232 results about "Ammonium nitrate" patented technology

The invention relates to the technical field of guanidine nitrate preparation, in particular to a method for preparing guanidine nitrate by a continuous dynamic tubular reaction process, which comprises the following steps: uniformly mixing dicyandiamide, target ammonium nitrate and target ammonium carbonate according to a mass ratio of 1: (1-3): (1-0.5); conveying the uniformly mixed material to a feeding section in a dynamic tubular reactor through a first conveying screw rod for mixing treatment, wherein the dynamic tubular reactor further comprises a heating section, a reaction section and a cooling section; sequentially conveying the target mixed material to a heating section for heating melting treatment, a reaction section for synthesis reaction treatment and a cooling section for cooling forming treatment through a second conveying screw rod to obtain an initial product; conveying the initial product into a cooling and crushing device for cooling and slicing to obtain a target guanidine nitrate product. According to the method disclosed by the invention, the mass and heat transfer efficiency can be improved, the online quantity and liquid holdup of the material are reduced, meanwhile, the raw material ratio and the reaction path are optimized, and the safety and the product purity are improved.

The invention discloses an ammonium nitrate solution concentration regulation reaction kettle with an explosion-proof function, and belongs to the technical field of reaction kettle equipment. The reaction kettle comprises a reaction kettle body, the bottom of the reaction kettle body is communicated with a discharge valve, a solution can be uniformly heated through an electric heating plate in a groove in the bottom of the inner wall of the reaction kettle body, and explosion caused by gas generated by decomposition of ammonium nitrate due to over-high local temperature is avoided; the stirring rod is matched with the top motor, so that an ammonium nitrate solution in the reaction kettle can be fully stirred, and the concentration distribution of the solution is uniform. The circular rings arranged on the upper surface and the lower surface of the reaction kettle body and the anti-explosion pipe fixedly connected with the circular rings effectively enhance the overall structural strength of the reaction kettle, the air outlet pipe of the top circular ring is matched with the air inlet pipe of the bottom circular ring, and external cold air enters the space between the anti-explosion pipe and the reaction kettle body, so that the reaction kettle body is uniformly cooled; and then the gas is discharged to the outside from the gas outlet pipe. The explosion-proof device has the advantage of good explosion-proof effect.

A composite oil phase and composite emulsion matrix for site-mixed emulsion explosive and preparation methods therefor. The composite oil phase is divided into material A and material B, wherein in the material A, a high-viscosity polyisobutylene maleic anhydride amine esterification derivative is used as a primary emulsifier to increase the strength and thickness of an emulsification film of an emulsion matrix, thereby improving the stability of the emulsion matrix; in the material B, a low-viscosity polyisobutylene maleic anhydride amine esterification derivative and SP-80 are used as primary emulsifiers to regulate the ammonium nitrate dissolution rate of the emulsion matrix, thereby improving the sensitization characteristic of the emulsion matrix; and the emulsion matrix prepared from two composite oil phases can effectively improve the water resistance of the emulsion matrix while the problems of high-temperature over-sensitization and low-temperature insensitivity are solved, so that the explosion quality is guaranteed.

The invention relates to an explosive wastewater green treatment process which comprises the following steps: S1, a pretreatment stage: pumping collected explosive wastewater into a micro-nano air flotation device to remove suspended solids, oils and surfactants in the explosive wastewater; s2, a resin adsorption stage: pumping the pretreated explosive wastewater into a resin adsorption system, and selectively adsorbing and removing ammonia nitrogen pollutants in the wastewater through resin; s3, a regeneration and desorption stage: carrying out sleeve washing and regeneration and desorption on the resin subjected to adsorption saturation by adopting dilute nitric acid so as to desorb and separate ammonia nitrogen adsorbed in the resin; and S4, a product recycling stage: carrying out impurity removal treatment on a concentrated regeneration desorption solution generated by desorption, and then adjusting the pH value to obtain an ammonium nitrate solution which is recycled in an explosive production process. And S5, a waste liquid treatment stage: adjusting the pH value of the resin adsorption effluent, and conveying the resin adsorption effluent to a sewage station for combined treatment. According to the method, the ammonia nitrogen pollutants in the explosive wastewater can be removed, and meanwhile explosive production raw materials can be recycled.

