The application discloses a multifunctional plugging removing agent for oil extraction and acidification of oil fields and a preparation method thereof. The plugging removing agent comprises the following raw materials in percentage: 10-15% of
hydrochloric acid, 5-8% of
formic acid, 5-8% of
citric acid, 0.3-0.5% of OP-10 and 1-1.5% of a modified additive, and the balance is water. In the using process of the acidification plugging removing agent, the modified additive can reduce the interfacial tension, change the rock surface into water wettability, make the residual acid after reaction and loose particles more easily carried back, significantly improve the permeability
recovery rate, the
nano silicon dioxide in the modified additive can fill the cavity of the surface polysiloxane
chain segment, can prevent the
curling of the polysiloxane
chain segment and the collapse of the
network structure, and further improve the
salt resistance of the modified additive, ensure the penetration effect of the acid liquid, the cage type
silsesquioxane structure on the surface can form a dense three-dimensional network, greatly improve the
mechanical strength,
shear resistance and long-term
thermal stability of the
oil displacement system, and is not easy to degrade and fail.