273 results about "Cobalt hydroxide" patented technology

The invention relates to the technical field of hydrometallurgy, in particular to a method for selectively leaching and separating cobalt and manganese from crude cobalt hydroxide leaching residues. The separation method provided by the invention comprises the following steps: S1, pre-reduction treatment; and S3, cobalt is leached through selective oxidation, and manganese is precipitated. According to the separation method, the synergistic effect of ORP and pH is regulated and controlled, proper reducing agents and oxidizing agents are selected, cobalt is selectively leached through step-by-step oxidation, dissolution of manganese is inhibited, manganese circularly entering a leaching and extraction system is reduced, the leaching and extraction operation cost is reduced, meanwhile, a selective complexing agent is introduced, impurity co-dissolution is reduced, the subsequent purification process is simplified, and the method is suitable for industrial production. The preparation method is simple to operate and easy for industrial production, and has a good application prospect.

The invention provides an improved treatment method for laterite-nickel ore. The improved treatment method comprises the following steps: S1, carrying out acid leaching on the laterite-nickel ore, and then filtering and washing to obtain a leached solution and first leached residues; step S2, the step S2 is selected from any one of a step S2-1, a step S2-2 and a step S2-3; s3, performing first-stage nickel and cobalt precipitation and dense filtration on the aluminum and scandium removed liquid or the iron and aluminum removed liquid by adopting a precipitator to obtain first-stage nickel and cobalt precipitation liquid and a nickel cobalt hydroxide product; and S4, carrying out second-stage nickel-cobalt precipitation on the first-stage nickel-cobalt precipitation solution by adopting a nickel-cobalt precipitation neutralizer and an oxidizing agent to obtain a magnesium sulfate manganese solution and nickel-cobalt-manganese slurry. In the traditional process, ferrous iron is oxidized by using compressed air, so that energy is wasted. According to the method, the manganese-containing substance is adopted as the oxidizing agent, ferrous iron is oxidized into ferric iron, the problems that the ferrous iron is low in oxidation rate under the low pH and compressed air is wasted are solved, and the scandium recovery rate is increased.

The invention discloses a preparation and application method of active magnesium oxide for cobalt precipitation, which comprises the following steps: adding acetate during preparation of an active magnesium oxide precursor magnesium hydroxide to obtain magnesium hydroxide with a double-tooth structure; when magnesium oxide is prepared through calcination, conversion from magnesium hydroxide to magnesium oxide can be achieved at a low temperature, and meanwhile high activity is obtained; and finally, the magnesium oxide slurry is added into the cobalt precipitation pre-solution for cobalt precipitation, the cobalt precipitation effect is good, and the obtained coarse cobalt hydroxide cobalt is high in grade. The magnesium hydroxide regulating agent is used for promoting generation of magnesium oxide rich in active sites, the magnesium hydroxide regulating agent is applied to the wet metallurgy cobalt deposition process, the cobalt deposition effect of active magnesium oxide prepared through a chemical method is effectively improved, other methods except for the method for reducing the particle size and promoting the activity of magnesium oxide are developed, acetate is selected as the magnesium hydroxide regulating agent, the dosage is small, and the cost is low. Magnesium oxide obtained through calcination is high in purity, the cobalt deposition process is not affected, unit consumption of magnesium oxide can be reduced, and cost is saved.

The invention discloses a foamed nickel loaded cobalt sulfide / nickel sulfide NF-CoS / NiS. The foamed nickel loaded cobalt sulfide / nickel sulfide NF-CoS / NiS is prepared by the following steps: firstly, taking foamed nickel NF as a substrate, loading cobalt hydroxide on the surface of the NF through first electrodeposition, then converting the NF into ZIF-67 through an impregnation method, then vulcanizing through thioacetamide and hydrothermal reaction, and finally loading Ni3S2 nanoparticles through second electrodeposition. The nickel foam loaded cobalt sulfide / nickel sulfide NF-CoS / NiS can be obtained. The preparation method comprises the following steps: 1, preparing foamed nickel electro-deposition cobalt hydroxide; 2, preparation of the foamed nickel loaded cobalt hydroxide / ZIF-67; 3, cobalt hydroxide / cobalt sulfide NF-Co / CoS is loaded on the foamed nickel; and 4, preparation of the foamed nickel loaded cobalt sulfide / nickel sulfide NF-CoSX / Ni3S2. When the material is used as a supercapacitor material, charging and discharging are carried out in a voltage window range of 0-0.5 V, and when the current density is 1mA cm <-2 >, the area specific capacitance is 8-9F cm <-2 >; and when the current density is 10mA cm <-2 >, 70-80% of the initial capacity is still kept after 5000 charge-discharge cycles are carried out.

