5893 results about "Smelting" patented technology

The invention relates to the technical field of metallurgical raw material batching control, and discloses a bottom blowing smelting furnace automatic batching intelligent control method and system based on deep learning, and the method comprises the steps: achieving intelligent batching through multi-source data fusion, physical constraint modeling and dynamic optimization control; edge calculation is adopted to realize data space-time alignment and purification, and physical and economic mixed features are constructed; modeling a reaction path based on a graph neural network, and embedding conservation law constraint to synchronously predict key process parameters; and finally, in combination with gradient sensitivity analysis and reinforcement learning, constructing a differentiable optimization framework to realize multi-target dynamic ratio decision and real-time compensation control, and forming a perception-decision-execution closed loop. The system comprises a global sensing and data purification module, an intelligent decision-making and optimization batching module and a high-precision execution and closed-loop control module. According to the invention, the batching strategy is adaptively adjusted, and optimal resource allocation and maximum economic benefit are realized.

The invention discloses a smelting wastewater trace arsenic real-time monitoring method based on an electrochemical sensing array, and relates to the technical field of electrochemical detection.The method comprises the steps that bypass sample flow is established through a peristaltic pump and pre-filtered, and stable sample flow is obtained; the sample flow is divided into a first passage and a second passage, and a form distinguishing sample flow is obtained after oxidation setting and medium equalization; performing short-time adsorption equilibrium to obtain an interface state parameter set, executing multi-segment coded deposition control based on the parameter set, and collecting a dissolution current curve; a dissolution signal set is obtained by applying single-frequency perturbation signals, characteristic peak parameters are extracted and subjected to correlation calculation with a multi-section response matrix, the total arsenic concentration and the pentavalent arsenic concentration are calculated through a weighted inversion algorithm, and a confidence interval is obtained; and calculating the concentration of the trivalent arsenic and determining an uncertainty range according to the two. According to the method, the quality judgment result is linked with the dynamic adjustment of the sampling flow, the potential amplitude and the deposition duration, so that the self-adaptive optimization control of the detection process is realized.

The invention relates to the technical field of steel smelting, and provides low-temperature corrosion-resistant steel for a high-cold frozen soil environment and a preparation method of the low-temperature corrosion-resistant steel. The invention relates to low-temperature corrosion-resistant steel for a high and cold frozen soil environment, which is prepared from the following components in percentage by mass: 0.04 to 0.06 percent of C, 0.15 to 0.40 percent of Si, 0.80 to 1.20 percent of Mn, less than or equal to 0.025 percent of P, less than or equal to 0.010 percent of S, 0.30 to 0.60 percent of Cr, less than or equal to 0.50 percent of Ni, 0.20 to 0.50 percent of Cu, 0.010 to 0.030 percent of Nb, 0.010 to 0.030 percent of Ti, 0.0010 to 0.015 percent of La, 0.0020 to 0.020 percent of Ce and the balance of Fe and inevitable impurity elements. Wherein the proportional relation of Nb, Ti, La and Ce is (Nb + Ti) / (La + Ce), and the value of the (Nb + Ti) / (La + Ce) is 1.5-9. Through the technical scheme, the problem of poor low-temperature toughness of steel in related technologies is solved.

The utility model discloses an energy-saving flue gas treatment device for an electric melting furnace, and relates to the technical field of flue gas treatment of electric melting furnaces. The device comprises a base and further comprises a purification box arranged on one side of the top of the base, a heat exchange box is arranged on the other side of the top of the base, a smoke inlet flue is connected to one side of the top of the heat exchange box in an inserted mode, and a liquid level meter is arranged at the front end of the heat exchange box. The spraying dust-settling assembly is arranged on the other side of the purifying box, water in the purifying box is pumped out through the pump machine during use, impurities in the filter cover are used for filtering, the situation that the impurities are sucked into the pump machine and attached to an impeller for a long time, and normal operation of the pump machine is affected is avoided, the impurities are conveyed into the annular spraying pipe through the conveying pipe, and the water purifying efficiency is improved. And then the flue gas which is fused with the water body and absorbs impurities is further absorbed and subjected to dust falling treatment under spraying of the spraying opening, so that the flue gas treatment effect of the device by utilizing a liquid absorption method is further improved, and the practicability is high.

