1106 results about "Light excitation" patented technology

The invention relates to the technical field of power equipment state monitoring, in particular to an oil-immersed transformer distributed temperature measurement method based on a fluorescent optical fiber sensor, and the method comprises the steps: arranging the fluorescent optical fiber sensor in a key temperature rise region in a transformer in a partitioned and layered three-dimensional topological structure, and forming a distributed temperature measurement network; exciting light is injected through a pulse laser to excite a fluorescence signal; a dual-channel phase-locked amplification technology is used to collect signals, and a dual-weight adaptive attenuation model and an oil flow coupling compensation function are combined to demodulate the temperature; reconstructing a dynamic temperature field based on a three-dimensional thermodynamic inversion algorithm, and marking high-gradient hot spots; and temperature, load current and oil flow velocity data are fused to realize graded alarm. According to the invention, the limitation of traditional single-point monitoring is broken through, the strong electromagnetic interference resistance is excellent, a global temperature field can be accurately reconstructed, dynamic early warning is realized, and the operation safety and the operation and maintenance efficiency of the transformer are remarkably improved.

The invention discloses an on-line detection method for gas in transformer oil based on photoacoustic spectrum self-correction, and relates to the technical field of spectrum detection and power equipment state monitoring, and the method comprises the following steps: S1, emitting modulation laser with a specific wavelength to a gas sample released by the transformer oil through a laser, and exciting gas molecules to generate photoacoustic signals; and S2, detecting the photoacoustic signal by using a photoacoustic sensor, converting the signal into an electric signal, and outputting the electric signal. According to the online detection method for the gas in the transformer oil, the correction coefficient is adjusted in real time through a self-correction algorithm, errors caused by light path changes and sensor aging are effectively compensated, the precision and stability of long-term detection are remarkably improved, and the detection accuracy is improved by combining a gas spectrum database and a mode recognition algorithm. According to the method, accurate qualitative and quantitative analysis of various gases is realized, the problem of cross sensitivity of multiple components is solved, and the method also has temperature and pressure compensation functions and can automatically adapt to environmental changes.

The invention belongs to the technical field of novel fluorescent materials, and particularly discloses application of a mechanical color change pyrenyl derivative in latent fingerprint fluorescence imaging and extraction. The mechanical color-changing pyrenyl derivative can be selectively combined with fingerprint residual substances under the excitation of ultraviolet light through the unique fluorescence response characteristic, so that potential fingerprints form high-contrast fluorescence imaging on smooth or rough surfaces (such as glass, metal, plastic and the like), and the mechanical color-changing pyrenyl derivative is compatible with conventional camera equipment to realize rapid acquisition. The compound design is based on a modular synthesis route, and has the advantages of simple and convenient synthesis process, controllable raw material cost, high reaction yield and the like. The product has excellent thermal stability and chemical stability, can be stored at normal temperature and does not need special treatment, and the practical application threshold is greatly reduced. Compared with a traditional fingerprint developing technology, the method has remarkable breakthroughs in the aspects of sensitivity, substrate adaptability and operation convenience, and an efficient, economical and environment-friendly novel solution is provided for the fields of criminal investigation, forensic identification and the like.

Provided are a fault diagnosis apparatus and method based on fluorescence multivariate correction analysis of transformer oil, relating to the field of transformer fault diagnosis technology. Thus, the problem of large volume and weight of the apparatus, high costs, and inconvenience to use caused when in the related art, a fluorescence spectrometer is directly used to acquire the fluorescence spectrum of transformer oil is solved. The monochromatic excitation light of an optimal excitation wavelength generated by a fluorescence excitation source is used to excite the transformer oil in a fluorescence excitation detection apparatus to generate fluorescence. The fluorescence excitation detection apparatus generates the fluorescence according to the input monochromatic excitation light and inputs the fluorescence to a fluorescence signal acquisition and analysis apparatus. Since the fluorescence signal acquisition and analysis apparatus acquires and analyzes the fluorescence signal emitted by the transformer oil by using a multivariate correction filter group, the emission monochromator component of the fluorescence spectrometer is replaced. In this manner, the equipment costs and the equipment volume are reduced, and data processing is rapid. Thus, the cost performance of the fault detection of the transformer oil is improved, thereby implementing the engineering application of the fluorescence monitoring technology in the online diagnosis of the transformer failure.

