3822 results about "Formic acid" patented technology

A forest fire retardant composition contains a retardant compound that includes a potassium salt. The potassium salt may include a potassium salt of an organic acid, a potassium salt of an inorganic acid, or mixtures thereof. The organic acid may include formic acid, acetic acid, propanoic acid, butanoic acid, lactic acid, oxalic acid, malic acid, gluconic acid, tartaric acid, uric acid, malic acid, or citric acid. The inorganic acid may include sulfuric acid, phosphoric acid, carbonic acid, or hydrochloric acid. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention discloses a preparation method of a permanent red pigment for an acid and alkali resistant coating, and belongs to the technical field of pigment preparation, a 2B acid derivative is diazotized and then coupled with 2-hydroxy-3-naphthoic acid, then a calcium chloride aqueous solution is added for color lake to obtain pigment particles, and finally the surfaces of the pigment particles are coated with silicon dioxide to obtain the permanent red pigment for the acid and alkali resistant coating. According to the permanent red pigment for the acid and alkali resistant coating prepared by the preparation method disclosed by the invention, the acid and alkali resistance and environmental stability of the pigment are further enhanced while the excellent characteristics of original pigment red 48: 2 are maintained, and the application performance of the pigment is remarkably improved.

The invention discloses a preparation method of a GLP-1R agonist Orforglipron, which comprises the following reaction steps: carrying out four-step reaction on an oxopiperidine compound (1) and (4-fluoro-3, 5-dimethylphenyl) hydrazine (2) to obtain a compound 8, and carrying out seven-step reaction on 5-bromo-indolecarboxylic acid (9) to obtain a compound 17. Then, the compound 8 and a compound 17 are subjected to an acid amine condensation reaction, and Orforglipron (LY3502970) is obtained. The preparation method is relatively low in cost, easy to operate, relatively short in synthetic route and suitable for industrial production and application, and the total yield can reach 32%.

The invention discloses a formate dehydrogenase mutant and application of the formate dehydrogenase mutant in catalysis of carbon dioxide reduction, the 223 arginine (Arg) of an amino acid sequence of formate dehydrogenase PsFDH48 derived from Paracoccus sp. MKU1 is mutated into proline (Pro) or the 242 proline (Pro) is mutated into phenylalanine (Phe) through a site-specific mutagenesis technology, and the obtained mutants R223P and P242F have higher catalytic activity and can be applied to catalysis of carbon dioxide reduction. The catalyst can catalyze CO2 to generate formic acid more effectively in vitro, and has potential application value in the aspects of efficient activation of CO2 and further conversion of CO2 into other mono-carbon compounds through cascade reaction.

The invention provides triazole anthracene methyl formate for a photosensitive resin composition, and relates to the field of photopolymerization. The invention also comprises a photosensitive resin composition containing the triazole anthracene methyl formate, a photosensitive dry film containing the triazole anthracene methyl formate, and applications of the photosensitive resin composition and the photosensitive dry film. The triazole formic acid anthracene methyl ester disclosed by the invention has photosensitivity, can be used as a photosensitizer in the photosensitive resin composition, can improve the adhesive force of the photosensitive resin composition on various metal surfaces, and has the characteristic of low migration; the method can be widely applied to the photo-curing fields of dry films, paints, coatings, printing ink, forming materials and the like.

The invention belongs to the technical field of mine filling materials, and discloses a solid-waste-based mine filling material and a preparation method thereof. The filling material comprises 70-100 parts of red mud, 1-10 parts of fly ash, 1-10 parts of slag, 5-20 parts of an acid activator, 10-30 parts of aggregate, 1-5 parts of a water reducing agent and 50-100 parts of water. The doping amount of the red mud of the filling material can reach 60% or above, the red mud is used as a main cementing material, formic acid, acetic acid, oxalic acid and other small-molecular organic acids are used as an acid activator, and an acid environment provided by the acid activator can reduce the alkalinity of the red mud and promote the dissolution of the red mud; the water and calcium silicate in the red mud can be more easily subjected to hydration reaction to generate a large amount of hydration products such as C-S-H gel, so that the strength of the filling material is enhanced. The acid activator used in the invention is low in cost, the cementing material and the aggregate are industrial solid wastes, and the cost of the mine filling material is reduced while the problem of resource utilization of the industrial solid wastes is solved.

