307results about "Alkali metal nitrate preparation" patented technology

The present invention describes a process for converting vapor streams from sources containing at least one nitrogen-containing oxidizing agent therein to a liquid fertilizer composition comprising the steps of: a) directing a vapor stream containing at least one nitrogen-containing oxidizing agent to a first contact zone, b) contacting said vapor stream with water to form nitrogen oxide(s) from said at least one nitrogen-containing oxidizing agent, c) directing said acid(s) as a second stream to a second contact zone, d) exposing said second stream to hydrogen peroxide which is present within said second contact zone in a relative amount of at least 0.1% by weight of said second stream within said second contact zone to convert at least some of any nitrogen oxide species or ions other than in the nitrate form present within said second stream to nitrate ion, e) sampling said stream within said second contact zone to determine the relative amount of hydrogen peroxide within said second contact zone, f) adding hydrogen peroxide to said second contact zone when a level of hydrogen peroxide less than 0.1 % by weight in said second stream is determined by said sampling, g) adding a solution comprising potassium hydroxide to said second stream to maintain a pH between 6.0 and 11.0 within said second stream within said second contact zone to form a solution of potassium nitrate, and h) removing said solution of potassium nitrate from said second contact zone.

A method for preparing potassium nitrate and ammonium chloride employing double decomposition reaction comprises the following steps: dissolving ammonium nitrate and potassium chloride in water according to a defined ratio at 110 DEG C, continuously adding potassium chloride and water, heating while stirring to ensure that potassium nitrate is in supersaturation state, after stopping heating, cooling the solution in a vacuum cooling crystallizer to 36-40 DEG C to separate potassium nitrate crystal, placing the potassium nitrate crystal in a centrifugal machine with a filter cloth lining to obtain coarse potassium nitrate, then washing the potassium nitrate with cold water, drying to obtain the finished potassium nitrate; in addition, adding ammonium nitrate in mother solution I and cleaning solution to adjust solution concentration so that ammonium chloride can reach supersaturation state, using a vacuum concentration device to perform negative pressure evaporation, separating and precipitating ammonium chloride by centrifuging and obtaining a solid ammonium chloride product, wherein, when dissolving ammonium nitrate and potassium chloride, the ratio of ammonium ion to chlorine ion is 1:2 and when using the centrifugal machine to obtain the coarse potassium nitrate, the separated mother solution is another mother solution I sharing the same saturation point of potassium nitrate and ammonium chloride. The solution of feed liquid circular reaction overcomes the defects of the prior art that the price of potassium nitrate used in reaction is high, the resource of potassium nitrate is in short supply and the cost of devices used in ion-exchange method is high, thus being applicable to the production of potassium nitrate.

The invention relates to a method for producing mineral-based potassium nitrate for agricultural use through rocks rich in potassium. The method comprises the following steps: crushing the rocks rich in the potassium, and milling the rocks after mineral dressing and trash extraction to obtain the powder with the main phase of potash feldspar; mixing the potash feldspar powder and lime according to the mass ratio of 1: 0.80-0.85, adding water according to the solid-liquid mass ratio of 1: 15-25, stirring and mixing the materials for reactions in a reaction kettle, carrying out a hydrothermal reaction on the condition of stirring at a temperature of between 180 and 250 DEG C, carrying out the reaction at constant temperature for 5 to 10 hours to obtain KOH solution and tobermorite; and preparing potassium nitrate through the obtained KOH solution, compounding the potassium nitrate with the tobermorite, and adding a binder for granulation and forming so as to obtain the novel mineral-based potassium nitrate for agricultural use. The KNO3 nutrient content can be adjusted in the range of between 22.0 and 58.6 percent.

The invention discloses a method for separating lithium carbonate from electrolyte acidic leachate. The method comprises the following steps of: S1, adding a soluble salt solution to aluminum electrolyte acidic leachate while stirring and heating are performed, monitoring the acidity and the concentration of fluoride ions, and stopping the addition when the pH value is greater than 5 and the concentration of the fluoride ions is less than 0.01 g/L, wherein the soluble salt is one or more selected from MeSO4, MeNO3 and MeCl, and Me is metal which can produce precipitate with F<->; S2, performing filtration on reactants, performing washing and drying on filter residues to obtain a fluoride salt of the metal Me, adding a soluble carbonate solution into the obtained filtrate with stirring andheating, and terminating the reaction when the concentration of lithium ions is less than 0.08 g/L; S3, filter the filtrate, performing washing and drying on the filter cake to obtain lithium carbonate, and performing evaporation, crystallization, washing and drying on the filtrate to obtain inorganic salts. According to the method for separating lithium carbonate from the electrolyte acidic leachate, the reaction process is controlled by controlling the concentration of the fluoride ions and the acidity, so that the lithium ions are separated from other ions, lithium carbonate with high recovery rate is obtained, and meanwhile high-purity fluoride and inorganic salt products are obtained.