The present application belongs to the technical field of gaseous arsenic adsorption, and particularly relates to a sulfur-tolerant gaseous arsenic adsorption material, a preparation method and application thereof. Manganese oxide and an iron source are mixed and placed in a ball mill jar, then the ball mill jar is sealed, argon is filled into the jar, and the iron-modified manganese oxide adsorption material is obtained by ball milling. The addition of iron improves the sulfur tolerance of manganese oxide, so that the adsorbent still has high gaseous arsenic adsorption capacity under high-concentration SO2 conditions, and is suitable for the removal of gaseous arsenic in typical high-SO2 flue gas, i.e. non-ferrous smelting flue gas. The preparation method is simple, the cost is low, the gaseous arsenic adsorption capacity is large, and the present application has a wide application prospect.

The invention relates to the technical field of non-ferrous metal smelting flue gas treatment and resource utilization, and discloses a non-ferrous metal smelting multi-source flue gas efficient mixing and intelligent regulation and control method and system.The method comprises the steps that flue gas from different kilns enters a main flue through a multi-source flue gas branch regulation and control unit, and through rotational flow momentum, the multi-source flue gas enters the main flue; the basic consistency of each source flue gas structure is achieved; carrying out real-time evaluation on the mixed smoke on a key section; the multi-point sensor array continuously measures data and calculates a uniformity index to realize instant identification of flow field uniformity, time stability and local anomaly; based on measurement data, the intelligent control and operation optimization unit solves a comprehensive performance function in real time on a DCS / PLC platform. The system comprises a plurality of flue gas outlets, a top-blown furnace discharge outlet, a multi-source flue gas branch regulation and control unit and an annularly-collected flue gas total outlet. According to the method, the influence of inlet disturbance on the mixing quality is regulated and reduced from the source.

The invention discloses a vacuum negative pressure vibration assisted precision casting forming method. The method comprises the steps of model preparation, sand box and dry sand pretreatment, layered vibration sand filling, film covering vacuumizing, molten metal smelting and purification treatment, negative pressure vibration pouring, pressure maintaining solidification, segmented temperature control and pressure relief box opening and multi-stage cleaning aftertreatment. The core of the method is that mechanical vibration and a vacuum negative pressure technology are deeply coordinated and penetrate through the whole process of modeling, pouring and solidification, and meanwhile, a series of fine control means such as dry sand accurate pretreatment, molten metal rotary blowing degassing and instantaneous inoculation, stepped negative pressure control, temperature-related segmented pressure relief and two-stage shot blasting cleaning are matched; through dynamic cooperation of vibration and negative pressure, the sand mold compaction uniformity, the molten metal mold filling capacity and the solidification feeding effect are remarkably improved, the casting defects of air holes, shrinkage porosity, insufficient pouring and the like are effectively reduced, and the internal density, the size precision and the surface quality of a casting can be remarkably improved.

The invention discloses a wire rod for 2000MPa-level prestressed steel with the large specification of 15mm and a preparation method of the wire rod, and belongs to the technical field of metal material preparation and metal pressure processing. The invention aims to develop a 15mm large-specification high-performance prestressed steel wire rod with a novel component system and a matched production process thereof, the tensile strength of the wire rod is greater than or equal to 1200MPa, and the percentage reduction of area (after aging) is greater than or equal to 30%; the product can be used as a large-specification high-strength high-speed rail plate prestressed steel wire and a 1960-2000MPa-grade high-performance prestressed steel wire and a steel strand. According to the method, the technological process of molten iron pretreatment, converter smelting, LF refining, RH refining, square billet continuous casting, casting billet slow cooling pit slow cooling, casting billet heating, high-pressure water descaling, controlled rolling and controlled cooling and PF line heat preservation channel slow cooling and a complete and controllable production process system are adopted; and the harsh requirements of large-size high-performance prestressed materials of modern important projects on the performance of the wire rod are met.