The invention is suitable for the technical field of inorganic luminescent materials, and provides a fluorescent powder material based on a double-perovskite structure and a preparation method and application thereof. The general chemical formula of the fluorescent powder is Ca2AlNbO6: xEu < 3 + >, wherein x is a molar fraction of 0.06 to 0.30; the excitation spectrum coverage range of the fluorescent powder under the condition of monitoring the emission wavelength of 615 nm is 260-500 nm, and the emission main peak is located at 615 nm; when x is equal to 0.18, the quantum efficiency under the excitation of 396nm ultraviolet light is greater than or equal to 91%, and the red light emission ratio is greater than or equal to 85%. According to the invention, Ca2AlNbO6 double perovskite is taken as a substrate, and a red fluorescent powder material with wide-spectrum excitation and high quantum efficiency is designed through Eu < 3 + > high-concentration doping and local symmetry regulation and control design engineering, so that the characteristics of high quantum efficiency, efficient red light emission, wide-spectrum excitation and excellent concentration quenching resistance are realized.

The invention relates to the technical field of industrial wastewater deep purification, and discloses an industrial wastewater deep purification system based on nano catalytic membrane separation, which comprises a pretreatment module, a catalytic degradation module, a membrane separation module, an intelligent control module and a regeneration maintenance module which are sequentially connected according to a treatment flow, the pretreatment module adjusts the water quality of inlet water to a range suitable for subsequent treatment through pH adjustment and suspended matter interception, that is, the pH is 2-11, and the turbidity is less than or equal to 50NTU; the catalytic degradation module is used for decomposing organic pollutants and mineralizing refractory substances under the excitation of ultraviolet / visible light by utilizing the photocatalytic characteristic of a nano catalytic membrane. The TiO2 / WO3 heterojunction nano catalytic membrane is adopted, so that deep oxidation of refractory pollutants such as phenol and sulfonamide antibiotics is realized, finally, the COD removal rate of 98.7% is achieved, and compared with a traditional photocatalytic process, the energy consumption is reduced by 54%.

The invention provides a preparation method of rare earth ion heavily-doped luminescent glass and application of a light source. The rare earth ion heavily-doped luminescent glass comprises the following components in percentage by mass: 50-68% of black talcum powder, 10-25% of LiF, 10-25% of NaF, 10-25% of CaF2, an externally-doped rare earth compound accounting for 15-25% of the total mass of other raw materials (black talcum powder + LiF + NaF + CaF2), and an externally-doped clarifying agent accounting for 0.5-2% of the total mass of other raw materials (black talcum powder + LiF + NaF + CaF2). The preparation raw materials of the luminescent glass are easy to obtain and low in price, the process is simple, and industrial production is easy; the emission peak of the obtained rare earth doped luminescent glass under the excitation of purple light / ultraviolet light is 450-750 nm, the internal quantum efficiency is greater than or equal to 85%, and the luminous intensity at 150 DEG C is more than 85% of the luminous intensity at room temperature. A light source packaged by the prepared luminescent glass has the characteristics of warm white light output, low color temperature (CCTlt, 4500K), high color rendering index (CRIGt, 90) and high lumen efficiency (LEgt, 851m / W).

The invention discloses an infrared photothermal imaging system and method in structured light illumination fluorescence detection, and belongs to the field of super-resolution imaging. The system comprises a structured light generation module, a fluorescence excitation module, a fluorescence collection module and a mid-infrared light thermal module. The structured light generation module generates structured light with adjustable phase and direction; the fluorescence excitation module inputs the structured light to a to-be-analyzed sample and excites the sample to emit fluorescence; meanwhile, infrared pulse laser can be input into a sample by utilizing a mid-infrared photothermal module, and the fluorescence intensity is modulated by utilizing a photothermal effect; finally, fluorescent light emitted by the sample is collected by a fluorescent light collecting module, and an infrared photothermal image in structured light illumination is obtained. The system breaks through the diffraction limit, the resolution ratio is increased by two times at most, the intrinsic infrared spectrum of the sample is obtained through mid-infrared photothermal imaging, and the chemical components and the structure of the sample are reflected. According to the invention, two technologies are combined, so that the intrinsic infrared spectrum information of the sample is provided under the sub-diffraction limit.

