439 results about "Pure oxygen" patented technology

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a method for melting and smelting ferrochrome in an all-oxygen hydrogen-rich low-carbon furnace, which comprises the following steps: (1) proportioning and uniformly mixing chromite pellets, coke and lime according to the mass ratio of 1: (0.15-0.2): (0.08-0.15), and filling the mixture into the all-oxygen hydrogen-rich low-carbon furnace; (2) high-temperature hydrogen-rich gas at the temperature of 900-1100 DEG C is introduced into the middle of the furnace body, and selective reduction of ferrochrome oxide is achieved; blowing industrial pure oxygen at the lower part of the furnace body, combusting with coke to generate CO, and driving a secondary reduction reaction; (3) maintaining a high-temperature environment in the furnace through oxygen-fuel combustion to completely melt the materials into molten iron, and carrying out central stirring on the molten iron to form a vortex with the height-diameter ratio of 0.5-1.5; and (4) discharging the molten iron after the reaction is completed. According to the method, the reduction rate of chromium in the chromite exceeds 92%, the carbon emission is reduced by 40% or above compared with a traditional blast furnace and submerged arc furnace process, meanwhile, the method has the advantages of being high in smelting efficiency, low in energy consumption, stable in product quality and the like, and a low-carbon and efficient innovative path is provided for ferrochrome smelting.

The invention discloses fluoride-salt-free and nitrate-free medium-temperature semitransparent glaze for steel plate enamel as well as a preparation method and application of the medium-temperature semitransparent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, potassium feldspar, anhydrous borax, sodium carbonate, titanium dioxide, monopotassium phosphate and zinc oxide according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 800-840 DEG C and the firing time of 20-30 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free high-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 840-880 DEG C and the firing time of 820-830 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride salt-free and nitrate-free low-temperature matte glaze for steel plate enamel as well as a preparation method and application of the low-temperature matte glaze, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, sodium carbonate, titanium dioxide, magnesium oxide, monopotassium phosphate, calcium carbonate, zinc oxide, magnesium carbonate, lithium carbonate, aluminum oxide and zirconium silicate according to a specific mass ratio. The preparation method comprises the following steps: mixing the raw materials, melting at 1300 + / -10 DEG C in a pure oxygen environment, and quenching after wiredrawing to detect a molten state. The matte glaze completely avoids the use of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are eliminated from the source, the fluorine content of the product is not detected through detection, and the limit value requirements of European Union REACH regulations are met. Zinc oxide and ZnO / TiO2 are added, so that the liquid phase viscosity is reduced, ion diffusion is accelerated, and the opacity (opacification performance) and gloss of the porcelain glaze are enhanced.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free low-temperature pearlescent glaze for steel plate enamel as well as a preparation method and application of the pearlescent glaze, and belongs to the technical field of enamel. The pearlescent glaze is prepared from quartz, anhydrous borax, titanium dioxide, magnesium carbonate, sodium tripolyphosphate, potassium carbonate, lithium carbonate, potassium feldspar, zinc oxide and V-26 according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The pearlescent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the pearlescent glaze has good porcelain surface, luster and low-temperature firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 760-800 DEG C and the firing time of 10-20 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free low-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for steel plate substrates, the firing temperature is 760-800 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