The invention relates to the technical field of alloys, in particular to a weldable high-temperature corrosion-resistant nickel-based alloy and a preparation process thereof. The nickel-based alloy comprises Cr, Mo, W, Ti, Al, Nb, Co, B, Zr, La, C, Si, Mn, P, S and the balance Ni and inevitable impurities. The element content meets the following conditions: Al + 0.5 Ti + 0.3 Nb is greater than or equal to 3.35 wt.% and less than or equal to 3.8 wt.%, the volume fraction of the gamma'phase is correspondingly 28-34%, and the electron vacancy number Nv is less than 2.6. According to the preparation process, VIM and PESR duplex smelting, multi-pass forging, solid solution rapid cooling and aging heat treatment are adopted, and the welding process is optimized in a matched mode. The alloy has excellent welding performance while maintaining excellent high-temperature strength and corrosion resistance, and is particularly suitable for high-temperature parts needing to be welded in the fields of aerospace, energy, chemical industry and the like.

The invention relates to a preparation process optimization method of a zirconium alloy material with high fretting wear resistance, which comprises the following steps: setting a chemical component optimization range of a zirconium alloy, including specific proportions of tin, iron, niobium, chromium and oxygen elements; establishing a computer simulation model, and predicting the wear volume, tribological stability and microstructure evolution of the material under the fretting wear condition; then, a complete optimization scheme is output based on the model optimization homogenization treatment temperature interval, the hot working deformation range, the cold working cumulative deformation degree and the annealing system; and finally, a preparation process sequence including smelting, homogenization treatment, hot working deformation, cold working deformation and final heat treatment is implemented, the zirconium alloy material with the equiaxed grain structure is prepared, and the wear resistance of the zirconium alloy material is verified through an experimental fretting wear performance test. Compared with the prior art, the method has the advantages that through systematic component design and process parameter simulation optimization, the material performance is remarkably improved, and the application reliability is enhanced.

The invention relates to the technical field of medium manganese steel, in particular to high-strength and high-toughness medium manganese steel and a preparation method thereof.The preparation method is characterized by comprising the steps that S1, smelting is conducted through an electric furnace according to the chemical component ratio of the medium manganese steel, then refining is conducted through a ladle refining furnace, then vacuum degassing treatment is conducted through a vacuum circulation degassing method, and then continuous casting is conducted to form a plate blank with the thickness being 200-300 mm; s2, the plate blank is heated to 1150-1250 DEG C in a walking beam furnace, heat preservation is conducted for 2-4 hours, and then a controlled rolling technology is adopted to machine the plate blank into a steel plate within the range of 4-20 mm; s3, after rolling is completed, the steel plate is treated through a composite cooling technology of ultra-fast cooling and laminar cooling; s4, the cooled steel plate is heated to 750-850 DEG C, heat preservation is conducted for 10-60 minutes, and a ferrite and austenite double-phase structure is formed; the comprehensive performance is greatly improved, and excellent strength, plasticity, low-temperature toughness and welding adaptability are shown.

The invention relates to the field of ferrous metallurgy and forge piece manufacturing, in particular to high-toughness, ultra-pure and large-quenching-depth 40CrNiMoRE rare earth special steel for a large ring piece and a preparation method of the high-toughness, ultra-pure and large-quenching-depth 40CrNiMoRE rare earth special steel. The invention relates to a high-temperature-resistant steel material, which comprises the following chemical components in percentage by weight: 0.3 to 0.5 percent of C, 0.1 to 0.5 percent of Si, 0.4 to 0.8 percent of Mn, 0.5 to 1.5 percent of Cr, 0.5 to 1.5 percent of Ni, 0.1 to 0.5 percent of Mo, 0.05 to 0.30 percent of V, 0.0005 to 0.0030 percent of B, 0.005 to 0.030 percent of RE and the balance of Fe and inevitable impurities. Through V, B and RE comprehensive microalloying, molten steel purification, inclusion modification and grain refinement, the hardenability is improved, and the surface quenching layer depth, hardness uniformity and impact toughness are ensured. And moreover, the high-toughness, ultra-pure and large-quenching-depth large ring piece is obtained through preparation technologies such as pure smelting, airtight protection pouring and uniform deformation, and the technical problems that an existing large ring piece is low in purity, poor in toughness, insufficient in hardenability, cracked in surface quenching and the like can be effectively solved.

