384 results about "Visible light irradiation" patented technology

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.

The invention discloses a preparation method of CoWO (cobalt tungsten oxide) modified NbOp-n heterojunction NbO5 / CoWO photocatalyst powder. The preparation method comprises the following steps: dissolving cobalt salt and tungsten salt in deionized water, stirring and mixing, carrying out hydrothermal reaction in an autoclave, washing and drying to obtain CoWO powder; the preparation method comprises the following steps: dissolving niobium oxalate and ammonium carbonate in deionized water, adding CoWO powder, carrying out a hydrothermal reaction in an autoclave, and carrying out washing and drying treatment to prepare NbO / CoWO photocatalyst powder. According to the method, the hydrothermal reaction temperature is regulated and controlled, and the mass ratio of raw materials is optimized, so that the catalyst forms a p-n heterojunction structure of NbOmicron flower loaded CoWOnano particles. The prepared catalyst has high norfloxacin wastewater degradation efficiency under visible light irradiation, has the advantages of simple preparation process, low reagent cost, high catalytic activity and good structural stability, and can be effectively applied to purification treatment of antibiotic polluted water.

The invention belongs to the field of organic synthetic chemistry, and relates to a preparation method of melatonin and meerythrine indole derivatives and compounds. Specifically, the indole derivative is efficiently synthesized by taking arylamine and carboxylic acid as raw materials through a one-pot two-step reaction in the presence of catalysis of ferric chloride hexahydrate (FeCl3. 6H2O), a ligand, a diazotization reagent, an additive and a solvent under the conditions of visible light irradiation, inert atmosphere and room temperature. According to the method, visible light induced iron-based LMCT catalysis and iron lewis acid catalysis functions are integrated, and efficient integration of diazotization, decarboxylation, free radical coupling and cyclization reaction is achieved. The method has the advantages that raw materials are cheap and easy to obtain, reaction conditions are mild, substrate applicability is wide, functional group compatibility is good, operation is easy, convenient and safe, and environment friendliness is achieved, gram-level scale preparation can be achieved, and a green and efficient synthesis path is provided for indole compounds with biological activity such as melatonin and meerythrine.

The invention discloses a preparation method of a high-stability photoresponse covalent organic framework membrane and application of the high-stability photoresponse covalent organic framework membrane in selective separation of multiple components. 4-azido azobenzene is prepared by carrying out azido reaction on 4-aminoazobenzene in an acidic aqueous solution, and then a BPTA-TAPB-COF membrane is used as a matrix to prepare the high-stability photoresponse covalent organic framework membrane. 4-azido azobenzene is efficiently grafted to the pore wall of the BPTA-TAPB-COF membrane through a click chemical reaction, the photoresponse covalent organic framework membrane is constructed, and the covalent organic framework membrane can be used for multi-component selective separation and is suitable for multi-component systems with different sizes. The azobenzene group in the pore channel of the prepared Azo-COF membrane is subjected to reversible cis-trans isomerization under the irradiation of ultraviolet / visible light, the response speed is high, and the cycle performance is good; the Azo-COF membrane has good application in the light-operated nanofiltration process, the performance of the Azo-COF membrane is not reduced after the Azo-COF membrane is continuously recycled for 12 days, and the structure of the Azo-COF membrane is kept stable.

The invention belongs to the technical field of organic synthesis, and particularly relates to a synthesis method of an isoxazole compound under a visible light catalysis condition. The method comprises the following steps: dissolving a compound 1 in 1, 2-dichloroethane, then adding tert-butyl nitrite, tribromomethane, alkali and a photocatalyst, in an inert gas environment, irradiating with visible light and stirring at room temperature to react, after the reaction is completed, reducing pressure to remove a solvent, and then performing silica gel column purification on a crude product to obtain a product, namely the isoxazole compound. The brand-new method for preparing the isoxazole compound through visible light catalysis is developed, the conditions of high temperature and high pressure in a traditional synthesis method are avoided, energy consumption and environmental pollution are remarkably reduced, and the yield of the isoxazole compound is effectively increased by regulating and controlling reaction conditions and optimizing raw material selection and proportion.

