370 results about "Photochromism" patented technology

Some variations provide a photochromic heterostructure comprising: first semiconductor nanoparticles that have an average first-nanoparticle effective diameter from 1 nanometer to 20 nanometers, wherein the first semiconductor nanoparticles are not doped; and second semiconductor nanoparticles that have an average second-nanoparticle effective diameter from 1 nanometer to 60 nanometers, wherein the second semiconductor nanoparticles are doped with one or more transition metals, wherein the second semiconductor nanoparticles have a bandgap energy that is higher than the bandgap energy of the first semiconductor nanoparticles, and wherein the first semiconductor nanoparticles and the second semiconductor nanoparticles are in physical contact with each other. The disclosed photochromic heterostructure is especially useful when lower-energy light excites lower-energy-bandgap first nanoparticles to cause higher-energy-bandgap, doped second nanoparticles to photodarken. If the first nanoparticles were not present, the doped second nanoparticles would require higher-energy light to cause darkening. Examples demonstrate embodiments of the invention.

Systems, methods and apparatuses are described for dimming one or more portions of an extended reality (XR) display. Control circuitry may be configured to generate for display, at the display, an XR object. A dimmable optical element may comprise a plurality of up-converting nanoparticles and a photochromic material, and is configured to cause a change in color of at least a portion of the display. The dimmable optical element may be irradiated with light of a first energy level which causes the plurality of upconverting nanoparticles to emit light of a second energy level higher than the first energy level. The photochromic material may absorb the light of the second energy level to cause the change in color of the at least a portion of the display.

The invention relates to the technical field of multi-point defocusing, in particular to an optical stable photochromic multi-point defocusing myopia control lens prescription generation method, which comprises the following steps of: based on eyes of a wearer, scanning cornea by using a non-contact optical device, extracting iris and pupil characteristics, monitoring an adjustment reaction, and performing three-dimensional reconstruction and multi-direction light path tracking analysis to obtain a myopia control lens prescription. And the distribution configuration of the annular belt is optimized, and the overlapping area is adjusted by combining the photochromic requirement, so that the fusion function partition structure is formed. Through collection of multi-source visual parameters and combination of spatial modeling and focusing path analysis, cut-through association of individual visual behaviors and structural attributes in lens customization is realized, functional requirements of different areas and photochromic response are dynamically fused through hierarchical adjustment of the spatial structure of an intervention area, and the visual performance of the lens is improved. And the material and microstructure data are synchronously output to a manufacturing link, so that the collaborative matching capability of the visual area partition is enhanced, and the requirements of a wearer on visual comfort and optical reaction are met.

The invention discloses a MoO3 / TiO2 heterojunction material with a photocatalytic memory effect and application of the MoO3 / TiO2 heterojunction material in degradation of quinolone antibiotics, and belongs to the technical field of inorganic non-metallic material preparation, solar energy utilization and environmental protection. A molybdenum source precursor solution and a titanium source precursor solution are adopted to react, polyvinylpyrrolidone is used for modifying the surface of the material, the MoO3 / TiO2 heterojunction material is obtained, and the material can generate photochromic and photocatalytic memory effects under the pre-illumination effect. The memory effect provides continuous driving force for the catalytic reaction, and the activity of the material in the dark-state catalytic process is remarkably enhanced. The MoO3 / TiO2 heterojunction material disclosed by the invention shows excellent catalytic degradation performance in practical application, and particularly shows extremely high catalytic efficiency in the aspect of water pollution control.

The invention relates to the technical field of multi-point defocusing, in particular to an optical stable photochromic multi-point defocusing myopia control lens prescription generation method, which comprises the following steps of: based on eyes of a wearer, scanning cornea by using a non-contact optical device, extracting iris and pupil characteristics, monitoring an adjustment reaction, and performing three-dimensional reconstruction and multi-direction light path tracking analysis to obtain a myopia control lens prescription. And the distribution configuration of the annular belt is optimized, and the overlapping area is adjusted by combining the photochromic requirement, so that the fusion function partition structure is formed. Through collection of multi-source visual parameters and combination of spatial modeling and focusing path analysis, cut-through association of individual visual behaviors and structural attributes in lens customization is realized, functional requirements of different areas and photochromic response are dynamically fused through hierarchical adjustment of the spatial structure of an intervention area, and the visual performance of the lens is improved. And the material and microstructure data are synchronously output to a manufacturing link, so that the collaborative matching capability of the visual area partition is enhanced, and the requirements of a wearer on visual comfort and optical reaction are met.