The invention relates to a high-performance non-quenched and tempered steel bar for a fan shaft and a manufacturing method of the high-performance non-quenched and tempered steel bar, and belongs to the field of iron-based alloys. The steel comprises the following chemical components in percentage by weight: 0.37 to 0.43 percent of C, 0.30 to 0.60 percent of Si, 1.20 to 1.70 percent of Mn, less than or equal to 0.025 percent of P, 0.030 to 0.070 percent of S, less than or equal to 0.50 percent of Cr, 0.10 to 0.30 percent of Ni, less than or equal to 0.30 percent of Mo, less than or equal to 0.30 percent of Cu, 0.010 to 0.030 percent of Al, 0.005 to 0.025 percent of Ti, 0.05 to 0.15 percent of V, 0.0100 to 0.0200 percent of N, less than or equal to 0.0002 percent of H, less than or equal to 0.0015 percent of O and the balance of Fe and inevitable impurity elements. The manufacturing process comprises the steps of converter / electric furnace smelting, LF furnace refining, RH / VD furnace vacuum degassing, continuous casting, casting blank reheating, cogging rolling, flame cleaning, intermediate blank finishing, intermediate blank heating, bar rolling, cooling and stress relief tempering. The total cross-section structure of the bar is a ferrite and pearlite structure. The bending degree per meter is smaller than or equal to 0.5 mm, the surface defect depth is smaller than or equal to 0.10 mm, and the internal quality meets the A-level requirement of the GB / T4162 standard.

The invention discloses an Al-Mg-Zn aluminum alloy plate with excellent strong plasticity and light weight characteristics as well as a preparation method and application of the Al-Mg-Zn aluminum alloy plate. The alloy comprises the following components in percentage by mass: 5.0%-5.5% of Mg, 1.5%-2.0% of Zn, 0.4%-0.5% of Mn, 0.1%-0.3% of Cu, 0.15%-0.25% of Sc, 0.1%-0.15% of Zr, 0.05%-0.15% of Ag, less than or equal to 0.1% of impurities and the balance of Al. The density is not more than 2.63 g / cm < 3 >, the tensile strength is not less than 470 MPa, and the ductility is not less than 23%. The preparation method comprises the steps of high-purity raw material smelting and casting, two-stage homogenization, hot rolling, intermediate annealing, cold rolling, solid solution treatment and single-stage aging. Wherein the total pressing amount of hot rolling is 80-85%, the total pressing amount of cold rolling is 20-35%, and the single-stage aging time is 120-140 DEG C * 16-24 h. The microstructure of the alloy is characterized in that the average size of dispersed AlSc particles is smaller than or equal to 100 nm, the area fraction of deformed grains is larger than or equal to 70%, the average size of nanometer beta-AlMg and T-Mg (Al, Zn) composite precipitated phases is smaller than or equal to 20 nm, the number density is larger than or equal to 1 * 10 < m >, the area fraction of micron-order second phases is smaller than or equal to 0.5%, and the alloy is only formed by impurity Fe. According to the method, the traditional two-stage aging process is simplified, low density, high strength and high plasticity are synchronously improved, and the method is suitable for large-scale industrial application.