The invention provides a composite oil phase material for improving water resistance and explosion performance of a porous granular ammonium nitrate fuel oil explosive. The composite oil phase material comprises the following raw materials in parts by mass: 80-100 parts of naphthenic oil, 2-7 parts of an amino-containing dispersant, 1-5 parts of a nanoscale molecular sieve and 0.3-3 parts of an oleate derivative stabilizer. The composite oil phase material can effectively improve the explosion performance and the water resistance of the on-site mixed porous granular ammonium nitrate fuel oil explosive. The raw materials are environment-friendly and easy to obtain, and high popularization value is achieved. The composite oil-phase material provided by the invention is high in flash point and low in condensation point, can replace diesel oil with the grade of minus 40 DEG C to minus 20 DEG C to be applied to preparation of a porous granular ammonium nitrate fuel oil explosive mixed and loaded on site in winter, the intrinsic safety of the explosive production process is improved, and the explosive preparation cost is reduced. The composite oil phase material provided by the invention can also provide good weak alkaline water resistance for the porous granular ammonium nitrate fuel oil explosive.

The utility model relates to an electric heating anti-crystallization ammonium nitrate aqueous solution sampling port device, which belongs to the technical field of chemical equipment and comprises a bottom plate, a solution storage tank is fixedly mounted at the top of the bottom plate, a sampling tube is fixedly connected to the outer side of the solution storage tank, and a high-performance heating unit is fixedly mounted on the outer side of the sampling tube. The device has the beneficial effects that the ammonium nitrate aqueous solution in the solution storage tank is discharged through the sampling pipe, and the temperature and the current of the high-performance heating unit can be monitored in real time and can be accurately adjusted according to actual requirements due to the matched use of the high-performance heating unit, the temperature sensor, the current sensor and the controller; according to the ammonium nitrate water solution sampling device, the heating effect is efficient and stable, accurate control over the temperature of an ammonium nitrate water solution sampling opening is achieved, the crystallization problem is effectively prevented, sampling smoothness and normal operation of equipment are guaranteed, and meanwhile energy consumption and maintenance cost are reduced.

The invention discloses a nitrate-containing waste liquid treatment method, which comprises: (1) waste acid treatment: diluting waste acid in a neutralization reaction kettle, adding ammonia water while stirring, controlling the temperature to be 70-95 DEG C, continuously adding ammonia water to adjust the pH value of the solution to be 7.5-10.0 after the neutralization is completed, and carrying out stirring distillation to obtain an ammonium sulfate nitrate aqueous solution or an ammonium sulfate nitrate crystal; (2) wastewater treatment: 1) wastewater steam stripping: transferring nitrate wastewater into a steam stripping kettle, adding a pH regulator to regulate the pH value to be 10-13, heating the steam stripping kettle to a boiling state by using steam, distilling, condensing and recovering nitrate in the wastewater; and 2) oxidation treatment: after steam stripping is finished, hydrogen peroxide is added into the steam stripping kettle in a boiling state, stirring reaction is performed, and the reacted wastewater can be discharged after reaching the standard. Compared with a traditional Fenton method and an activated carbon adsorption method, the method has the advantages that secondary pollutants Fe (OH) 3 generated by treatment and saturated activated carbon after adsorption can be avoided, harsh reaction conditions such as light, electricity and microwaves can be avoided, the operation cost is reduced, the method is safe, environment-friendly and free of secondary pollution, the nitrate removal rate can reach 100%, and the method is suitable for industrial production. The COD (Chemical Oxygen Demand) of the treated wastewater is less than 100mg / L, and the wastewater can reach the direct discharge standard.

Disclosed is a system for the production of urea ammonium nitrate (UAN), which is particularly suitable for processing relatively small ammonium nitrate waste streams into UAN. The system comprises a concentration for ammonium nitrate, a treatment section which allows recovering and recirculating nitrogen compounds entrained in vapor from the concentration section, and a pH control section allowing to adjust the pH of the processed ammonium nitrate waste stream to the extent necessary.