The application discloses a composite precipitant for wet refining of laterite nickel ore and a wet refining method of laterite nickel ore. The composite precipitant for wet refining of laterite nickel ore is composed of a mixture of magnesium oxide and sodium hydroxide, and the mass fraction of sodium hydroxide in the composite precipitant is greater than 0 and less than or equal to 99%. The wet refining method of laterite nickel ore comprises the following steps: directly or after being grinded, the composite precipitant is added into an acidic solution to be refined, and stirring is performed to make the composite precipitant fully react with the acidic solution to be refined; after concentration, a clear liquid and a solid-containing slurry are obtained; the solid-containing slurry is filtered and washed with water to obtain a solid containing nickel hydroxide, cobalt hydroxide or nickel hydroxide-cobalt hydroxide, so that nickel, cobalt or nickel-cobalt is precipitated. The composite precipitant and the wet refining method of laterite nickel ore have the advantages of simple process, low cost, easy process control, easy settlement and filtration of nickel hydroxide (and cobalt hydroxide) precipitation, and the production efficiency can be significantly improved and the energy consumption can be reduced.

The invention relates to the technical field of drying, in particular to a flash evaporation drying device for cobalt hydroxide production, which comprises a drying cylinder, fan blades, a ceramic ring and a first-stage separation assembly, a drying cavity is formed in the drying cylinder, the fan blades are rotatably arranged at the lower part of the drying cavity, and the fan blades can rotate around the axis of the fan blades; and the ceramic ring is arranged at the upper part of the drying cavity and used for driving the air in the drying cavity to spirally move from bottom to top. The first-stage separation assembly is arranged, materials which are not discharged out of the drying cavity through the pottery ring can fall into the first vortex disc, the materials with different particle sizes are adaptively crushed in the first vortex disc, so that the particle uniformity of the materials entering the drying cavity again from the first vortex disc is improved, and in addition, the larger the particle size of the materials is, the larger the particle size of the materials is, the larger the particle size of the materials is. And the retention time of the materials in the first-stage separation assembly is longer, so that the temperature uniformity of the materials is also improved.

The invention provides an iridium / cobaltosic oxide mesoporous monocrystal oxygen evolution catalyst and a preparation method thereof, and relates to the technical field of catalyst preparation, and the preparation method comprises the following steps: S1, preparing a mesoporous monocrystal cobalt hydroxide sheet; s2, dispersing mesoporous monocrystal cobalt hydroxide and an iridium-containing compound in an ethanol-water mixed solution, heating to a certain temperature, stirring to react for a period of time, and then washing and drying a reaction product; and S3, roasting the dried reaction product in an air atmosphere for a period of time to obtain the catalyst. The catalyst disclosed by the invention has high Ir load, extremely low overpotential and ultrahigh stability, and has huge potential in practical application of electrolyzed water.

A cobalt-coated sodium ion battery precursor, and a preparation method and use therefor. The cobalt-coated sodium ion battery precursor sequentially comprises, from inside to outside, a core, a transition layer and an outer coating layer. The core comprises a nickel-iron-manganese precursor material. The transition layer comprises a nickel-iron-manganese-cobalt precursor material. The coating layer comprises a cobalt hydroxide material. By carrying out gradient coating of cobalt on the nickel-iron-manganese core, cobalt is sequentially increased from inside to outside, such that the surface structure stability of the nickel-iron-manganese precursor is improved, side reaction between the electrode and the electrolyte is inhibited, and the use voltage and rate capability of the sodium-ion battery are effectively improved.