The invention relates to the field of organic chemical synthesis, in particular to a synthetic method and application of pyrimidone compounds. The invention provides a synthesis method, reactants are o-amino heterocyclic formamide and triethyl orthoformate respectively, a solvent system is a hexafluoroisopropanol solvent, and a product is a heterocyclic pyrimidone compound. The reaction does not need strong acid or strong alkali conditions, does not need additional reducing agents or oxidizing agents, does not need transition metal catalysis, is economical and practical, the reaction conditions are relatively mild, and the synthesized pyrimidone compound has a good antibacterial effect.

The invention discloses a synthesis method of 2-bromomethyl-5-trifluoromethyl furan, which comprises the following steps: S1, carrying out reaction on acetoacetate and halogenated trifluoroacetone under the action of an alkaline substance and a catalyst to generate a 2-acetyl-5, 5, 5-trifluoro-4-oxovalerate crude product; s2, carrying out a cyclization reaction on the 2-acetyl-5, 5, 5-trifluoro-4-oxovalerate crude product, so as to obtain a 2-methyl-5-(trifluoromethyl) furan-3-formate crude product, and carrying out a cyclization reaction on the 2-acetyl-5, 5, 5-trifluoro-4-oxovalerate crude product to obtain a 2-methyl-5-(trifluoromethyl) furan-3-formate crude product; s3, adding an alkaline substance into the crude product, carrying out hydrolysis, and adding acid to adjust the pH value after the hydrolysis is completed, so as to obtain 2-methyl-5-(trifluoromethyl) furan-3-formic acid; s4, the 2-methyl-5-(trifluoromethyl) furan-3-formic acid is subjected to a heating decarboxylation reaction, and 2-methyl-5-(trifluoromethyl) furan is obtained; and S5, carrying out a bromination reaction on the 2-methyl-5-(trifluoromethyl) furan and a bromination reagent to obtain a final product 2-bromomethyl-5-(trifluoromethyl) furan. The raw materials used in the synthesis method are easy to obtain, use of control chemicals is not involved, and industrialization is easy to achieve.

The invention belongs to the technical field of liquid chromatography-mass spectrometry detection pretreatment, and particularly relates to a pretreatment method for liquid chromatography-tandem mass spectrometry analysis of pesticide and veterinary drug residues in serum, which comprises the following steps: (S1) carrying out heating reaction on Sc (III) salt, Cu (II) salt and 1H-pyrazole-4-formic acid (H2PyC) in a polar aprotic solvent, and cooling to obtain a green crystal, namely MOF-919; the chemical formula of the MOF-919 is [Sc < 3 > (mu3-O) (OH) < 3 >] [Cu3 (mu3-O) (mu-PyC) < 3 > (H2O) < 6 >] < 2 >; (S2) mixing the serum sample with an acetonitrile solution containing formic acid, carrying out ultrasonic treatment, vortex oscillation and centrifugation, taking supernate, and diluting the supernate with an aqueous solution containing formic acid to obtain a to-be-purified solution; and (S3) adding MOF-919 into the to-be-purified liquid, mixing, performing ultrasonic treatment, performing vortex oscillation, centrifuging, and taking supernate, thereby completing the pretreatment of the to-be-purified liquid. According to the method, the MOF-919 is used for adsorbing chemical pollutant residues in serum, especially phospholipids, so that the purpose of removing the chemical pollutant residues in blood is achieved. The method is simple and convenient to operate, small in organic solvent consumption and good in purification effect, and can be widely applied to residue analysis of chemical pollutants in serum.

