585 results about "Pure oxygen" patented technology

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a method for melting and smelting ferrochrome in an all-oxygen hydrogen-rich low-carbon furnace, which comprises the following steps: (1) proportioning and uniformly mixing chromite pellets, coke and lime according to the mass ratio of 1: (0.15-0.2): (0.08-0.15), and filling the mixture into the all-oxygen hydrogen-rich low-carbon furnace; (2) high-temperature hydrogen-rich gas at the temperature of 900-1100 DEG C is introduced into the middle of the furnace body, and selective reduction of ferrochrome oxide is achieved; blowing industrial pure oxygen at the lower part of the furnace body, combusting with coke to generate CO, and driving a secondary reduction reaction; (3) maintaining a high-temperature environment in the furnace through oxygen-fuel combustion to completely melt the materials into molten iron, and carrying out central stirring on the molten iron to form a vortex with the height-diameter ratio of 0.5-1.5; and (4) discharging the molten iron after the reaction is completed. According to the method, the reduction rate of chromium in the chromite exceeds 92%, the carbon emission is reduced by 40% or above compared with a traditional blast furnace and submerged arc furnace process, meanwhile, the method has the advantages of being high in smelting efficiency, low in energy consumption, stable in product quality and the like, and a low-carbon and efficient innovative path is provided for ferrochrome smelting.

The invention discloses fluoride-salt-free and nitrate-free medium-temperature semitransparent glaze for steel plate enamel as well as a preparation method and application of the medium-temperature semitransparent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, potassium feldspar, anhydrous borax, sodium carbonate, titanium dioxide, monopotassium phosphate and zinc oxide according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 800-840 DEG C and the firing time of 20-30 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free high-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 840-880 DEG C and the firing time of 820-830 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride salt-free and nitrate-free low-temperature matte glaze for steel plate enamel as well as a preparation method and application of the low-temperature matte glaze, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, sodium carbonate, titanium dioxide, magnesium oxide, monopotassium phosphate, calcium carbonate, zinc oxide, magnesium carbonate, lithium carbonate, aluminum oxide and zirconium silicate according to a specific mass ratio. The preparation method comprises the following steps: mixing the raw materials, melting at 1300 + / -10 DEG C in a pure oxygen environment, and quenching after wiredrawing to detect a molten state. The matte glaze completely avoids the use of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are eliminated from the source, the fluorine content of the product is not detected through detection, and the limit value requirements of European Union REACH regulations are met. Zinc oxide and ZnO / TiO2 are added, so that the liquid phase viscosity is reduced, ion diffusion is accelerated, and the opacity (opacification performance) and gloss of the porcelain glaze are enhanced.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a preparation method for producing an ultra-pure oxygen-free copper rod through an up-drawing continuous casting method, and belongs to the technical field of metal material machining. Comprising the following steps: selecting a cathode copper sheet as a raw material, performing oxygen-free copper rod traction in a three-body furnace consisting of a melting furnace, a transition bin and a holding furnace by adopting an up-drawing continuous casting method, adding the dried electrolytic copper sheet and charcoal into the melting furnace, and adjusting the temperature of a melt in the melting furnace; the molten copper liquid automatically flows into a transition bin to be subjected to standing and impurity removal, and charcoal and graphite flakes are laid on the surface of the copper liquid; a graphite crystallizer is inserted into molten copper, a guide rod is connected, a guide rod is prepared, the inlet and outlet water temperature of the crystallizer is adjusted, and the traction speed and pitch of a cast rod are set. According to the method, the oxygen content of the produced ultra-pure oxygen-free copper rod can be reduced to 3 ppm or below by controlling the quality of the cathode copper sheet of the copper rod, the temperature of the copper liquid, the solidification supercooling degree of the copper rod, the rod casting speed, the conditions of the crystallizer and combined control over charcoal and graphite flake reduction, and the application additional value of the oxygen-free copper rod is greatly improved.