The invention belongs to the technical field of optical devices, and provides a single photon avalanche diode array, a receiving sensor and a laser radar, at least two SPAD units are arranged in an array, a microlens converges incident light to the corresponding SPAD unit, a back metal grid connects the SPAD unit and a corresponding external electrode, a first dielectric layer is arranged between the microlens and the SPAD unit, and a second dielectric layer is arranged between the microlens and the SPAD unit. The second dielectric layer is arranged between the SPAD units and the front metal wiring layer, and the front metal wiring layer is electrically connected with the corresponding SPAD units through contact metal wires. The deep groove isolation columns are arranged between the adjacent SPAD units, and the metal filling structures are arranged between the deep groove isolation columns and the back metal grids, so that self-excitation photons generated when the SPAD units are excited by incident light can be isolated, the self-excitation photons are prevented from entering the adjacent SPAD units through grid gaps, the probability of photon crosstalk is reduced, and the optical crosstalk of the device is reduced.

The invention discloses a long-life phosphorescent sulfur quantum dot, a multicolor long-life phosphorescent sulfur quantum dot composition and a preparation method and application thereof, and belongs to the technical field of phosphorescent materials and information encryption. The preparation method comprises the following steps: carrying out solvothermal reaction on a sulfur source and ethylenediamine to obtain sulfur quantum dots, and adding a sulfur quantum dot aqueous solution into a boric acid matrix to react to prepare long-life phosphorescent sulfur quantum dots (SQDs-MA); the long-life phosphorescent sulfur quantum dots and a rhodamine B aqueous solution are blended and dried to prepare the multicolor long-life phosphorescent sulfur quantum dot composition (RhB / SQDs-MA). When excited by ultraviolet light, the SQDs-MA shows a wide absorption range of 200 to 700 nm. When excitation is carried out at 362 nm, the SQDs-MA shows a blue fluorescence emission peak at 436 nm. The SQDs-MA powder emits bright green phosphorescence after the irradiation of an ultraviolet lamp is turned off, and under the optimal excitation of 373 nm, the maximum phosphorescence emission value is displayed at 526 nm. Under the irradiation of ultraviolet light, the RhB / SQDs-MA can emit yellow, orange and red phosphorescence at the wavelength of 584 nm, 600 nm and 620 nm.

The invention relates to a red fluorescent material excited by blue light, an LED device and fluorescent ceramic. The chemical formula of the red fluorescent material is La (2-x) MgNbO6.5: xEu < 3 + >, wherein x is more than or equal to 0.01 and less than or equal to 0.1. The preparation method comprises the following steps: weighing lanthanum oxide, magnesium oxide, niobium oxide and europium oxide raw materials according to a stoichiometric ratio, grinding and uniformly mixing; sintering the uniformly mixed powder in a muffle furnace at high temperature, and cooling to room temperature to obtain the red fluorescent material. Compared with the prior art, the novel oxide-based red fluorescent powder prepared by the invention can emit positive red light of which the central wavelength is 616nm under the excitation of 465nm blue light, and can be used for white light LED (Light Emitting Diode) luminescent devices and fluorescent ceramics.

The invention provides rare earth doped fluorescent powder capable of emitting light through polychromatic light excitation and thermal excitation and a preparation method and application of the rare earth doped fluorescent powder. The fluorescent powder comprises rare earth doped fluoride, the chemical formula of the rare earth doped fluoride is Cs2NaLnF6: xRe < 3 + >, wherein Ln represents a rare earth element, Re < 3 + > represents a doped rare earth ion, and Ln and Re < 3 + > are respectively selected from different rare earth elements; x is the doping amount of Re in each mole of rare earth doped fluoride, 0 lt; xlt; and 100 mmol%. According to the invention, the advantages of wide band gap and appropriate fluorine vacancy trap of the Cs2NaLnF6 material are utilized, and the trap distribution and luminescence performance of the material can be effectively regulated and controlled by doping different types of rare earth ions with different concentrations and contents; polychromatic light excitation and thermal excitation luminescence of one or more rare earth ions under different doping concentrations are realized, and the application potential is high. The Cs2NaLnF6 fluorescent powder composite film material disclosed by the invention is excellent in flexibility, good in water resistance, high in stability and simple in preparation process, and has a great application prospect in the fields of information storage, encryption, counterfeiting prevention and the like.

