6115 results about "Ultraviolet lights" patented technology

The invention relates to a composite solid electrolyte membrane with high ceramic content and a preparation method and application thereof. The preparation method comprises the following steps: mixing ceramic solid electrolyte particles activated by a silane coupling agent with an in-situ polymerization solution containing a cross-linking agent, an organic monomer, a plasticizer, a lithium salt, an ultraviolet light initiator and a thermal initiator to form solid electrolyte slurry, wherein the ceramic solid electrolyte particles account for 60-90% of the total mass of the composite solid electrolyte membrane; the preparation method comprises the following steps: coating a positive pole piece with solid electrolyte slurry, initiating shallow organic matter monomers and a cross-linking agent to generate in-situ polymerization through an ultraviolet light initiator, covering a negative pole piece for hot pressing treatment, initiating residual organic matter monomers and the cross-linking agent to generate in-situ polymerization through a thermal initiator, and forming a composite electrolyte membrane with high ceramic content. The invention also discloses an all-solid-state battery containing the composite solid electrolyte membrane. The solid-state battery containing the in-situ formed composite solid-state electrolyte membrane has relatively high cycling stability.

The invention relates to the technical field of polyurethane films, in particular to a long-acting, stable, flexible, impact-resistant and resistance-reducing protective film and a preparation process thereof. According to the invention, the raw materials such as polyethylene glycol, a modified fluorosilicone monomer, isophorone diisocyanate, hydroxyethyl acrylate, an acrylic antifouling monomer, dodecafluoroheptyl methacrylate and the like are added to prepare the anti-drag coating. Mixing a polyurethane thermoplastic elastomer, aminopropyl polydimethylsiloxane, an antioxidant and an ultraviolet light absorber, and carrying out melt extrusion and blow molding to form a film, so as to obtain a flexible impact-resistant base film; and uniformly coating the surface of the flexible anti-impact base film with the anti-drag coating, and carrying out ultraviolet curing to obtain a finished product. The finished product prepared by the invention has good impact resistance, and can effectively reduce frictional resistance, so that the finished product has wide application prospects in the technical field of polyurethane films.

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

A kit for creating a miniature replica of a food or beverage item, the kit including a base object that forms a base of the miniature replica of the food or beverage item, the base object comprising a miniature replica of a component of the food or beverage item, a resin container storing a resin configured to be applied to the base object and to adhere to the base object, the resin container comprising a miniature replica of a container associated with the food or beverage item, and one or more ingredient objects configured to be at least partially embedded in the resin, the one or more ingredient objects comprising miniature replicas of one or more ingredients associated with the food or beverage item, the base object and the resin comprising complementary properties that enable the ultraviolet light to penetrate the resin and thereby cure the resin.

The invention provides a perovskite thin film and a preparation method thereof, and belongs to the technical field of perovskite thin films, and the preparation method comprises the following steps: S1, preparing modified octa (aminophenyl trioxosilane); s2, preparing a precursor solution; and S3, spin-coating the pretreated substrate with the precursor solution, dropwise adding ethyl acetate at the same time, performing illumination treatment under ultraviolet light, and then immediately performing micro-vibration and curing annealing on the substrate to obtain the perovskite thin film. According to the perovskite thin film obtained by the invention, the purposes of synchronously increasing the open-circuit voltage and the filling factor of a solar cell, improving the photoelectric conversion efficiency and enhancing the long-term stability can be achieved.

The invention relates to a polyethylene and silica gel mixed material, a preparation method thereof and application of the polyethylene and silica gel mixed material in a composite optical cable silicon core tube. The composite material comprises the following components in parts by weight: high-density polyethylene, an ethylene-siloxane copolymer elastomer, a maleic anhydride grafted polyolefin elastomer, hydroxylated nano silicon dioxide, liquid paraffin, a crystallization nucleating agent, an ultraviolet light absorber, an auxiliary stabilizer, a processing aid and color master batch. The liquid paraffin is formed by blending dual-molecular-weight paraffin with different carbon chain lengths, and part of the liquid paraffin is grafted and modified by polybutylene so as to enhance the anchoring capacity of the lubricating phase; in addition, nano cellulose crystals grafted by a PEG-PCL (Polyethylene Glycol-Polycaprolactone) block copolymer are introduced, so that the dimensional stability and the interface structure integrity of the material are synergistically enhanced. The composite material has excellent low friction, thermal oxidation stability, creep resistance and ultraviolet aging resistance, and is suitable for preparation of a high-performance composite optical cable silicon core tube.

