6496 results about "Hydrogen peroxide" patented technology

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

The invention relates to a bioelectrochemical sensor used for detecting hydrogen peroxide and a manufacturing method of the bioelectrochemical sensor. The novel bioelectrochemical sensor is a sensor with a three-electrode system, wherein the counter electrode is a platinum electrode, the reference electrode is saturated calomel electrode and the working electrode is gold electrode. The sensor is based on orientation combination of a polypeptide horse radish peroxidase with characteristic sequence, the promotion effect of the polypeptide horse radish peroxidase on the activity of the enzyme and the characteristic of high sensitivity of electrochemical detection methods. The sensitivity of hydrogen peroxide sensors is effectively improved and satisfactory results are obtained.

The invention relates to the technical field of chemical safety and intelligent control, in particular to an explosion-proof intelligent temperature control method and system for a hydrogen peroxide storage tank based on multi-modal monitoring, and the method comprises the steps: collecting multi-dimensional data such as temperature, pressure and H2O2 concentration through a sensor array, carrying out the Kalman filtering and wavelet transform denoising, recognizing local abnormal points through an improved WMDS-DBSCAN algorithm, and obtaining the explosion-proof intelligent temperature control of the hydrogen peroxide storage tank based on the WMDS-DBSCAN algorithm. Predicting a hot spot diffusion trend in combination with an unsteady heat conduction equation and an RF-ADI algorithm; weighted Delaunay triangulation is utilized to construct a self-adaptive monitoring grid, risk area probability distribution is output through an SAM-LSTM-CNN hybrid neural network, and a dynamic amplitude limiting fuzzy PID controller adjusts the opening degree of a nozzle to achieve temperature control. According to the method, multi-modal data and an intelligent algorithm are fused, abnormal accurate detection, risk prediction and self-adaptive temperature control are realized, a closed-loop optimization mechanism is formed, and the operation safety and reliability of the hydrogen peroxide storage tank are effectively improved.

The present application relates to the field of wastewater treatment, and provides a treatment system and method for electroless nickel-plating waste liquid. The treatment system comprises a decomplexing pretreatment system; an oxidation-decomplexing system comprising a redox reactor and a decomplexing reactor which are connected in sequence, wherein an oxidizing agent in the redox reactor is oxygen, and an oxidizing agent in the decomplexing reactor is hydrogen peroxide; a chemical precipitation system comprising a neutralization reaction tank and a sedimentation tank which are connected in sequence, wherein the sedimentation tank is equipped with a filter system; and an evaporation crystallization system comprising an evaporation device, a crystallization device, and a separation device which are arranged in sequence. In the treatment system and method for electroless nickel-plating waste liquid, a two-stage oxidation method is employed to achieve oxidation and decomplexing of the waste liquid; in addition, combining chemical precipitation treatment and evaporation crystallization treatment not only reduces the waste liquid treatment cost but also avoids the introduction of other impurities, and allows for the separation of nickel salts and phosphate salts, so that the operation is easy and convenient, the treatment cost is low, the nickel removal rate is high, and resource utilization of nickel is facilitated.

The invention discloses a multistage circulating fluidized bed hydrogen peroxide integrated production method, and relates to the field of hydrogen peroxide preparation.The method comprises the steps that continuous efficient synthesis of hydrogen peroxide is achieved by constructing a multistage serial circulating fluidized bed reaction system; meanwhile, a genetic algorithm based on historical data is introduced to perform off-line optimization on process parameters such as reaction temperature, flow velocity, catalyst particle size, gas-liquid ratio and retention time, so that the hydrogen peroxide yield is improved, the energy consumption per unit yield is reduced, and the generation of byproducts is inhibited; the constructed optimization objective function adopts a weighted mean square error structure, multiple objectives are balanced, and it is ensured that the overall working condition is optimal; an optimization result is used for guiding initial setting and steady-state operation of a reaction system, and efficient reaction can be realized without real-time sensor control. The system has the advantages of high process structure integration level, high control strategy intelligence degree, good operation stability and the like, and is suitable for continuous optimization operation of medium and large hydrogen peroxide production devices.