The invention provides a membrane separation oxygen production device capable of simultaneously producing medical oxygen and oxygen-enriched air, the device comprises a common oxygen production main machine, a membrane separation purification system and a pure oxygen production main machine, when the common oxygen production main machine needs to be purged, oxygen-enriched nitrogen, high-concentration oxygen-enriched air and waste gas can be utilized to purge an adsorption tower. The system has the advantages that the oxygen concentration can be automatically switched according to the requirements of a hospital, and medical oxygen and oxygen-enriched air are provided for the hospital at the same time or are independently provided for any one of the medical oxygen and the oxygen-enriched air; the membrane separation oxygen production technology is adopted, high-concentration waste gas generated during membrane separation medical oxygen production is used in the production process of oxygen-enriched air, the air-oxygen ratio is optimized, and the gas consumption is lower compared with a medical oxygen production system on the market; the waste gas exhausted from the direct current side in the medical oxygen generation process is rich in oxygen which is still contained in gas mainly containing argon and nitrogen and still contains high-concentration oxygen, the oxygen is used for producing oxygen-enriched air, the production efficiency is improved, the air amount needed by a product is reduced, and the effect of reducing energy consumption is achieved.

The invention discloses fluoride-salt-free and nitrate-free low-temperature pearlescent glaze for steel plate enamel as well as a preparation method and application of the pearlescent glaze, and belongs to the technical field of enamel. The pearlescent glaze is prepared from quartz, anhydrous borax, titanium dioxide, magnesium carbonate, sodium tripolyphosphate, potassium carbonate, lithium carbonate, potassium feldspar, zinc oxide and V-26 according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The pearlescent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the pearlescent glaze has good porcelain surface, luster and low-temperature firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 760-800 DEG C and the firing time of 10-20 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free low-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for steel plate substrates, the firing temperature is 760-800 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention belongs to the field of new energy, and particularly relates to a water-cooled grate biomass gasifier and a biomass gasification method. The water-cooled grate biomass gasification furnace comprises a gasification furnace body of a downdraft structure, the gasification furnace body is internally provided with a feeding system, the feeding system comprises a feeding chute, a feeding sealing door and a feeding sealing door, the feeding chute is provided with an anaerobic system pipeline, and a feeding grate is located below the feeding sealing door; the water-cooling fire grate assembly is composed of multi-stage welding type water-cooling fire grate segments, and a cooling water cavity is formed in the water-cooling fire grate assembly. The hearth is divided into a drying layer, a pyrolysis layer, a reduction layer and an oxidation layer in the material moving direction. The gasifying agent supply system comprises a primary air duct, a secondary air duct, a steam injection pipeline I and a water vapor injection pipeline II, wherein pure oxygen is introduced into the primary air duct; the cooling circulation system comprises a circulation pipeline, a circulation water pump and a radiator, wherein the circulation water pump and the radiator are installed on the circulation pipeline. The circulation pipeline is communicated with the water-cooling fire grate assembly to form a closed circulation loop. The device is high in reliability, long in service life, low in emission, easy to control and good in gasification effect.

The invention discloses a preparation method of a metal oxide coated high-nickel ternary positive electrode material, which comprises the following steps of: dissolving a solution containing coated metal in an organic solvent under a stirring condition to obtain a solution containing metal oxide; adding the high-nickel ternary material powder into an organic solvent under ultrasonic operation to obtain a solution of the high-nickel ternary positive electrode material powder; dropwise adding the solution containing the metal oxide into the solution of the high-nickel ternary positive electrode material powder under ultrasonic operation to obtain a mixed solution; heating the mixed solution under a magnetic stirring condition to volatilize the solvent, collecting the material, and drying in a vacuum drying oven; and calcining the dried material in pure oxygen to obtain the metal oxide coated high-nickel ternary positive electrode material. The electrochemical performance of the high-nickel ternary positive electrode material at low temperature can be effectively improved, specifically, the surface of the positive electrode is regulated and controlled, the contact area of the surface of the ternary positive electrode material and electrolyte at low temperature is reduced, so that side reaction is reduced, and meanwhile, the coating layer with certain mechanical strength can be formed in the long-term cycle process at low temperature, so that the electrochemical performance of the high-nickel ternary positive electrode material is improved. Positive electrode breakage is effectively reduced, and the cycling stability of the high-nickel ternary positive electrode at low temperature is effectively improved.