The invention belongs to the technical field of nanocrystal nucleus early strength agents, and provides a damp and hot nanocrystal nucleus early strength agent, a tailing solidification filling material and a preparation method and application of the damp and hot nanocrystal nucleus early strength agent and the tailing solidification filling material. The invention discloses a molybdenum ore tailing slurry which is prepared from the following raw materials in parts by weight: 1 part of Portland cement, 4 to 6 parts of molybdenum ore tailings, 0.06 to 0.1 part of zeolite powder, 0.07 to 0.1 part of nanoscale attapulgite powder, 0.06 to 0.1 part of gamma-glycidyl ether oxypropyl trimethoxy silane, 0.03 to 0.1 part of potassium silicate, 0.04 to 0.1 part of sodium hydroxide, 0.06 to 0.1 part of calcium formate, 0.04 to 0.1 part of lithium metaaluminate and 1.25 to 1.75 parts of water. According to the technical scheme, the problem that a filling body prepared from an early strength agent in the prior art is low in early and later strength is solved, and meanwhile, the early strength agent is simple and convenient in preparation mode, low in cost and wide in application range.

The invention discloses a construction method and an identification method of characteristic chromatograms of a senecio scandens medicinal material as well as decoction pieces, standard decoction and formula granules thereof, and relates to the technical field of traditional Chinese medicine identification. The construction method of the specific chromatogram comprises the following steps: extracting a to-be-detected sample with methanol to obtain a test solution; the method comprises the following steps: dissolving 5-caffeoylquinic acid, chlorogenic acid, caffeic acid, 4-caffeoylquinic acid, rutin, hyperoside, isoquercitrin and 4, 5-dicaffeoylquinic acid with methanol to obtain a reference solution; and a liquid chromatograph is adopted for determination. A chromatographic column of the liquid chromatograph takes phenyl-methyl polysiloxane as a stationary phase, acetonitrile as a mobile phase A and 0.05 vol%-0.3 vol% formic acid aqueous solution as a mobile phase B for gradient elution. The information of the characteristic chromatogram constructed by the method is rich, and the quality of the senecio scandens medicinal material, decoction pieces, standard decoction and formula granules can be quickly and comprehensively reflected.

The present disclosure provides a method for determining content of olaflur in toothpaste by liquid chromatography-tandem mass spectrometry, comprising the following steps: obtaining to-be-tested toothpaste; dissolving the to-be-tested toothpaste in water and then adding methanol for dilution to obtain a to-be-tested solution; and placing the to-be-tested solution in a liquid chromatograph for determination under following chromatographic conditions: a C4 column; a mobile phase as a combination of phase A being methanol with 0.1% formic acid and phase B being acetonitrile, or a combination of phase A being methanol with 0.1% formic acid and phase B being water; and isocratic or gradient elution. The method can analyze the purity of organic olaflur in fluoride-containing anti-caries toothpaste and olaflur raw materials, and enables quantitative analysis of olaflur by an internal or internal standard method. Furthermore, the method can accurately and qualitatively identify olaflur through characteristic ions.

Mixed metal metal-organic frameworks (MM-MOFs) of copper-1,3,5-benzenetricarboxylate (BTC), M-Cu-BTC, wherein M is Zn(II), Ni(II), Co(II), and / or Fe(II) may be made using post-synthetic exchange (PSE) with metal ions. Such MM-MOFs may be used in H2 storage, especially Ni(II) and Co(II) MM-MOFs. Selected metal exchanged materials can provide gravimetric H2 uptake around 1.63 wt. % for Zn—Cu-BTC, around 1.61 wt. % for Ni—Cu-BTC, around 1.63 wt. % for Fe—Cu-BTC, and around 1.12 wt. % for Co—Cu-BTC.