The invention relates to a battery material preparation technology, in particular to a method for preparing high-purity cobaltous sulfate from crude cobaltous hydroxide, which comprises the following steps: S1, reacting the crude cobaltous hydroxide with sulfuric acid to generate magnesium sulfate; s2, washing to remove magnesium; s3, adding sulfuric acid and hydrogen peroxide into the crude cobalt hydroxide after magnesium washing; adding crude cobalt hydroxide to adjust the pH value to obtain a purified solution; s4, adding sodium fluoride into the purified liquid, and filtering after reaction to obtain filtrate; s5, saponifying with sodium hydroxide by using an acidic extractant, then performing soap conversion by using a cobalt sulfate solution, extracting manganese in the filtrate by using an obtained organic phase, and then performing reverse extraction on the organic phase by using sulfuric acid to obtain a manganese sulfate solution; s6, the raffinate obtained after manganese extraction is introduced into an adsorption tower loaded with a zirconium-based composite fluorine adsorbent; and S7, concentrating and crystallizing the defluorinated solution. According to the method, the zirconium-based composite fluorine adsorbent is introduced to be coupled with the process, fluorine ions can be removed, and cobalt loss caused by cobalt fluoride precipitation and the influence of the fluorine ions on the quality of a cobalt sulfate product are avoided.

The present disclosure belongs to the field of batteries, and particularly relates to cobalt hydroxide and a preparation method therefor, a positive electrode material, a battery and electrical equipment. Provided in the present disclosure is cobalt hydroxide, the particles of which are in the shape of a sheet and have an average thickness of 10-20 nm. The cobalt hydroxide of the present disclosure is nanosheets having an extremely small average thickness and a larger surface area, which can thus improve the coating effect thereof on a positive electrode material, thereby effectively inhibiting the formation of a nickel oxide rock salt-like phase in the positive electrode material, reducing the concentration of residual lithium on the surface of the positive electrode material and enabling lithium ions to be quickly deintercalated / intercalated; therefore, the electrical properties of the positive electrode material prepared therefrom can be significantly improved.

The utility model relates to the technical field of drying and energy saving, and particularly discloses a cobalt nickel hydroxide or cobalt hydroxide drying system based on waste heat steam utilization, which comprises a mixing device, a steam rotary drying device, a dust removal device and a spray washing device which are connected in sequence, steam in the upstream flash evaporation process is subjected to deacidification treatment and then is introduced into a heat exchange tube bundle of the steam rotary drying device to serve as a heat source; the discharging end of the steam rotary drying device is respectively connected with a discharging branch and a material returning loop through a discharging screw; the material returning loop is connected to one feeding hole of the material mixing device, and the other feeding hole of the material mixing device is connected with a nickel cobalt hydroxide or cobalt hydroxide wet material conveying device. An indirect heat exchange mode is adopted, only a small amount of hot air is needed to serve as moisture-carrying gas, the tail gas amount is greatly reduced, meanwhile, damage to materials caused by direct contact with high-temperature hot air in a traditional drying mode is avoided, the physical property of the materials can be kept, and the particle size and quality of products are improved.

The invention relates to a low-cobalt-salt adhesion promoter and a preparation method thereof, and relates to the technical field of rubber adhesives, the low-cobalt-salt adhesion promoter is of a core-shell structure and comprises, by mass, 10-15 parts of core metal precursor powder, 15-20 parts of a shell SiO2 shell layer and 5-8 parts of long-chain alkylsilane grafted to the surface of the SiO2 shell layer; the metal precursor powder comprises cobalt hydroxide, manganese hydroxide and ferric hydroxide, and the molar ratio of the cobalt hydroxide to the manganese hydroxide to the ferric hydroxide is 1: (2-3): (1-1.5). According to the invention, the dispersibility of the low-cobalt salt adhesion promoter and the compatibility with rubber can be effectively improved.

The invention relates to a preparation method and application of a single-crystal or single-crystal-like ultrahigh-nickel lithium ion battery ternary positive electrode material, and the preparation method comprises the following steps: step 1, dispersing and uniformly mixing a cobalt-nickel-manganese hydroxide ternary precursor, a lithium source and a metal oxide serving as columnar metal ions to obtain a premixed material; carrying out primary sintering on the premixed material, sieving, dispersing and washing to obtain a primary sintering product; 2, urea phosphate and N-methyl pyrrolidone NMP are fully mixed to prepare an in-situ wet coating agent, the primary sintering product and the in-situ wet coating agent are evenly mixed, and then suction filtration, presintering drying and sieving are conducted to obtain a presintering product; and carrying out secondary sintering and secondary sieving dispersion on the pre-sintered product to obtain the single-crystal or single-crystal-like ultrahigh-nickel ternary positive electrode material for the lithium ion battery. The problems of poor structural stability and poor electrochemical performance of a single-crystal or single-crystal-like ultrahigh-nickel lithium ion battery ternary positive electrode material under high voltage in the existing scheme are solved.