The invention relates to the technical field of pharmaceutical analysis, in particular to a method for detecting the content of guanidine nitrate by precolumn derivatization-high performance liquid chromatography, which comprises the following steps: oscillating and uniformly mixing a guanidine nitrate reference substance or sample and pure water at room temperature, adding sulfuric acid concentrated liquor in cold water bath to perform derivatization reaction, after the reaction is finished, placing at room temperature, and performing column chromatography to obtain the guanidine nitrate content. Adding liquid caustic soda for neutralization, carrying out gradient constant volume by using a mobile phase, and filtering by using a microporous filter membrane to respectively obtain a derivatization reference solution and a derivatization sample solution; and respectively injecting the derivatization reference substance solution and the derivatization sample solution into HPLC, recording peak areas, and calculating the content of guanidine nitrate in the sample by adopting an external standard method. The guanidine nitrate sample is pretreated through the precolumn derivatization reaction, the guanidine nitrate derivative generated through the reaction has the advantages of being high in stability and easy to separate, ammonium nitrate and nitric acid impurities can be effectively prevented from interfering the detection result, the explosive picric acid is not adopted in the detection method, and the detection method is simple, safe and easy to implement.

The invention discloses a powdery emulsion explosive with eutectic inorganic salt as an internal phase and a preparation method, and relates to the technical field of powdery emulsion explosives, the powdery emulsion explosive comprises the following raw materials by weight: 90-110 parts of eutectic inorganic salt and 5-7 parts of a composite oil phase; wherein the eutectic inorganic salt is prepared by recrystallizing ammonium nitrate and sodium chloride. Ammonium nitrate and sodium chloride are combined in a recrystallization manner, so that sodium chloride is uniformly distributed in ammonium nitrate crystals in a lattice doping manner, a molecular-level dispersion effect is realized, and the flame inhibitor is more uniformly dispersed in an inner phase; secondly, the eutectic inorganic salt has a synergistic decomposition peak at 210-240 DEG C, and chloride ions are released in advance to interact with active groups generated by explosion; under the combined action of the two factors, sodium chloride is used as a flame inhibitor to play a role more effectively at the flame front, the flame temperature is reduced, and flame propagation is inhibited.

The utility model discloses an ammonium nitrate solution concentration blending reation kettle with anti -explosion function belongs to reation kettle equipment technical field, the utility model discloses a reation kettle body is communicated with the discharge valve at reation kettle body bottom, can carry out even heating to solution through the electric heating plate in the reation kettle body inner wall bottom groove, avoid local temperature too high and cause ammonium nitrate to decompose gas and cause explosion, the cooperation design of stirring rod and top motor can carry out sufficient stirring to ammonium nitrate solution in reation kettle, make solution concentration distribution even. The annular ring and the explosion -proof pipe fixedly connected with the annular ring that reation kettle body surface sets up up and down, effectively enhanced the overall structural strength of reation kettle, the gas outlet pipe of top annular ring and the gas inlet pipe of bottom annular ring mutually cooperate, and the outside cold gas enters the space between the explosion -proof pipe and reation kettle body, and then even cooling is carried out to reation kettle body, and then gas is discharged to the outside from the gas outlet pipe, and the device has the advantages that the explosion -proof effect is good.

This invention relates to the field of solid propellant technology, specifically disclosing a neutral polymer bonding agent, its preparation method, and its application in solid propellants. The neutral polymer bonding agent is prepared by polymerization of poly(hydroxyalkyl polyacrylate) and cyanoacetic acid as raw materials. It can achieve controllable molecular weight and controllable proportion of functional groups in the polymer. Moreover, the active group -CN in the neutral polymer bonding agent has low steric hindrance and is more easily adsorbed on the surface of ammonium nitrate particles, thereby improving the bonding effect.