The application discloses a device for detecting crack defects of porcelain insulators and relates to the technical field of defect detection. The device aims at the problem of poor crack recognition effect when the existing crack detection device of the porcelain insulator adopts optical detection technology. The device comprises a box body, a fixed plate is fixedly connected to the upper side of the box body, and a containing box is arranged on the upper side of the fixed plate. The device has the advantages that the insulator body with a higher heating rate than normal temperature can be immersed into normal-temperature photochromic paint in the immersion tank, the cracks on the insulator body are caused to move away by thermal expansion and cold contraction, the paint is sucked into the cracks after the insulator body is cooled, the paint in the cracks is caused to change color when the ultraviolet lamp irradiates the insulator body, the color contrast between the cracks and the insulator body is obviously increased, the recognition effect of the high-definition camera is improved, and the recognition and detection efficiency and accuracy of the device are improved.

The invention belongs to the technical field of material science, and relates to a preparation method and application of an unsaturated bond extended tetraphenyl ethylene siloxane compound. An unsaturated bond is introduced into a siloxane group, and the siloxane group containing the unsaturated bond and a tetraphenyl ethylene derivative are subjected to a coupling reaction. The coupling reaction is carried out in an inert atmosphere, the temperature is 90-150 DEG C, and the time is 6-24 hours. And purifying the product by silica gel column chromatography to obtain the target compound. Unsaturated bonds are introduced into a tetraphenyl ethylene structure, so that the adjustability of the photochromic wavelength is realized, the performance of the compound is remarkably improved, the application range of the compound is remarkably widened, and a new thought and a new method are provided for development of photochromic materials.

The present application relates to the field of organic photo-functional materials, and particularly relates to a photochromic porous organic polymer based on spirooxazine and a preparation method and application thereof; compared with a spirooxazine molecular monomer, the photochromic porous organic polymer based on spirooxazine is formed by connecting two groups through an imine bond to form a covalent bond skeleton on the basis of not changing the structure of spirooxazine; compared with a conventional small-molecule spirooxazine compound, the porous organic polymer has solid-state photochromic ability, and has advantages of good fatigue resistance and excellent stability.

The invention provides a plush fabric invisible anti-counterfeiting method based on an optically variable material, and belongs to the technical field of textile anti-counterfeiting. The method comprises the following steps: providing a plush fabric with a final style; preparing anti-counterfeiting slurry containing photochromic microcapsules, a low-temperature crosslinking adhesive, a flatting agent and deionized water; applying the slurry to the base cloth of the fabric or the root of fluff through screen printing or digital ink-jet printing; and carrying out low-temperature fixation at 80-120 DEG C. The obtained fabric has the same appearance and handfeel under natural light, an anti-counterfeiting pattern is shown under ultraviolet light or sunlight irradiation, and the pattern disappears after a light source is removed. According to the method, complete invisibility of anti-counterfeiting is achieved, the soft hand feeling of the plush fabric is not damaged, the anti-counterfeiting threshold is high, and the method is suitable for the fields of high-end plush toys, home textiles and the like.

This invention discloses a method for preparing and intelligently identifying microscopic stealth codes by integrating artificial intelligence and hyperspectral imaging, belonging to the field of anti-counterfeiting technology. The method comprises two parts: preparation and identification. During preparation, photochromic materials are doped into a substrate to form microscopic code points. A hyperspectral feature library is established, and a digital twin initial model containing partial differential equations is constructed, followed by pre-training of a physical information neural network. During identification, measured hyperspectral data of the code points to be tested are collected. Combined with environmental parameters and historical data, the expected state is predicted using the trained physical information neural network. The authenticity is determined by comparing the measured data with the expected state. This invention embeds physical laws into the identification process through a digital twin model and a physical information neural network, achieving proactive prediction of the evolution of the microscopic stealth code state, significantly improving the accuracy, robustness, and anti-counterfeiting capability of anti-counterfeiting identification.