The invention discloses a hydrogel patch for gastric perforation repair and a preparation method thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: dissolving acryloyl valine, acrylic acid, methylene bisacrylamide, a compound A and a photoinitiator in an alcohol solvent, and defoaming to obtain a precursor solution; and placing the precursor solution in a mold, carrying out ultraviolet-induced curing, soaking the obtained hydrogel in a hydrochloric acid solution, and replacing the alcohol solvent to obtain the hydrogel patch for gastric perforation repair. The hydrogel patch provided by the invention has the advantages of strong acid corrosion resistance, good biocompatibility, low swelling ratio, stable adhesion performance in a fluctuating pH environment and the like. The tough and stable adhesion performance ensures that the hydrogel can be permanently and reliably adhered to a gastric perforation part in a dynamic gastric acid environment, and a stable platform is provided for drug delivery, so that the surgical operation time is expected to be shortened, and wound healing is promoted.

The invention discloses a multi-scale synergistically enhanced self-healing solid polymer electrolyte and a preparation method thereof, and belongs to the technical field of electrolyte materials. The preparation method of the electrolyte comprises the following steps: S1, adding the eight-arm star polymer, the carborane lithium salt, the neutral plastic crystal additive, the ionic liquid monomer and the crown ether functionalized boron alkene two-dimensional filler into a mixed solvent to form electrolyte slurry; s2, uniformly coating a base material with the electrolyte slurry to form a wet film, and drying the wet film; s3, transferring the dried membrane to an environment filled with inert gas, and initiating in-situ polymerization of an ionic liquid monomer by using ultraviolet irradiation to form a polyionic liquid nanofiber network; and S4, placing the membrane under a vacuum condition at a constant temperature of 120 DEG C for 5 hours to obtain the solid polymer electrolyte membrane. The solid polymer electrolyte membrane provided by the invention overcomes the problems of low ionic conductivity, low lithium ion transference number, insufficient mechanical properties, poor interface stability, narrow electrochemical window and the like of the existing solid polymer electrolyte.

The invention discloses a photocuring 3D printing mechanism method for multi-material cooperative spraying, and relates to the field of cooperative control, and the photocuring 3D printing mechanism method comprises the following steps: layering a model, generating a material distribution map, and labeling a functional area and a transition area; a multi-nozzle array is used for accurately positioning and spraying according to the atlas; a gradual change path is planned in the transition area, and gradient change of material components is achieved through cooperative spraying; a partition curing strategy is adopted, ultraviolet light full curing and visible light semi-curing are adopted, and leveling is promoted in combination with micro-vibration; spraying a penetrating agent between layers to form a mechanical interlocking enhanced interface; based on visual online defect detection, printing parameters are fed back and adjusted in real time through a CNN model. The device and the method have the advantages that accurate mixing of multiple materials is realized through cooperative spraying of the multiple piezoelectric sprayers and gradual change path planning, and real-time defect detection and correction can be realized by matching with differentiated photocuring, high-frequency micro-vibration leveling and interlayer penetrating agent interlocking, so that high-precision multi-material functional component forming is efficiently completed.

The invention discloses a light-moisture dual-curing underwater epoxy coating with a self-repairing function as well as a preparation method and a construction method of the light-moisture dual-curing underwater epoxy coating. The epoxy coating comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (1.5-3.5): 1; the component A is prepared from the following raw materials: bisphenol F type epoxy resin, dynamic disulfide bond modified polysulfide rubber, boron nitride nanosheet and silicon carbide nanowire hybrid filler, a photoinitiator and a silane coupling agent; the component B is prepared from the following raw materials: moisture-cured polyether amine, a boric acid ester bond cross-linking agent and hydrophobic modified graphene oxide. According to the invention, a light-moisture dual-curing mechanism is adopted, ultraviolet irradiation initiates rapid surface curing, and then environmental moisture permeates to complete deep curing. The material provided by the invention has the advantages of rapid curing, excellent self-repairing function, significantly improved underwater adhesion and good thermal conductivity, and provides a new solution for rapid repairing and long-acting protection of underwater structures.