The invention provides a visible light photocatalytic hydrogen production material based on a D-pi-A type PTA-TFPTA imine bond COF as well as a preparation method and application of the visible light photocatalytic hydrogen production material, belongs to the technical field of functional material technologies and photocatalytic hydrogen production, and is used for solving the problem that a covalent organic framework material is generally insufficient in catalytic activity in the photocatalytic hydrogen production process. The material is prepared by mixing and reacting 2, 5, 8, 11-tetra (4-aminophenyl) perylene and an electron-deficient monomer; during application, the material is mixed with a sacrificial agent and a cocatalyst, and photocatalytic hydrogen production can be realized under visible light irradiation. The preparation process is simple and convenient, does not need complex equipment and harsh conditions, and is easy for large-scale production; the obtained material is good in crystallinity, excellent in visible light absorption performance and outstanding in photocatalytic hydrogen production activity.

The invention belongs to the technical field of catalytic synthesis, particularly relates to a method for preparing a nitrogen-containing fused ring compound through quantum dot catalyzed [4 + 2] cycloaddition, and aims to solve the problems of limited product structure and complex reaction system in the existing synthesis method. The synthesis method disclosed by the invention comprises the following steps: in an inert atmosphere, adding 1-phenylpyrrole and fumarate as reaction raw materials, quantum dots as a photocatalyst and an organic solvent into a reaction container, carrying out [4 + 2] cycloaddition reaction under visible light irradiation, and then filtering, concentrating, separating and purifying to obtain the nitrogen-containing fused ring compound. The reaction condition is mild, and the method can be realized by irradiating the quantum dot catalyst with a visible light source at normal temperature and pressure; a reaction system is simple, strong oxidants and additives are not needed, operation steps are convenient, and atom economy is achieved.

The invention discloses a synthesis method of a glutaric acid ester compound, which comprises the following steps: reacting a propionate compound as shown in a formula 1 with a diazo compound as shown in a formula 2 in a solvent in a nitrogen atmosphere in the presence of a reducing agent under the illumination condition of visible light, and after the reaction is completed, separating out the glutaric acid ester compound, thereby obtaining the glutaric acid ester compound. And separating and purifying the reaction mixture to obtain the glutaric acid ester compound as shown in the formula 3. The propionate compound and the diazo compound are used as reaction substrates, the compound can be generated through reaction under mild conditions, the yield of the target product is improved, operation is easy and convenient, the reaction conditions are mild, the price of raw materials and solvents used in the whole process is low, and cost control is facilitated.

The invention discloses a photocatalytic synthesis method of diethyl disulfide, and relates to the technical field of organic synthesis. The preparation method specifically comprises the following steps: mixing Co (NO3) 2.6 H2O and Ni (NO3) 2.6 H2O, and adding methanol to obtain a solution A; 2-methylimidazole and methyl alcohol are mixed, and a solution B is obtained; mixing the solution A and the solution B to obtain a zeolite imidazole framework material; selenium powder and the zeolite imidazole framework material are mixed and calcined, and a NiCoSe2 material is obtained; the preparation method comprises the following steps: mixing a NiCoSe2 material, ZnCl2, InCl3 and C2H5NS, adding an ethanol water solution, and carrying out microwave hydrothermal synthesis to obtain a NiCoSe2-coated ZnIn2S4 photocatalyst; the NiCoSe2-coated ZnIn2S4 photocatalyst and ethanethiol are subjected to a photocatalytic reaction under N2 atmosphere protection and visible light irradiation, and diethyl disulfide and hydrogen are generated. The method is mild in reaction condition and high in product stability.

The invention belongs to the technical field of biomedical materials, and discloses a viola philippica exosome-loaded composite hydrogel as well as a preparation method and application thereof, the composite hydrogel is prepared by mixing methacrylated polylysine (PLMA), oxidized dextran (ODex), viola philippica exosome (V-E), a photoinitiator and a physiologically compatible solvent and performing illumination crosslinking; the preparation method comprises the following steps: respectively preparing PLMA and ODex solutions, extracting and purifying V-E, adding a photo-crosslinking agent (LAP), mixing the components to obtain a precursor liquid, and carrying out in-situ curing molding through ultraviolet-visible light irradiation. The composite hydrogel provided by the invention solves the problems that the existing wound dressing is difficult to fit with irregular wounds, is antibacterial and easy to resist drugs, and lacks active anti-inflammatory and efficient healing promotion capabilities, and is suitable for repair treatment of infectious open wounds such as burns, trauma, diabetic foot ulcer and postoperative infected incisions.