The present application relates to the technical field of metallurgy, and particularly relates to a production method of a large-wall-thickness pipeline steel with improved carbon dioxide corrosion resistance and strength and toughness, and specific measures include: (1) controlling the bottom blowing mode and end point requirement in the converter process; (2) controlling the tapping time and replacing the tapping hole opportunity in the tapping process; (3) feeding the CAS aluminum wire and controlling the CAS argon blowing time; (4) controlling the top slag addition amount, heating time and outgoing mode in the LF refining process; (5) controlling the wire feeding parameters, soft blowing time and outgoing requirement of RH in the RH refining process; (6) controlling the precision requirement, casting speed fluctuation and crystallizer liquid level fluctuation of the continuous casting equipment in the continuous casting process to obtain the casting blank. Through controlling the parameters of each process in the smelting and rolling process, the present application realizes the whole-process steel cleanliness control and ladle grain refinement, and further improves the strength, low-temperature toughness, HIC resistance and carbon dioxide corrosion resistance of the large-wall-thickness pipeline steel.

The invention provides corrosion-fatigue-resistant ultrahigh-strength maritime work steel and a preparation method thereof, and relates to the technical field of maritime work steel manufacturing. The maritime work steel comprises the following components in percentage by mass: 0.04 to 0.07 percent of C, 0.20 to 0.26 percent of Si, 1.45 to 1.60 percent of Mn, less than or equal to 0.01 percent of P, less than or equal to 0.015 percent of S, 1.44 to 1.52 percent of Cr, 1.44 to 1.52 percent of Ni, 0.88 to 0.96 percent of Cu, 0.08 to 0.12 percent of Nb, 0.08 to 0.12 percent of Sb and the balance of Fe and inevitable impurities. The corrosion-fatigue-resistant ultrahigh-strength maritime work steel is prepared through raw material smelting and casting, austenitizing heat treatment, multi-pass hot rolling and cooling and temperature control. The corrosion resistance, the fatigue resistance and the corrosion fatigue resistance of the ultrahigh-strength maritime work steel are remarkably improved while the mechanical property of the ultrahigh-strength maritime work steel is improved, and the ultrahigh-strength maritime work steel has great significance in guaranteeing safe and stable operation of ocean engineering.

The invention relates to the technical field of precious metal recovery, in particular to a process for separating precious metal from copper-nickel smelting waste, which comprises the following steps: crushing and grading the waste, adding a sulfuric acid solution containing etidronic acid, leaching, and washing, drying and crushing filter residues to obtain a pretreated material; mixing the pretreated material with a sodium peroxide-sodium carbonate composite flux, roasting, leaching with water, and filtering to obtain a filter residue B; adding a leaching agent containing hydrochloric acid, sodium chlorate and 1, 2-cyclohexanediamine tetraacetic acid into the filter residue B according to the ratio of 1: 3-1: 5, and filtering to obtain filtrate C and filter residue C; adjusting the pH value of the filtrate C to 1.5-2.5, adding an ethanol solution of sodium N, N-diethyldithiocarbamate, precipitating, washing and calcining to obtain sponge palladium; adding ammonium chloride into the filtrate D, precipitating and calcining to obtain sponge platinum; and leaching the filter residue C by using a hydrochloric acid-chloroauric acid mixed solution containing diphenylthiourea, and replacing and calcining zinc powder to obtain crude gold. According to the process, the leaching rates of platinum, palladium and gold and the product purity are greatly improved; flux and reagent systems are optimized, consumption and energy consumption are reduced, waste liquid treatment is matched for up-to-standard discharge, and efficient resource recovery and environment-friendly cooperation are achieved.

