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861 results about "Nano catalyst" patented technology

Nanometer photocatalyst material supported embedded composite film and preparation method and application thereof

The invention discloses a method for preparing a nanometer photocatalyst material supported embedded composite film. The method comprises the following steps: dissolving an organic polymer base film material, a pore-forming agent and a nanometer catalyst in a solvent, stirring and standing to prepare a casting film solution; dispersing the nanometer photocatalyst in the solvent to obtain dispersion liquid, spreading the dispersion liquid on a plate to prepare a spreading solution, and drying the spreading solution to obtain a spreading film; and covering the spreading film with the casting film solution, scraping a liquid film by utilizing a film scraper, immersing the scraped liquid film in a constant temperature gel bath, and curing the liquid film to prepare the nanometer photocatalyst material supported embedded composite film. The invention also provides the nanometer photocatalyst material supported embedded composite film and application thereof. According to the method, a nanometer photocatalyst coating is uniformly, effectively, stably and firmly supported on the surface of the embedded composite film. Moreover, according to the composite film, the removal rate of pollutants is effectively improved, and film pollution is reduced.
Owner:SHANGHAI JIAO TONG UNIV

A functionalized graphene supported nickel palladium bi-metal nanometer catalyst, and preparation and applications of the catalyst

A functionalized graphene supported nickel palladium bi-metal nanometer catalyst, and preparation and applications of the catalyst are provided. A preparation method does not include a high-temperature hydrothermal reaction or a step of adding other catalysts, and only includes adding nickel chloride (NiCl2) and sodium tetrachloropalladate (Na2PdCl4) which are metal precursors into a mixed solution of 3-aminopropyl-3-ethoxysilane (APTS) and graphite oxide (GO), rapidly reducing Ni<2+> and Pd<2+> ions into NiPd metal particles by utilizing sodium borohydride (NaBH4) and allowing the metal particles to grow on a -NH2-functionalized graphene substrate (NiPd/N-FG). The prepared nickel palladium metal nanometer particles are uniformly distributed on the substrate and have a very small particle size (1.2-2.4 nm). The synthesized Ni<0.4>Pd<0.6>/N-FG catalyst still has extremely good catalytic performance when the content of the non-noble metal Ni accounts for 40% of the total metal content. The method is simple, effective and low in cost, overcomes problems such as long synthesis time, high synthesis temperatures, and high nanometer particle sizes, and promotes practical application of formic acid as a hydrogen storage material in fuel cells and vehicle-mounted mobile hydrogen source materials.
Owner:JILIN UNIV

Nitrogen-doped hierarchical pore carbon and preparation method and application thereof

The invention discloses a preparation method of nitrogen-doped hierarchical pore carbon. The preparation method includes: using biomass as a raw material, and mixing the biomass with a composite activator; heating for calcining, mixing a calcining product with deionized water, standing for precipitation, and filtering to obtain precipitate; performing after-treatment to obtain the nitrogen-doped hierarchical pore carbon, wherein the composite activator is sodium hydrogen carbonate/nitrogen-containing compound, a mass ratio of sodium hydrogen carbonate to the nitrogen-containing compound is 0.25-4:1, the nitrogen-containing compound comprises at least one of ammonium oxalate, ammonium hydrogen carbonate, ammonium chloride and ammonium nitrate, and a mass ratio of the biomass to the composite activator is 1:2-16. The composite activator is utilized to activate the biomass to obtain a functionalized nitrogen-doped hierarchical pore carbon material, the preparation method is simple and easy to operate, the biomass existing in nature can be utilized directly, the obtained carbon material has rich hierarchical pore structure and can be used as a catalyst carrier to prepare high-performance nano catalysts, and utilization value of the biomass is increased greatly.
Owner:ZHEJIANG UNIV

Preparation method of catalyst for cathode of direct methanol fuel cell

The invention provides a preparation method of catalyst for the cathode of a direct methanol fuel cell, comprising the following steps: adding solvent into a reactor; adding with nitrogen; adding withM-salt and stabilizing agent in proportion; dropwise adding with reducing agent; reacting to prepare M nanometer catalyst solution; vacuuming and filtering to obtain M nanometer particles; dissolvingthe M nanometer particles into the solvent and stirring; adding with platinum base compound and stabilizing agent; ultrasonically stirring; adding with hydrazine hydrate solution and reacting; preparing black nanometer catalyst solution; separating and washing; and vacuum drying to obtain black powdered M-Pt core-shell structure nanometer particles catalyst. By using the characteristics that thenoble metal has higher catalytic activity to oxygen reduction and the transition metal has a special electronic structure, the method uses the transition metal with more d belt electron holes and lower electron negativity as core to prepare M-noble metal core shell structure nanometer particles which are used for oxygen electrode reduction catalyst of the direct methanol fuel cell, wherein the catalyst has higher oxygen reduction activity, methyl alcohol resistibility and stability, and the preparation method is simple and is low in cost.
Owner:TAIYUAN UNIV OF TECH

Preparation method of membrane electrode of direct methanol fuel cell

The invention relates to a preparation method of the membrane electrode of a direct methanol fuel cell. The method comprises the following steps: an electrostatic spinning technology is adopted to construct a nano-fiber network structure thin membrane mixed by active carbon powder and Nafion resin; a precious metal nano-catalyst is deposited on the surface of the manufactured nano-fiber network structure thin membrane, so that a cathode catalyst layer thin membrane and an anode catalyst layer thin membrane are manufactured respectively; or the mixture of the precious metal nano-catalyst and the Nafion resin is taken as raw materials to directly construct the cathode catalyst layer thin membrane and the anode catalyst layer thin membrane through the electrostatic spinning technology; a cathode gas diffusion layer, the anode catalyst layer thin membrane, a Nafion membrane, the cathode catalyst layer thin membrane and a cathode gas diffusion layer are hot-pressed finally, so that the aggregation of the membrane electrode of the direct methanol fuel cell is manufactured; the membrane electrode with a nano-fiber three-dimensional network structure is constructed through the electrostatic spinning technology, so that the maximization of the three-phase reaction interface of the membrane electrode is achieved, and the improvement of electrocatalytic activity, mass-transfer efficiency and utilization efficiency of the catalyst is achieved.
Owner:SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI

Preparation method of three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres

The invention relates to a preparation method of three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres, and relates to the technical field of multi-level structured nano-grade catalyst materials. First, nickel nitrate hexahydrate and cobalt nitrate hexahydrate are adopted as a nickel source and a cobalt source, a deionized water-isopropanol mixed phase with a proper proportion is adopted as a solvent, methanol is adopted as a reactant, and no additional base precipitating agent is adopted; a three-dimensional flower-shaped nano-sheet microsphere precursor is prepared in a Ni<2+>-Co<2+>-NH3-NH4<+>-SG<n->-H2O-IPA-CH3OH system (SG<n-> is CO3<2-> or HCOO<->); the temperature is increased to 300-400 DEG C in an air atmosphere with a speed of 1 DEG C/min, and the precursor is calcined for 2-3h, such that the three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres are obtained. According to the invention, co-precipitation of the formulated cobalt and nickel in the raw materials is realized. The prepared three-dimensional flower-shaped nickel cobaltate nano-sheet mesoporous microspheres are spinel cubic phases with high purity, and are formed by ultrathin nano-sheet self-assembly. The microspheres comprise rich mesopores, and have a large specific surface area. The method has the advantages of simple operation, appropriate conditions and easy control.
Owner:BEIJING UNIV OF CHEM TECH

Preparation of magnetic nano Cu-Fe3O4/grapheme composite catalyst and application of composite catalyst in reduction of nitro-compounds

The invention relates to a magnetic nano Cu-Fe3O4/grapheme composite catalyst and application of the composite catalyst in reduction of nitro-compounds. The preparation method comprises the steps of (1) placing graphite oxide into a water soluble alcohol for ultrasonic dispersion; (2) dissolving ferrous salts in water in an ultrasonic mode, then dropwise adding into a solution of Step (1), and mixing uniformly; and (3) dissolving copper salts in water in an ultrasonic mode, adding a sodium hydroxide solution to adjust the pH to be in a range of 10-11, conducting suction filtration and washing to obtain solid products, placing in the water soluble alcohol for ultrasonic dispersion, dripping into a mixing solution of Step (2), mixing uniformly, dropwise adding the sodium hydroxide solution to adjust the pH to be in a range of 10-11, mixing uniformly, and then transferring a mixture system into a hydrothermal still for reaction to obtain the magnetic nano Cu-Fe3O4/grapheme composite catalyst. The preparation method is few in step and simple in process, the prepared composite catalyst can be effectively separated in an applied magnetic field, the problem that the nano catalyst is difficult to recover is solved, and simultaneously, the catalyst has the high catalytic activity in terms of reduction of nitro-compounds.
Owner:HUAWEI TEHCHNOLOGIES CO LTD

Bimetal nanometer catalyst as well as preparation and application method thereof

The invention discloses a bimetal nanometer catalyst used for preparing dimethyl oxalate through CO gas-phase oxidative coupling as well as preparation and an application method of the bimetal nanometer catalyst, and belongs to the technical field of preparation of the dimethyl oxalate. The bimetal nanometer catalyst is characterized in that a catalyst carrier is Alpha-aluminium oxide, an active component is Pd-Cu nanometer grains, the average size of the grain is 2-3nm, the Pd content of the active component is 0.01-2% and Cu content is 0.01-0.04% according to the mass of the catalyst carrier. The catalyst is prepared through a room temperature normal position load method, the preparation method is simple, the energy dissipation is low, the catalyst is suitable for industrial production, the active component Pd-Cu nanometer grains in the catalyst has high dispersity, large specific surface area, small size and uniformity in distribution; the catalyst provided by the invention adopts the Pd-Cu bimetal nanometer grains as the active component, and a bimetal component synergistic effect and a nanometer effect are utilized to reduce the content of the noble metal PD to 0.1% under the premise of keeping the high activity and stability of the catalyst, therefore and the cost of the catalyst is greatly reduced, and the partial substitution of the noble metal is realized.
Owner:贵州鑫醇科技发展有限公司

Alloy nanoparticles, preparation method and applications thereof

The invention discloses alloy nanoparticles, a preparation method and applications thereof. According to the method, a metal precursor loaded on a substrate is rapidly reduced at a high temperature, wherein the metal is rapidly nucleated to avoid the generation of the split-phase alloy so as to form the alloy nanoparticles with ultra-small particle size; and by controlling the types of the metal salts in the precursor, the components in the alloy nanoparticles can be effectively regulated. According to the present invention, the FeCoPtPdIr@GO (FeCoPtPdIr alloy particles are loaded on the surface of graphene oxide) prepared in the embodiments of the invention shows excellent electrochemical hydrolysis hydrogen production performance, can stably operate for 150 h under a condition of 10 mA.cm<-2>, has excellent electrochemical stability, and has the Faraday efficiency of 99.4%, wherein the eta 10 of the product of the present invention is equal to 42 mV, and far exceeds the eta 10 of thecommercial Pt/C of 64 mV (the smaller the eta 10, the better the electrochemical hydrolysis hydrogen production performance); and the new thought is provided in the preparation of alloy nanoparticlesand alloy nanometer catalysts, and the development of alloy nanometer catalysts in catalysis and energy is promoted.
Owner:ZHEJIANG UNIV
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