The invention discloses a fuel gas rock cracking agent and a preparation method thereof, and belongs to the technical field of gunpowder. In order to solve the technical problems of danger in reprocessing of propellant powder, low utilization rate, environmental pollution and the like, the invention provides a gas rock cracking agent which comprises the following components: 25-75% of main charge, 20-70% of performance regulator and 2-5% of curing agent, the main charge is at least one of single-base propellant powder, double-base propellant powder or three-base propellant powder, the performance regulator is at least one of ammonium nitrate, potassium nitrate, sodium nitrate and ammonium dinitramide, and the curing agent is nitrocotton. The gas rock cracking agent is stable and free of overall explosion hazard, has the characteristics of low vibration, controllable flying rocks, clean products and the like when being used for rock cracking, and can well meet rock cracking operation under sensitive environments and various special working conditions; by adopting a wet mixing process, the fire blast risk caused by friction and static electricity in the mixing process of the propellant powder and the performance regulator can be effectively reduced.

This proposal discloses an additive and method for producing ultra-thin electrolytic copper foil with high tensile strength and high elongation. The additive comprises an inorganic nitrate and an organic compound; the inorganic nitrate is one or a combination of ammonium nitrate, copper nitrate, and bismuth nitrate; and the organic compound is a crown ether, a cyclic alcohol, and glycolic acid. By adding the inorganic nitrate / organic compound additive, the present invention produces ultra-thin electrolytic copper foil with a thickness of 6 μm or less, achieving a tensile strength exceeding 500 MPa and an elongation exceeding 5%.

The utility model relates to the technical field of material storage equipment, and discloses a porous granular ammonium nitrate stock bin which comprises an upper stock bin and a controller, a stock bin top cover is fixed at the top of the upper stock bin, a speed reducer is fixed in the center of the top of the stock bin top cover, the rotating end of the speed reducer penetrates through the stock bin top cover and is fixedly provided with a rotating shaft, and the rotating shaft is connected with the controller. A plurality of stirring blades are fixed at equal intervals in a circle center array on the outer surface of the rotating shaft. According to the utility model, by adopting the two feed ports, the conical height of porous granular nitric acid accumulated at the feed ports is reduced, so that the space utilization rate of the stock bin in a natural feeding state is improved, and the accumulation height can be reduced by half compared with the accumulation height of one feed port; the material level sensor conveys the material to the controller, and the controller starts the speed reducer to drive the rotating shaft and the stirring blades to flatten the stacked materials at the two discharging openings, so that the space utilization rate of the stock bin is increased.

The invention discloses a composite propellant containing a high-nitrogen ferrocene derivative and a preparation method of the composite propellant. The composite propellant is prepared from the following components: 14.05% of hydroxyl-terminated polybutadiene (HTPB), 7.03% of diisooctyl sebacate (DOS), 0.92% of 2, 4-toluene diisocyanate (TDI), 1% of the high-nitrogen ferrocene derivative, 59% of ammonium perchlorate (AP) and 18.00% of aluminum powder (Al). N, N-dimethylaminomethylferrocene in the three high-nitrogen ferrocene derivatives has the effects of improving the burning rate of the composite propellant and reducing the pressure index as the ferrocene derivative, nitrate, picric acid, 3-nitro-1, 2, 4-triazole-5-ketone and the like are rich in C, H, O and N elements, and are similar to oxidizing agents such as typical components ammonium nitrate, HMD and the like in the composite propellant; the fuel can be decomposed to provide energy for propellant combustion; the propellant has a low combustion rate pressure index in a pressure range of 1-10 MPa, and has more excellent combustion stability.

The utility model relates to the technical field of on-site explosive loading, in particular to a blast hole filling length measuring device based on an on-site mixed loading ammonium nitrate fuel oil explosive truck, which is used for the mixed loading explosive truck and comprises a top spiral cylinder connected with the tail end of a top spiral of the mixed loading explosive truck. A pulley is connected to the mounting base through a pin shaft, an inner groove is formed in the periphery of the pulley, a rope slides in the inner groove, the two ends of the rope are connected with a balancing weight and a tension sensor respectively, a depth sensor is arranged in the balancing weight, and after the balancing weight is arranged at a preset position in a blast hole, explosive can be fed into the blast hole in real time; compared with the conventional mode of manually measuring the filling length of the blast hole after filling the explosive, the method provided by the utility model has the advantage that the measuring efficiency is obviously improved.