The invention provides a method for optimizing an integrated coal gasification combined cycle process by utilizing solar energy. The method comprises the following steps: generating hydrogen and oxygen through photovoltaic electrolysis of water; the dead steam / oxygen mixed gas is heated through fused salt generated through photo-thermal; the coal gasifier is heated through fused salt generated through photo-thermal; carrying out pre-combustion carbon capture on the cooled synthesis gas through an MOF material with a photoinduced structural transformation property; the synthesis gas subjected to carbon capture in the combustion chamber and the other part of oxygen are subjected to pure oxygen combustion; and cooling the flue gas for carbon capture after combustion. According to the method, the operation load fluctuation, the energy consumption and the carbon capture cost of the coal gasification combined cycle process are reduced, and the overall economy is improved.

A process and a plant for the production of hydrogen or for the synthesis of ammonia, said process comprising the following steps: (a) performing a reforming process (101) of a hydrocarbon feedstock (1) to generate a raw syngas (2), said reforming process comprising at least an autothermal reforming step (104) in presence of oxygen-enriched air or pure oxygen (3) produced by an air separation unit (ASU; 103); (b) subjecting said raw syngas (2) to a post-treatment (102) providing hydrogen (H2; 4), a CO2-enriched stream (5), and a residual gas (6); said post-treatment comprising at least a water gas shift conversion step (105) of said raw syngas into a shifted syngas (7), a pressure swing absorption step (106), and a cryogenic separation step (107); wherein said pressure swing absorption step produces said hydrogen and a first tail gas (8) comprising carbon monoxide (CO), carbon dioxide (CO2), residual hydrogen (H2) and unreacted hydrocarbon feedstock from the shifted syngas (7), and said cryogenic separation step separates the CO2-enriched stream and a second tail gas (9) from said first tail gas; said post-treatment (102) comprising a further separation step (120) of a CO2-containing stream (11) and of the residual gas (6) from said second tail gas; (c) recycling said residual gas (6) as feed to said reforming process and / or as fuel to one or more fired heater(s) (10) of said process; (d) optionally feeding a portion (4.8) of said hydrogen (4) obtained in step (b) as fuel to one or more fired heater(s) of said process; (e) optionally an ammonia synthesis step (110) wherein said hydrogen (4) and a nitrogen (N2)-containing stream (12) produced by said ASU (103) are reacted in a given stoichiometric ratio and in ammonia (NH3) synthesis conditions to obtain an ammonia-containing product (13).

The invention relates to a preparation method of a lead selenide room-temperature medium-wave infrared detector, which comprises the following steps of: (1) depositing a lead selenide film layer on a substrate by adopting a magnetron sputtering technology and taking oxygen as reaction gas; (2) placing the lead selenide film in a horizontal tube furnace, and realizing high-temperature oxidation in normal-pressure pure oxygen; and (3) putting the lead selenide film into a vertical tube furnace, and realizing high-temperature iodination in a normal-pressure environment. The lead selenide thin film is prepared through the magnetron sputtering technology, compared with chemical bath deposition, the quality of the thin film is effectively improved, and large-area and high-uniformity thin film preparation is achieved; the magnetron sputtering film is subjected to high-temperature oxidation-iodination treatment, the magnetron sputtering film has excellent photoresponse to infrared light, and the sensitization technology is specific and clear and good in repeatability; the sensitized lead selenide thin film layer and the top electrode form the photoconductive detector, the specific detection rate of the device is 7.6 * 10 < 9 > Jones at 4.3 microns at the room temperature of a medium-wave infrared band, and the performance is excellent.