The invention relates to a multi-spectral diagnosis result credibility evaluation method. The method comprises the following steps: synchronously acquiring three-spectral images and environmental parameters of target equipment; the collected three-spectrum image is preprocessed; inputting the preprocessed image into the improved model to obtain a prediction probability distribution vector of fusion features and three-spectral-band branches; obtaining a prediction category and uncertainty entropy; carrying out confidence score calculation; judging whether to trigger a feedback condition; according to the method, the complementary characteristics of three spectrums of visible light, infrared light and ultraviolet light are utilized, and the CBAM attention module is introduced, so that key characteristics under different spectrums are enhanced, and the sensing ability of the model to an abnormal region is improved; the method achieves the prediction result confidence evaluation based on a Monte Carlo Dropout reasoning mechanism, effectively recognizes a low-confidence result, gives a diagnosis conclusion, can also evaluate the confidence, is suitable for deployment in key scenes such as a high-pressure valve hall, and facilitates the improvement of the overall safety and stability of a system.

The invention discloses a wafer quality analysis method based on image recognition, and particularly relates to the field of semiconductor manufacturing quality detection, which comprises the following steps: synchronously acquiring wafer two-dimensional images under visible light, infrared and ultraviolet spectrums through a multispectral and high-resolution fusion camera combination model; the structured light three-dimensional reconstruction technology is used for obtaining surface three-dimensional shape data, a self-adaptive noise suppression algorithm is applied, noise features are recognized through frequency domain analysis, filtering parameters are dynamically adjusted, targeted noise reduction is achieved, a multi-scale feature pyramid and quantum dot mark recognition fusion model is constructed, defect contours and material heterogeneous areas are extracted in a layered mode, and the defect detection precision is improved. The method comprises the following steps: extracting microstructure characteristic parameters by combining a quantum dot fluorescence labeling technology, mapping microscopic characteristics and three-dimensional shape data to a multi-modal space model, generating three-property parameters of a wafer, establishing a three-dimensional evaluation system, comprehensively judging a quality grade and outputting an analysis report, so that the precision and efficiency of wafer quality detection are remarkably improved.

The invention relates to the technical field of oil stain detection, and discloses an oil-filled equipment oil stain detection method based on fluorescence reflection. The method comprises the following steps: carrying out cleaning pretreatment on a to-be-detected surface; an ultraviolet light source is utilized to excite the oil stain to generate fluorescence; collecting a fluorescence image through an imaging device with a filter; performing noise reduction and edge processing on the image to extract an oil stain area; and finally judging the existence and type of oil stain and estimating the thickness according to image features. According to the invention, the fluorescence characteristic of the oil stain is utilized, no fluorescent agent needs to be added, and pollution-free, high-precision and high-efficiency non-contact detection is realized.

The invention relates to the technical field of transmission membranes, in particular to a transmission membrane based on dithienylethene and a preparation method of the transmission membrane. The transmission film comprises a base film and light-operated molecules, the base film is coated with the light-operated molecules, and the light-operated molecules have light response groups. A detection result shows that after ultraviolet irradiation, the transmission film can quickly realize complete conversion from an open loop to a closed loop; after visible light irradiation is recovered, the transmission film can efficiently and reversibly recover to an open-loop state. In addition, the transport membrane has a high on-off ratio to five ions of sodium, potassium, lithium, magnesium and calcium. The transmission membrane based on dithienylethene, which is prepared by taking terminal amino-modified dithienylethene as a basic unit, not only has abundant nano-channels, but also is endowed with the characteristic of regulating and controlling the opening and closing of the nano-pore by a photoresponse functional group, and the closing and opening of an ion channel can be accurately regulated and controlled through the alternate irradiation of ultraviolet light and visible light, so that the transmission membrane has a good application prospect. And the controllability of light-operated ion transmission is finally realized.

The invention provides a self-assembled hypha flexible carbon electrode material and a preparation method and application thereof, and belongs to the technical field of battery packs. The preparation method of the self-assembled hypha flexible carbon electrode material comprises the following steps: treating basswood with white rot fungus mycelia, crushing and roasting to obtain porous basswood / hypha composite carbon powder; and putting the porous basswood / hypha composite carbon powder and a carbon nanotube into a sterilized conical flask containing a potato glucose culture solution, inoculating gloeophyllum trabeum, performing activation culture, adding a dopamine hydrochloride aqueous solution, performing polymerization after ultraviolet irradiation, taking out and tabletting to obtain the self-assembled hypha flexible carbon electrode material. In the preparation process of the self-assembled hypha flexible carbon electrode material, the flexible carbon electrode material is synthesized by taking porous basswood / hypha composite carbon powder as a matrix, taking gloeophyllum trabeum hypha as an adhesive, taking polydopamine as a reinforcing agent and adding carbon nanotubes as a conductive reinforcing material, so that the technical problem of poor cycle performance of a lithium ion battery is solved.