The invention discloses a foamed nickel-based composite material based on an electro-deposition / hydrothermal synthesis method, which is characterized in that firstly, foamed nickel NF is used as a substrate, cobalt hydroxide is loaded on the surface of the NF through electro-deposition, and Co (OH) 2 / NF with a lamellar stacked flower-shaped structure is obtained; the preparation method comprises the following steps: preparing NiCo-LDH (layered double hydroxide) Co (OH) 2 / NF, then converting the NiCo-LDH (layered double hydroxide) Co (OH) 2 / NF into ZIF-67 through an impregnation method to obtain ZIF-67 (at) Co (OH) 2 / NF with a regular dodecahedron structure, and finally, preparing NiCo-LDH (at) Co (OH) 2 / NF with a honeycomb stacked structure through a hydrothermal method. The preparation method comprises the following steps: 1, preparing foamed nickel electro-deposition cobalt hydroxide; 2, preparing the foamed nickel loaded ZIF67 and cobalt hydroxide; and 3, preparing the nickel foam loaded nickel-cobalt layered double-metal hydroxide and cobalt hydroxide. When the material is used as a supercapacitor material, the area specific capacitance is 17-18F cm <-2 > when the current density is 1mA cm <-2 >; and when the current density is 10mAcm <-2 >, 70-80% of the initial capacity is still kept after 5000 charge-discharge cycles are carried out.

This invention discloses a method for preparing a tufted nickel-cobalt hydroxide nanomaterial modified electrode material. The tufted nickel-cobalt hydroxide is prepared on carbon paper using a constant potential method. The electrolyte is a solution of nickel sulfate and cobalt sulfate. The specific operation is as follows: S1. Carbon paper pretreatment; S2. Electrode preparation is a solution containing nickel sulfate and cobalt sulfate; S3. Electrode preparation finally obtains the tufted electrode material.

A method of manufacturing a cobalt-nickel-containing solution including: preparing a crude nickel hydroxide and / or a crude cobalt hydroxide as a starting material, the crude nickel or cobalt hydroxide containing cobalt and nickel and elements except the cobalt and nickel as impurities, the crude nickel hydroxide containing the nickel more than the cobalt, and the crude cobalt hydroxide containing the cobalt more than the nickel; a water-washing process for obtaining a post-water-washing crude hydroxide from the starting material; a leaching process for obtaining a post-leaching solution from the post-water-washing crude hydroxide; a neutralization process of subjecting the post-leaching solution to neutralization and solid-liquid-separation to remove the impurities as a post-neutralization residue containing one or more of iron, silicon, aluminum, and chromium, thereby obtaining a post-neutralization solution; and an extraction process of subjecting the post-neutralization solution to solvent extraction to obtain a post-extraction solution containing cobalt and nickel with the impurities reduced.

The application relates to the technical field of chemical product preparation, in particular to a cobalt hydroxide preparation device and a preparation process thereof. The cobalt hydroxide preparation device comprises a reaction kettle provided with a manhole, the manhole is provided with a manhole cover, the manhole cover comprises a lower seat and a fixing assembly, a support is hinged to the lower seat, a connecting seat is arranged on the support, an upper cover is arranged on the connecting seat, the upper cover is used for controlling the opening and closing of the manhole, a sealing ring is arranged between the lower seat and the upper cover, the fixing assembly is used for fixing the lower seat and the upper cover, the upper cover can rotate around a second axis, the direction of the gravity of the connecting seat and the upper cover and the second axis are coplanar, when the manhole is opened through the upper cover, the lower end surface of the upper cover and the upper end surface of the lower seat are kept parallel in a short time, and then the damage of the sealing ring caused by uneven stress is avoided, the connecting seat can rotate around a first axis, the first axis and the second axis are perpendicular, the upper cover has the freedom of two rotating directions, and the damage of the sealing ring is reduced.