The invention discloses a recombinant halomonas for producing polyhydroxyalkanoate as well as a construction method and application of the recombinant halomonas. The recombinant halomonas comprises an exogenous gene, the exogenous gene comprises a combination of an aldD gene, a dhaT gene and an orfz gene, and the recombinant halomonas weakens the expression of an endogenous prpc gene. According to the invention, a P34HB synthesis route is successfully constructed through a synthesis route of exogenous introduction from 1, 4-butanediol (BDO) to 4-hydroxybutyryl coenzyme A, the proportion of each monomer in the copolymer can be effectively regulated and controlled, especially after exogenous addition of short-chain fatty acids (such as formic acid, acetic acid, propionic acid, butyric acid and the like), the synthesis of copolymers such as PHB, PHBV, P34HB, P34HB3HV and the like can be further improved, and the synthesis efficiency of the copolymer is improved. And the proportion of different monomers is adjusted, so that the diversity and yield of the copolymer are enhanced.

The invention relates to a content determination method of a traditional Chinese medicine composition fingered citron drink. The traditional Chinese medicine composition is prepared from the following medicinal raw materials: fingered citron, orange peel, malt, liquorice, Chinese date, purple perilla, citron, almond and donkey-hide gelatin. The content determination method comprises the following steps: preparing a reference solution and a test solution; detecting the reference substance solution and the test solution by high performance liquid chromatography; a mobile phase adopted by the high performance liquid chromatography is an acetonitrile and formic acid aqueous solution, and the elution mode is gradient elution. According to the content determination method, the content of various components can be simply, conveniently and rapidly determined, and richer chemical information and more comprehensive basis are provided for quality evaluation of the components.

The invention provides a hydrogen water irrigation coupled carbon dioxide gas fertilizer application system and method, in the system and method, formic acid is used as a raw material to decompose and prepare hydrogen and carbon dioxide, and the decomposed hydrogen and irrigation water are mixed through an aeration head to form hydrogen water for farmland irrigation; the decomposed carbon dioxide is compressed into high-pressure carbon dioxide to be stored in a gas steel cylinder, and the high-pressure carbon dioxide is interlocked with a carbon dioxide gas detector in the greenhouse, so that the concentration of the carbon dioxide in the greenhouse can be supplemented and adjusted in real time, the coupling application of hydrogen water irrigation and carbon dioxide gas fertilizer is realized, and the growth of crops is promoted. The system and the method can reduce the use of chemical fertilizers, reduce environmental pollution and improve the soil structure, and conform to the green agriculture development concept.

The invention discloses a Cl-Bi carbon dioxide reduction electrocatalyst, a preparation method thereof and application of the Cl-Bi carbon dioxide reduction electrocatalyst in preparation of formic acid through catalytic reduction of carbon dioxide, and belongs to the technical field of electrocatalyst materials. The preparation method comprises the following steps: preparing a sodium chloride solution, adjusting the pH value with acid, adding Bi2O3, carrying out a stirring reaction, washing a reactant, and drying to obtain BiOCl; the preparation method comprises the following steps: dispersing BiOCl, carbon black and naphthol in ethanol, carrying out ultrasonic treatment to obtain ink, dripping the ink onto hydrophobic carbon paper, drying, and reducing under negative voltage to obtain the Cl-Bi carbon dioxide reduction electrocatalyst. The prepared Cl-Bi carbon dioxide reduction electrocatalyst is simple in preparation method, free of pollution, rich in raw material and low in price, and the Cl-Bi carbon dioxide reduction electrocatalyst has high formic acid production selectivity, high formic acid yield and excellent stability.