The invention relates to lactobacillus gasseri FMTA1125B with the effect of preventing, relieving or treating vaginitis and application of the lactobacillus gasseri FMTA1125B. The lactobacillus gasseri FMTA1125B is classified and named as lactobacillus gasseri, and the preservation number of the lactobacillus gasseri FMTA1125B is CGMCC No.34292. The lactobacillus gasseri FMTA1125B has the effects of preventing, relieving or treating vaginitis and the application of the lactobacillus gasseri FMTA1125B. The bacterium can produce beneficial components such as lactic acid, gamma-aminobutyric acid and hydrogen peroxide through metabolism so as to regulate the genital tract environment and improve the health degree; and the traditional Chinese medicine composition has relatively good bacteriostasis and sterilization effects on common vaginal pathogenic bacteria such as escherichia coli, staphylococcus aureus, gardnerella vaginalis, candida albicans, neisseria gonorrhoeae and the like. Therefore, the lactobacillus gasseri FMTA1125B strain can be used for preparing a preparation with the effect of improving related genital tract diseases such as vaginitis.

The invention relates to the technical field of organic synthesis, and discloses a preparation method of bromo-pyrrole nitrile. The method comprises the following steps: (1) mixing p-chlorophenylglycine, acetonitrile, trifluoroacetic acid and a catalyst, then dropwise adding acyl chloride and carrying out acylation reaction, and after the reaction is completed, purging with an inert gas; (2) under the inert gas, mixing the mixture obtained in the step (1) with inorganic salt, then dropwise adding 2-chloroacrylonitrile, carrying out cyclization reaction, and separating a liquid phase from the obtained mixture; and (3) under the inert gas, mixing the liquid phase obtained in the step (2), hydrobromic acid and hydrogen peroxide, carrying out a bromination reaction, then extracting with acetonitrile to obtain an acetonitrile layer, then removing the acetonitrile, and then carrying out cooling crystallization to obtain the bromo-pyrrolenitrile. According to the technical scheme, the reaction yield is high, different solvents do not need to be frequently replaced, and the solvents can be recycled.

The invention discloses a method for rapidly preparing a hard carbon negative electrode material from a waste wind turbine blade, an obtained product and application, and the method comprises the following steps: putting the waste wind turbine blade into a mixed solution of acetic acid and hydrogen peroxide, heating for reaction, filtering after the reaction, and distilling filtrate to obtain degraded resin; and carrying out heating curing on the degraded resin to obtain cured resin, carrying out pre-carbonization on the cured resin, and then carrying out Joule heat high-temperature carbonization to obtain the hard carbon negative electrode material. According to the method, fibers and resin in the waste wind turbine blades are separated through one-step reaction by adopting a chemical recovery method, and the hard carbon negative electrode material is prepared by utilizing a Joule heating technology, so that the preparation period of the hard carbon negative electrode material is shortened, the energy consumption is reduced, and the application of the hard carbon negative electrode material in the sodium-ion battery has good application prospects. And the initial coulombic efficiency, platform capacity and total capacity of the prepared sodium ion battery can be simultaneously improved.

The invention provides a preparation method of a semiconductor structure and the semiconductor structure, and particularly relates to the technical field of semiconductors. The preparation method of the semiconductor structure comprises the following steps: providing an initial semiconductor structure, wherein a metal layer is deposited on the initial semiconductor structure; performing first annealing treatment on the metal layer to generate a metal silicon compound; processing the initial semiconductor structure by using a first cleaning solution, wherein the first cleaning solution is a mixed solution of sulfuric acid, hydrogen peroxide and ferrous ions; processing the initial semiconductor structure by using a second cleaning solution, wherein the second cleaning solution is a mixed solution of hydrochloric acid, hydrogen peroxide and water; and performing second annealing treatment on the metal silicon compound to generate a self-aligned silicide layer. By adopting the preparation method of the semiconductor structure, the removal temperature of the unreacted metal layer can be reduced, the influence and damage of high temperature on the thermal stability of the metal silicon compound are avoided, and the product yield is improved.