The invention discloses fluoride-salt-free and nitrate-free low-temperature pearlescent glaze for steel plate enamel as well as a preparation method and application of the pearlescent glaze, and belongs to the technical field of enamel. The pearlescent glaze is prepared from quartz, anhydrous borax, titanium dioxide, magnesium carbonate, sodium tripolyphosphate, potassium carbonate, lithium carbonate, potassium feldspar, zinc oxide and V-26 according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The pearlescent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the pearlescent glaze has good porcelain surface, luster and low-temperature firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 760-800 DEG C and the firing time of 10-20 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses high-grade non-oriented silicon steel and a preparation method thereof, and relates to the technical field of non-oriented silicon steel. The high-grade non-oriented silicon steel comprises the following components in percentage by weight: less than or equal to 0.002% of C, 3.0-3.6% of Si, 0.15-0.25% of Mn, 0.05-0.20% of Als, less than or equal to 0.001% of S, less than or equal to 0.015% of P, less than or equal to 0.0015% of N, less than or equal to 0.002% of Ti and the balance of Fe and inevitable impurities. The manufacturing method of the high-grade non-oriented silicon steel in the claim 1 sequentially comprises the following steps of converter smelting, RH refining, continuous casting, heating, hot rolling, coiling, normalizing, acid pickling, cold rolling, annealing and coating. Wherein the heating temperature is controlled to be 1110 DEG C to 1200 DEG C; the hot rolling comprises rough rolling and finish rolling, and the hot rolling temperature is controlled to be 900-1000 DEG C; the coiling temperature ranges from 550 DEG C to 600 DEG C; the normalizing temperature ranges from 850 DEG C to 970 DEG C; the total reduction rate of cold rolling is 80-87%; and the annealing temperature ranges from 840 DEG C to 960 DEG C. According to the invention, through precise control of chemical components and a two-stage annealing process, collaborative improvement of low iron loss and high magnetic induction is realized.

The invention discloses fluoride-salt-free and nitrate-free low-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for steel plate substrates, the firing temperature is 760-800 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention relates to a production method of thin cold-rolled strip steel for food cans, which comprises the following steps of: smelting molten steel according to preset smelting components, and continuously casting after smelting; the casting blank subjected to continuous casting enters a hot rolling procedure, the final rolling temperature of the casting blank corresponds to the carbon content, and finally hot-rolled strip steel with the thickness of 2.0-2.3 mm is obtained; hot-rolled strip steel enters a rolling procedure after being subjected to acid rolling uncoiling, a five-rack rolling mode is adopted for acid rolling, and the total reduction rate is controlled to be 91%; coiling and then entering a continuous annealing process; in the annealing furnace, the annealing temperature and the strip steel speed are in a proportional relation, and finally finished strip steel is obtained. The thin-gauge strip steel can be produced at a high cold rolling speed, meanwhile, vibration of the rolling mill is effectively relieved, the production cost is reduced, and the product quality is not affected.

The invention discloses a method for increasing the recovery rate of lead fire refining alkaline residues. The temperature of the roasting furnace is set to be 580-650 DEG C, after the actual temperature reaches the set temperature, the refined alkaline residues are conveyed into the roasting furnace, the rotating speed of the roasting furnace is controlled to be 0.5-1 circle / min, the amount of blown air is 2-5 m < 3 > / min, the materials are subjected to oxidizing roasting in the roasting furnace for 30-60 min, the temperature is reduced to 30-50 DEG C, and roasted sand materials are obtained; detecting the roasted product material to obtain the content of the S element; the roasted sand materials and corresponding auxiliary materials are put into a smelting furnace in batches, the temperature in the furnace is controlled to be 900-1100 DEG C, the smelting time is 2-3 h, and produced lead bullion is discharged after the smelting time is up; the auxiliary materials are prepared according to the input amount of a single-batch roasted product material and the content of the S element. The recovery rate of lead, tin, antimony and copper in the pyrorefining alkaline residues can be effectively increased, and the cost of smelting auxiliary materials is reduced.

The embodiment of the invention provides an electric furnace steelmaking prediction model training method and device, electronic equipment and a storage medium, and relates to the technical field of electric furnace steelmaking, and the method comprises the steps: collecting historical electric furnace steelmaking data, cleaning the historical electric furnace steelmaking data to obtain first electric furnace steelmaking data, labeling the first electric furnace steelmaking data, and obtaining a second electric furnace steelmaking prediction model; performing feature extraction on the second electric furnace steelmaking data to obtain a plurality of features, acquiring features meeting process conditions from the plurality of features to obtain a plurality of target features, and training a to-be-trained electric furnace steelmaking prediction model by taking each target feature as a training set to obtain a trained electric furnace steelmaking prediction model; and obtaining a trained electric furnace steelmaking prediction model. Accurate control over the electric furnace steelmaking process can be achieved, the smelting period is shortened, and the molten steel quality is improved.