The invention discloses a method for preparing potassium nitrate by means of double decomposition. The method comprises the following steps: taking potassium chloride, ammonium nitrate and water solution as raw materials, and controlling the concentrations of Cl<-> and NH4<+> in the reaction solution to be 14-19% and 6-9.6% respectively, wherein the temperature of the reaction solution is 85-95 DEG C; lowering the temperature of a solution obtained from the reaction till a temperature of 0-20 DEG C is realized, crystallizing and precipitating KNO3 semi-finished product, and obtaining a filtrate mother liquor I by means of filtration; flushing KNO3 crystals with water till the Cl<-> concentration is 1-2% and the NH4<+> concentration is 1-3%; and recovering the flushing solution; positioningthe KNO3 crystals in a double decomposition device so that the KNO3 crystals can be fully dissolved, and controlling the solution concentration to be 44-52 Be; lowering the temperature for purpose ofprecipitating the KNO3 crystal, drying the KNO3 crystal till the water content of the KNO3 is less than or equal to 0.1%, and then obtaining the KNO3 finished product. In the method, the double decomposition device is used during the double decomposition reaction process and no stirring device is needed, therefore, the contact reaction of the reaction solution is more complete, and balance, continuous cyclic industrial production, productivity improvement and production cost reduction are realized in the precondition of ensuring 'two highs'.

The invention discloses a harmlessness and reclamation treatment method of aluminum scrap electrolyte and belongs to the technical field of inorganic chemistry. The method comprises the main steps that 1, aluminum scraps are electrolyzed and subjected to crushing and screening, and aluminum electrolyte particles are obtained; 2, acid liquor with the concentration of 1 mol/L and an aluminum salt solution with the concentration of 1 mol/L are prepared for standby application; 3, the aluminum electrolyte particles obtained in the step 1 are placed in the acid liquor prepared in the step 2 and leached on the heating and stirring conditions, the PH of the solution is controlled to be smaller than 5, when the fluorinion leaching rate is higher than 94%, leaching is finished, impurities are filtered, and a leaching solution is obtained; 4, the aluminum salt solution prepared in the step 2 is added to the leaching solution in the step 3, the mixture is heated and stirred, Al3+/Na+ is controlled to be larger than 0.3, when sediment is generated in the solution, the solution is filtered, filter residues and filter liquor are obtained, and the filter residues are washed and dried to obtain alkali type aluminum fluoride products; and 5, the filter liquor in the step 4 is evaporated and crystallized to obtain sodium salt products.

A pulverized coal/coke (PC) boiler combusts carbon-based fuel with substantially pure oxygen and a flue gas recirculation stream (containing predominately carbon dioxide) at varied ratios to achieve a desired boiler temperature profile while producing captured sulfur, a high purity captured CO₂ and electric power. The boiler includes at least one of (a) a mechanism for admixing a pulverized solid carbon-based fuel with an alkali metal salt and (b) injecting alkali metal salt into the boiler combustion zone containing a pulverized solid carbon-based fuel.

The invention provides a method for using nitratine to produce sodium nitrate, which is characterized in that the method comprises the steps of: crushing a piece of nitratine raw ore, and sieving the raw ore to obtain nitratine ore and nitratine ore powder; adding water into the nitratine ore powder, and agitating and leaching the powder and then gaining a clear liquid by sedimentation and clarification; positioning the nitratine ore in a leaching pond, feeding a mother liquor for cold separation and/or a washing liquid, starting up a circulating pump to circulate the leaching solution, and leaching the ore under normal temperature; inputting the leaching solution to a solar pond after the leaching; heating the leaching solution to a temperature between 30 DEG C and 80 DEG C by utilizing the stored energy in the solar pond, and extracting high-temperature concentrated solution from the bottom of the solar pond after evaporation concentration; and separating out NaNO3 through crystallization by cooling. The method is applied to low grade nitratine resources, and locations of resources are areas short of water seriously and rich in solar energy resources, and the method has advantages of energy and water saving and easy realization.