The invention relates to a copper-molybdenum-titanium etching solution as well as a preparation method and application thereof. The copper-molybdenum-titanium etching solution comprises a main agent, the main agent is prepared from organic acid, a fluorine-containing compound, a surfactant, organic alkali, a corrosion inhibitor, hydrogen peroxide and deionized water. The copper-molybdenum-titanium etching solution provided by the invention does not contain phosphorus, the cost and environmental protection risk in a wastewater treatment link are greatly reduced, and meanwhile, the copper-molybdenum-titanium etching solution contains low fluorine, so that the etching solution has good etching activity, corrosion to equipment is effectively reduced, a powerful guarantee is provided for stable operation of production, and the copper-molybdenum-titanium etching solution is suitable for industrial production. And meanwhile, the safety of an operation environment is improved. Especially, under the condition of low hydrogen peroxide content, the copper-molybdenum-titanium etching solution shows excellent etching performance. In addition, the etching solution also has long copper service life, can effectively inhibit the negative influence of copper ions on the etching performance, prolongs the effective service time of the etching solution in a high copper content state, greatly reduces the replacement frequency of the etching solution, reduces the production cost, and improves the production efficiency.

The invention relates to a wafer cleaning solution and a cleaning method, the cleaning solution is used for an SC-2 cleaning process, and the cleaning solution comprises hydrochloric acid, hydrogen peroxide and deionized water; wherein the pH value of the cleaning solution is greater than 2. According to the invention, particulate matters can be effectively prevented from depositing on the surface of the wafer, so that the deposition quantity of the particulate matters on the surface of the wafer is reduced, and the cleaning effect on the wafer is improved.

The invention relates to preparation of a covalent organic framework material (COF) containing methyl and thiophene and application of the covalent organic framework material in production of hydrogen peroxide. Two thienyl covalent organic framework materials are prepared respectively, and the problem that the yield of hydrogen peroxide produced through photocatalysis of an existing covalent organic framework material is not high is solved. A solvothermal method is adopted for preparation, the preparation process is simple and efficient, the solvent consumption is low, the method is green and environmentally friendly, the yield is high, the problem that the energy utilization efficiency is too low due to mutual compounding of photon-generated carriers and electrons in the photocatalysis process is solved, and the efficiency of photocatalytic production of hydrogen peroxide is effectively improved. The BTTPa-2COF is applied to photocatalytic production of hydrogen peroxide, experimental results show that the BTTPa-2COF has excellent performance of photocatalytic production of hydrogen peroxide, and the performance of hydrogen peroxide production can reach 3680 [mu] molg <-1 > h <-1 > under visible light irradiation.

The invention discloses a recovery technology for waste lithium iron phosphate batteries, and aims to prepare high-purity iron phosphate and lithium phosphate and comprehensively recover valuable metals such as iron, aluminum and copper in the high-purity iron phosphate and lithium phosphate. The method mainly comprises the following steps that waste lithium iron phosphate battery powder is subjected to oxidizing roasting to obtain roasted battery powder, the roasted battery powder is mixed with phosphoric acid and hydrogen peroxide in different molar ratios, the liquid-solid ratio is adjusted through deionized water, oxidizing leaching is conducted, and lithium-rich liquid and primary leaching residues are obtained; the secondary leaching residues are subjected to phosphoric acid activation, and high-purity iron phosphate dihydrate is obtained after the pH is adjusted; and performing metal ion precipitation on the lithium-rich liquid by adjusting the pH value, and finally performing high-temperature calcination to obtain high-purity lithium phosphate. The method not only realizes efficient leaching and separation of lithium, but also improves the precipitation efficiency of iron phosphate, solves the problems of low metal resource recovery rate and serious process pollution in the prior art, and is suitable for large-scale treatment of waste lithium iron phosphate batteries.

The invention discloses a method for catalytically oxidizing lignin to depolymerize into an aviation oil intermediate by using a cellulose carbon aerogel supported copper nano-catalyst. Comprising the following steps: (1) dissolving cellulose powder into a mixed alkali solution of NaOH and urea, and stirring at low temperature to obtain a clear and transparent cellulose solution; and washing to be neutral to obtain well dispersed cellulose suspension. And (2) carrying out suction filtration molding, and freeze-drying for a period of time to obtain the cellulose aerogel. And (3) immersing in an ethanol solution of copper nitrate for ultrasonic treatment, and drying in a vacuum drying oven. And (4) carrying out high-temperature calcination in an N2 atmosphere to obtain a catalyst which is marked as Cu / CA. And (5) the catalyst can efficiently catalyze a Fenton-like reaction to oxidize a dimer model compound of lignin in acidic, neutral and alkaline environments to obtain products including benzoic acid, acetophenone, benzyl alcohol, phenol and the like, the required hydrogen peroxide concentration is low, and the catalyst has the advantages of simple process, high catalytic activity, low cost and the like, can be used for effectively degrading lignin to prepare aviation oil intermediates, and has wide application prospects. And repeated cyclic utilization is realized.