The invention belongs to the technical field of ceramic decorative materials and photochromism, and provides a photochromic dynamic pattern design method for multilayer overprinting partition photosensitive ceramic stained paper aiming at the industrial pain points that patterns of traditional ceramic stained paper are fixed, and existing photochromic stained paper is low in overprinting precision, slow in color change response and the like. According to the method, a five-layer composite structure is constructed and sequentially comprises a ceramic substrate layer, a bottom bonding layer, a photochromic functional layer, a partitioned photosensitive control layer and a surface protection layer, multi-region independent photochromism is achieved through the partitioned photosensitive control technology, and the overprinting precision can reach within 5 microns. The photochromic response time of the product does not exceed 0.5 second, the cycle discoloration life is not less than 150 thousand times, the interlayer peeling strength reaches 3N / cm or above, the product can be widely applied to the field of architectural ceramic and domestic ceramic decoration, and the visual expressive force and interactive experience of the product are effectively improved.

The utility model relates to the technical field of lenses, in particular to a spherical lens and cylindrical lens double-control fusion lens, which comprises a lens body and is characterized in that the lens body comprises a base layer I, and an anti-reflection layer, an ultraviolet-proof layer, an impact-resistant layer, a photochromic layer and a stain-resistant layer are arranged on the surface of the lens body. An anti-reflection layer is fixedly adhered to one side of the base layer I through a resin adhesive, and an ultraviolet-proof layer is adhered to the other side of the anti-reflection layer through the resin adhesive. According to the scheme, the functionality is remarkably improved through the multi-layer composite structure design (the anti-reflection layer, the ultraviolet-proof layer, the anti-impact layer and the like), in addition, the micro lenses of the first base layer and the second base layer are distributed in a staggered mode by rotating by 30 degrees, the one-person two-mirror alternate wearing mechanism (alternating every 2-4 weeks) is combined, fatigue of retina cells caused by fixed stimulation is avoided through dynamic out-of-focus stimulation, and the anti-fatigue performance of the retina cells is improved. Meanwhile, alternate recovery is promoted, so that myopia development is intervened more scientifically.

The invention relates to the technical field of organic synthesis, and particularly provides a thiophene-containing tetraarylethene compound as well as a preparation method and application thereof. According to the invention, two phenyl groups of tetraphenylethylene are replaced by methyl formate thiophene groups, and the substituted tetraarylethylene compound has more remarkable photochromic and mechanochromic dual functions through the interaction of a specific substituent group at the position 2 of thiophene and a large conjugated group formed by four aromatic rings; and light-operated double-color display in a polymer mechanism can be realized. The mechanochromism of the compound does not depend on ultraviolet light, when the compound is subjected to mechanical force, the molecular accumulation mode and conjugate planarity are changed, and the color change can be directly observed by naked eyes. Different from traditional tetraphenyl ethylene force-induced discoloration recessive fluorescence change, the dominant color change can be used in the fields of visual stress monitoring, anti-counterfeiting marks, inkless writing materials, safe ink and the like in ultraviolet-free environments (such as indoor and closed spaces), and the application prospect is wide.

This invention discloses a polishing method and apparatus for nickel-based alloys based on photocatalysis and photothickening synergy. It achieves dual-driven processing by simultaneously triggering photocatalytic workpiece surface modification and photo-triggered thickening of the polishing slurry through an integrated dual-light system, realizing surface softening and medium thickening. Composite abrasive particles loaded with TiO2 / ZnO photocatalysts form a low-hardness oxide layer on the nickel-based alloy surface under ultraviolet light irradiation, reducing processing resistance. Precise viscosity control of the polishing slurry is achieved through azobenzene / cinnamic acid photochromic molecules, combined with shear-induced particle agglomeration to form a dual thickening system, improving viscosity stability. This invention solves the technical pain points of work hardening in nickel-based alloys, large viscosity fluctuations in traditional shear-thickening polishing slurries, and poor processing uniformity, improving processing efficiency and workpiece surface quality. It is suitable for efficient and precise machining of difficult-to-machine nickel-based alloys such as Inconel 718 and GH4169.