The invention discloses application of bismuth vanadium tetraoxide as a photocatalyst in preparation of allantoin. According to the method, a decahedral single crystal micron material bismuth vanadium tetroxide is used as a photocatalyst, uric acid is used as a substrate, a photocatalytic reaction is performed under the irradiation of visible light, and uric acid is oxidized, hydrolyzed, decarboxylated and converted into allantoin; compared with a traditional chemical synthesis method, the method has the advantages that the bismuth vanadium tetraoxide serves as a photocatalyst, uric acid is converted into allantoin through photocatalytic reaction, selective activation of chemical bonds is achieved through directional regulation and control of photo-induced electron-hole pairs, and the method is mild in reaction condition, low in energy consumption and the like.

The present invention relates to a method for functionalizing a biopolymer having an -OH group or an -NH2 group by reacting the biopolymer with at least one compound having at least one C=C bond or C≡C bond and containing a chromophore that absorbs UV-Vis radiation directly adjacent to this bond. The present invention also relates to a method for obtaining a solid biopolymer material by reversibly crosslinking the functionalized biopolymer obtained by the above method under UV-Vis light irradiation. Furthermore, the present invention relates to the use of functionalized biopolymers as support materials for 3D bioprinting, or as materials for manufacturing structures selected from spheroids, organoids, artificial organs, coatings, and tissue models.

A light-emitting device (1) is attached to a support body of a mobile body (100) alongside an imaging device (2), and emits invisible light which is detected by the imaging device (2) toward the ground. In the light-emitting device (1), a position (PP) of peak illuminance in an irradiation region (IA) of the invisible light with which the ground is irradiated is present at a position away from the support body. The irradiation region (IA) includes a first region (A1) including the position (PP) of peak illuminance, and a second region (A2) surrounding the first region (A1). When irradiance with which a white line (210) drawn on the ground can be detected is defined as white line irradiance, the first region (A1) is a region irradiated with the invisible light at an irradiance equal to or higher than the white line irradiance, and the second region (A2) is a region irradiated with the invisible light at an irradiance lower than the white line irradiance.

This invention discloses a Cu2O / Cu3VO4 heterojunction catalyst, its preparation method, and its application in the photocatalytic reduction of CO2 to multi-carbon products, belonging to the field of catalyst materials technology. The preparation method includes: dissolving a copper source and a vanadium source in water to obtain a solution; mixing the solutions and adjusting the pH to 5-8 to obtain an initial solution; dispersing the solid from the initial solution after centrifugation in a mixture of ethylene glycol and water; and performing a hydrothermal reaction at 150-200℃ for 8-12 hours; washing and drying the reactants, and then calcining them at 500-600℃ for 2-5 hours under an inert atmosphere to obtain the Cu2O / Cu3VO4 heterojunction catalyst. In this catalyst, Cu2O and Cu3VO4 form a closely contacted heterojunction structure, enabling efficient separation of photogenerated electrons and holes under a built-in electric field and enhancing the absorption of visible light. Under visible light irradiation, this catalyst can reduce CO2 to multi-carbon products such as CO, CH4, C2H4, and C2H6, with an electron selectivity of up to 79% for the C2 products. The preparation process of this invention is simple and low-cost, and the resulting catalyst has broad application prospects in the field of photocatalytic CO2 reduction.

To provide a method for efficiently decomposing water into hydrogen and oxygen even under visible light irradiation by using a hydrogen-generating photocatalyst. The method for splitting water by light of the present invention is a method in which light is irradiated onto an aqueous solution containing one type of photocatalyst and a compound having oxidation-reduction ability dissolved therein.

The invention discloses a composite catalyst for anchoring coordinated copper anion micromolecules (preferably [Cu (BCA)] <->) in a cationic covalent organic framework (preferably EBCOF) skeleton pore channel through an ion exchange strategy, and a preparation method and application thereof. According to the catalyst, a directional electron transmission channel composed of a COF framework-ionic bond-anion copper complex is constructed in a COF body, the catalyst is used for CO2 reduction reaction under the conditions of visible light irradiation and triethanolamine as a sacrificial agent, high selectivity is shown for C2 products, the ethane generation activity is improved by about 2.62 times compared with a control sample not subjected to ion exchange treatment, and the selectivity of the catalyst is greatly improved. And the activity retention rate is not less than 90% after circulation for 5 times. The method is simple in process and mild in condition.