The application provides a one-dimensional iron oxide nanorod heterojunction composite material and a preparation method and application thereof, and belongs to the technical field of photoelectrocatalytic water splitting hydrogen production. The composite material provided by the application comprises: one-dimensional iron oxide nanorods, cuprous sulfide nanoparticles loaded on the one-dimensional iron oxide nanorods, and cobalt hydroxide nanosheets coated on the surfaces of the one-dimensional iron oxide nanorods and the cuprous sulfide nanoparticles. On one hand, the Fe2O3 / Cu2S p-n heterojunction is introduced to accelerate the separation of photo-generated carriers in the Fe2O3 nanorod array, and on the other hand, the Co(OH) x The surface OECs accelerate the kinetics process of interfacial water oxidation, the rapid depletion of photo-generated holes further improves the charge separation of the photoanode surface, and the synergistic effect between the Fe2O3 / Cu2S p-n heterojunction and the OECs significantly improves the PEC water splitting performance of the iron oxide nanorod array composite material.

Provided is a method for separating impurities and cobalt without using an electrolysis process from a cobalt chloride solution containing impurities and producing a high purity cobalt sulfate. The production method for cobalt sulfate includes: a copper removal step (S1) of adding a sulfurizing agent to a cobalt chloride solution containing one or more impurities of copper, zinc, manganese, calcium, and magnesium and generating a precipitate of sulfide of copper to separate to remove copper; a neutralization step (S2) of adding a neutralizer or a carbonation agent to a cobalt chloride solution having undergone through the copper removal step (S1) and generating cobalt hydroxide or basic cobalt carbonate to separate magnesium; a leaching step (S3) of adding sulfuric acid to the cobalt hydroxide or the basic cobalt carbonate to obtain cobalt sulfate solution; and a solvent extraction step (S4) of bringing an organic solvent containing an alkyl phosphoric acid-based extractant to the cobalt sulfate solution and extracting zinc, manganese, and calcium into the organic solvent to separate to remove zinc, manganese, and calcium. These steps are sequentially executed.

The invention provides a method for removing acidic silicon in nickel cobalt hydroxide pickle liquor. The method comprises the following steps: firstly, carrying out acid leaching treatment on nickel cobalt hydroxide to obtain an acid leaching solution; adjusting the first-stage temperature and the first-stage pH value of the pickle liquor, and adding a first precipitator to obtain a first solution; then adjusting the second-stage pH value and the second-stage temperature of the first solution, and adding a second precipitator for precipitation reaction to obtain a second solution; and finally, adjusting the third-stage pH value and the third-stage temperature of the second solution, and carrying out solid-liquid separation so as to remove acidic silicon, wherein the pH value of the second stage is higher than the pH value of the first stage and the pH value of the third stage, and the pH value of the second stage is lower than 4.0. According to the method provided by the invention, the acidic silicon impurities in the nickel cobalt hydroxide pickle liquor can be efficiently removed, so that the high-purity battery-grade nickel sulfate material is prepared.

The invention relates to the technical field of preparation of sodium-ion battery electrode materials, in particular to an oxygen reduction function NaxCoO2 surface modified sodium-ion battery layered oxide positive electrode material and a preparation method thereof.The positive electrode material takes NaNixFeyMnzO as a matrix, cobalt salt and alkali liquor are mixed in absolute ethyl alcohol, and the sodium-ion battery layered oxide positive electrode material is prepared. The cobalt ions are driven by electrostatic adsorption to preferentially form a cobalt hydroxide coated precursor layer on the surface of the substrate, and the NaxCoO2 coating modified sodium ion battery layered oxide positive electrode material is obtained through high-temperature sintering; according to the coating, the performance of the battery is improved through a triple synergistic mechanism: a Co < 3 + > / Co < 4 + > multivalent state is utilized to reduce a movable active oxygen species formed in a charging process into immovable O < 2->, and lattice oxygen precipitation is inhibited; the direct contact between the electrode and the electrolyte is reduced, and the electrode / electrolyte interface side reaction is inhibited; the material has a sodium ion / electron conduction function, and the rate capability of the material is improved. The capacity retention rates of the material prepared by the invention are respectively 81.2% and 55.9% after the material is circulated for 500 times under the voltage of 4.0 V and 4.3 V, the cycle life is long, and the preparation process is simple and controllable.