A potassium nitrate production process by a double decomposition-air cooling crystallization method is disclosed. Ammonium nitrate and potassium chloride are adopted as raw materials. A double decomposition reaction is adopted to produce the potassium nitrate and ammonium chloride. In a process of producing the potassium nitrate and the ammonium chloride, an air cooling crystallization process is adopted, air is adopted as a cooling medium and is directly mixed with and in contact with a solution and convective heat transfer and diffusion heat transfer occur, thus achieving cooling crystallization of the potassium nitrate and the ammonium chloride. The potassium nitrate production process has characteristics of high raw material utilization rate, significant energy conservation and consumption reduction, good potassium nitrate product quality and good ammonium chloride product quality, and achieves large-scale continuous production.

A technology for producing highly pure potassium nitrate through a reaction of sodium nitrate and potassium chloride comprises the following steps: 1, adding clear water or a mother liquor into a reactor, dosing raw materials potassium chloride and sodium nitrate according to a molar ratio of 1:0.9-1.5, and carrying out a metathesis reaction at 70-150DEG C under normal pressure or an elevated pressure for 0.5-5h; 2, carrying out solid-liquid separation; 3, carrying out solid-liquid separation; 4, crystallizing; 5, dissolving crude potassium nitrate in water at 50-120DEG C to obtain a potassium nitrate solution; 6, filtering the potassium nitrate solution obtained in step 5 through a filtering device, or adding a flocculating agent to clarify the potassium nitrate solution; 7, re-crystallizing; and 8, washing purified potassium nitrate, centrifuging, and drying to obtain potassium nitrate. The technology has the advantages of realization of continuous or intermittent production, stable and reliable quality of the above product, and low energy consumption. The product meets superior product requirements, and the main content of potassium nitrate reaches 99.9% or above.

This invention relates to a method for preparing KNO3 and NH4Cl taking KCl and NH4NO3 as the raw materials and applying a de-analyzing method, in which, in the mixed solution of KNO3 mother solution and NH4NO3, evaporation of water and crystallization of NH4Cl are finished in the process of evaporation and crystallization, the mixed solution is evaporated in a continuous evaporator under 100-120deg.C and evaporation pressure of 540-935mmHg.

The invention discloses a method for hierarchically recycling phosphoric acid, acetic acid and nitric acid from an aluminum scrap etching solution, which comprises the following steps of volatilizingthe acetic acid and nitric acid in the aluminum etching solution by reduced pressure distillation, and recycling by condensation; adding an additive into the residual phosphoric acid solution, crystallizing, washing, dissolving and the like to obtain the high-purity phosphoric acid; adding the sodium acetate into the collected distillate containing the acetic acid and nitric acid, and distilling to collect the acetic acid; and carrying out vacuum concentration, crystallization, filtration and drying on the acetic acid distilled liquid to obtain a sodium nitrate finished product. The reusable high-purity phosphoric acid is obtained by methods of distillation, concentration, recrystallization and the like, the acetic acid is recycled, and the nitric acid is converted into the available sodium nitrate, so that the useful components in the aluminum etching solution are reasonably and effectively utilized, and the resource waste and the environmental pollution are avoided. The method is high in recycling rate and high in operability, can meet the large-scale production, realizes the resource cyclic utilization to the maximum extent, and avoids the direct emission of the aluminum etchingsolution.

The invention relates to a process for producing sodium nitrate by using nitratine reverse-flow circulation extraction, which comprises steps as follows: (1) breaking ores into the grains smaller not larger than 5cm, (2) reverse-flow circulation leaching: after 2-6 stages of reverse-flow circulation immerge, the sodium nitrate content of extraction solution is increased from 300-380g/l to 390-500g/l, (3) separating, washing and drying at low temperature that exchanges heat between the extraction solution and low-temperature separation mother liquid, to reduce temperature, mixing and reducing temperature to -10-20DEG C, and keeping temperature for 100-140min, separating solid and liquid, filtering and washing via a saturated sodium nitrate, according to the mass ratio between product and sodium nitrate solution as 6/1-5/1, then drying to obtain sodium nitrate product, and feeding the separated mother liquid into the step (2), to process next circulation. The invention can save water more than 40%, and save energy more than 25%, while the single-process collecting rate is more than 25% and the total collecting rate of sodium nitrate in ore is more than 95.0%. The product obtained by low-temperature separation contains sodium nitrate more than 92%, and the washed product contains sodium nitrate more than 98%. The invention can use low-grade nitratine mine to produce sodium nitrate.