The invention discloses a temperature and gas detection system and method based on an ultraviolet to near infrared spectrum, relates to the technical field of spectral measurement, and solves the technical problems that the space in a smelting furnace is occupied and the complexity of the system is increased due to the fact that two sets of independent equipment are adopted for temperature measurement and environment monitoring in the smelting process respectively in the prior art. The method comprises the following steps: acquiring spontaneous radiation light of a to-be-detected target; carrying out dispersive light splitting on the spontaneous radiation light to obtain spectral data of a full wave band from ultraviolet light to near-infrared light; performing denoising processing on the spectral data to obtain a spectrum of the to-be-detected target; obtaining temperature data according to the spectral analysis of the to-be-detected target; calculating based on the spectrum and a pre-established spectrum database to obtain gas concentration; the temperature of the to-be-measured target can be accurately measured, and the measurement accuracy is improved.

The invention discloses a hydroxyl-rich ruthenium / titanium dioxide catalyst as well as a preparation method and application thereof, and the preparation method comprises the following steps: step 1, loading a ruthenium precursor on a titanium dioxide carrier by adopting an impregnation method or a deposition-precipitation method, and drying and calcining to obtain a Ru / TiO2 catalyst; and step 2, placing the Ru / TiO2 catalyst in an atmosphere environment containing water vapor or forming a physical adsorption water film on the surface of the Ru / TiO2 catalyst, and performing ultraviolet irradiation treatment to obtain the Ru / TiO2 catalyst. According to the method, water is physically adsorbed through ultraviolet light dissociation, hydroxyl is directly generated on the surface of Ru / TiO2 in an in-situ mode, the method is easy to operate, complex liquid phase treatment is not needed, and the stability of the generated hydroxyl under the subsequent high-temperature gas-solid phase hydrogen-rich reaction condition is obviously superior to that of hydroxyl introduced through a traditional method. The stable hydroxyl enriched on the surface serves as an effective Lewis base site and cooperates with a Ru active site, adsorption and activation of CO2 molecules are remarkably promoted, and therefore the catalytic activity of the CO2 methanation reaction is greatly improved.

Techniques for computationally generating a faux-stain image of an unstained sample using intensity measurements of visible light and ultraviolet light through, or reflected by, the unstained sample. In some cases, the faux-stain image is provided as input to a trained deep neural network and an outcome prediction such as likelihood of metastasis is determined based on output of the trained deep neural network.

The nano titanium oxide main body photocatalytic sterilization multi-element material provided by the invention comprises 85%-98% of a nano titanium oxide material, 2%-15% of a perovskite material and a modifier, the modifier comprises silver, silver oxide and graphene, and the modifier comprises a nano titanium oxide main body and a nano titanium oxide main body. The nano titanium oxide main body photocatalytic sterilization multi-element material can fully utilize the characteristics of a perovskite structure material, overcomes the defects of a nano titanium oxide material, improves the light utilization rate, inhibits carrier recombination, improves the antibacterial durability, can utilize ultraviolet light to carry out catalytic sterilization and can also utilize ions to carry out sterilization, and the antibacterial effect is good. Sterilization can be achieved through the photolysis reaction of visible light, the synergistic composite sterilization effect is achieved, harmful germs are rapidly and effectively killed, the environment is kept fresh and safe, and the comprehensive sterilization and deodorization effect can be achieved by adding the modifier; the preparation method of the nano titanium oxide main body photocatalytic sterilization multi-element material provided by the invention is simple in steps, convenient to operate and easy to implement.

The invention belongs to the technical field of back contact cells, and particularly relates to a back contact cell with a specific front surface structure and a cell assembly thereof, and the specific front surface structure comprises a tunneling oxide layer and a specific doped amorphous silicon layer which are sequentially arranged on the front surface of a silicon substrate, a low-doped amorphous silicon layer, a high-doped amorphous silicon layer and an oxygen-doped amorphous silicon layer are sequentially arranged in the specific doped amorphous silicon layer along the direction far away from the tunneling oxide layer, and the specific doped amorphous silicon layer is doped with a P element and contains an H element; the P doping concentration C1 of the low-doping amorphous silicon layer and the P doping concentration C3 of the oxygen-doping amorphous silicon layer are respectively smaller than the P doping concentration C2 of the high-doping amorphous silicon layer, and the specific front structure enables the back contact cell to absorb incident light within 400 nm, and the highest absorptivity exceeds 85%. The back contact battery disclosed by the invention can still keep good performance after being exposed to ultraviolet rays for a long time, the UV reliability of the battery is improved, meanwhile, high light transmittance is realized, and relatively high battery efficiency is also realized.