Integrated target waveguide devices and optical analytical systems comprising such devices are provided. The target devices include an optical coupler that is optically coupled to an integrated waveguide and that is configured to receive optical input from an optical source through free space, particularly through a low numerical aperture interface. The devices and systems are useful in the analysis of highly multiplexed optical reactions in large numbers at high densities, including biochemical reactions, such as nucleic acid sequencing reactions. The devices provide for the efficient and reliable coupling of optical excitation energy from an optical source to the optical reactions. Optical signals emitted from the reactions can thus be measured with high sensitivity and discrimination. The devices and systems are well suited for miniaturization and high throughput.

The invention relates to the technical field of medical materials, and discloses a photosensitive material with a vascular repair function, a preparation method of the photosensitive material and a balloon dilatation catheter. A chemical structural formula of the photosensitive material comprises a first functional group and a second functional group, the first functional group has a function of triggering amino acid in a blood vessel wall to be crosslinked under light excitation, and the second functional group has a function of inhibiting cell proliferation. The photosensitive material provided by the invention has good fat solubility, can accurately anchor a diseased region, exerts a vascular repair function, also can exert an anti-cell proliferation effect together, and further reduces the risk of intravascular restenosis.

The invention discloses a light-emitting super-structure surface capable of realizing incoherent fluorescence holography and multi-dimensional super-structure display and a preparation method thereof. The light-emitting super-structure surface is mainly composed of an optical waveguide structure layer, a micro-nano structure layer and a fluorescence emission layer. The optical waveguide structure layer comprises a substrate and a waveguide layer and is responsible for guiding fluorescence propagation; the micro-nano structure layer is located above the waveguide layer, is composed of nano bricks and can regulate and control light; the fluorescence emission layer is arranged above the micro-nano structure layer, contains quantum dots and is excited by the pump light to emit fluorescence. The metasurface can regulate and control the emergent angle, wavefront and emergent intensity of fluorescent light and pump light, the time-space coherence of the fluorescent light is enhanced through the waveguide layer, and phase modulation is carried out by using a method based on a circuitous phase. Based on the super-structure surface, through the steps of fluorescence excitation, coherence enhancement, phase modulation, diffraction calculation, hologram generation, multi-dimensional display and the like, incoherent fluorescence hologram and multi-dimensional super-structure display can be achieved, and the functions of fluorescence nanometer printing and multi-channel holographic display are covered.

The invention relates to a purple-light-excited blue-light fluorescent material for a sunlight-like LED (light-emitting diode) as well as a preparation method and application of the blue-light fluorescent material. The chemical expression of the fluorescent material is Ca2LuZr2Al1. 5Ga1. 5O12: xCe < 3 + >, wherein x is more than or equal to 0.02 and less than or equal to 0.07. The blue light fluorescent material for the purple light excitation type sunlight LED is a brand new and unreported purple light excitation Ce < 3 + > doped oxide blue light emission fluorescent material, the fluorescent powder has a wide excitation band, the effective absorption range covers 300-450 nm, the fluorescent powder can be excited by purple light, and blue light with the central wavelength being 485 nm is emitted. The fluorescent powder has the advantage of stable physical and chemical properties, can be prepared by adopting a conventional solid-phase reaction method, has the characteristics of simple preparation process and facilitation of industrial production, and can be used as a good candidate material for wide application of a next-generation full-spectrum illumination white light LED (light-emitting diode). The fluorescent powder can be completely and well matched with the existing purple light chip, meets the commercial market requirements, and is suitable for application of white light LEDs, sunlight-like LEDs, full-spectrum LEDs and the like.