The technological process of preparing potassium nitrate and magnesium chloride includes the following steps: adding powdered magnesite into nitric acid solution to react, adding potassium chloride for reacting with coarse potassium nitrate, adding additive, maintaining the temperature to deposit, filtering, cooling to crystallize, centrifugally separating and drying to obtain potassium nitrate product for farm use; mixing mother liquor I and mother liquor III, evaporating to concentrate, and cooling to crystallize and separate magnesium chloride hexahydrate crystal; cooling mother liquor II to crystallize, and centrifugally separating to obtain coarse potassium nitrate and mother liquor III. The technological process is simple, low in power consumption, hermetically circulated and without waste produced.

The invention provides a desulfurization liquid cooperated chlorine dioxide gas-phase oxidation denitration integrated flue gas purification device and process, a desulfurization tower, an oxidation denitration tower and a secondary purification tower are communicated through a flue, and the flue gas flow direction is in an S-shaped layout. The flue gas subjected to dust removal firstly enters a desulfurizing tower and is desulfurized in an alkali liquor spraying and absorbing manner; the desulfurized flue gas is firstly mixed with ClO2 gas in an oxidation denitration tower to oxidize NO intoNO2, and then denitration is carried out in an alkali liquor spraying absorption mode; and the desulfurized and denitrified flue gas are sprayed and cleaned in the secondary purification tower again by using a desulfurizing solution, residual NOx and SO2 are absorbed in the flue gas, and demisting is performed by using wet electric precipitation to finish final purification. According to the invention, desulfurization, oxidation denitration, secondary purification and waste liquid pretreatment links which are independently arranged and organically combined are utilized to realize effective utilization of desulfurization liquid, ultra-clean treatment of flue gas, recovery of desulfurization and denitration products and reuse of process water, so that the effects of water saving and emissionreduction are achieved while the flue gas is purified.

The invention relates to a continuous triple-effect falling-film concentration and vacuum crystallization system and method in potassium nitrate production through a double-decomposition method. The continuous triple-effect falling-film concentration and vacuum crystallization system comprises a mixing tank, a concentration preheater, a backflow triple-effect concentration device, an ammonium chloride crystallizer, a thickener and a centrifuge, which are sequentially connected. The continuous triple-effect falling-film concentration and vacuum crystallization method comprises the following steps: adding potassium nitrate mother liquid and ammonium nitrate into the mixing tank for uniformly mixing, subsequently conveying to the mixture to the concentration preheater for preheating, feeding into the backflow triple-effect concentration device for concentration, feeding into the ammonium chloride crystallizer for crystallization after concentration, further sequentially feeding into the thickener and the centrifuge, separating a solid ammonium chloride product from the centrifuge, and returning the separated solution as a circulating mother liquid to a potassium nitrate production process through the double-decomposition method for circulation. Under the condition that the number of concentration equipment is not increased, the continuous triple-effect falling-film concentration and vacuum crystallization system and method in potassium nitrate production through double-decomposition method, provided by the invention, can achieve large-scale and continuous production, and the production efficiency is improved.

The invention relates to a potassium nitride preparation method, in particular to a method for preparing potassium nitride from a calcium nitride byproduct of nitro phosphate, which belongs to the technical field of production of agricultural potassium nitride fertilizers. The method includes steps of a, firstly, adding water in a dissolving tank, starting to stir and dissolve after industrial potassium chloride or potassium sulfate is poured, preparing the potassium chloride or potassium sulfate into saturated solution and pumping the saturated solution into a potassium nitride reaction tank; b, secondly, metering wet calcium nitride crystals, adding the wet calcium nitride crystals into the potassium nitride reaction tank, mixing and stirring the wet calcium nitride crystals with the solution obtained in the step a to carry out double replacement reaction, and preparing potassium nitride reaction liquid; and c, finally, crystallizing the potassium nitride reaction liquid prepared in the step b, and then separating potassium nitride crystals. The method solves problems of treatment of calcium nitride industrial byproducts of nitro phosphate, simultaneously, produces high-quality high-concentration potassium nitride fertilizers, and cannot produce waste difficult to be treated in a procedure.