The invention provides an electrochemical active oxygen supply device for a washing machine and a preparation method. The device comprises a shell, a single closed reaction chamber is formed in the shell, a bifunctional anode electrode and a bifunctional cathode electrode are integrated in the reaction chamber, and a compact and uniform reaction area is formed between the anode electrode and the cathode electrode. When water flows through the reaction area, hydrogen peroxide (H2O2) and / or hydroxyl radicals (OH) are / is electrochemically generated on the surface in situ by accurately adjusting the electrode potential of the difunctional anode, so that instant generation and instant utilization of active oxygen are realized. The active oxygen directly enters a washing system of the washing machine along with water flow, bacteria, viruses and fungi can be efficiently inactivated under the normal-temperature or low-temperature washing condition without additionally adding chemical disinfectants, organic stains and peculiar smell molecules are synchronously degraded, and green, efficient and intelligent healthy washing is achieved.

The invention belongs to the technical field of pharmaceutical chemical processes, and particularly relates to a preparation method of a penem antibiotic intermediate 4-BMA, which comprises the following steps: adding Zn powder, chlorosilane, aliphatic tertiary amine, zinc salt and 4-AA in a formula (I) into THF (tetrahydrofuran), uniformly stirring, dropwise adding a THF solution of alpha-haloamide with an induction group in a formula (II) for reaction, filtering the reaction solution, removing the zinc powder, and drying to obtain the penem antibiotic intermediate 4-BMA. Extracting the filtrate to obtain a THF phase, washing with an aqueous solution of potassium oxalate, and recovering THF to obtain a formula (III); and carrying out oxidative hydrolysis, sulfur dioxide quenching, sulfur dioxide acid regulation crystallization and recrystallization on the formula (III) to obtain the intermediate 4-BMA. According to the preparation method disclosed by the invention, a zinc salt is used as a catalyst during preparation of the formula (III), potassium oxalate is used for removing residual Zn (II) in a THF phase, SO2 is used for quenching hydrogen peroxide and acid regulation and crystallization of 4-BMA, the oxygenolysis problem of 4-BMA is solved, and the preparation method has the characteristics of greenness, safety and high efficiency, is strong in product competitive advantage and is suitable for industrial production.

The invention provides nutritional moisturizing ceramsite as well as a preparation method, application and an application method.The method comprises the following steps: firstly, uniformly mixing sieved power plant fly ash with commercial cement, solid nutrition powder and coal gangue powder, and adding hydrogen peroxide to obtain porous ceramsite; the preparation method comprises the following steps: adsorbing a nutritional agent by porous ceramsite, wrapping the porous ceramsite with phosphorylated chitosan, carrying out hydroformylation and alkynylation, and reacting with the modified microcapsule to obtain the nutritional moisturizing ceramsite. The invention also provides an application of the nutritional moisturizing ceramsite in desertification soil improvement. According to the application method of the nutritional moisturizing ceramsite in desertification soil improvement, the nutritional moisturizing ceramsite is divided into large, medium and small ceramsite according to the particle size, and directly covers a desertification land to form a nutritional moisturizing ceramsite layer in a big-end-up form, a uniform form, an interlayer form, a mixed form or a uniform mixing form. The nutritional moisturizing ceramsite prepared by the invention can improve soil fertility and promote plant growth.

The invention relates to the technical field of state monitoring, and discloses a hydrogen peroxide purification process state monitoring method. The method comprises the following steps: performing multi-point real-time monitoring and hydrogen peroxide decomposition risk target factor calculation on the temperature, pressure, conductivity and organic matter content of hydrogen peroxide purification equipment to obtain an evaluation result of the influence of temperature gradient and impurity content on hydrogen peroxide stability; carrying out predictive control parameter calculation on the heating power, the cooling flow and the feeding rate to obtain a safe operation parameter range of the equipment; and performing dynamic safety boundary calculation on the temperature distribution and the concentration boundary in the purification process to obtain a hydrogen peroxide decomposition risk early warning index. Through construction of the dynamic safety boundary and calculation of the risk early warning index, stable operation of the hydrogen peroxide purification equipment is realized, so that the production process of the electronic-grade high-purity hydrogen peroxide is safer, more stable and more efficient.

