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1029 results about "Absorbance spectra" patented technology

Combinative multivariate calibration that enhances prediction ability through removal of over-modeled regions

A novel multivariate model for analysis of absorbance spectra allows for each wavelength or spectral region to be modeled with just enough factors to fully model the analytical signal without the incorporation of noise by using excess factors. Each wavelength or spectral region is modeled utilizing its own number of factors independently of other wavelengths or spectral regions. An iterative combinative PCR algorithm allows a different number of factors to be applied to different wavelengths. In an exemplary embodiment, a three-factor model is applied over a given spectral region. The residual of the three-factor model is calculated and used as the input for an additional five-factor model. Prior to the additional five factors being applied, some of the wavelengths are removed. This leads to a three-factor model over the first region and an eight-factor model over the second region. This analysis of residuals can be repeated such that a one to n factor model could be applied to any given wavelength, or rather any number of factors may be employed to model any given frequency or spectral region. A method of predicting concentration of a target analyte from sample spectra applies a calibration developed using the inventive PCR algorithm to a matrix of sample spectral to generate a vector of predicted concentrations for the target analyte.
Owner:GLT ACQUISITION

Complex monitor for automatically monitoring multiple parameters of water on line

The invention discloses a method for automatically monitoring water quality indexes on line and a device for implementing the method. A method of combining an ultraviolet and visible spectroscopy and various sensors is adopted, dozens of water quality indexes including chemical oxygen demand and ammonia nitrogen can be measured at one time, measurement indexes can be configured in a building block mode according to requirements, and chemical agents are not required. According to the device, the constructed digital optical fiber spectrometer is taken as a core, ultraviolet and visible absorption spectrum data of a water sample is processed in a mode of sequentially combining wavelet de-noising, principal component analysis and a support vector machine, and water quality indexes such as chemical oxygen demand and biochemical oxygen demand of water are acquired. Various physical and electrochemical sensors acquire water quality indexes such as ammonia nitrogen, dissolved oxygen and conductivity. All hardware and software for implementing the method is put in a cabinet to form the device, and the device analyzes the introduced water sample under the control of an embedded industrial control computer system, and automatically monitors the water quality indexes in real time.
Owner:SICHUAN BELAM TECH

Cavity enhanced absorption spectrum device and method for simultaneous measurement of trace gas concentration and aerosol extinction

The invention relates to a cavity enhanced absorption spectrum device and method for simultaneous measurement of trace gas concentration and aerosol extinction. The LED temperature is controlled by a semiconductor refrigeration chip to ensure the stability of light intensity output. High reflectivity mirrors at both ends of an optical cavity have the same curvature radius and reflectivity greater than 99.9%, and compose a stable optical resonator. Usually, cavity enhanced absorption spectrum measures the light intensity in the cavity with or without gas absorption and the variation curve of the high reflectivity mirrors' lens reflectivity along with the wavelength, and finally the concentration of absorption gas in the cavity can be obtained. The device and the method provided by the invention can realize simultaneous measurement of trace gas concentration and aerosol extinction. The actual measured total absorption coefficient is divided into two parts, one part is a trace gas absorption structure changing rapidly along with the wavelength, and the other part is gas scattering and aerosol extinction coefficient changing slowly along with the wavelength. Nonlinear least-square fitting is carried out on the measured total absorption coefficient to calculate the concentration of the to-be-measured trace gas, and finally the gas absorption structure and gas scattering are deducted from the total absorption coefficient so as to obtain the aerosol extinction coefficient.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Multicomponent gas concentration quantitative analysis method based on absorption spectrogram reconstruction

The invention discloses a multicomponent gas concentration quantitative analysis method based on absorption spectrogram reconstruction, which comprises the following steps: preestimating the concentration of each component in analyzed gas and converting absorbance, and reconstructing the spectrogram according to a Lambert-Beer theorem; then constructing a hook-shaped loss function by taking the difference of the spectral lines of the reconstructed spectrogram and an actual spectrogram. Input takes zero as a boundary; when the input is less than zero, a function value decreases progressively, and the decrease amplitude is smaller; when the input is greater than zero, the function value increases progressively, and the increase amplitude is bigger. Then iteration operation is carried out on the concentration of each component in the gas to be analyzed by adopting a momentum method or a genetic algorithm until the concentration difference of each component in the iteration results of two adjacent times is less than a preset admissible value to end the iteration operation. The method has high analysis speed, accurate result and small influence of interference on an analysis result, can be used for gas logging, product quality check and fault diagnosis and the multicomponent gas quantitative analysis of the fields of hardware, chemical industry, environmental protection and the like.
Owner:XI AN JIAOTONG UNIV