The invention relates to a combustion optimization and cryogenic separation-based carbon dioxide enrichment and hydrogen production synergy process for a combined device, which is characterized in that regeneration of a spent catalyst in a catalytic cracking device is changed into pure oxygen incomplete combustion, and circulating carbon dioxide is used for stabilizing fluidization and controlling tail combustion. And after the regenerated flue gas is subjected to deep purification and cryogenic separation, the part rich in carbon monoxide is fed into a medium-temperature change reactor of the steam hydrocarbon reforming device for hydrogen production, so that resource upgrading of catalytic coke is realized. And compressing and cooling the part rich in carbon dioxide to obtain about 98% of liquid phase product for subsequent application. According to the catalytic cracking device, only the regenerator needs to be adjusted, the deep purification and compression cryogenic separation unit is additionally arranged, the hydrogen production device can improve the treatment capacity of the medium-temperature change reactor, implementation is convenient, and the catalytic cracking device is suitable for new and old devices. The invention further relates to a system for carbon dioxide enrichment and hydrogen production synergy of the integrated device based on combustion optimization and cryogenic separation.

The utility model relates to a raw gas source upgrading system for an internal heating type vertical furnace. The raw gas source upgrading system comprises a dry distillation furnace, a carbon dioxide removal device and a pure oxygen preparation device, the device further comprises a first multi-stage mixer, a second multi-stage mixer, a gas sampling analysis tube and a gas component detector. Pure oxygen is adopted as a combustion improver, so that the content of nitrogen in the raw gas is greatly reduced, and the application scene of coal gasification production and deep processing of the internal heating type vertical furnace is expanded; the components of combustion-supporting gas, combustible gas and inert gas in mixed gas in a lattice wall of the dry distillation furnace are controlled by adopting double-circulation control of carbon dioxide and recirculated gas, the combustion intensity and the uniformity degree are strictly controlled under the condition that dry distillation heat supply is met, and scabbing and burning loss of a dry distillation furnace body are avoided.

The invention relates to the technical field of hydrogen production through water electrolysis, and provides an electrolytic hydrogen production system capable of reducing the lower limit of production load and a control method, the system comprises an electrolytic bath, a hydrogen separator, an oxygen separator and a pure oxygen module; a hydrogen side outlet is formed in the cathode side of the electrolytic bath, and the hydrogen separator is connected with the hydrogen side outlet; an oxygen side outlet is formed in the anode side of the electrolytic bath, and the oxygen separator is connected with the oxygen side outlet; the pure oxygen module is suitable for outputting high-purity oxygen into the oxygen separator, the high-purity oxygen is used for being mixed with initial oxygen at the oxygen side outlet, and under the condition that the hydrogen content in the initial oxygen does not meet the set condition, the hydrogen content in mixed oxygen at the outlet of the oxygen separator meets the set condition. Through the arrangement, the upper limit of the hydrogen content in the initial oxygen at the oxygen side outlet can be greatly improved, so that the lower limit of the production load of the electrolytic hydrogen production system is reduced, and the electrolytic hydrogen production system can fully adapt to wide rapid fluctuation of renewable energy treatment.

The invention discloses a continuous preparation and supply method of green hydrogen, and relates to the technical field of green hydrogen production. Comprising the following steps: (1) generating power by utilizing solar energy, wind energy or tidal energy, introducing the obtained electric energy into an electrolysis center through a line, electrolyzing water by the electrolysis center to produce green oxygen and green hydrogen, and enabling the green oxygen to enter a straw pure-oxygen gasification furnace for gasification reaction to obtain raw material gas; and (2) mixing the raw material gas obtained in the step (1) with green oxygen generated by an electrolysis center, and carrying out pure oxygen combustion in a gas-fired boiler to generate steam and high-purity CO2. According to the method disclosed by the invention, green hydrogen, CO and CO2 can be continuously and stably produced by adopting a straw gasification mode, and particularly, the green hydrogen effectively supplements the unstable green hydrogen production process of wind energy and solar energy, so that the organic combination and supplementation of renewable energy and straw energy are realized. The green hydrogen produced by the method can be used for synthesizing chemicals such as ammonia, methanol, methane and the like.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.