The present invention aims to provide a photochromic compound capable of exhibiting photochromic properties regardless of matrix, and the compound is stably dispersed without aggregation in a process of molding (curing) an optical base material. According to the present invention, a polymer photochromic compound, which has a block polymeric group of an oligomeric chain group having relatively favorable compatibility with a solid matrix and an oligomeric chain group having poor compatibility with a solid matrix, forms a nano- to micro-phase separation structure in a solid matrix. The compound does not rely on the solid matrix, its dispersibility is improved and aggregation is prevented or reduced, whereby excellent photochromic properties can be exhibited.

The purpose of the present invention is to provide a photochromic compound which can exhibit photochromic characteristics regardless of a matrix, and is stably dispersed and present without being aggregated in an optical substrate forming process (during curing).　According to the present invention, a polymer photochromic compound, which has a group having a shape of a block polymer of an oligomer chain group having relatively excellent compatibility with a solid matrix and an oligomer chain group having poor compatibility with a solid matrix, forms a nano- to micro-phase separation structure in a solid matrix, improves dispersibility regardless of a solid matrix, and suppresses aggregation. As a result, a high level of photochromic characteristics can be exhibited.

This application relates to the technical field of reactive dyes, specifically to a photochromic red fluorine-containing reactive dye, its preparation method, and its application. The general structural formula of this photochromic red fluorine-containing reactive dye is as follows: [Formula omitted for brevity]. Wherein, R1 and R2 are -H, -SO3M, -CH3, -COOM, -NO2, or -NHCONH; R3 is -Cl or -SO3M; and M is Na, K, or Li. The reactive dye provided in this application exhibits good wash fastness, rubbing fastness, chlorine fastness, and good solubility on cotton fabrics, while also possessing excellent light fastness and superior fixation rate on cotton fabrics during medium-temperature dyeing.

The invention discloses a photochromic polyacrylate material, a photochromic adhesive sheet and a preparation method of the photochromic polyacrylate material. The photochromic polyacrylate material is prepared from the following raw material components in parts by weight through free radical copolymerization: 2.5-10 parts of a photochromic monomer; 6-24 parts of a soft monomer; 9-36 parts of a hard monomer; 3-12 parts of a functional monomer; 0.07 to 0.28 part of an initiator; and 30-120 parts of a first solvent. According to the invention, a photochromic group is connected to a polymer main chain in a chemical bond form in a copolymerization manner, so that the problem that toner is easy to separate out in physical blending is thoroughly solved, and the uniformity and stability of the material are remarkably improved; the photochromic polyacrylate material prepared by the preparation method disclosed by the invention is excellent in photochromic performance and strong in durability, and can still keep stable color change after multiple light cycles; the preparation method disclosed by the invention is simple to operate and high in feasibility, industrial production is easy to realize, and powerful technical support is provided for practical application of the photochromic material.

The invention relates to the technical field of vehicle-mounted display, and provides a head-up display device capable of preventing sunlight from flowing backwards. The image generation device comprises an image generation unit and a lenticular grating array, and the upper portion of the image generation unit is attached to the lenticular grating array. The lenticular grating array is prepared by mixing a transparent optical base material and a photochromic material. The invention has the following beneficial effects: (1) the physical characteristic that the photochromic material changes color when encountering strong light is utilized, so that automatic and passive protection against sunlight backflow is realized; by absorbing and blocking high-energy sunlight on a key path of light focusing, the problem that an LCD screen is burnt down due to backward flowing of sunlight can be effectively prevented, and the safety and reliability of a product are improved. (2) under the normal working condition, the photochromic material is in a transparent state, so that the influence on the brightness, the contrast ratio and the color fidelity of display light is extremely small, and the normal display effect under most scenes is ensured;

The invention relates to a photochromic lens with a photochromic dye grafted nanoparticle composite film layer and a preparation method of the photochromic lens, and belongs to the technical field of optical lenses. The photochromic lens comprises a lens base material, a priming coat, a photochromic dye grafted nanoparticle composite film layer and a protective layer which are sequentially stacked from bottom to top, wherein chemical bond grafting is formed between the photochromic dye and the surfaces of the gold / silver nanoparticles through sulfydryl or carboxyl at the tail end of a molecule of the photochromic dye. The localized surface plasmon resonance effect of the covalent grafting structure and the nanoparticles synergistically solves the bottlenecks of easy agglomeration, low loading capacity and slow response of the dye in the traditional technology. The lens disclosed by the invention has the characteristics of extremely fast color-changing response, high color fading efficiency, high mechanical strength, good environmental stability and the like, and the comprehensive performance and the service life of the color-changing lens are remarkably improved and prolonged.