The invention belongs to the field of photocatalysis, and particularly discloses a perovskite composite photocatalyst for photocatalytic ethanol dehydrogenation and application. The composite photocatalyst takes a CdS nanorod as a carrier, a Cs2AgBiBr6 double perovskite active component formed by CsBr, AgBr and BiBr3 precursors is loaded on the surface of the CdS nanorod through a vacuum in-situ growth method, and a Pt, Rh or Ni metal cocatalyst can be further loaded. The method comprises the following steps: dispersing a CdS nanorod and a perovskite precursor in a mixed organic solvent, carrying out vacuum freezing-air exhaust circulation treatment, and removing the solvent under a heating condition to prepare the composite photocatalyst. When the photocatalyst is used for an ethanol photocatalytic dehydrogenation reaction under an anaerobic condition, hydrogen, acetaldehyde and acetal can be efficiently generated under the irradiation of visible light. According to the method, the photo-generated charge separation efficiency and the reaction stability are remarkably improved, and a new way is provided for ethanol high-valued conversion.

The invention relates to the technical field of organosilicon chemistry, in particular to a preparation method of a phenyltrimethoxysilane oligomer. According to the method, a photooxidation reduction catalytic system is adopted, a hydrolytic condensation reaction is carried out under the irradiation of visible light, the ratio of M / T substance amount is controlled, a proton coupling electron transfer mechanism is adopted to activate silane bonds, and an acid-base catalyst does not need to be additionally added. Efficient synthesis is realized in a continuous flow microchannel reactor by introducing innovative components such as a cyanoalkyl silane end-capping reagent, an organic titanium prepolymer catalyst and polyhedral oligomeric silsesquioxane. The obtained oligomer has a controllable molecular structure and excellent performance, the methoxy residual quantity is lower than 0.3%, the yield reaches 90% or above, the viscosity is controlled to be 18-25 mm < 2 > / s, the refractive index is 1.460-1.465, and the oligomer has the reversible crosslinking characteristic and is suitable for high-end cosmetics and electronic packaging materials.

The application relates to an In2O3 / PPy / g-C3N4 heterojunction material synthesized by a solvothermal method and an in-situ polymerization method, which is used for detecting CO2 gas under room temperature and visible light irradiation. The composite material combines the unique electronic properties of In2O3, the high conductivity of PPy and the good visible light absorption characteristics of g-C3N4, improves the photo-generated charge separation efficiency through the heterojunction effect, and significantly improves the detection performance of CO2. The sensing material not only has high sensitivity, low detection limit, good stability and reusability, but also is environment-friendly, conforms to the environmental protection development trend, and has wide application prospects in the fields of environmental monitoring and the like.

A Cu x The preparation method of O / BNAD composite photocatalyst adopts a soft template method. Porous h-BN (p-BNNS) is prepared by high-temperature calcination of the precursor. Under low-temperature conditions, a diazotization reaction is used to generate p-BNNS diazonium salt, which is then coupled with an aromatic amine to obtain a porous boron nitride azo compound (p-BNAD) covalently linked by -N=N-azo bonds. Finally, copper oxide / boron azo nitride (Cu) is prepared by vacuum impregnation with copper salt. x This invention utilizes an O / BNAD composite photocatalyst for the efficient reduction of Cr(VI) and the inhibition of bacteria. Under simulated sunlight, Cu... x O / BNAD can effectively reduce Cr(VI) ions, with an apparent kinetic constant of 0.071 min. ‑1 The conversion rate is as high as 88.67%. Under visible light irradiation, it can effectively inhibit the reproduction of Gram bacteria, with an antibacterial rate of 98.0-99.9%.

The invention belongs to the technical field of organic synthetic chemistry, and particularly relates to a preparation method and medical application of a visible-light-driven bis (trifluoromethyl) selenide compound. The preparation method of the bis (trifluoromethyl) selenide compound comprises the following steps: by taking olefin, trifluoromethylselenotetramethylammonium and bis (trifluoromethylseleno) diselenide as reaction raw materials, stirring and reacting under the conditions of proper temperature and visible light irradiation in the presence of cuprous salt to obtain the bis (trifluoromethyl) selenide compound. The method has the advantages of mild reaction conditions, simplicity and convenience in operation, good functional group compatibility and the like. In addition, the bis (trifluoromethyl) selenide compound provided by the invention shows good potential in the aspect of anticonvulsion, and has the prospect of being further developed into anticonvulsion drugs.