The invention discloses a preparation method of a PA6 / PEO micro-nanofiber air filtering membrane with a bent form, which comprises the following steps: (1) weighing PA6 particles and PEO powder with a certain mass, and dissolving in a formic acid solution with the mass fraction of 88% to obtain a mixed solution; (2) stirring the mixed solution to obtain a PA6 / PEO spinning solution; (3) forming a fiber membrane under a room-temperature dry condition through a gas jet spinning machine; (4) drying overnight at 60 DEG C to remove the residual solvent; (5) performing heat treatment in a drying oven, and (6) at normal temperature, placing the fiber membrane subjected to heat treatment in a container, and adding deionized water to immerse the fiber membrane; (7) heating the container in a water bath, and repeating the water bath treatment twice; and (8) immediately taking out the sample after the reaction is finished, and performing vacuum drying treatment. According to the invention, oily and salty ultrafine particles can be efficiently filtered at the same time, and the technical problem that effective filtration of fine oily and salty particles is difficult to realize in the prior art is solved by optimizing the structural characteristics of the fiber membrane.

The present invention belongs to the technical field of methane resource utilization and plasma chemical synthesis, and relates to a method for plasma-catalytic oxidation of methane to methanol. Specifically as follows: In a dielectric barrier plasma reactor, methane and oxygen are used as raw material gases. Methane and oxygen are activated through a DBD reactor, and methanol is synthesized in one step under the action of a non-metal supported catalyst. The method of the present invention has high methanol selectivity, and the catalyst used does not generate carbon dioxide. The supported boron-based catalyst adopted in the present invention enables the reaction to occur at low temperature and normal pressure, with mild conditions and simple operation; the process belongs to a one-step method, with a simple process flow, a green method, and solves the problem that the conventional catalytic oxidation of methane to methanol requires high temperature and high pressure. It is applicable to the oxidation synthesis of organic compounds from various lower hydrocarbons, and products such as formaldehyde, formic acid, ethanol, and acetic acid can be obtained in addition to methanol.

The purpose of the present invention is to provide a method for producing a methyl compound. Provided is a method for producing a methyl compound using formic acid.

The invention discloses a method for preparing a methanol fuel cell anode catalyst by doping a modified multi-walled carbon nanotube carrier. The method comprises the following steps: 1) acidizing an unmodified multi-walled carbon nanotube; (2) preparing the cerium oxide doped modified multi-walled carbon nanotube; and 3) preparing the cerium oxide doped modified multi-walled carbon nanotube carrier loaded PtFe bimetallic alloy catalyst. According to the method disclosed by the invention, the MWCNTs are induced by doping CeO2 to generate more oxygen vacancy defects, so that anchoring of more active sites of the PtFe alloy is facilitated, and MOR is promoted to improve the activity of the catalyst; the stable Ce < 4 + > can deform the surface structure of Pt, so that the binding bond energy of COads and-OH is stronger, and an anti-poisoning effect is achieved; the introduced Fe element and Pt have metal electronegativity difference, so that the adsorption bond energy of formic acid, formaldehyde and carbon monoxide intermediates generated by gradual dehydrogenation of Pt and methanol can be weakened, and the anti-toxicity effect is achieved; and the PtFe alloy and the CeO2 / MWCNTs are in synergistic interaction, so that the stability of the catalyst can be enhanced.

The invention discloses a method for synthesizing alkyl carbonate through gas-phase carbonylation. Comprising a dechlorination method and a chlorine circulation process in the process of preparing alkyl carbonate through a gas-phase oxidative carbonylation reaction of carbon monoxide and alkyl nitrite. The content of water and alkyl alcohol in circulating gas is controlled through solvent absorption, alkyl chloride is synthesized with a chlorine supplementing agent HCl and alkyl chloroformate under the action of a dechlorinating agent, and the alkyl chloride is separated from a product through gas-liquid separation. When alkyl carbonate is produced by adopting the dechlorination method and the dechlorination process, the problem of equipment corrosion caused by chlorides can be avoided, the dechlorination process is a low-cost and environment-friendly chlorine circulation process, and stable operation of an industrial device is realized.