Photochromic polyimide material and preparation method, coating, coating, optical device and application; photochromic polyimide material, by introducing photochromic unit into polyimide structure, the material can quickly respond and present color change under ultraviolet light irradiation, and restore to colorless state by visible light or heating; and the polyimide matrix provides high mechanical strength, thermal stability and chemical resistance, so that the material maintains stable color changing ability in multiple light-color changing cycles. At the same time, the weather resistance of the material is greatly improved, which can adapt to outdoor and harsh environment, and expands the application prospect of the material in the fields of intelligent coating, optical device, sensor and the like, thereby solving the problem that the existing photochromic material cannot simultaneously have photoresponsivity, mechanical performance, chemical stability and weather resistance.

This invention relates to photochromic compounds represented by the following general formula 1, in which Az represents an unsubstituted or substituent monovalent azazine cyclogroup, L represents a divalent or higher linking group, D represents a photochromic pigment structure, a and c each independently represent an integer of 1 or more, and b represents an integer of 0 or 1 or more. When general formula 1 contains multiple Az groups, the multiple Az groups may be the same or different; similarly, when general formula 1 contains multiple L groups, the multiple L groups may be the same or different.

The invention discloses a preparation method and application of a triarylethene photochromic material with multicolor switching, and relates to the technical field of organic functional materials. The material provided by the invention mainly comprises a series of derivatives of a dual photochromic material system. On the basis of a triarylethene system, a naphthopyran structure is fused to construct an organic dual photochromic system; different colors appear after one material is excited, and the color gradually changes along with time lapse. After an excitation source is removed, the color gradually changes from red to orange, then changes to yellow and finally recovers to a colorless state. And the material can be obviously changed from colorless to orange photochromic under the excitation of visible light, and the photochromic effect can be realized at a relatively low concentration.

This invention relates to the field of inorganic photochromic materials, specifically to an inorganic photochromic material, its preparation method, and its applications. Compared with existing technologies, the preparation method provided by this invention uses potassium carbonate, bismuth oxide, and titanium dioxide in a molar ratio of potassium, bismuth, and titanium of 1:3:4-x as raw materials, where 0≤x≤1, and calcines at a high temperature of 900℃~1000℃ to prepare an inorganic photochromic material with good photochromic properties and reversibility. The preparation method of this invention is simple, the raw materials are readily available, and the preparation cost is low. Furthermore, the irradiation light source required for the prepared inorganic photochromic material is a common 365nm ultraviolet light source, resulting in low application cost. Therefore, it solves the technical problem that existing inorganic photochromic materials cannot be applied to large-scale industrial applications. Experimental results show that the inorganic photochromic material prepared by the method of this invention can be successfully used to prepare anti-counterfeiting and encryption materials.

The application discloses a kind of photochromic circular polarized luminescent carbon dots long afterglow composite materials and preparation method and application thereof, belong to chiral luminescent functional material technical field;The composite material with photochromic and long afterglow luminescence characteristics carbon dots as luminescent center, and with cellulose nanocrystal through self-assembly to form chiral composite system with cholesteric helical structure.Carbon dots provide fluorescent emission, photochromic and long afterglow luminescence characteristics, while the chiral structure of cellulose nanocrystal can selectively circularly polarized modulation to luminescence, so as to realize the enhancement of circular polarized luminescent signal.The composite material can realize reversible photochromic luminescence behavior under ultraviolet irradiation, and produce long afterglow emission after excitation stops, while showing obvious circular polarized luminescence characteristics.The material has the advantages of stable structure, simple preparation method, high functional integration, etc., and has good application prospect in information anti-counterfeiting, optical encryption, chiral optoelectronic devices and intelligent display fields.

One aspect of the invention relates to a method for producing a plastic article or semi-finished product from a polymerizable mixture of isocyanates and isocyanate-reactive components, wherein the mixture comprises at least one photochromic dye, at least one surface additive, an isocyanate component and at least one of the following components: - a poly(thio)urethane prepolymer produced from isocyanates and isocyanate-reactive components, wherein the ratio of the two components is such that there is an excess of isocyanate-reactive groups in relation to isocyanate groups; - a poly(thio)urethane prepolymer produced from isocyanates and isocyanate-reactive components, wherein the ratio of the two components is such that there is an excess of isocyanate groups in relation to isocyanate-reactive groups; - a thiol component; wherein the mixture contains at least one photobase generator, a photochromic dye and a surface additive. Further aspects of the invention relate to a plastic article or a plastic article provided with an additional layer, each produced by a method according to another aspect of the invention, as well as a polymerisable mixture.