A process and a plant for the production of hydrogen or for the synthesis of ammonia, said process comprising the following steps: (a) performing a reforming process (101) of a hydrocarbon feedstock (1) to generate a raw syngas (2), said reforming process comprising at least an autothermal reforming step (104) in presence of oxygen-enriched air or pure oxygen (3) produced by an air separation unit (ASU; 103); (b) subjecting said raw syngas (2) to a post-treatment (102) providing hydrogen (H2; 4), a CO2-enriched stream (5), and a residual gas (6); said post-treatment comprising at least a water gas shift conversion step (105) of said raw syngas into a shifted syngas (7), a pressure swing absorption step (106), and a cryogenic separation step (107); wherein said pressure swing absorption step produces said hydrogen and a first tail gas (8) comprising carbon monoxide (CO), carbon dioxide (CO2), residual hydrogen (H2) and unreacted hydrocarbon feedstock from the shifted syngas (7), and said cryogenic separation step separates the CO2-enriched stream and a second tail gas (9) from said first tail gas; said post-treatment (102) comprising a further separation step (120) of a CO2-containing stream (11) and of the residual gas (6) from said second tail gas; (c) recycling said residual gas (6) as feed to said reforming process and / or as fuel to one or more fired heater(s) (10) of said process; (d) optionally feeding a portion (4.8) of said hydrogen (4) obtained in step (b) as fuel to one or more fired heater(s) of said process; (e) optionally an ammonia synthesis step (110) wherein said hydrogen (4) and a nitrogen (N2)-containing stream (12) produced by said ASU (103) are reacted in a given stoichiometric ratio and in ammonia (NH3) synthesis conditions to obtain an ammonia-containing product (13).

The invention relates to a preparation method of a lead selenide room-temperature medium-wave infrared detector, which comprises the following steps of: (1) depositing a lead selenide film layer on a substrate by adopting a magnetron sputtering technology and taking oxygen as reaction gas; (2) placing the lead selenide film in a horizontal tube furnace, and realizing high-temperature oxidation in normal-pressure pure oxygen; and (3) putting the lead selenide film into a vertical tube furnace, and realizing high-temperature iodination in a normal-pressure environment. The lead selenide thin film is prepared through the magnetron sputtering technology, compared with chemical bath deposition, the quality of the thin film is effectively improved, and large-area and high-uniformity thin film preparation is achieved; the magnetron sputtering film is subjected to high-temperature oxidation-iodination treatment, the magnetron sputtering film has excellent photoresponse to infrared light, and the sensitization technology is specific and clear and good in repeatability; the sensitized lead selenide thin film layer and the top electrode form the photoconductive detector, the specific detection rate of the device is 7.6 * 10 < 9 > Jones at 4.3 microns at the room temperature of a medium-wave infrared band, and the performance is excellent.

The utility model relates to a raw gas source upgrading system for an internal heating type vertical furnace. The raw gas source upgrading system comprises a dry distillation furnace, a carbon dioxide removal device and a pure oxygen preparation device, the device further comprises a first multi-stage mixer, a second multi-stage mixer, a gas sampling analysis tube and a gas component detector. Pure oxygen is adopted as a combustion improver, so that the content of nitrogen in the raw gas is greatly reduced, and the application scene of coal gasification production and deep processing of the internal heating type vertical furnace is expanded; the components of combustion-supporting gas, combustible gas and inert gas in mixed gas in a lattice wall of the dry distillation furnace are controlled by adopting double-circulation control of carbon dioxide and recirculated gas, the combustion intensity and the uniformity degree are strictly controlled under the condition that dry distillation heat supply is met, and scabbing and burning loss of a dry distillation furnace body are avoided.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.

The application discloses a device and method for preparing green hydrogen through biomass pyrolysis and gasification, relates to the technical field of green hydrogen preparation, and solves the problems of blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process, and the problem of low energy utilization rate. The device for preparing green hydrogen through biomass pyrolysis and gasification comprises a pyrolysis reaction device, and the pyrolysis reaction device comprises a pyrolysis reaction tank connected with a high-temperature heat carrier conveying spiral, a biomass raw material storage bin, a biomass raw material conveying spiral and a pyrolysis solid-phase product conveying spiral. In the application, biomass raw materials are converted into biochar and pyrolysis oil gas through pyrolysis technology, the biomass ash is effectively cut, and problems such as blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process are effectively avoided; the high-temperature pyrolysis oil gas is directly subjected to pure oxygen gasification reaction through gasification technology, the sensible heat and latent heat in the pyrolysis oil gas are fully utilized, and the energy utilization rate is high.

