The invention discloses an
imine type COFs (Covalent Organic Frameworks) material for adsorbing gold as well as a preparation method and application thereof, and belongs to the technical field of
precious metal recovery. The preparation method specifically comprises the following steps: (1) mixing terephthalaldehyde and
acetic acid, and stirring to obtain a suspension; (2) mixing N1, N1 '-(1, 4-
phenylene) bis (N1-(4-aminophenyl)
benzene-1, 4-
diamine and deionized water, dropwise adding the mixture into the suspension, and stirring the mixture; and (3) after the reaction is finished, collecting the generated precipitate, washing and
drying to obtain the product. The
Schiff base type COFs material with high
thermal stability, high specific surface area and good
crystallinity is synthesized by pre-activating an
aldehyde monomer and an amine
monomer with
acetic acid in a room-temperature
aqueous solution by utilizing the
oxidation resistance characteristic of hydroxyl and the dynamic repairing capacity of an
imine bond, and the adsorption material has the advantages of high adsorption capacity, high stability and high accuracy, and can be used for preparing the COFs material with high specific surface area and good
crystallinity. And the preparation method is green, simple, convenient, universal and efficient, and realizes accurate adsorption of single
metal ions under the coexistence of multiple
metal ions.