The application relates to the technical field of photocatalysts, in particular to a Fe3O4 / P / CuO x Nano-array composite photocatalyst, preparation method and application thereof. The preparation method is as follows: S1, a copper base material with CuO x nano-arrays is prepared; S2, the copper base material obtained in step S1 is immersed in a protective layer growth solution, the base material is taken out after reaction, and then washed and dried; the protective layer growth solution is prepared from one or more of dopamine mixed solution, tannic acid mixed solution and tea polyphenol mixed solution; S3, the base material obtained in step S2 is immersed in Fe3O4 nanoparticle dispersion liquid for a period of time, and then washed and dried after being taken out, so that the composite photocatalyst is prepared. Under visible light irradiation, the adsorption rate of the application to Cr(VI) reaches more than 98%, the proportion of elemental Cr in the reduction product is more than 60%, and the decomposition rate of the antibiotic reaches more than 99%.

This invention discloses a fully optically modulated photoelectric synaptic device, its fabrication method, and its applications. This device successfully simulates the synaptic behavior of nerve cells within the ultraviolet to visible light spectrum. Furthermore, the device exhibits positive responses to both ultraviolet and visible light, with an increase in photocurrent. However, when irradiated with ultraviolet light first and then with visible light, the visible light inhibits the photocurrent generated by the ultraviolet light, causing a rapid decrease in photocurrent.

The application provides a cobalt-nickel sulfide-indium oxide composite nanosheet material, a preparation method and application thereof. The preparation method of the cobalt-nickel sulfide-indium oxide composite nanosheet material comprises the following steps: synthesizing CoNi2S4 nanosheet powder; synthesizing In2O3 nanosheet powder; compounding the CoNi2S4 nanosheet and the In2O3 nanosheet: the CoNi2S4 nanosheet powder and the In2O3 nanosheet powder are fully dispersed in water according to a molar ratio of (1-2):(1:2), are placed in a light-transmitting container, are irradiated with visible light for 1 h, and then are centrifugally separated to obtain a precipitate, are washed with water, and are vacuum dried to obtain the cobalt-nickel sulfide-indium oxide composite nanosheet material. The cobalt-nickel sulfide-indium oxide composite nanosheet material prepared by the method can catalytically reduce carbon dioxide into carbon monoxide and methanol under visible light irradiation, the yield of methanol can reach 129.73 μg·g ‑1 ·h ‑1 , the selectivity and the electronic selectivity of methanol can reach 52.65% and 76.29%, respectively, and the methanol production performance does not show attenuation at least for 30 h.

The invention belongs to the technical field of organic synthetic chemistry, and discloses a method for efficiently synthesizing methyl 2-chloro-3-oxovalerate. According to the method, high-selectivity chlorination is performed on a beta-site C-H bond of methyl 3-oxovalerate under a mild condition by taking sodium chloride as a chlorine source and adopting a dual-catalysis system consisting of engineered halogenase and a visible light-sensitive catalyst under visible light irradiation. The engineered halogenase is a HalB triple mutant, and the affinity and regioselectivity of a substrate are remarkably improved; the photosensitive catalyst is a ruthenium bipyridine complex and synergistically drives generation of chlorine free radicals. According to the invention, a brand new biological-photochemical synergistic catalysis platform is constructed by organically combining the substrate recognition capability of the engineered halogenase and an electron transfer mechanism driven by visible light catalysis, so that the contradiction among selectivity, mildness and atomic efficiency of a traditional chlorination method is solved; and the method can be expanded to precise synthesis of other beta-functionalized ketone ester compounds.

The invention relates to the technical field of photocatalysis, in particular to a strontium bismuth vanadium oxide photocatalyst and a preparation method and application thereof.The chemical formula of the photocatalyst is Sr3. 59Bi19.41 V4O42, the crystal structure of the photocatalyst belongs to an orthorhombic system, the space group of the photocatalyst is Immm, and the photocatalyst is of a unique layered structure composed of cation triple plate layers; the photocatalyst is synthesized by a molten salt method, and shows the activity of photocatalytic decomposition of water to produce oxygen under visible light. The preparation method comprises the following steps: mixing and grinding SrO, Bi2O3 and VO precursors with a molten salt medium, and then carrying out temperature programming calcination to synthesize a target product; the catalyst prepared by the method has the characteristics of high crystallinity, few defects and regular morphology, the photocatalytic oxygen production performance of the catalyst is remarkably superior to that of a same-component sample synthesized by a traditional solid-phase method, and photocatalytic water decomposition and oxygen production can be realized by taking a silver nitrate, ferric nitrate, ferric chloride or potassium ferricyanide aqueous solution as a sacrificial agent system under the irradiation of visible light with the wavelength of more than or equal to 420 nm.