The invention discloses a low-nitrogen gas burner suitable for various working conditions and a using method of the low-nitrogen gas burner. The low-nitrogen gas burner comprises an assembly cylinder, an outer-layer fire pan, a central fire pan, an inner-layer gas gun, an outer-layer gas gun and an oxygen gun. The height of the center fire pan is adjusted through the lifting assembly, and switching of three modes of air combustion supporting, oxygen-enriched combustion supporting and pure oxygen combustion supporting is achieved. The air adjusting assembly controls the combustion-supporting air flow; the flow comprehensive adjusting assembly adjusts fuel gas supply and oxygen supply in a linkage mode. The combustor adopts a staged combustion design, the inner-layer gas gun forms first-stage flame at a fire pan gap, the outer-layer gas gun and a combustion-supporting medium ejected from the central fire pan form second-stage combustion, and the temperature of the flame is reduced by ejecting hearth smoke. Cooperative control over all the executing mechanisms is achieved through the driving motor and the speed setting assembly, the beneficial effects that combustion modes are automatically switched, the flame temperature is accurately regulated and controlled, and emission of oxynitride is low are achieved, and the clean combustion requirements of different industrial furnaces can be met.

The invention relates to the technical field of chemical raw material preparation, and discloses a process and equipment for preparing liquid sulfur dioxide through pure oxygen incineration, the system deeply couples dynamic optimization of three high-energy-consumption links of waste heat recovery, combustion reaction and deep freezing through hardware collaboration and algorithm innovation, and compared with a traditional process, the comprehensive energy consumption of unit products is reduced by 35%, and the production cost is reduced. Meanwhile, the three technical problems of liquid sulfur solidification, furnace temperature out-of-control and non-condensable gas accumulation are solved.

The invention discloses three-layer porous graphene and a preparation method thereof, and belongs to the field of nano materials. The preparation method of the three-layer porous graphene comprises the following steps: growing graphene on a copper substrate by adopting a chemical vapor deposition method to obtain the three-layer porous graphene, wherein hydrogen, shielding gas, methane and oxygen-containing gas or pure oxygen are introduced in the chemical vapor deposition process; the growth temperature of the chemical vapor deposition enables the copper substrate to be molten into a liquid state. Compared with the traditional method, the method provided by the invention does not need complex manpower and material resources, does not need special treatment on the substrate, and provides a method capable of realizing more efficient growth of the three-layer porous single crystal graphene.

The utility model relates to the technical field of converter steelmaking, and discloses an oxygen lance nozzle for a 120-ton vanadium extraction converter and the vanadium extraction converter. The oxygen lance nozzle comprises a lance body, wherein a cavity is formed in the lance body; the spraying hole is in a Venturi tube shape, is formed in the front portion of the gun body and is used for spraying oxygen, and the narrow portion in the middle of the spraying hole is a throat portion. The oxygen lance nozzle increases the oxygen flow, so that the pure oxygen blowing time is shortened under the same oxygen pressure, the smelting time of a vanadium extraction converter is shortened, and the production efficiency of the vanadium extraction converter is improved.

According to the oxygen-enriched combustion system of the circulating fluidized bed boiler and the operation method, under the oxygen-enriched combustion working condition, part of low-temperature and clean flue gas at the tail is led back, mixed with pure oxygen and then fed into a hearth, the total in-furnace gas flow after mixing is kept equivalent to the original total in-furnace air flow, and the total in-furnace gas flow after mixing is kept equivalent to the original total in-furnace air flow; when the mixed gas entering the furnace keeps the oxygen volume concentration equivalent to or slightly higher than that of air, the problems of fluidization, combustion and heat transfer in a hearth can be completely solved, and safe, reliable, economical and environment-friendly operation of a unit can be guaranteed; after air is completely replaced by the mixed gas, the CO2 concentration in the generated flue gas is greatly improved and can reach 80% or above at most, and CO2 can be captured with low cost and high efficiency; according to the invention, free switching between air combustion and oxygen-enriched combustion can be realized.