The application discloses a method and system for preparing ammonium bifluoride from hydrofluoric acid waste liquid, which comprises the following steps: (1) adding the hydrofluoric acid waste liquid into an electrolytic cell, transporting the electrolytic cell to a first reaction kettle after electrodepositing treatment, adding silicon dioxide, then stirring and reacting, and returning the generated silicon tetrafluoride and hydrofluoric acid into a spray tower to react and then return to the first reaction kettle, and then adding ammonia water to perform neutralization reaction; (2) filtering the solid-liquid mixture I, evaporating and drying the obtained filtrate I to obtain an ammonium nitrate product, and returning the obtained filter cake I to a second reaction kettle, adding ammonia water to adjust the pH value, and then stirring and reacting; (3) filtering the solid-liquid mixture II, returning the obtained filter cake II to the first reaction kettle for reuse, transporting the obtained filtrate II to a reactor, adding hydrofluoric acid to perform reaction, and then performing evaporation and drying treatment to obtain an ammonium bifluoride product. The method is simple in process, low in energy consumption, convenient to operate and convenient for industrialized production and application.

The present application relates to the technical field of combustible substance detection in ammonium nitrate, and provides an automatic device for detecting combustible substance in ammonium nitrate, which comprises a reagent storage unit for storing ammonium nitrate sample, sodium persulfate reagent and phosphoric acid reagent; a CO2 infrared analyzer is connected with the reagent storage unit, the CO2 infrared analyzer can receive the reagent supplied by the reagent storage unit and determine the content of CO2 after the combustible substance in the ammonium nitrate sample is oxidized by the sodium sulfate reagent to form CO2; a controller controls the reagent storage unit to supply the reagent to the CO2 infrared analyzer, and receives and analyzes the content information of CO2 determined by the CO2 infrared analyzer to obtain the content of combustible substance in ammonium nitrate. The automatic device for detecting combustible substance in ammonium nitrate provided by the present application realizes efficient detection of combustible substance by using wet oxidation-infrared quantitative technology.

The utility model discloses a granular ammonium nitrate feeding device for an on-site mixed loading explosive truck, which comprises a feed box, a support frame is fixedly arranged on the periphery of the feed box, a discharge port is arranged at the lowest point of the feed box, and a discharge mechanism is arranged outside the discharge port. The discharging mechanism comprises a discharging cover plate covering the discharging port and a plurality of sets of driving connecting rods and driven connecting rods, one end of each driven connecting rod is hinged to one end of the corresponding driving connecting rod in the same set, the other end of each driven connecting rod is hinged to the discharging cover plate, the other end of each driving connecting rod is vertically and fixedly connected with an operating rod, and the operating rod is fixedly connected with the discharging port. The two ends of the operating rod are rotationally connected with the supporting frame in a shaft hole positioning mode, and the operating rod is perpendicularly and fixedly connected with a plurality of operating handles. The device has the advantages of being simple in structure, free of maintenance, convenient to use, low in energy consumption, small in equipment investment and the like.

The utility model relates to the technical field of explosive filling, and discloses an ammonium nitrate fuel oil explosive truck explosive guiding pipe which comprises an outer pipe sleeve, an inner pipe fitting is fixedly sleeved with the outer pipe sleeve, a movable pipe is movably sleeved with the inner pipe fitting, a discharging pipe head is fixed to the end, extending out of the inner pipe fitting, of the movable pipe, and the discharging pipe head is fixedly connected with the outer pipe sleeve. A guide assembly is arranged between the movable pipe and the outer pipe sleeve, a limiting plate is fixed to one end of the outer pipe sleeve, a plurality of ventilation through holes are formed in the side wall of the limiting plate in a circular array mode, and the portion, located outside the ventilation through holes, of the side wall of the limiting plate is sleeved with a ring piece in a clamped mode. According to the utility model, the construction range of the existing ammonium nitrate fuel oil explosive truck is enlarged, the problem that operation cannot be carried out in some environments is solved, and the operation efficiency is improved.