This invention discloses a method for preparing sheet-like nano-sized cobalt hydroxide. The method includes the following steps: using cobalt nitrate as the cobalt source and sodium hydroxide solution as the precipitant, a co-precipitation reaction is carried out. The cobalt nitrate solution and sodium hydroxide solution are added together to a reaction vessel. By controlling the synthesis pH and temperature, the synthesized cobalt hydroxide slurry is washed with hot pure water, dried, and crushed using an air jet mill to obtain sheet-like nano-sized pink cobalt hydroxide with low sodium content. Specifically, the key to preparing sheet-like nano-sized cobalt hydroxide is to prevent oxidation and particle agglomeration during the synthesis process. This invention uses a low-temperature (40-60℃), low-pH (8.0-9.0) cobalt hydroxide synthesis process with a small amount of antioxidant added to prepare sheet-like micron-sized cobalt hydroxide that is not easily oxidized or agglomerated. In addition, at the low pH, the sodium content is low, making the subsequent filtration and washing steps easier to operate.

A positive electrode active material having both higher capacity and safety is provided. Provided is a method for manufacturing a positive electrode active material, including forming a mixed solution containing a cobalt compound and a nickel compound dissolved; making the mixed solution react with an alkaline aqueous solution to obtain a suspension in which a cobalt nickel hydroxide is precipitated; performing first suction filtration of the suspension with use of water; and after the first suction filtration, performing second suction filtration with use of an organic solvent. In the cobalt nickel hydroxide, an atomic ratio of nickel in the sum of an atomic ratio of cobalt and the atomic ratio of nickel is greater than 0 and less than or equal to 0.01.

The invention discloses lithium nickel cobalt manganese oxide powder with a porous layered structure and a preparation method thereof, and belongs to an electrode material of a lithium ion battery and a lithium ion supercapacitor. The preparation method comprises the following steps: (1) carrying out ball-milling mixing on nickel hydroxide, cobalt hydroxide, manganese hydroxide and lithium hydroxide to obtain a mixed material; (2) performing ultrasonic stirring and mixing on the mixed material, a structure guiding agent and a surfactant to obtain mixed slurry; (3) transferring the mixed slurry into a high-pressure reaction kettle for hydrothermal reaction to obtain a nickel cobalt lithium manganate precursor; and (4) putting the nickel cobalt lithium manganate precursor into a muffle furnace for high-temperature calcination to obtain the nickel cobalt lithium manganate powder with the porous layered structure. The nickel cobalt lithium manganate powder prepared by the invention is formed by stacking hexagonal micron sheets, has a porous and layered structure, and has excellent energy storage characteristics. The preparation method is simple in process, low in production equipment requirement, low in production cost, safe, free of pollution and suitable for large-scale batch production.

The present invention provides a method for selectively leaching and removing impurities from nickel and cobalt hydroxide. The method comprises: slurrying nickel and cobalt hydroxide raw materials, then sequentially adding acid and nickel and cobalt hydroxide to adjust the pH value, and obtaining a pre-leached liquid and a pre-leached residue after leaching; slurrying the pre-leached residue, then sequentially adding acid, a reducing agent, and nickel and cobalt hydroxide to obtain a first leachate and a first leach residue after leaching; slurrying the first leach residue, then adding acid, and obtaining a second leachate and a second leach residue after leaching; wherein the second leachate contains copper ions, iron ions, and aluminum ions; mixing the second leachate with a pH adjusting agent, and obtaining a third leachate and a third leach residue after leaching; wherein the third leach residue contains iron and aluminum elements; mixing the third leachate with acid, then adding a copper reducing agent to carry out a reduction reaction, and obtaining a fourth leachate and a fourth leach residue after leaching. This method can improve efficiency and save costs.