Pure liquid nitrogen, liquid air or dirty liquid nitrogen generated by a rectifying tower of the air separation device is subjected to secondary pressurization through a hydraulic pump and then enters a main heat exchanger or a recooling device to recover cold energy, and high-pressure gas formed by heat absorption and gasification enters a high-pressure expansion machine to expand and do work; exhaust gas of the high-pressure expansion machine enters the rectifying tower to provide cold energy required by air separation, and pure nitrogen, waste nitrogen and pure oxygen which are discharged from the rectifying tower and are subjected to cold energy recovery through the main heat exchanger are output. The purposes of energy conservation and consumption reduction of the air separation device are achieved through the processes of primary pressurization of the compressor, secondary pressurization of the hydraulic pump, cold returning, gasification and expansion.

The invention relates to a pure oxygen pulverized coal burner which comprises a pulverized coal bin, a pulverized coal conveying cylinder, an oxygen header pipe, oxygen spray pipes and burner blocks. The oxygen spray pipe and the pulverized coal conveying cylinder extend into the burner block; a pulse valve is arranged on the oxygen spraying pipe, an accumulation groove and a pulverized coal striking head are arranged at the tail end of the pulverized coal conveying barrel, pulverized coal falls into the accumulation groove through conveying of the pulverized coal conveying barrel, and the pulverized coal striking head is connected with a striking head driving motor through a striking head transmission shaft to rotate at a high speed to strike the pulverized coal falling into the accumulation groove. Compared with the prior art, the pulse jet oxygen is supplied after the pulverized coal is scattered and scattered, so that the torch time is effectively shortened, and the thermal radiation of a continuous combustion torch to a nozzle is eliminated to a great extent. The supply of the pulverized coal and the supply of the oxygen can be flexibly controlled through the opening and closing interval time of the valve, and the power of the combustor can be conveniently adjusted according to the required furnace temperature and heat supply amount, so that the oxygen and the pulverized coal can be fully and uniformly mixed regardless of the power, and the optimal air-fuel ratio is achieved.

The utility model provides a combined heat and power supply air supply system of a fuel cell, which utilizes a byproduct high-pressure pure oxygen generated by hydrogen production through water electrolysis as a working fluid, realizes air humidification and cyclic utilization of electric pile waste gas through combination of an injection device and an air compressor branch, reduces the use of a humidifier and an intercooler, and reduces the complexity and air flow resistance of the system. The system comprises an air inlet main path, an oxygen inlet branch path, an air inlet branch path and an injection device, waste oxygen is introduced into the oxygen inlet branch path, the air inlet branch path is provided with an air compressor, and the injection device mixes the waste oxygen and fresh air and supplies the mixed waste oxygen and fresh air into a galvanic pile. The air outlet pipeline is connected with the water segregator, waste gas is recycled to humidify fresh air, and a backflow adjusting valve is arranged. The system reduces the power consumption of the air compressor and improves the cogeneration efficiency of the fuel cell.

The utility model discloses a submerged pure oxygen oxygenation water pushing device, which relates to the technical field of oxygenation devices, and comprises a device body, a water inlet, a water outlet and a water outlet, an atomizing assembly is fixedly mounted on one side of the water-oxygen mixing cavity, and a water pushing assembly is fixedly mounted on the other side of the water-oxygen mixing cavity; the atomization assembly is communicated with the water inlet; the air vent is communicated with the water-oxygen mixing cavity; the water-oxygen mixing cavity is used for mixing water and oxygen introduced from the air vent to obtain oxygen-dissolved water; the atomizing assembly comprises an atomizing pipeline and a plurality of atomizing nozzles, and the atomizing nozzles are used for atomizing water; the air vent can exhaust air and is connected with an air supply device; and the water inlet can be connected with a water supply device. The oxygen dissolving device is mainly used for avoiding waste of oxygen in the oxygen dissolving process and improving the oxygen dissolving efficiency and the oxygen content of a water body.