The present invention combines a fluorescence sensor with an array to provide a fluorescence sensing array detection platform and a detection method for multiple plasticizers. The fluorescence sensing array detection platform includes a B-doped graphene quantum dot solution using N,N-dimethylformamide as a solvent and a B-GQDs solution using cyclohexane as a solvent; the fluorescence intensity of the B-GQDs solution with DMF as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 391 nm, 413 nm, and 434 nm are used as array points 1, 2, and 3; the fluorescence intensity of the B-GQDs solution with CH as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 386 nm, 408 nm, and 430 nm are used as array points 4, 5, and 6; thus, a 3×2 fluorescence sensor array is constructed. The detection method using the fluorescence sensor array of the present invention has simple steps, and has satisfactory specificity, reproducibility, stability and practicability, and has application potential.

The invention relates to a method for detecting a marine corrosion primary process, which comprises the following steps of: constructing three vacuum chambers and connecting the three vacuum chambers by using vacuum pipelines to form a detection system; ultrafast femtosecond laser with the repetition frequency being 1 kHz, the single pulse energy being 6 mJ, the pulse width being 35 fs and the central wavelength being 800 nm is generated through a pulse amplifier; one beam of 2mJ enters a vacuum chamber pipeline to be transmitted as a pulse light beam for detection in the original process of ocean corrosion, the other beam of 4mJ is transmitted outside the vacuum chamber to be used as a pump pulse light beam, and 400 nm pump pulse laser is generated through frequency doubling of a BBO crystal; the pump light beam and the detection light beam are incident on a sample of a sample mechanism in the third vacuum chamber, then the pump light beam is blocked, and only the detection light beam is incident on the sample; xUV light beams reflected from the sample are subjected to spectral dispersion and then enter a CCD detector, and the dynamic response of the sample after being excited by the pump light is monitored by measuring the transmissivity, reflectivity or absorption change of the surface of the sample.

The invention discloses a high-resolution semiconductor surface and interior flaw detection method and device based on a multi-photon nonlinear fluorescence effect, and relates to nonlinear optics and optical imaging semiconductor detection. The short-wave infrared light penetrates through a semiconductor to be detected, a surface or an internal defect to trigger scattering, the transmittance / reflectivity and the power are changed, the thin film containing the high-order nonlinear fluorescent nanoparticles is excited, the luminance generates magnitude order change, and the defect detection contrast ratio and the imaging resolution ratio are improved. Full-automatic control is achieved through an FPGA and LabVIEW, sub-images are automatically collected and spliced, and gray scale abnormal areas are analyzed to judge defect types and distribution. The optical imaging device comprises an exciting light generation module, a sample scanning module, a nonlinear fluorescent film imaging module and an intelligent control analysis module, realizes short-wave infrared light excitation and visible light-near infrared detection, and has the advantages of intelligence, high resolution, low cost and large-area full-automatic flaw detection. The method is suitable for large-scale semiconductor efficient flaw detection, gets rid of dependence on an infrared imaging camera, and reduces system cost.

The invention relates to an optical time domain reflectometer, a signal generation method and device, equipment and a medium. The optical time domain reflectometer comprises a laser, a first optical switch, an EDFA amplifier and a second optical switch which are connected in sequence. The optical switch time sequence control unit controls the first optical switch and the second optical switch to be periodically turned on and turned off so as to form a periodic optical pulse signal; wherein the second optical switch is turned on and turned off in a delayed manner relative to the first optical switch in a period, and the pulse width of the required optical pulse can be generated by controlling the delayed turn-on and the delayed turn-off; when a current period optical signal is normally output, the signal light is amplified by erbium ions excited by the pump light of the EDFA amplifier; if input light is cut off, erbium ions in a metastable state are still continuously gathered to a saturation state, signal light input is recovered in the next period, energy jump is generated, light surge is caused, output light power is instantly increased, and a pulse peak value is increased, so that the dynamic range of the optical time domain reflectometer is improved, and detection of the hollow-core optical fiber is realized.