The invention discloses a FeCoY-MOF / BiOBr composite material as well as a preparation method and application of the FeCoY-MOF / BiOBr composite material. The FeCoY-MOF / BiOBr composite material comprises a FeCoY-MOF material and BiOBr particles deposited on the surface of the FeCoY-MOF material, wherein the FeCoY-MOF material is an MOF material obtained by taking pyridine-2, 3-dicarboxylic acid as a ligand and coordinating the pyridine-2, 3-dicarboxylic acid with Co < 3 + >, Fe < 3 + > and Y < 3 + > ions. According to the invention, the transfer of photon-generated carriers can be promoted, and the separation efficiency of the photon-generated carriers is improved, so that the performance of photocatalytic degradation of organic pollutants is improved, and tetracycline can be efficiently subjected to photocatalytic degradation under the irradiation of visible light.

To provide an apparatus and a method for estimating the degree of steaming of tea leaves, capable of objectively estimating the degree of steaming of steamed leaves, and to provide a method for producing tea leaves.SOLUTION: A steaming degree estimation device for tea leaves includes first measurement means for measuring light intensities of reflected light at a plurality of specific wavelengths by irradiating a plurality of tea leaf samples each having a known steaming degree with light in a visible region, prediction model creation means for creating a steaming degree prediction model representing a correspondence relationship between the light intensities of the reflected light at the plurality of specific wavelengths measured by the first measurement means and the known steaming degrees in the plurality of tea leaf samples, storage means for storing the steaming degree prediction model created by the prediction model creation means, and second measurement means for measuring a light intensity of reflected light at a specific wavelength by irradiating target tea leaves whose steaming degree is to be estimated with light in a visible region. And a steaming degree estimation means for obtaining the steaming degree of the target tea leaves corresponding to the light intensity of the reflected light measured by the second measurement means.SELECTED DRAWING: Figure 4

The invention relates to a metal organic framework for improving charge separation efficiency based on a conjugated benzene ring, a preparation method thereof and application of the metal organic framework in degradation of methyl orange. The invention relates to a complex of MOF-2 [Zn8 (NDC) 8 (TRZ) 8] n, in which NDC is 2, 6-naphthalenedicarboxylic acid, and TRZ is 1, 2, 4-triazole, and a preparation method of the complex of MOF-2 [Zn8 (NDC) 8 (TRZ) 8] n. The extended pi conjugation in MOF-2 results in significant improvements, including reduced band gap, enhanced visible light absorption, and more excellent charge separation efficiency, as proved by comprehensive ultraviolet-visible spectroscopic analysis, electrochemical analysis, and valence band-XPS measurements. 83.8% of methyl orange degradation is realized by the MOF-2 under the irradiation of visible light within 30 minutes. According to mechanism research performed by using a free radical capture technology and electron spin resonance (ESR) spectroscopy, superoxide free radicals (. O2 <->), singlet oxygen (1O2) and hydroxyl free radicals (. OH) are determined as main active species.

The invention discloses a preparation method of a full-organic ionic liquid confinement nano catalytic material and application of the full-organic ionic liquid confinement nano catalytic material in photocatalytic CO2 methanation, and belongs to the technical field of photocatalytic materials. The invention aims to solve the problems that the existing photocatalytic material is small in specific surface area and insufficient in active sites due to difficulty in regulation and control of microstructure and pore structure, environmental and biological toxicity is caused by dependence on noble metal / transition metal, and preparation of CH4 by photocatalytic CO2 reduction is restricted. The method comprises the following steps: 1, preparing 5, 5 '-(benzo [c] [1, 2, 5] thiadiazole-4, 7-diyl) bipyridine aldehyde; 2, preparing a pyridine tricarboxylate ionic liquid; 3, PTZpy is prepared; 4, preparing PTZpy (+); and 5, preparing the IL (at) PTZpy (+) nano catalytic material. The catalyst is applied to preparation of methane by photocatalytic reduction of carbon dioxide under visible light irradiation and a pure water system. The method has a good application prospect in the fields of solar fuel preparation and carbon resource conversion.