The invention discloses a method for improving castability of a high-purity industrial pure iron small square billet production line. The method comprises the following steps of KR molten iron pretreatment, converter smelting, LF refining, RH vacuum treatment and continuous casting. According to the method, in the early stage of LF, oxidizing slag is used for removing manganese and phosphorus, in the later stage, slagging-off modification treatment is carried out, a minimum LF and minimum outbound oxygen formula is formulated, so that the RH carbon-oxygen reaction requirement is met, vacuum natural decarburization is used, RH end point carbon can be stably controlled to be 0.0007-0.001%, after RH aluminum is added for deoxidation, a calcium deoxidizing agent is added under the low-true-degree condition for inclusion denaturation, and the RH carbon-oxygen reaction requirement is met. By means of the method, continuous production can be achieved on an industrial pure iron small square billet production line, the finished product C is smaller than or equal to 0.0015%, Mn is smaller than or equal to 0.025%, P is smaller than or equal to 0.003%, S is smaller than or equal to 0.003%, the high industrial level can be achieved, the number of continuous casting furnaces is larger than or equal to 7, and the method is particularly suitable for producing pure iron on a production line without RH top lance equipment in the RH procedure.

The invention discloses a method for recovering rare earth and valuable metal from waste rare earth alloy by using ionic liquid, and belongs to the technical field of non-ferrous metal metallurgy. Comprising the following steps that (1) recycled waste rare earth alloy is smashed, and waste rare earth alloy powder is obtained; (2) the waste rare earth alloy powder is put into ionic liquid to be subjected to a leaching reaction, solid-liquid separation is conducted after leaching is completed, and solid rare earth salt and filtrate are obtained; and (3) the filtrate serves as electrolyte, an electrolytic deposition system is constructed for electrodeposition, and valuable metal is obtained. The recovery method also has the advantages of simple process, environmental friendliness, high purity of the regenerated electrolyte and stable performance, and has great popularization and application prospects.

The invention discloses a high-thermal-conductivity Mg-Zn magnesium alloy suitable for rheoforming and a preparation and processing method of the high-thermal-conductivity Mg-Zn magnesium alloy. The alloy comprises the following components in percentage by weight: 1-8% of Zn, 0.5-5% of Cu, 0.2-2% of Sn, 0.2-1% of Sc and the balance of Mg and inevitable impurities. The preparation and processing method comprises the following steps: (1) preparing raw materials according to the composition of the alloy components, and smelting by adopting a medium-frequency induction furnace and taking mixed gas of tetrafluoroethane and argon as a protective atmosphere; (2) mechanical stirring and ultrasonic synergistic stirring are combined to form a uniform melt; (3) preparing semi-solid slurry with a solid phase ratio of 35-50%; (4) forming; (5) cooling and opening the mold; (6) the obtained rheoforming blank is heated to 340-430 DEG C, heat preservation is conducted for 2-12 h, and after heat preservation is finished, quenching is conducted immediately, and cooling is conducted to the room temperature; (7) pre-aging; and (8) aging. By reasonably designing alloy components and optimizing rheoforming parameters, the defects of shrinkage, hot cracking and segregation of a conventional cast Mg-Zn alloy are overcome, and meanwhile, high heat conductivity and mechanical properties are guaranteed.

A cold rolled and double annealed steel sheet, made of a steel having a composition including, by weight percent: C: 0.03-0.18%, Mn: 6.0-11.0%, 0.2≤Al<3%, Mo: 0.05-0.5%, B: 0.0005-0.005%, S≤0.010%, P≤0.020%, N≤0.008%, and including optionally one or more of the following elements. In weight percentage: Si≤1.20%, Nb≤0.050%, Ti≤0.050%, Cr≤0.5%,V≤0.2%, the remainder of the composition being iron and unavoidable impurities resulting from the smelting, the steel sheet having a microstructure including, in surface fraction, from 0% to 45% of ferrite, from 20% to 50% of retained austenite, from 5 to 80% of annealed martensite, less than 5% of fresh martensite, a carbon [C]A and manganese [Mn]A content in austenite, expressed in wt %, such that the ratio ([C]A2×[Mn]A) / (C %2×Mn %) is from 4.5 to 11.0, C % and Mn % being the nominal C and Mn weight percent in the steel and a carbides density below 4×106 / mm2.