The invention belongs to the technical field of deep eutectic gel wave-absorbing materials, and particularly relates to a preparation method of sodium alginate modified deep eutectic gel with wave-absorbing and strain-sensing functions, which comprises the following steps: mixing sodium alginate with deionized water, mechanically stirring for the first time to form gel A, adding a certain amount of acrylamide, mechanically stirring for the second time to form gel B, and stirring for the second time to form gel B; adding a certain amount of deep eutectic solution, mechanically stirring for the third time, performing ultrasonic vibration, vacuumizing to form gel C, and finally performing ultraviolet curing treatment on the gel C to obtain sodium alginate modified deep eutectic gel; according to the preparation method, complex equipment is not needed, the preparation period is short, the sodium alginate modified deep eutectic gel is added into deep eutectic solutions with different contents, the real part and imaginary part of the dielectric constant of the material are accurately controlled, the characteristic impedance is close to the free space impedance, meanwhile, the ion conduction efficiency is guaranteed, and optimization of wave absorption and sensing is achieved.

The invention discloses a low-temperature curing high-throwing-power cathode electrophoretic coating and a preparation method and application thereof, and belongs to the field of automobile coating materials, the coating is composed of epoxy resin, a fluorosilicone copolymerization type epoxy modifier, a polyamino siloxane-acrylic acid hybrid and other components, and performance improvement is achieved through the synergistic effect of the two brand-new modifiers. Wherein the fluorine-silicon copolymerization type epoxy modifier is prepared by taking bisphenol A epoxy resin as a framework, introducing fluorine-containing alkyl and siloxane groups and carrying out ultraviolet reaction, so that the surface energy is reduced, and low-temperature crosslinking is promoted; the polyamido siloxane-acrylic acid hybrid takes siloxane as a core, and acrylic acid and polyamido are bridged through isocyanate, so that the crosslinking density and the water solubility are enhanced. When the coating is prepared, the two modifiers are mixed with epoxy resin, a solvent and the like, and the coating is prepared through dispersion and dilution. The coating can be cured at low temperature, so that a uniform thick film is obtained in an inner cavity of a complex workpiece, and meanwhile, the coating has excellent corrosion resistance and adhesive force and is suitable for efficient and environment-friendly coating of an automobile body and parts.

The invention relates to the technical field of printing equipment, in particular to a printing ink drying device for anti-counterfeiting stained paper, which comprises a rack, a conveying mechanism is arranged above the rack, a drying box body is arranged above the conveying mechanism, and the drying box body is sequentially divided into a leveling preheating area, a main curing area and a forced cooling area along the conveying direction; the conveying mechanism comprises a high-temperature-resistant conveying mesh belt and a vacuum adsorption platform arranged below the mesh belt; an LED-UV cold light source assembly is arranged in the main curing area, infrared heating pipes transversely arranged in the leveling preheating area and a reflecting cover above the infrared heating pipes are matched with the LED-UV cold light source assembly with a water-cooling circulation flow channel in the main curing area and an external cooling-water machine, and printing ink is evenly heated through infrared radiation to be leveled firstly; curing is completed through low-temperature ultraviolet light, a light source is cooled synchronously in a circulating mode, the effects of ink flat curing and paper low-heat deformation are achieved synchronously, and high-speed continuous operation is effectively supported.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention relates to conductive silk fibroin loaded methacrylated gelatin hydrogel and a preparation method thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: S1, adding silk fibroin fibers into a dopamine hydrochloride solution, stirring, standing, then adjusting the pH value to 8-9, and carrying out a heating reaction to obtain polydopamine grafted silk fibroin fibers; s2, sequentially dipping the polydopamine grafted silk fibroin fibers in an ammonium persulfate solution and a pyrrole solution to obtain conductive silk fibroin fibers; and S3, adding the conductive silk fibroin fibers into the methacrylated gelatin solution, carrying out ultraviolet light cross-linking curing, and then soaking the conductive silk fibroin fibers in a glycerol solution to obtain the conductive silk fibroin loaded methacrylated gelatin hydrogel. The method not only can ensure the structural integrity and conductive continuity of a conductive network in the hydrogel, but also breaks through the dependence of in-situ polymerization on the permeability of a matrix.