The invention relates to a conjugated microporous polymer based on a dicarbazole structure and a preparation method and application thereof, the conjugated microporous polymer has a dicarbazole structure unit and a nitrogen-containing aromatic structure unit, the dicarbazole monomer structure is represented by the formula (I): # imgabs0 #, in the structure represented by the formula (I): R = H, R1 = C = H or R1 = H, R = C = H; the structure of the nitrogen-containing aromatic monomer is shown as a formula (II): # imgabs 1 #, wherein the aromatic structure in the structure shown as the formula (II) is any one of benzene, pyridine, pyrimidine, pyrazine and pyridazine. A plurality of conjugated microporous polymers with excellent photocatalytic performance are obtained by changing aromatic monomers with different nitrogen contents, and the conjugated microporous polymers can be applied to high-efficiency production of hydrogen peroxide under photocatalytic conditions.

The invention belongs to the technical field of rare and precious metal recovery, and particularly relates to a method for recovering metallic silver from waste crystalline silicon battery pieces, which comprises the following steps: (1) putting the waste crystalline silicon battery pieces into an inorganic alkali aqueous solution for soaking reaction to obtain an aluminum-containing solution and dealuminized crystalline silicon pieces; (2) adding the dealuminized crystal silicon wafer into a mixed solution of organic acid and hydrogen peroxide for soaking reaction, filtering and washing to respectively obtain silver-containing filtrate and a silver-removed silicon wafer; (3) carrying out chlorination precipitation reaction on the silver-containing filtrate and a chlorine source, filtering and drying to obtain silver chloride powder; (4) adding silver chloride powder into an ammonia water solution, heating and stirring to completely dissolve silver chloride to obtain a silver-ammonia solution; (5) adding PVP (Polyvinyl Pyrrolidone) into the silver-ammonia solution, heating and stirring until the PVP is completely dissolved, adding ascorbic acid, and carrying out reduction reaction at room temperature to obtain metal silver powder precipitate; and filtering, washing and drying the precipitate to obtain the spherical silver powder. According to the method, the silver recovery efficiency is high, the spherical nanoscale silver powder can be prepared, and the purity is high.

The invention relates to a process for recycling and regenerating a waste lithium iron phosphate positive electrode material by using a specific chelating agent. The method comprises the following steps: carrying out heat treatment on a waste lithium iron phosphate positive electrode material, putting separated waste lithium iron phosphate powder into a ball milling tank, adding organic acid and a chelating agent, and carrying out ball milling; after the ball milling is finished, adding hydrogen peroxide, uniformly stirring and mixing, adjusting the pH value to 2-3 by using nitric acid, and filtering to obtain a filter cake which is iron phosphate; adding saturated sodium carbonate into the filtrate, precipitating, and recovering lithium carbonate; putting the iron phosphate, the lithium carbonate, the iron source, the lithium source and the phosphorus source in the step S3 into a ball mill for ball milling, and performing high-temperature solid-phase sintering after ball milling to obtain a regenerated lithium iron phosphate material; the chelating agent disclosed by the invention is prepared from (9ci)-2-(2-propenyl)-1-cyclopentene-1-carboxylic acid, 2-mercaptobenzimidazole carboxylic acid, an ethylene boric anhydride pyridine complex and potassium persulfate. The regenerated lithium iron phosphate material prepared by the method has excellent electrochemical performance.

The present invention belongs to the technical fields of nanomaterials, analytical detection, and food safety, and specifically relates to a single-atom POD-mimicking enzyme nanomaterial, a preparation method thereof, and a food safety detection application. The single-atom POD-mimicking enzyme nanomaterial comprises a noble metal Os and a defective metal oxide, wherein the defective metal oxide is an oxide of metal Cu, and the Os is anchored on the defective metal oxide in the form of single atoms. The present invention also relates to the use of the single-atom POD-mimicking enzyme nanomaterial in the preparation of a detection reagent having POD activity and in the colorimetric detection of hydrogen peroxide or nitrite.