The invention relates to an ophthalmic article (1), in particular for sunglasses, comprising at least one substrate (9) and a photochromic filter compound (15), the ophthalmic article (1) having a first transmission spectrum in an activated state of the photochromic filter compound (15) and a second transmission spectrum in a deactivated state of the photochromic filter compound, such that: ⋅—the first and the second transmission spectra at wavelengths lower than 380 nm is lower than 1%, ⋅—the first and the second transmission spectra have a relative first maximum between 460 nm and 510 nm, ⋅—the first and the second transmission spectrum have a relative first minimum between 560 nm and 610 nm, and where ⋅—Tvactivated is the luminous transmittance according to ISO_13666 in the activated state of the photochromic filter compound. ⋅—Tvdeactivated is the luminous transmittance according to ISO_13666 in the deactivated state of the photochromic filter compound. ⋅The lens has a reduced transmission in the blue between 400 and 450 nm and a reduced transmission around 585 nm. The lens provides a good contrast and reduces glare.TvdeactivatedTvactivated>2.5TvactivatedTνdeactivated

The invention relates to an optical article comprising at least: (a) a substrate having a front main face and with a rear main face: (b) at least one photochromic compound that is able to undergo a transformation from one state, defined as “deactivated state” to another state, defined as “activated state” in response to predetermined wavelengths of the electromagnetic spectrum, (c) coated directly or indirectly onto the front face of said substrate (a), a mirror coating, said mirror coating—comprising at least two layers having a low refractive index which is lower than 1.55, defined as “LI layer”, and at least two layers having a high refractive index which is equal to or higher than 1.55, defined as “HI layer”,—and having a mean light reflection factor for wavelengths ranging into said predetermined wavelengths of the electromagnetic spectrum, defined as Rm(predetermined spectrum) that is lower than or equal to 1.0%, for an angle of incidence of 15°; a mean light reflection factor in the visible region Rv that is lower than or equal to 10.0% for an angle of incidence of 15°; and an optical robustness corresponding to the standard deviation of said mean light reflection factor in the visible region Rv, defined as “σRv” that is lower than or equal to 0.7% for an angle of incidence of 15°.

The present application relates to a kind of tungsten oxide-based super-amphiphobic photochromic coating material preparation method, application, in the preparation process, zinc ion and sodium dodecyl benzene sulfonate are introduced to the morphology of WO3 / ZnO powder is doubly regulated.In the low surface energy treatment of WO3 / ZnO powder after improvement method, finally obtainable reentrant micro / nano structure of flower-like.The prepared super-amphiphobic photochromic coating is blue within 3min under ultraviolet irradiation, fade after heating 90min in air, photochromism obtains great promotion.The contact angle of the coating to water and edible oil is all greater than 150°.In addition, when facing sand impact, water impact, corrosive solution, long-term ultraviolet irradiation, still maintain super-amphiphobicity, and also have antifouling and self-cleaning ability.The present application provides new insights for developing super-amphiphobic photochromic material with good stability and high repeatability, and has good application prospect in the field of optical information storage, anti-fake and rewritable material.

Provided is a photochromic compound represented by General Formula 1. In General Formula 1, R30 and R31 each independently represent a linear or branched alkyl group having 2 or more carbon atoms, which is unsubstituted or has one or more substituents; a cyclic alkyl group having 3 or more carbon atoms which is unsubstituted or has one or more substituents; or represents a group represented by - (R100)nR101 which is unsubstituted or has one or more substituents, R100 represents an alkyleneoxy group, R101 represents an alkyl group, n represents an integer of 1 or more, a total number of carbon atoms of n alkyleneoxy groups represented by R100 and alkyl groups represented by R101 is 2 or more, R32 to R35 each independently represent a hydrogen atom or a substituent other than an electron-attracting group, and R36, R37, B7 and B8 each independently represent a hydrogen atom or a substituent.