The application discloses a device and method for preparing green hydrogen through biomass pyrolysis and gasification, relates to the technical field of green hydrogen preparation, and solves the problems of blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process, and the problem of low energy utilization rate. The device for preparing green hydrogen through biomass pyrolysis and gasification comprises a pyrolysis reaction device, and the pyrolysis reaction device comprises a pyrolysis reaction tank connected with a high-temperature heat carrier conveying spiral, a biomass raw material storage bin, a biomass raw material conveying spiral and a pyrolysis solid-phase product conveying spiral. In the application, biomass raw materials are converted into biochar and pyrolysis oil gas through pyrolysis technology, the biomass ash is effectively cut, and problems such as blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process are effectively avoided; the high-temperature pyrolysis oil gas is directly subjected to pure oxygen gasification reaction through gasification technology, the sensible heat and latent heat in the pyrolysis oil gas are fully utilized, and the energy utilization rate is high.

The invention discloses a low-nitrogen gas burner suitable for various working conditions and a using method of the low-nitrogen gas burner. The low-nitrogen gas burner comprises an assembly cylinder, an outer-layer fire pan, a central fire pan, an inner-layer gas gun, an outer-layer gas gun and an oxygen gun. The height of the center fire pan is adjusted through the lifting assembly, and switching of three modes of air combustion supporting, oxygen-enriched combustion supporting and pure oxygen combustion supporting is achieved. The air adjusting assembly controls the combustion-supporting air flow; the flow comprehensive adjusting assembly adjusts fuel gas supply and oxygen supply in a linkage mode. The combustor adopts a staged combustion design, the inner-layer gas gun forms first-stage flame at a fire pan gap, the outer-layer gas gun and a combustion-supporting medium ejected from the central fire pan form second-stage combustion, and the temperature of the flame is reduced by ejecting hearth smoke. Cooperative control over all the executing mechanisms is achieved through the driving motor and the speed setting assembly, the beneficial effects that combustion modes are automatically switched, the flame temperature is accurately regulated and controlled, and emission of oxynitride is low are achieved, and the clean combustion requirements of different industrial furnaces can be met.

The invention relates to the technical field of chemical raw material preparation, and discloses a process and equipment for preparing liquid sulfur dioxide through pure oxygen incineration, the system deeply couples dynamic optimization of three high-energy-consumption links of waste heat recovery, combustion reaction and deep freezing through hardware collaboration and algorithm innovation, and compared with a traditional process, the comprehensive energy consumption of unit products is reduced by 35%, and the production cost is reduced. Meanwhile, the three technical problems of liquid sulfur solidification, furnace temperature out-of-control and non-condensable gas accumulation are solved.

The present invention discloses a proton exchange membrane fuel cell power generation system with a pressure swing adsorption oxygen generation device, further comprising a fuel cell system, an exhaust gas recycling system and a valve control system; the pressure swing adsorption oxygen generation device and the fuel cell system share a set of muffler, filter, air compressor and intake air flowmeter. In this system, while generating electricity, the pressure swing adsorption oxygen generation device can continuously produce pure oxygen with a purity of more than 90%. When the pure oxygen is used as the cathode working medium of the fuel cell, the power density of the fuel cell can be significantly increased. This system can realize the switching between the air-hydrogen and oxygen-hydrogen modes to meet the changes in working conditions. The exhaust gas recycling system of this system recovers the chemical energy of unreacted hydrogen for the anode exhaust gas of the fuel cell; for the cathode exhaust gas, waste heat recovery, water recovery and oxygen recovery and utilization are carried out respectively. In addition, this system also collects part of the waste gas of the pressure swing adsorption device, which is mainly nitrogen, for purging the fuel cell.

The utility model relates to the technical field of metal smelting efficient combustion equipment, in particular to a pure oxygen combustor which comprises a three-way distribution valve and further comprises an upper fixing plate, a mounting block and a lower fixing plate, the mounting block is arranged at the bottom of the upper fixing plate, and the lower fixing plate is embedded in the mounting block and is parallel to the upper fixing plate; the top of the upper fixing plate is fixedly provided with a natural gas cover, the top of the natural gas cover is communicated with a natural gas pipeline, the bottom of the upper fixing plate is provided with a plurality of natural gas branch pipes communicated with the natural gas cover, and the lower parts of the natural gas branch pipes are fixedly connected with the lower fixing plate; a pure oxygen pipeline is fixedly arranged on the upper fixed plate, and the lower part of the pure oxygen pipeline is fixedly connected with the fixed plate; an ignition gun pipeline, a flame detection pipeline and a flame detection standby pipeline are further fixedly arranged on the upper fixing plate. According to the utility model, the fuel entering the smelting furnace can be effectively combusted uniformly and fully, and meanwhile, the heating is more uniform.