The invention relates to the technical field of biomass fibers, in particular to a modified biomass fiber for a resin anticorrosive coating as well as a preparation method and application of the modified biomass fiber, and the modified biomass fiber is a biomass fiber with a rare earth complex anchored on the surface; the rare earth complex is formed by combining rare earth metal ions serving as central ions with organic ligands through coordinate bonds; rare earth ions and organic ligands are grafted to the surfaces of the pretreated biomass fibers through chemical reaction, so that the binding capacity of the biomass fibers in resin can be improved, and the biomass fibers are endowed with fluorescence characteristics; and moreover, the biomass fibers subjected to fluorescence modification are doped into the resin coating, so that the integrity of the coating can be self-detected under ultraviolet light, and the effect of monitoring the resin coating in real time can be achieved.

The invention discloses an ultra-flexible stretchable dimming film and a preparation method thereof, and relates to the technical field of dimming films, and the ultra-flexible stretchable dimming film comprises an upper transparent electrode layer, a dimming function layer and a lower transparent electrode layer which are sequentially stacked from top to bottom; the preparation method comprises the following steps: 1) preparing a main matrix material / ultraviolet curing resin mixture; 2) assembling the dimming film; and 3) ultraviolet light curing. According to the invention, through surface phosphonic acid functionalization treatment, covalent bond anchoring of cerium oxide nanoparticles is realized on a thermoplastic polyurethane fiber network; by constructing a full-thermoplastic polyurethane material system, the breakthrough of interfacial compatibility between a fiber reinforced phase and a polymer matrix is realized, so that the film has high tensile strain capacity and excellent fatigue resistance on the premise of keeping high transparency.

The invention belongs to the technical field of polymer electrolyte membrane materials, and particularly relates to a high-ionic-conductivity polymer electrolyte membrane and a preparation method thereof.The preparation method comprises the steps that 1, PEO and lithium salt are added into a polar aprotic solvent, and the mixture is rapidly and violently stirred to be completely dissolved; (2) adding a cross-linking agent and a photoinitiator into the mixed solution, and violently stirring to obtain a mixed solution; and (3) coating the mixed solution in a polytetrafluoroethylene template, heating to remove the solvent, and performing ultraviolet radiation. According to the invention, a three-dimensional cross-linked network is formed by photocuring of an acrylate group of the cross-linking agent, PEO chain segment crystallization is inhibited, and lithium salt anions (such as TFSI-) are physically embedded. A benzene ring structure in a cross-linked network endows the electrolyte membrane with flexibility, mechanical property deterioration caused by a plasticizer or a diluent is avoided, the compact structure of the electrolyte membrane can inhibit lithium dendrite growth, the ionic conductivity reaches 1.7 * 10 <-4 > S / cm, and the electrochemical window reaches 4.9 V. The method is simple in process and suitable for large-scale preparation of the high-energy-density solid-state lithium battery.

The invention belongs to the technical field of power cables, and particularly relates to an anti-bending flexible cable and a preparation method thereof.The cable sequentially comprises a conductor, an insulating layer, a buffer layer, a shielding layer and a protective layer from inside to outside, the insulating layer is divided into an inner layer, a middle layer and an outer layer in the radial direction, and the inner layer of the insulating layer comprises the following components in parts by weight; 100 parts of crosslinked polyethylene, 6-10 parts of amino-modified photoresponse graphene quantum dots, and 2-4 parts of a plasticizer DOS; 2-3 parts of amino modified photoresponse graphene quantum dots, 100 parts of crosslinked polyethylene and 2-4 parts of a plasticizer DOS; the protective layer comprises the following components in parts by weight; the insulation layer comprises 100 parts of shape memory polyurethane, 15-22 parts of composite microspheres and 0.5-1.0 part of a light stabilizer, and the insulation layer adopts a cross-linked polyethylene, amino modified light response graphene quantum dot gradient distribution and plasticizer system; and three-channel co-extrusion and three-section type ultraviolet curing are matched, so that inner layer under-crosslinking / outer layer over-crosslinking is avoided.

The invention discloses a light conversion film based on a benzotriazole compound as well as a preparation method and application of the light conversion film. The benzotriazole compound is a compound as shown in a formula I, and the definition of each group in the formula I is described in the specification. According to the invention, cyano modification is carried out on the benzotriazole compound used as the light conversion agent, so that the transmission of ultraviolet light is further reduced, the external quantum efficiency response of the heterojunction cell is improved, and the power of the assembly is improved.