The utility model relates to a photoluminescence-based silicon wafer subfissure detection device, which comprises a conveying streamline, a laser excitation mechanism and an infrared camera mechanism, the laser excitation mechanism comprises a mounting bracket and a laser excitation assembly mounted on the mounting bracket, and the infrared camera mechanism is mounted on the mounting bracket and positioned above the laser excitation assembly; the two ends of the laser excitation assembly are rotationally connected with the mounting support through light source fixing arms. The laser excitation assembly is rotationally connected with the mounting bracket through a light source fixing arm, so that a laser light source on the laser excitation assembly can swing around an X axis to adjust a light source illumination angle, and the light source adjustment only has one adjustment variable to simplify the imaging adjustment work; meanwhile, based on the photoluminescence principle, the laser excitation assembly emits laser with specific wavelength to serve as an excitation light source, the infrared camera mechanism carries out light sensing and imaging, whether the sample wafer has the hidden crack defect or not is judged, imaging is easier, and defect parameter detection is reliable and accurate.

The invention provides a light-excited lateral flow immunosensor reagent strip, a detection analysis method and application of the light-excited lateral flow immunosensor reagent strip. The reagent strip comprises an electrode substrate, a combination pad, a sample pad layer, a chromatography membrane and a water absorption pad, and the sample pad layer, the combination pad, the chromatography membrane and the water absorption pad of the reagent strip are connected end to end and are sequentially overlapped and pasted on the electrode substrate. The light-excited lateral flow immunosensor reagent strip is applied to quantitative analysis of various disease markers in biological fluids such as blood, saliva, cerebrospinal fluid or urine.

The invention relates to a fluorescent probe for detecting negative electrode lithium precipitation in a lithium ion battery and a detection method, and belongs to the technical field of lithium ion batteries. The fluorescent probe comprises a complex formed by coordination combination of 8-hydroxyquinoline-5-sulfonic acid and metal ions, the complex emits fluorescence under excitation of ultraviolet light, and the standard electrode potential of a metal simple substance corresponding to the metal ions is higher than that of lithium. The fluorescent probe can rapidly, simply and sensitively realize qualitative and quantitative detection of negative electrode lithium precipitation, and compared with large-scale instruments and visual inspection, the fluorescent probe can effectively simplify operation, reduce cost and improve detection efficiency and accuracy, meanwhile, a battery does not need to be disassembled under the condition of full charge, and detection safety is improved.

The present invention includes methods for reducing photoexcitation of a photoswitchable photoinitiator in volumetric printing including a volume of a photohardenable composition at locations in the volume at which intersection of two wavelengths does not occur; methods of three-dimensional (3D) printing including dual-wavelength photoexcitation of a photohardenable composition included in a volume, the method including photoexcitation by a modified or controllably-sized light sheet including a first wavelength and an optical projection including a second wavelength; and methods for extending the reuse-printing lifetime of a photohardenable composition including a photoswitchable photoinitiator. Preferably the photohardenable composition includes the dual-wavelength photoinitiator and a photohardenable resin component. The present invention also includes a photohardenable composition including a photoswitchable photoinitiator with an improved reuse-printing lifetime.

The invention discloses a femtosecond pulse laser modulation-based GaN-based micro light-emitting diode test system, which comprises a femtosecond pulse laser excitation module, a first detection light path, a to-be-tested GaN-based micro light-emitting diode, a photovoltage detection and bias control module, a photoluminescence detection module and a control module, the control module is configured to control the excitation power and the external bias voltage of the femtosecond pulse laser excitation module, and synchronously collect a photoluminescence spectrum signal and a photovoltage signal; according to the excitation power, the external bias voltage, the photoluminescence spectrum signal and the photovoltage signal, the competition relation between carrier drift extraction and local radiation recombination under different bias electric field conditions is obtained, and therefore an experimental basis is provided for structural design and working bias optimization of the GaN-based micro light-emitting diode device to be tested.

