4results about How to "Easy to oxidize" patented technology

This invention relates to conjugated polymers containing dibenzofuran (thiophene) and carbazole units, their preparation methods, and applications. To address the problems of poor optical contrast, slow response time, and poor cycling stability of existing conjugated polymers as electrochromic materials, this invention uses 2,8-dibromodibenzofuran or 2,8-dibromodibenzothiophene as reactants, reacting them with 9-hexyl-3,6-bis(4,4,5,5-tetramethyl-1,3,2-dioxoborane-2-yl)-carbazole or 9-phenyl-3,6-bis(4,4,5,5-tetramethyl-1,3,2-dioxoborane-2-yl)-carbazole to form conjugated polymers with dibenzofuran (thiophene) and carbazole units in the main chain. The conjugated polymers of this invention exhibit excellent electrochromic properties, including excellent cycling stability, fast switching time, high optical contrast, and low voltage start-up. This invention is expected to be applied in fields such as smart windows, rearview mirrors, military camouflage, and electronic tags in the construction and automotive industries.

This invention discloses a heterocyclic polyarylamide-polyhydroxyarylamide precipitated fiber, its preparation method, and a heterocyclic polyarylamide-polybenzodioxazole paper, belonging to the technical field of high-performance organic fiber and paper preparation. The preparation method of the precipitated fiber includes the following steps: A. Preparation of the polymerization solution: 3,3'-dihydroxybenzyl diamine (DHB) and 2-(4-aminophenyl)-5-aminobenzimidazole (DAPBI) are dissolved in an organic solvent containing a solubilizing salt, and then terephthaloyl chloride is added to react and obtain a polymer solution with a solid content of 1-10%; B. Precipitation: After degassing, filtering, metering, and spinning, the polymer solution is mixed with a coagulation bath and precipitated to obtain the heterocyclic polyarylamide-polyhydroxyarylamide precipitated fiber. A heterocyclic polyarylamide-polybenzodioxazole paper prepared from this precipitated fiber is also provided. This invention introduces a heterocyclic polyaromatic amide structure through copolymerization, which not only improves the strength and composite properties of the cyclized PBO paper, but also maintains a decomposition temperature comparable to that of pure PBO fiber, exceeding 600℃, demonstrating excellent thermal stability. Furthermore, this method is simple and easy to implement, making it suitable for industrial production applications.

The application discloses a Cu-Sn-S metal sulfide adsorbent for capturing Ni 2+ , and has the molecular formula K 2‑ x Cu x (H2O) x [Cu2Sn2S6], x =0.1~1.9; has a two-dimensional layered structure, each electronegative layer skeleton is sequentially composed of [Sn-Cu-S], [Cu-S] and [Sn-Cu-S] three sub-layers, wherein K + is located in the pores of two [Sn-Cu-S] sub-layers and is used for balancing the charge of the layer skeleton; when Ni 2+ is adsorbed, Cu + in the [Sn-Cu-S] sub-layer is exchanged with Ni 2+ , so that the high-efficiency and high-selectivity capture of Ni 2+ in radioactive wastewater is realized.

Provided is a joint of a copper terminal and an aluminum conductor. A copper terminal connecting member of the joint is connected to a conductive core of the aluminum conductor by means of a transition welding layer, and the joint can also be provided with a reinforcing welding layer. Further provided is a method for preparing the joint using plasma arc welding. According to the invention, the connection portion of the copper terminal with the aluminum conductor is filled with solder in a plasma arc welding manner, such that copper and aluminum are connected by means of the solder. Damage to an aluminum oxide layer during welding increases the conductivity and can also isolate the copper terminal and the aluminum conductor, thus preventing an electrochemical reaction between the copper and the aluminum, prolonging the service life of the joint of the copper terminal and the aluminum conductor, and ensuring the mechanical and electrical performance of the connection structure.