The invention provides a material for removing sodium ions in saline-alkali soil and a preparation method, and relates to the field of sodium ion adsorbents, the preparation method comprises the following steps: (1) lignin modification: under a water bath condition, dissolving sulfate lignin in a mixed solution of analytically pure acetic acid and 30% hydrogen peroxide, then adding ferric chloride, reacting for 1.5-2.5 hours, diluting with distilled water by 7-8 times, centrifuging and washing to obtain modified lignin; drying to obtain oxidized lignin; (2) hydrogel synthesis: mixing and stirring the oxidized lignin and analytically pure acrylic acid, adding a cross-linking agent and an initiator, and reacting in a drying oven at 65-75 DEG C for 1.5-2.5 hours to form a sodium ion adsorption material with a porous interpenetrating network structure; by modifying the lignin, particularly introducing more hydroxyl and carboxyl groups, the performance of the lignin in the application of adsorbing ions, preparing hydrogel and the like can be improved.

The invention belongs to the technical field of acyclic compounds, and particularly relates to a preparation method of tert-butyl peroxyisobutyrate. Stirring and cooling a solvent, a tert-butyl hydroperoxide aqueous solution and deionized water to obtain a mixed solution A; adding liquid caustic soda and a solid base catalyst into the mixed solution A under a stirring condition, and continuously stirring for reaction to obtain a mixed solution B; under the stirring condition, isobutyryl chloride and a water-soluble distributing agent are added into the mixed solution B, stirring reaction continues to be conducted, and a mixed solution C is obtained; standing and layering the mixed solution C, separating to obtain a tert-butyl peroxyisobutyrate crude product, and refining the tert-butyl peroxyisobutyrate crude product to obtain the tert-butyl peroxyisobutyrate. According to the method, the raw material utilization rate is increased, the reaction speed is increased, the reaction time is shortened, and the product yield is high.

The invention provides lactobacillus plantarum XZFMCC101.23155, a probiotic agent and application of the lactobacillus plantarum XZFMCC101.23155 and belongs to the technical field of microorganisms. The invention provides lactobacillus plantarum XZFMCC101.23155, and the preservation number of the lactobacillus plantarum XZFMCC101.23155 is GDMCC No: 65783. The lactobacillus plantarum XZFMCC101.23155 can tolerate hydrogen peroxide, a fermentation product of the lactobacillus plantarum XZFMCC101.23155 has the capacity of removing DPPH, hydroxyl free radicals and superoxide anions, and the total antioxidant activity is high. The fermentation product can also significantly reduce the MDA content in mouse serum, significantly improve the SOD level in mouse serum, improve the GSH content in mouse serum and the like. The lactobacillus plantarum XZFMCC101.23155 and commercial zymophyte are jointly used as a leavening agent to prepare the cheese, and the antioxidant activity of the cheese can be remarkably improved.

The invention discloses a method for recycling a waste lithium battery positive electrode material, and relates to the technical field of lithium battery positive electrode materials. When the lithium battery positive electrode material is prepared, the waste lithium iron phosphate battery is discharged and then disassembled, a current collector is separated through cyclic soaking in cold and hot water, lithium ions are selectively leached through sulfuric acid-hydrogen peroxide after calcination, and the recycled lithium carbonate is obtained through recycling; preparing a carbonic acid ternary precursor by using a coprecipitation method; mixing the carbonic acid ternary precursor, recycled lithium carbonate, silicon monoxide, lithium fluoride and neodymium oxide, and performing secondary calcination to obtain a doped modified ternary positive electrode material; compounding and coating lanthanum, aluminum and zinc on the surface of the doped modified ternary positive electrode material by using a potassium-sodium alloy reduction method to prepare a coated modified ternary positive electrode material; and mixing the coated modified ternary positive electrode material with a conductive agent and a binder, and coating a carbon-coated aluminum foil with the mixture to prepare the lithium battery positive electrode material. The lithium battery positive electrode material prepared by the invention has high charge-discharge specific capacity, long cycle life and good rate capability.