The invention discloses a quick-setting high-strength expansive type leakage crack plugging material and method and application, and belongs to the technical field of cement-based material admixtures, the quick-setting high-strength expansive type leakage crack plugging material is prepared by adopting a mixing method, and the quick-setting high-strength expansive type leakage crack plugging material comprises a base material formed by compounding cement, desulfurized gypsum, calcium oxide, alkaline aluminum oxide, calcium formate, hydrated calcium silicate, carboxyl cellulose and a solid polycarboxylate superplasticizer; the active component is formed by compounding polyaluminum sulfate, magnesium sulfate, disodium ethylene diamine tetraacetate, borax and a defoaming agent; the superfine fly ash, the superfine silicon dioxide, the superfine hydroxyapatite, the superfine zinc sulfate, the nano titanium dioxide and the superfine boron nitride are compounded to form a structure regulating functional component. The three components are uniformly stirred by adding water, and then are mixed with an exciting agent to be used for plugging leakage cracks and filling gaps. The leakage plugging material provided by the invention has the advantages of scientific and reasonable composition, simple preparation and application methods, rapid curing, high strength, good durability, micro-expansion and the like, and has good plugging and filling effects on water bursting, water permeation and gas.

The invention relates to a serum liquid chromatography-tandem mass spectrometry pretreatment method, which comprises: (S1) mixing a serum sample and a formic acid-containing acetonitrile solution, carrying out ultrasonic treatment, vortex oscillation and centrifugation, taking the supernatant, and diluting with a formic acid-containing aqueous solution to obtain a liquid to be purified; (S2) mixing the to-be-purified liquid with PCN-777, performing ultrasonic treatment, vortex oscillation and centrifugation, and taking supernate to obtain to-be-detected liquid; the PCN-777 is a C24H23N3O16Zr3 phospholipid removal material, and the PCN-777 is a C24H23N3O16Zr3 phospholipid removal material, and the PCN-777 is a C24H23N3O16Zr3 phospholipid removal material. According to the present invention, the serum ultra-high performance liquid chromatography-tandem mass spectrometry pretreatment method is developed by using the known MOFs material PCN-777, such that different types of phospholipids in the serum can be specifically, rapidly and effectively removed, the efficient recovery and detection of pesticide and veterinary drugs can be achieved, and the interference of phospholipids can be avoided.

The application discloses a thickened oil viscosity reducer for a main viscosity contribution component of colloid and a preparation method thereof. The thickened oil viscosity reducer comprises the following components in percentage by weight: diethylene glycol methyl ether 25-35%, propylene glycol formate 15-25%, dispersant 5-8%, chelating agent 2-4%, anti-coking agent 0.5-1%, anti-swelling agent 1-2% and corrosion inhibitor 1-2%; and the balance is water. The application is a polar + non-aromatic hydrocarbon solvent system; completely avoids high-risk substances such as nonylphenol polyoxyethylene ether, petroleum sulfonate sodium and organic chlorine; is designed in pertinence and can effectively inhibit metal-induced asphaltene bridging; can withstand working conditions from normal temperature to 250 DEG C and up to 300 DEG C; thermal stability is significantly enhanced, and residual carbon after aging is lower than 8%; viscosity reduction efficiency is higher; the system is more stable, flexible in compounding and suitable for field construction.

The invention relates to low-temperature lead-free formic acid solder paste and a preparation method and application thereof, and belongs to the technical field of welding materials. The low-temperature lead-free formic acid solder paste is prepared from the following raw materials in percentage by mass: 85-90% of alloy welding powder and 10-15% of scaling powder, the soldering flux comprises the following raw materials in parts by weight: 10-15 parts of an activating agent, 1-5 parts of a rheological agent, 20-30 parts of an organic solvent, 20-30 parts of a paste forming agent, 3-5 parts of a surfactant and 0.1-0.5 part of a corrosion inhibitor, the activating agent is a composition of hydrogenated dimer acid, glycollic acid and ethylenediaminetetraacetic acid, and the organic solvent is a composition of tetrahydrofurfuryl alcohol and cyclohexanol. The paste forming agent is polyethylene glycol. The solder paste is suitable for a low-temperature welding process at the temperature of 120-150 DEG C, welding energy consumption can be reduced, the residual rate after welding is low, follow-up cleaning is not needed, the production environment can be improved, and the production cost can be reduced.

