipment is prolonged.

The invention belongs to the field of metal coating preparation, and particularly relates to a thick coating suitable for a silicon steel surface layer and a preparation method thereof. Graphene is modified by polyethylene glycol diglycidyl ether (PEGDGE), and silver nanoparticles are combined, so that the high-conductivity antibacterial composite material is prepared. An auxiliary agent solution is rapidly synthesized by a microwave ultrasonic technology, so that the hardness and wear resistance of the coating are enhanced. And an anti-ultraviolet and chemical-corrosion-resistant additive is added into the coating, so that the durability and the service life of the coating are improved. A spraying method is adopted for uniform coating, and high-temperature curing ensures that the coating is stable. The whole process is optimized, the conductivity, the antibacterial property, the ultraviolet resistance, the chemical corrosion resistance, the hardness, the wear resistance and the like of the coating are remarkably improved, and the high-performance coating is prepared.

The invention discloses a water-based weather-resistant mildew-proof coating and a preparation method and application thereof.The mildew-proof coating comprises a water-based coating, organic mildew-proof agent missible oil and an inorganic nano-material, the water-based coating comprises water-based acrylic resin and alkyd resin, the mass ratio of the water-based acrylic resin to the alkyd resin is (20-25): 1, the organic mildew-proof agent missible oil is 1: 1, and the inorganic nano-material is 1: 1. The inorganic nano material comprises at least one of nano titanium dioxide, nano zinc oxide and nano silicon dioxide. The preparation method comprises the following steps: mixing the water-based paint, the organic mildew preventive missible oil, the inorganic nano-material, the coalescing agent, the nonionic surfactant and the deionized water to form a mixed solution, and emulsifying the mixed solution under a water bath condition of 50-60 DEG C to obtain the water-based weather-resistant mildew-proof paint. The stability and the storage stability of the mildew-proof coating are at least doubled compared with those of an existing scheme, and the mildew-proof performance is improved by 80% or above.

The invention relates to the technical field of coating preparation, and particularly discloses a multifunctional composite filler modified water-based coating and a preparation method thereof.The water-based coating is prepared from, by weight, 80-100 parts of modified core-shell acrylic acid dispersoid, 5-7 parts of multifunctional composite filler, 0.5-1 part of defoaming agent, 0.5-1 part of wetting agent, 2-5 parts of thickening agent, 1-2 parts of coalescing agent and 25-35 parts of deionized water. The water-based paint provided by the invention is modified by adding a proper amount of multifunctional composite filler, the performance is excellent, the stability is good, the components in the water-based paint have good compatibility by optimizing the preparation process conditions of the water-based paint, and the preparation method is simple to operate and suitable for industrial production.

The invention discloses a preparation method of an antibacterial self-repairing organic silicon coating, and belongs to the technical field of organic silicon resin preparation, octamethylcyclotetrasiloxane, siloxane and / or amino silane and a catalyst are sequentially added into a four-neck flask filled with nitrogen, after stirring and heating, acid treatment is performed to obtain amino polysiloxane with a quaternary ammonium salt modified side chain, and then the amino polysiloxane with the quaternary ammonium salt modified side chain is added into the four-neck flask to obtain the antibacterial self-repairing organic silicon coating. Adding carbon tetrachloride and methyl acrylate, adding sodium hydroxide after the reaction is finished, heating and refluxing, filtering to obtain a liquid product, carrying out rotary evaporation to obtain amino acid modified polysiloxane, uniformly stirring the amino acid modified polysiloxane and a solvent to obtain a component A, uniformly stirring an antibacterial cross-linking agent and a solvent to obtain a component B, stirring the component A and the component B, coating, and drying to obtain a finished product. And curing to obtain the amino acid modified polysiloxane for self-repairing the antibacterial coating. Through synthesis of amino acid modified polysiloxane, reversible crosslinking of polysiloxane is realized through chelation of amino and carboxyl on metal ions, the reversible crosslinking can be repeated for multiple times, and the metal ions have an antibacterial effect, so that the service life of the coating is prolonged.