This invention discloses a method for preparing g-C3N4-based composite energetic materials. The method employs simple physical grinding, in-situ reduction, and electrostatic self-assembly. First, g-C3N4 and explosive are physically ground at a specific mass ratio to obtain composite material 1. Then, ultrasonically treated g-C3N4 and GO are coated onto the surface of the explosive crystals through in-situ reduction to obtain composite material 2. Finally, the highly cationic properties of polyethyleneimine are used to modify the surface of ammonium nitrate explosives, and composite material 3 is obtained through electrostatic self-assembly. This invention combines g-C3N4 and GO to desensitize ammonium nitrate explosive crystals, resulting in an ammonium nitrate explosive composite material that simultaneously possesses desensitization and high energy performance. The high stability, high thermal conductivity, and lubricity of g-C3N4 and GO are utilized to passivate the mechanical sensitivity of the energetic material.

Provided are an ammonium nitrate manufacturing apparatus, which is an apparatus for manufacturing ammonium nitrate from a diluted nitrogen oxide, including: a cathode; an anode which is arranged to be opposite to and spaced apart from the cathode; and an electrolyte placed between the anode and cathode, wherein the cathode and the anode are independently of each other gas diffusion electrodes including: a porous substrate; metal organic frameworks (MOFs) dispersed in the porous substrate; and a metal catalyst placed on one surface of the porous substrate, and a method for manufacturing ammonium nitrate using the same.

The utility model discloses a safe, efficient and energy-saving ammonium nitrate solution production system which comprises an efficient tubular reactor, a reactor flash tank and a reflux mixer, the efficient tubular reactor is communicated with the reactor flash tank and the reflux mixer, and an ammonia gas pipe and a nitric acid pipe are connected to the efficient tubular reactor. An adjusting loop is connected among the ammonia gas pipe, the nitric acid pipe and the efficient tubular reactor, the reflux mixer comprises a neutralization washing tower, and the reactor flash tank is further connected with a falling film primary evaporator. Compared with the prior art, the system provided by the utility model has the advantage that the ammonium nitrate solution can be prepared safely, efficiently and in an energy-saving manner by utilizing the pressurized tubular reactor and the MVR evaporator.

The invention discloses a large-size tin-phosphor bronze / Q235B composite plate and a preparation method thereof, and belongs to the field of material forming, the method comprises the following steps: by taking a Q235B steel plate as a base plate and a tin-phosphor bronze plate as a compound plate, sequentially laying a base plate, the Q235B steel plate, a support column, the tin-phosphor bronze plate, a protective layer, a fence structure, a low-detonation-velocity rock expanded ammonium nitrate fuel oil explosive layer and an inert layer on an explosion field from bottom to top, and forming the composite plate. And then the tin-phosphor bronze plate and the Q235B steel plate are subjected to metallurgical bonding after high-speed collision by detonating the explosive, the large-size tin-phosphor bronze / Q235B composite plate is obtained, the interface bonding rate of the obtained composite plate is larger than 98%, the interface shear strength exceeds 274 MPa, and the composite plate has the advantages of excellent high strength, wear resistance and the like of tin-phosphor bronze and low cost of Q235B steel.

The utility model discloses an expanded ammonium nitrate explosive finished product packaging, sealing and edge folding device which comprises a conveying belt arranged on a conveying base, a first electric push rod inserted into the top of the conveying base, a lifting plate arranged at the output end of the first electric push rod, a vertical plate arranged at the top of the lifting plate, an abutting plate inserted into the vertical plate, and a second electric push rod arranged on the side face of the vertical plate. A side plate is arranged on the rear side of the conveying base, a third electric push rod is arranged on the rear side of the side plate, a sliding groove is formed in the surface of the side plate, a lifting rod is arranged in the sliding groove, the rear end of the lifting rod is connected with a transverse rod, a motor is arranged at the front end of the lifting rod, a rotating block is arranged on an output shaft of the motor, and a telescopic column is arranged on the side face of the rotating block; a U-shaped frame is arranged at the other end of the telescopic column, an extrusion roller is arranged in the U-shaped frame, and the telescopic column is sleeved with a spring; according to the device, the two side cover plates I and the two side cover plates II at the top of the carton can be automatically turned over, follow-up automatic sealing with adhesive tape is facilitated, time and labor are saved, and the working efficiency is improved.