This invention discloses an organocobalt salt for improving the tensile strength of rubber and its preparation method, belonging to the field of rubber technology. The organocobalt salt for improving the tensile strength of rubber comprises, by mass parts, 140-210 parts of organosilicon vegetable fatty acid, 20-30 parts of solvent, 20-30 parts of cobalt hydroxide, and 10-16 parts of propionic acid. The organosilicon vegetable fatty acid is obtained by reacting rosin with organosilicon maleimide. The organosilicon maleimide is obtained by reacting maleic anhydride with a silicon-containing long-chain fatty amine. The silicon-containing long-chain fatty amine is obtained by reacting methyldiethoxysilane with an unsaturated long-chain fatty amine. The organocobalt salt obtained by this invention has a good effect on promoting the adhesion between metal and rubber while effectively improving the tensile strength of rubber.

A method for low-cost extraction and separation of battery-grade nickel and cobalt from laterite-nickel ore, comprising the following steps: adjusting a pH value of a laterite-nickel ore high-pressure leachate to 2.5 or above to obtain a leachate A; introducing the leachate A into a continuous ion exchange resin device to adsorb nickel to obtain a nickel-adsorbed resin and a resin adsorption tail liquid; desorbing the nickel-adsorbed resin to obtain a first nickel salt solution; performing extraction, washing and back-extraction on the first nickel salt solution by means of an extraction organic phase to obtain a battery-grade nickel solution of a target concentration; adding a reducing agent into the obtained resin adsorption tail liquid, adding a precipitant after the reaction to adjust the pH value of the resin adsorption tail liquid to 7-8, and performing pressure filtration to obtain a cobalt hydroxide intermediate product; and preparing a battery-grade cobalt salt solution of a target concentration by using the cobalt hydroxide intermediate product as a raw material. According to the method, nickel and cobalt are separated at an early stage of a metallurgical process, thereby solving the problem of a tedious process flow of nickel and cobalt extraction and separation, saving a large amount of usage of a flocculant and liquid alkali, and reducing costs.

The invention discloses a cobalt hydroxide electrode, the cobalt hydroxide electrode is cobalt hydroxide loaded by foamed nickel, the cobalt hydroxide is amorphous phase cobalt hydroxide, and the microstructure of the cobalt hydroxide is a nanoneedle. The electrode obtained by the invention has the characteristics of relatively high catalytic activity and relatively strong reaction kinetics. The invention further discloses a preparation method and application of the cobalt hydroxide electrode.

The invention discloses a preparation method of an efficient bionic photocatalytic material. The preparation method comprises the following steps: soaking rose leaves in a glutaraldehyde solution; soaking the rose leaves in a hydrochloric acid solution; the pretreated rose leaves are placed in a tetrabutyl titanate solution, and a precursor material A is obtained; oxidizing cobalt hydroxide into cobalt oxide in a muffle furnace to obtain a precursor material B; depositing indium nitrate on the precursor material B to obtain a precursor material C; calcining the precursor material C in a muffle furnace, removing part of the biological template, and converting the remaining biological template into a biological carbon carrier; placing the carbon-based bionic photocatalyst in an N2 inert gas protective atmosphere, and calcining the carbon-based bionic photocatalyst in a tubular furnace; and taking out the calcined material, cooling to room temperature, and cleaning the cooled material for multiple times to obtain the bionic photocatalyst. The preparation method of the efficient bionic photocatalytic material is used for efficiently degrading organic matters in water.

The invention provides a multi-stage combined leaching method for ultra-low grade laterite nickel ore, including: firstly, the raw laterite nickel ore slurry is treated by high pressure acid leaching to obtain the high pressure leaching tailings containing iron, aluminum and magnesium and the high pressure leaching solution containing nickel, cobalt and manganese. The mass percentage of nickel in the raw laterite nickel ore is less than 1.0%; Secondly, the high pressure leaching solution, laterite nickel ore slurry and acid solution were mixed to obtain the mixed solution, and the mixed solution was subjected to multi-stage atmospheric pressure leaching treatment, after concentration treatment, the final concentrated atmospheric pressure leaching solution and the final concentrated atmospheric pressure leaching slurry with the same concentration as the raw laterite nickel ore slurry. Finally, the final concentrated atmospheric pressure leaching solution and high pressure leaching tail residue were successively recycled leaching, multi-stage pre-neutralization, counter-current decantation washing, Fe / Al / Cr removal and MHP precipitation to obtain nickel and cobalt hydroxide products. the invention can effectively restrain the scaling rate of conventional high pressure acid leaching treatment and prolong the production cycle.