The invention relates to the technical field of glass melting furnaces, in particular to a glass melting furnace which comprises a melting part melting pool. The melting part molten pool comprises a plurality of pure oxygen combustion areas and a plurality of air combustion areas; the pure oxygen combustion area and the air combustion area are sequentially and circularly arranged in the melting part molten pool; the pure oxygen combustion area is connected with a pure oxygen combustion gun; the air combustion area is connected with a small furnace; the small furnace is connected with a heat storage chamber; according to the invention, a pure oxygen combustion and air combustion combined distribution structure is adopted, the advantages of high melting temperature and high heat radiation efficiency of pure oxygen combustion are fully played, and a forced melting effect is achieved in a specific area; meanwhile, flue gas generated by pure oxygen combustion and flue gas in an adjacent air combustion area are mixed and are quickly discharged together through a heat storage chamber of the air combustion area, the water content in the kiln cannot be greatly increased, and excessive foam cannot be generated; the higher smoke temperature of the pure oxygen combustion area can improve the heat storage temperature of the air heat storage chamber, and the heat storage efficiency is further improved.

The invention relates to an MOFs-COFs composite material based on covalent bond combination, a preparation method of the MOFs-COFs composite material and application of the MOFs-COFs composite material in the field of photocatalytic hydrogen peroxide production, and belongs to the field of green chemical engineering. The invention aims to provide a method for efficiently producing hydrogen peroxide by photocatalysis based on a covalent bond combination MOFs (at) COFs composite material, and provides an application of the composite material in preparation of hydrogen peroxide. According to the novel method for preparing hydrogen peroxide through photocatalysis, a sacrificial agent and a cocatalyst are not used, so that the method is green, environment-friendly and pollution-free; high yield can be obtained without a pure oxygen environment and an air environment, visible light is used as an energy source, energy consumption is low, safety is high, operation is easy and convenient, reaction conditions are mild, the reaction mechanism is novel, and the yield of hydrogen peroxide in unit time is higher than that of similar prototype materials.

The application discloses a method for improving critical current of REBCO superconducting layer and relates to the technical field of superconducting materials.The method for improving critical current of REBCO superconducting layer comprises the following steps: REBCO superconducting tapes are annealed in a pure oxygen atmosphere, quenched to 20-25 DEG C, and then the surface silver layer is removed by a chemical method, after which the REBCO superconducting tapes are annealed in a mixed atmosphere of ozone and oxygen, and a protective layer is deposited, so that the critical current of the REBCO superconducting layer is finally improved.The carrier concentration of the REBCO superconducting tapes can be effectively controlled through the specific multi-step oxidation process, so that the REBCO superconducting tapes break through the under-doped state commonly existing in the prior art, reach the over-doped level, and then the critical current performance of the tapes is significantly improved.The method has simple process, high stability and high industrial feasibility, and can meet the demand of higher current-carrying capacity of REBCO tapes in key fields such as power transmission and high-field magnets.

The utility model discloses a full water jacket pure oxygen continuous gasification furnace, which relates to the technical field of gasification furnaces and comprises a gasification furnace main body, the top of the gasification furnace main body is provided with an automatic stoker, a hydraulic coke detector, a radar coke detector and a gas outlet pipe, and the side end face of the gasification furnace main body is provided with an upper water jacket and a lower water jacket. A fire grate is arranged at the bottom of the inner end face of the gasification furnace body, a central air bellow, an ash discharging assembly and a fire bar machine assembly are arranged at the bottom of the gasification furnace body, a feeding hopper is arranged at the top of the automatic stoker, a discharging opening is formed in the bottom of the automatic stoker, and a secondary distributor is arranged in the discharging opening. The gasification furnace has the advantages of high efficiency, stability, environmental protection and energy conservation, and solves the problems of'blow-over 'and'cavity' phenomena caused by unreasonable height-diameter ratio design of a traditional gasification furnace and carbon layer height fluctuation caused by a single ash discharge port.