The invention discloses an oil film test method based on micron-thickness fluorescent paint, and belongs to the technical field of oil film tests.The high-brightness fluorescent paint with the thickness of 5-10 microns is sprayed on the surface of a fluorescent oil film test model, the surface characteristics of the model are kept, the fluorescence intensity excited by ultraviolet light and the oil film image acquisition frequency are improved, the application conditions of an optical flow method are met, and the oil film test method has the advantages of being high in practicability and easy to popularize. The precision of the oil film movement speed is ensured; a nano light-absorbing material with good intersolubility with oil is dissolved into an oil film in an unsaturated manner, and monotonous phenomena that the oil film thickness is smaller when an oil film image is brighter and the oil film thickness is thicker when the oil film image is darker are generated on the surface of an experimental model, so that the technical problem of fluorescent molecule precipitation of a micron-thickness oil film is solved; and the measurement accuracy of the thickness of the thin oil film based on the fluorescence intensity is improved. And compared with the existing fluorescent oil film test, the device has higher fluorescent oil film movement speed, oil film thickness and friction resistance measurement accuracy.

The invention relates to a radiation contamination simulation detection equipment control method based on an ultraviolet fluorescence signal, which is applied to radiation contamination simulation detection equipment, and the equipment comprises a detection probe. The method comprises the steps that a fluorescence intensity original signal and an ambient light interference signal of a target area are collected, the distance between a detection probe and a target surface is obtained, a fluorescence simulation agent is sprayed on the target area and irradiated by an ultraviolet LED lamp, and the simulation agent is used for emitting fluorescence with the wavelength larger than 450 nm under excitation of ultraviolet light; based on the distance and the ambient light interference signal, performing coupling compensation on the fluorescence intensity original signal; and calculating a radiation simulation value according to the calibration fluorescence intensity signal, and outputting information such as the radiation simulation value, the safety level and the component type. According to the method, through non-radiation simulation agent replacement, signal calibration and multi-dimensional analysis technical means, the safety of radiation detection training is improved, the health threat of a real radioactive source to trainees is eliminated, and the accuracy and the information amount of a detection result are remarkably improved.

The invention discloses a fluorescent cone embedded hexagonal array composite structure fluorescent ceramic as well as a preparation method and application thereof. According to the composite structure fluorescent ceramic, ceramic with the component being T serves as a base body, cone fluorescent ceramic units which are arranged in order are constructed in the base body through the combination of the gel technology and the photocuring 3D printing technology, and finally the fluorescent cone embedded hexagonal array composite structure fluorescent ceramic is formed. The problem of light spot expansion of the fluorescent ceramic is effectively solved by accurately regulating and controlling the matching relationship between the size of the conical bottom surface and the incident laser light spot and utilizing the synergistic effect generated by the optical characteristic difference between the ceramic matrix and the fluorescent ceramic. In addition, a three-dimensional efficient heat conduction network is formed between the ceramic matrix and the fluorescent ceramic, and heat accumulated under excitation of high-power-density laser can be quickly dissipated. The composite structure fluorescent ceramic with the fluorescent cone embedded into the hexagonal array can realize high-collimation, high-efficiency and high-brightness luminescence, and can be widely applied to the fields of laser illumination and display after being packaged with a laser excitation source.

The invention discloses novel dual-emission dissimilar metal MOFs, the chemical formula of which is [Eu2 (na) 6 (CH3OH) 2 (Cu4I4)], and na-is a nicotinic acid radical ion. The MOFs have two secondary structural units: a cubic alkane [Cu4I4] cluster and a 1D inorganic-organic chain [Eu (na) 3] n, each [Cu4I4] cluster serves as a four-connection node, and the 1D [Eu (na) 3] n chain is connected through a nitrogen atom of a na-ligand, so that a three-dimensional skeleton structure is expanded. Tests show that at room temperature, when the compound is excited by 338 nm ultraviolet light, the compound shows two emission centers, a wide emission peak at 557 nm belongs to cluster center triplet emission of a [Cu4I4] cluster, and emission of sharp peaks at 591, 611 and 701 nm corresponds to characteristic emission of Eu < 3 + >. Particularly, the intensity ratio of two fluorescence emission peaks of the compound at 567 nm and 610 nm in the temperature range of 125-300 K and the temperature have a good linear relation, the compound is a sensitive ratio type fluorescence temperature sensing material, and a new thought is provided for application of the ratio type fluorescence temperature sensing material.