The invention provides a method for recovering tungsten and rhenium from tungsten-rhenium alloy waste, which comprises the following steps: S1, collecting the tungsten-rhenium alloy waste, and crushing to obtain tungsten-rhenium alloy waste powder; s2, the cleaned tungsten-rhenium alloy waste powder is put into a reactor, and then a strong alkaline solution containing hydrogen peroxide is added into the reactor for a reaction; in the strong alkaline solution, the concentration of OH <-> dissociated by the strong alkaline substance is 2.0-4.0 mol / L, and the mass fraction of hydrogen peroxide in the strong alkaline solution is 5-15%; in the reaction process, synchronously and continuously introducing oxidizing gas into the reactor and applying ultrasonic treatment; and S3, after the reaction is finished, carrying out solid-liquid separation, collecting a leaching solution, then separating tungsten-containing ions and rhenium-containing ions in the leaching solution to respectively obtain a tungsten-containing ion solution and a rhenium-containing ion solution, and carrying out subsequent treatment to obtain tungsten salt or metal tungsten and rhenium salt or metal rhenium. According to the method, the passivation problem can be effectively solved, and the leaching rate and recovery rate of W and Re can be increased.

The preparation method comprises the following steps: S1, preparing a phosphoric acid solution, a hydrogen peroxide solution, a Ti salt, a phosphor salt solution and a ferrite solution; s2, Ti salt and the ferrite solution are mixed, and a titanium iron salt solution is obtained; mixing the phosphoric acid solution and the phosphorus salt solution to obtain a phosphorus source solution; s3, adding the titanium iron salt solution into a reaction kettle, and adding the hydrogen peroxide solution; s4, adding the phosphorus salt solution into the reaction kettle to obtain yellow slurry; s5, after the color of the slurry is heated to be white, white slurry is obtained; s6, carrying out solid-liquid separation on the white slurry to obtain an iron phosphate dihydrate filter cake; and S7, drying and calcining the iron phosphate dihydrate filter cake to obtain the Ti-doped battery-grade anhydrous iron phosphate. The titanium-doped iron phosphate is firstly prepared by a one-step method, the pH value of the reaction system is controlled by controlling the molar ratio of the iron element to all phosphorus elements in total phosphorus, ammonium phosphate and phosphoric acid in the reaction system, and the retention of the Ti element in the finished product and the regulation and control of the iron-phosphorus ratio in a specified range are ensured.

The invention provides a method for recycling a waste lithium iron phosphate battery positive electrode material based on organic solvent soaking. The method comprises the following steps: mixing waste lithium iron phosphate positive electrode material powder and a crown ether chelating type co-dissolving agent to obtain a leaching solution; hydrogen peroxide is added into the leachate, the pH is adjusted, a diammonium hydrogen phosphate solution is added, and iron phosphate and filtrate containing lithium ions are obtained; adding sodium carbonate into the filtrate containing lithium ions, and adjusting the pH value to obtain lithium carbonate; mixing the iron phosphate with a phosphoric acid solution to obtain purified iron phosphate; and mixing the purified iron phosphate, lithium carbonate and acetylene black to obtain the regenerated lithium iron phosphate positive electrode material. According to the method for recycling the positive electrode material of the waste lithium iron phosphate battery based on soaking of the organic solvent, the leaching rate of the lithium element is effectively increased, the selectivity to other metal ions is low, and the regenerated positive electrode material of the lithium iron phosphate battery has relatively high discharge capacity and good cycling stability.

The invention discloses a quality-divided treatment and recycling method for lead-zinc beneficiation wastewater, and belongs to the technical field of beneficiation wastewater treatment.The method comprises the steps that beneficiation tail water is introduced into a Fenton reaction tank, a catalyst is added firstly, then hydrogen peroxide is added, a Fenton oxidation reaction is conducted, after the Fenton oxidation reaction is finished, the beneficiation tail water is introduced into a coagulation reaction tank, caustic soda liquid is added, and the mixture is stirred and mixed uniformly; adding a precipitating agent, a flocculating agent and a stabilizing agent, and flocculating and settling the precipitate; introducing the beneficiation tail water added with the treatment agent into a honeycomb inclined tube sedimentation tank, further flocculating and settling, then returning flocculated precipitates in a bottom tank to a coagulation reaction tank, and discharging redundant bottom mud into a tailing pond; and settled clear water enters a clear water tank and is used as production water for ore grinding classification and flotation operation. According to the invention, through quality-divided treatment-quality-divided recycling of the beneficiation wastewater, it is ensured that the beneficiation tail water meets the requirements of ore grinding and flotation production indexes, the treatment cost of concentrate overflow water and filtered water is reduced, and the purpose of 100% recycling of the beneficiation wastewater after quality-divided treatment is achieved.