The invention relates to the technical field of chemical detection, and discloses an automatic detection system for the pH value and concentration of an ammonium nitrate solution. The dilution module comprises a mixing tank, and the mixing tank is connected with the sampling valve through a pipeline; the input end of the condenser is connected with the mixing tank through a pipeline, and the condenser is used for cooling the diluent; the pH detection module comprises a cooling tank, the cooling tank is connected with the output end of the condenser through a pipeline, and a pH sensor is arranged in the cooling tank; through dilution and cooling treatment, the concentration and temperature of the ammonium nitrate solution are reduced, the service life of the sensor is prolonged, and the measurement precision is improved. The concentration detection module is used for detecting the concentration of the diluent based on a non-contact electromagnetic wave spectrum analysis method; the concentration is detected by adopting an electromagnetic wave spectrum analysis method, and interference and potential safety hazards of a traditional method are avoided. The real-time, continuous and automatic detection of the pH value and the concentration value of the ammonium nitrate solution is realized, and the production safety is ensured.

This application provides a continuous titration method for the sulfuric acid and ammonium nitrate content of silicon etching solution. The continuous titration method includes the following steps: weigh m grams of silicon etching solution sample into a sample bottle, add phenolphthalein indicator, titrate with a first sodium hydroxide standard solution of concentration C1 until a pink color is achieved, and record the volume consumed V1. Calculate the sulfuric acid content. Add neutral formaldehyde solution to the same solution and let it stand for a first preset time to generate a free acid solution. Continue titrating the free acid solution with a second sodium hydroxide standard solution of concentration C2 until the solution turns pink. Gently heat the solution to a preset temperature and maintain this temperature for a second preset time. If the pink color persists, the titration endpoint is determined, and the volume consumed V2 is recorded. Calculate the ammonium nitrate content. This method achieves continuous titration of two components with a single sample, eliminates mutual interference between components, optimizes the endpoint determination method, and thus achieves a simple operation, high accuracy, low sample consumption, and high detection efficiency.

The invention discloses a liquid energetic material composed of non-dangerous chemical raw materials and a preparation method of the liquid energetic material, the liquid energetic material is formed by mixing an oxidizing agent concentrated solution and glycerin in proportion, and the oxidizing agent concentrated solution is obtained by mixing calcium ammonium nitrate, ammonium carbonate and water in proportion and then conducting filtration and vacuum concentration. According to the invention, the prior art is greatly improved, and the three raw materials are all non-dangerous chemicals, so that the traffic and storage safety in the long-time land and marine transportation process in the offshore oilfield operation can be greatly improved; the mode of obtaining the liquid energetic material on site is simple, and seamless butt joint operation with existing liquid gunpowder deflagration fracturing can be achieved; the influence of temperature on solubility is overcome, the composition proportion is moderate, the system can be completely dissolved after being prepared, the operation water adding amount is reduced by utilizing crystal water in the raw materials, and the preparation method is suitable for the environment in shortage of water resources.

The invention relates to the technical field of explosive conveying, and discloses an underground ammonium nitrate fuel oil explosive conveying device which comprises a conveyor body, an annular distribution mechanism is installed in the conveyor body, an automatic feeding mechanism is arranged above the annular distribution mechanism, the annular distribution mechanism comprises a material pushing block and well falling barrels arranged on the lower portion in a surrounding mode, and the automatic feeding mechanism is arranged above the material pushing block. A material distributing assembly is arranged between the material pushing block and the well falling barrel. The material pushing block can be driven to slide on the fixing frame in a reciprocating mode through rotation of the guide rail disc, the ammonium nitrate fryer charge falling into the material pushing opening is pushed out of the stacking barrel, meanwhile, the well falling barrel can also rotate, and when the material pushing opening is aligned with a containing opening in one end of the fixing frame, the well falling barrel can also be aligned with the containing opening; by means of the annular arrangement, the pressure of the explosive charge on the well bottom can be more uniform, and the risk that the structure is unstable or the explosive is detonated in advance due to the fact that local stress is too large is avoided.