The invention discloses a method for recovering iron in tailings of copper separation from copper smelting slag through combination of microwave-assisted oxidizing roasting and magnetic separation, and belongs to the technical field of metallurgical solid waste resource utilization. The method comprises the steps that high-temperature copper smelting slag is subjected to water quenching, crushing and ore grinding, flotation and copper removal to obtain tailings containing silicon iron, after a calcium-based additive is added for ball milling and mixing, microwave oxidizing roasting is conducted under the oxygen-enriched condition, roasting products are subjected to high-gradient magnetic separation after crushing and ore grinding, and iron ore concentrate and magnetic separation tailings are obtained. According to the method, the strong wave-absorbing characteristic of fayalite is utilized, the roasting temperature and energy consumption are reduced through microwave heating, iron-silicon separation is achieved through a calcium-based additive, and iron is recycled through magnetic separation in one step. The final magnetic separation iron recovery rate reaches 85% or above, the iron ore concentrate grade exceeds 60%, magnetic separation tailings can be used as building materials, the process is simple, the cost is low, environment friendliness is achieved, the defects of a traditional process are overcome, and high-value utilization of solid waste is achieved.

The invention discloses a method for reducing impurity element sulfur in cast high-temperature alloy return scraps, and belongs to the technical field of metal material smelting. The method comprises the following steps: carrying out vacuum induction melting on pretreated cast high-temperature alloy return scraps of the same mark to obtain a return scrap alloy induction ingot; surface oxide skin of the obtained return scrap alloy induction ingot is removed, a primary shrinkage cavity in the upper end is cut off, then the return scrap alloy induction ingot and an auxiliary electrode are coaxially welded, and a consumable electrode is obtained; and after the consumable electrode is baked, electroslag remelting is conducted under the protective atmosphere, and an electroslag ingot is obtained. On the basis of vacuum induction melting, the protective atmosphere electroslag remelting technology is further adopted for conducting deep purification melting treatment on the return scrap alloy ingot, the content of the impurity element S in the return scrap alloy ingot can be reduced to 0.5 ppm or below, and the content of the impurity element S in the return scrap alloy ingot reaches the level lower than the content of the element S in a new material; and the high-temperature oxidation resistance and corrosion resistance of the alloy can be obviously improved, and the fatigue, durability and other mechanical properties of the alloy are improved.

The application provides an aluminum alloy, which comprises the following components in percentage by mass: Zn 4.0-5.0%, Mg 1.2-1.8%, Cu 0.1-0.3%, Zr 0.08-0.12%, Ti 0.02-0.06%, Fe less than or equal to 0.25%, and the balance of Al. The alloy elements containing Zn 4.0-5.0%, Mg 1.2-1.8%, Cu 0.1-0.3%, Zr 0.08-0.12%, Ti 0.02-0.06% and Fe less than or equal to 0.25% are added into a smelting furnace together with pure aluminum, smelted at 700-750 DEG C to form a melt, refined by blowing in inert gas or adding a refining agent, and the gas and inclusions are removed. The application utilizes the shearing force generated by the different rotating speeds of the upper and lower rollers of a differential rolling mill to break the coarse structure, refine the grains, and increase the dislocation density. The aluminum alloy is rolled at 480-500 DEG C to reduce the deformation resistance, promote dynamic recrystallization, maintain the processing performance, and further enhance the performance by 60-70% of the total deformation. After rolling, the aluminum alloy is subjected to multi-directional forging, the strain direction is changed multiple times, the grains are broken, the structure is homogenized, and anisotropy is eliminated, so that the comprehensive performance and application range of the aluminum alloy profile are improved. The problem that the structure cannot be refined and the dislocation density cannot be increased during the rolling process is solved.