The invention provides a method for preparing large particle size doped tricobalt tetroxide. The method takes a cobalt solution with a certain concentration as a cobalt source, a sodium carbonate solution is taken as a precipitant, an ammonia solution is taken as a complexing agent, a hydrazine hydrate solution is taken as a reducing agent, a mixed solution of a doping element solution and the complexing agent is taken as a dopant, and cobalt carbonate having a particle size of 20-30 [mu]m is synthesized in the shortest time through modes such as the reduction of the amount of crystal nucleusformed in the initial stage of synthesis. In the reaction process, the appropriate time is selected to add the doped solution into a reaction kettle to participate in the reaction; after the synthesiscomes to an end, under a certain pH value condition, a hydrogen peroxide solution with a certain solubility is utilized to oxidize the synthetic product into the hydroxyl cobaltous oxide, and the mixture is washed, dried and calcined to obtain the large particle size doped tricobalt tetroxide. The synthesis time of the process is short and is only 10-15 h, the product physicochemical index is good, the laser particle size is 15-25 [mu]m, the tap density is more than 2.0 g/cm3, the specific surface area is 1.0-3.0 m<2>/g, and the doping elements include Ni, Mn, Al, Cu, Ce, Y, Nb and Mg.