The application discloses a cast iron enamel high-temperature matte glaze without fluorinated salt and nitrate, and a preparation method and application thereof, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, titanium dioxide, sodium carbonate, calcium carbonate, barium carbonate, aluminum oxide, sodium tripolyphosphate, potassium carbonate and lithium carbonate according to specific mass proportions. The preparation comprises raw material mixing, smelting at 1300+ / -10 DEG C under a pure oxygen environment, and rapid cooling after wire drawing detection of the smelting state. The matte glaze completely avoids the use of fluorinated salt and nitrate, eliminates the problems of fluoride emission and environmental protection equipment blockage from the source, and the fluorine content of the product is not detected through detection, thereby meeting the limit value requirements of the EU REACH regulation. Meanwhile, the matte glaze has good enamel surface, excellent firing performance and matte performance, is suitable for a cast iron substrate, has a firing temperature of 780-800 DEG C, and can be used for the production of green and environmentally-friendly enamel products.

This invention discloses an O3-phase high-entropy layered oxide cathode material, its preparation method, and its application, belonging to the technical field of sodium-ion battery cathode materials. The O3-phase high-entropy layered oxide cathode material has the chemical formula NaNi. 1‑ 8x Ca x Co x Al x Fe x Mn x Si x Ti x Zr x O2, x = 0.05~0.1. Raw materials are weighed according to stoichiometric ratio, mixed, and pulverized to obtain precursor powder. The precursor powder is then sintered in a pure oxygen atmosphere to obtain a first sintered product, which is then pulverized again. The pulverized product is then sintered in a pure oxygen atmosphere for a second step, and after cooling, an O3 phase high-entropy layered oxide cathode material is obtained. Sodium-ion batteries assembled based on this cathode material exhibit excellent high-rate performance and long-cycle stability.

The invention discloses a method for continuously oxidizing olefin wax by pure oxygen based on a micro-channel reactor, the micro-channel reactor comprises a plurality of gas-liquid mixers and a plurality of reinforced mixing micro-channel reactors, and two adjacent reinforced mixing micro-channel reactors are connected through the gas-liquid mixers; the method comprises the following steps: melting olefin wax, introducing the olefin wax into a microchannel reactor, injecting pure oxygen into a reinforced mixing microchannel reactor in sections by adopting a gas-liquid mixer, filling the reinforced mixing microchannel reactor with a triangular spiral filler and a glass bead material with two-stage sizes, and in the reaction process, enabling the volume concentration of oxygen to be always lower than 25% and the reaction temperature to be 100-180 DEG C, the pressure is 0-2 MPa. On the basis of the micro-channel reactor, an efficient and safe olefin wax pure oxygen oxidation process is realized through oxygen segmented injection and a safety control strategy.

A method for smelting high-proportion sefstromite by using an oxygen blast furnace. The method comprises the following steps: with pure oxygen blowing being used in a blast furnace, injecting pure oxygen, hot coal gas and pulverized coal from a tuyere, adding an iron charge and coke from the top of the furnace, wherein the volume percentage of N2 in coal gas at the top of the furnace is less than 25%, removing CO2 from the coal gas at the top of the furnace, and then recycling same. The method for smelting high-proportion sefstromite by using an oxygen blast furnace in the present invention can achieve such smelting that the proportion of sefstromite in the blast furnace is greater than 60%, the mass fraction of TiO2 in blast-furnace slag is greater than 15%, but smaller than 45%, and the emission of CO2 is reduced by 30% or more, and solves the problems of thick furnace slag, difficulties in slag-iron separation, blast wandering, high costs, high carbon emissions, etc., of conventional blast furnace smelting in the case of an increase in the proportion of sefstromite, thereby achieving higher utilization efficiency of vanadium-titanium resources, lower smelting costs and lower carbon emissions.