The invention discloses an antibacterial corrosion-resistant coating and a preparation method thereof, and relates to the field of coating materials. The coating is prepared from the following components in percentage by mass: 2 to 5 percent of nano silver ion loaded mesoporous silicon dioxide nano particle antibacterial aid, 5 to 10 percent of zinc powder-containing corrosion inhibitor, 3 to 8 percent of nano montmorillonite, 30 to 40 percent of modified epoxy resin, 20 to 30 percent of polyurethane prepolymer and other aids. The nano silver ion antibacterial auxiliary agent is loaded in mesoporous silica nanoparticles through an ion exchange method, the zinc powder corrosion inhibitor is prepared through stirring and ball milling dispersion, and the modified epoxy resin is modified by adopting a silane coupling agent. The preparation process of the coating comprises the stages of premixing, grinding and refining, initiating polymerization and post-treatment, wherein a grinding medium is zirconium oxide beads with the diameter of 0.5-2 mm. The coating has excellent antibacterial and corrosion-resistant performance, is suitable for metal surface protection, and can effectively solve the problems that an existing coating is not lasting in antibacterial effect, insufficient in corrosion-resistant performance and not ideal in comprehensive performance.

The invention discloses a high-temperature-resistant and corrosion-resistant coating and a preparation method thereof, and belongs to the technical field of coatings. The preparation method comprises the following steps: uniformly stirring 40-50 parts by weight of epoxy resin, 25-35 parts by weight of phenolic resin, 20-30 parts by weight of modified filler, 4-10 parts by weight of pigment and 50-65 parts by weight of solvent, then adding 5-10 parts by weight of curing agent and 0.5-1 part by weight of accelerant, and stirring to obtain the coating. The modified filler contains inorganic fillers such as titanium dioxide and glass flakes, a benzotriazole structure and a hindered phenol structure, and the modified filler has good compatibility with other raw materials and has chemical action with epoxy resin, so that the modified filler can stably exist in the coating, is not easy to migrate and fall off, and plays a role for a long time; under the combined action of other raw materials, the coating has excellent and stable high temperature resistance, corrosion resistance, aging resistance, flame retardance and the like, and the service life is greatly prolonged.

This invention belongs to the field of marine antifouling, and specifically relates to a transparent, self-lubricating organosilicon hybrid antifouling coating with a negatively charged surface and its preparation method. The antifouling coating is obtained by a sol-gel reaction of modified nanocellulose, hydroxy acid, and functional fluorine / siloxane monomers; the mass ratio of the hydroxy acid to the modified nanocellulose is 10–100:1; the mass ratio of the functional fluorine / siloxane monomer to the modified nanocellulose is 10–300:1. This invention, based on a multi-element green antifouling strategy, constructs a material surface with negative charge, self-lubrication, and low surface energy. The prepared antifouling coating exhibits excellent transparency, mechanical properties, and static antifouling performance. This antifouling coating is environmentally friendly and has broad application prospects in the field of marine antifouling.

The invention discloses an antibacterial solventless coating and a preparation method thereof, and belongs to the field of paints.The antibacterial solventless coating comprises a component A and a component B, the component A is prepared from the following components in parts by weight: 45 to 70 parts of plant oil-based modified polyol, 0.5 to 1.5 parts of antibacterial agent, 20 to 40 parts of pigment filler and 4 to 8 parts of coalescing agent; the component B is a silane modified end isocyanate group prepolymer; the mass ratio of the component A to the component B is (2-2.4): 1; the antibacterial agent in the component A is a composite antibacterial agent, and the composite antibacterial agent comprises nanoscale zinc-loaded hydroxyapatite, ceric ammonium nitrate modified nano TiO2 and an intermediate carrier; the intermediate carrier is a microsphere with pores distributed on the surface; the mass ratio of the nanoscale zinc-loaded hydroxyapatite to the ceric ammonium nitrate modified nano TiO2 to the intermediate carrier is 3: 2: 5. The coating disclosed by the invention has excellent antibacterial performance.