The invention provides a biosensing probe based on a pyrene-doped metal organic framework composite material, and a preparation method and a reagent thereof. The pyrene-doped metal organic framework composite material PCA-UiO-66 is prepared by adopting a one-pot method, the target product can be prepared by directly introducing 1-pyrenecarboxylic acid in the synthesis process of the UiO-66, PCA in the prepared PCA-UiO-66 composite material has stability and flexibility in MOF, the PCA-UiO-66 composite material is suitable for application in the aspect of biosensing, and the application range is wide. The biosensing probe Apt (at) PCA-UiO-66 prepared on the basis has good flexibility, excellent selectivity and anti-interference capability, excellent reproducibility and stability, wide detection range and extremely low detection limit.

The invention provides chlorotrifluoroethylene continuously prepared based on a microchannel reactor and a preparation method of the chlorotrifluoroethylene, and the chlorotrifluoroethylene comprises the following raw materials in parts by weight: 1, 1, 2-trifluoro-1, 2, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3 The low-temperature refrigerant refrigerant is prepared from the following components in parts by weight: 90 to 100 parts of 1, 2-trichloroethane, 1 to 5 parts of a zinc fluoride induced palladium-copper bimetallic catalyst, 8 to 15 parts of a cyclohexyl dimethyl ether-formic acid composite hydrogen donor, 0.5 to 2 parts of trifluoroacetic anhydride, 0.1 to 0.5 part of a perfluoropolyether lubricant, a proper amount of a low-temperature mixed refrigerant and 15 to 20 percent by weight of diluted hydrochloric acid. According to the invention, the preparation efficiency and product purity of chlorotrifluoroethylene can be improved, and stable operation of the preparation system and reasonable treatment of byproducts can be guaranteed.

The invention discloses a method for producing formic acid by reducing carbon dioxide through a hydrogen-driven hollow fiber catalytic membrane reactor, and relates to the technical field of carbon dioxide resource utilization. In order to solve the problems of low formic acid product selectivity, low CO2 conversion efficiency and high cost in the prior art, hydrogen is used as the only energy source, and a hollow fiber non-porous membrane is utilized to realize bubble-free efficient mass transfer of H2 to form a compact hydrogen-rich layer on the surface; the nano-metal particle catalyst loaded on the surface of the membrane synergistically activates hydrogen at a gas-liquid-solid three-phase interface to generate active hydrogen atoms, and CO2 transferred in a dissolved state or a gas phase is subjected to directional catalytic reduction to form formic acid with high selectivity. The method is operated at normal temperature and normal pressure, so that the H2 utilization efficiency and the CO2 mass transfer efficiency are remarkably improved, and the byproduct separation cost and the operation energy consumption are effectively reduced; the produced formic acid can be used as an important chemical raw material and intermediate, an excellent liquid hydrogen storage carrier, a formic acid fuel cell fuel and a microbial carbon source, and has wide application value.

The invention relates to a method for synthesizing tetrasubstituted ‑1,3‑enedicarboxylic acid, and discloses a method for synthesizing tetrasubstituted ‑1,3‑enedicarboxylic acid. The method comprises the following steps: using 1,3‑enyne and iodide as raw materials, potassium formate as a formate source, DABCO as a hydrogen transfer catalyst, Ir(bpy)2(dtbpy)PF6 as a photocatalyst, and cesium carbonate as a base, introducing CO2 under normal pressure, and obtaining an enedicarboxylic acid compound with an excellent to good yield under room temperature and visible light irradiation for 24 hours. The method has mild reaction conditions, good regioselectivity, and good functional group tolerance, and makes up for many deficiencies of the prior art.