The utility model discloses a system for increasing dissolved oxygen in a water body. The system comprises an air separation oxygen generator, a liquid oxygen storage tank, a gas distributor and an aeration device. The air separation oxygen generator is used for preparing liquid oxygen, the liquid oxygen storage tank is used for storing the liquid oxygen, and the aeration device is used for dissolving pure oxygen in a water body through aeration to increase the dissolved oxygen in the water body so as to restore the dissolved oxygen in the anoxic water body to the normal concentration, and is used for increasing the dissolved oxygen in the anoxic river, lake and reservoir water bodies so as to restore the normal dissolved oxygen concentration.

The invention relates to ultra-pure oxygen-free copper and a preparation method thereof.The preparation method comprises the steps that firstly, cathode copper is added into a graphite crucible of an electric vacuum high-temperature purification furnace to be melted into molten copper; secondly, after the molten copper is subjected to standing and heat preservation, a heating cover of the electric vacuum high-temperature purification furnace is slowly lifted upwards, and the molten copper in the graphite crucible is slowly solidified from the bottom till the molten copper is completely solidified; and then, the solidified cast ingot is taken out, the two ends of the cast ingot are cut off, the remaining cast ingot obtained after cutting is conducted repeatedly according to the first two steps, and the ultra-pure oxygen-free copper cast ingot is obtained after circulation is conducted for 3-5 times. The purity of the prepared ultra-pure oxygen-free copper is 5N-6N, the oxygen content is less than 2ppm, and the hydrogen content is less than 1ppm. The method is simple and reliable to operate, cast ingots with different copper contents can be prepared according to different application directions, and meanwhile, the oxygen content is also controlled at an extremely low level due to the fact that the cast ingots are extremely low in gas content and good in compactness.

The invention provides a method for reducing the interface state density of a SiC-MOS device and an MOS capacitor. The method comprises the following steps: providing a silicon carbide substrate; forming a silicon dioxide oxide layer on the silicon carbide substrate; pure oxygen annealing is carried out by adopting a rapid annealing process; pure nitrogen annealing is carried out by adopting a rapid annealing process; forming a gate electrode on the silicon dioxide oxide layer; and forming a substrate electrode at the bottom of the silicon carbide substrate to obtain the SiC-MOS capacitor. According to the invention, the two-step annealing process of low-pressure pure oxygen annealing and pure nitrogen annealing is carried out on the silicon dioxide (SiO2) / silicon carbide (SiC) interface, so that the device has relatively low interface state density and relatively high flat-band voltage stability.

The invention discloses three-layer porous graphene and a preparation method thereof, and belongs to the field of nano materials. The preparation method of the three-layer porous graphene comprises the following steps: growing graphene on a copper substrate by adopting a chemical vapor deposition method to obtain the three-layer porous graphene, wherein hydrogen, shielding gas, methane and oxygen-containing gas or pure oxygen are introduced in the chemical vapor deposition process; the growth temperature of the chemical vapor deposition enables the copper substrate to be molten into a liquid state. Compared with the traditional method, the method provided by the invention does not need complex manpower and material resources, does not need special treatment on the substrate, and provides a method capable of realizing more efficient growth of the three-layer porous single crystal graphene.

The utility model relates to the technical field of converter steelmaking, and discloses an oxygen lance nozzle for a 120-ton vanadium extraction converter and the vanadium extraction converter. The oxygen lance nozzle comprises a lance body, wherein a cavity is formed in the lance body; the spraying hole is in a Venturi tube shape, is formed in the front portion of the gun body and is used for spraying oxygen, and the narrow portion in the middle of the spraying hole is a throat portion. The oxygen lance nozzle increases the oxygen flow, so that the pure oxygen blowing time is shortened under the same oxygen pressure, the smelting time of a vanadium extraction converter is shortened, and the production efficiency of the vanadium extraction converter is improved.