The invention discloses a synthesis method of water-absorbent resin with a novel structure. The synthesis method is characterized by comprising, by weight, 200-300 parts of acrylic acid, 1-5 parts of cross-linking agents, 700-800 parts of deionized water, 0.5-2 parts of oxidation reduction initiating agents, 50-80 parts of octylene glycol, 10-80 parts of ethyl alcohol, 5-15 parts of butanediol diglycidyl ether, 20-40 parts of aluminum sulfate, 2-5 parts of silicon dioxide and sodium hydroxide solution. According to the synthesis method, the acrylic acid is firstly polymerized at the indoor temperature and then neutralized by the aid of the sodium hydroxide solution, triple cross-linking treatment of the surface is performed, so that the water-absorbent resin has high gel intensity and pressurizing absorption capacity, good liquid passing performance and water retention capacity and fundamentally solves the problem that gel intensity and absorption ratio cannot be completely considered, and the synthesized water-absorbent resin is quite excellent in performance and has high infiltration speed, super-low reverse osmosis and super-dry and comfortable surfaces when being applied to paper diapers.