Analytical method of multi-source spectrum fusion water quality

The invention discloses an analytical method of multi-source spectrum fusion water quality. The method takes an ultraviolet/visible absorption spectrum signal and a multi-dimensional fluorescence emission spectrum signal of a water sample to be tested as input, and respectively adopts independent component pretreatment method to extract characteristic signals, remove interference information and obtain characteristic signals of the spectrums. According to the contribution of the characteristic signals of the spectrums to a water quality analyzing model, and aiming at avoiding information hiding, the combined characteristic signal number of the two types of spectrums is determined, the characteristic signals are combined into a spectrum characteristic signal federated data set, and the optimal spectrum configuration combination is solved. Based on an improved support vector machine algorithm, a Boosting method is adopted for modeling, and the optimal spectrum fusion water quality analyzing model is obtained by combining a plurality of modeling results. Based on the spectrum characteristic signal federated data set, the computation model is adopted to compute the comprehensive organic substance pollution index value of the water sample to be tested. The method has the remarkable advantages of high analyzing accuracy, high analysis speed, no pollution of chemical agent, simple operation and maintenance and the like.
Owner:ZHEJIANG UNIV

Rapid detecting method and device for optical property of heavy-caliber optical element

The invention discloses a rapid detecting method and device for the optical property of a heavy-caliber optical element. Firstly, a pumping light beam is irradiated on a measurement point 1 on the surface of a measured sample, pumping light reflected by the measurement point 1 is irradiated on a measurement point 2 on the surface of the measured sample again after passing through an energy recovery reflecting mirror, by parity of reasoning, the pumping light interacts with the surface of the measured sample many times after passing through the energy recovery reflecting mirror, and thus, partial material characteristic change is caused from the measurement point 1 to the measurement N on the surface of the measured sample. The partial material characteristic change of the N measurement points is detected in parallel by using detecting light beams. The laser energy reflected by the measured sample is recycled by using the pumping light energy recovery reflecting mirror, so that the speed for detecting the optical property of the heavy-caliber optical element is greatly increased. The method and device can be used for various fields such as photo-thermal nondestructive detection, photo-thermal precise measurement, optical absorption spectrum, photo-thermal imaging, defect analysis and the like and are particularly suitable for rapidly detecting and imaging the weak absorption characteristic of a heavy-caliber laser reflecting mirror.
Owner:合肥利弗莫尔仪器科技有限公司

Quantitative measurement method and device for transient combustion field

The invention designs a quantitative measurement method and device for a transient combustion field and belongs to the technical field of combustion diagnosis. The device comprises a clock synchronization and delay triggering module, a tunable laser generation module, an optical fiber beam splitter, a lens group, a photoelectric detector array, a high-speed multi-path data acquisition module, a high-energy pulse laser generation module, an area array photoelectric detector, a control and calculation module and the like. The optical parameters of a laser-induced fluorescence test system are calibrated by utilizing a steady-state combustion field; the calibrated device is used for measuring the same section of the transient combustion field; and low-resolution temperature distribution obtained by laser absorption spectrum tomography is substituted into an established laser-induced fluorescence calculation model, so that high-resolution temperature and the concentration distribution of measured groups and molecules can be obtained. According to the method and device of the invention, laser-induced fluorescence and a laser absorption spectrum are fused, so that the method and device are of great application value for the monitoring and diagnosis of a combustion field.
Owner:BEIHANG UNIV

Open type long optical distance CO and CH4 online testing instrument

The invention discloses an open type long optical distance CO and CH4 online testing instrument which comprises a host box and an open type long optical distance system, a DFB (distributed feedback) semiconductor infrared laser with a center wavelength of 2334nm and a corresponding laser current control and temperature control circuit and a signal generating circuit are arranged in the host box, the host box is also provided with an off-axis parabolic mirror and a photoelectric detector; a modulation signal generated by the signal generating circuit effects on the laser current control and temperature control circuit to tune the DFB (distributed feedback) semiconductor infrared laser to produce laser with the center wavelength of 2334nm for scanning CO and CH4 absorption spectrums, the laser is perpendicularly emitted into an open type long optical distance optical path, and is reflected by a corner cube reflector to return along the original optical path to the photoelectric detector to obtain the CO and CH4 gas absorption spectrums, spectrum signals are collected, and the column concentrations of CO and CH4 gases can be calculated by inversion by a multispectral fitting algorithm, and are displayed and managed on an upper computer.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI +1
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