6787results about "Solidification" patented technology

One ozone concentrating chamber is provided therein with a part of a cooling temperature range where ozone can be selectively condensed or an oxygen gas can be selectively removed by transmission from an ozonized oxygen gas, and a part of a temperature range where condensed ozone can be vaporized, and condensed ozone is vaporized by moving condensed ozone with flow of a fluid or by gravitation to the part where condensed ozone can be vaporized, whereby the ozonized oxygen gas can be increased in concentration. Such a constitution is provided that a particle material 13 for condensation and vaporization filled in the ozone concentrating chambers 11 and 12 has a spherical shape of a special shape with multifaceted planes on side surfaces, or an oxygen transmission membrane 130 capable of selectively transmitting an oxygen gas in an ozone gas is provided.

A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. In recent years, the preferred method of separating a hydrocarbon gas stream generally includes supplying at least portions of the gas stream to a fractionation tower having at least one reboiler, and often one or more side reboilers, to supply heat to the column by withdrawing and heating some of the tower liquids to produce stripping vapors that separate the more volatile components from the desired components. The reboiler and side reboilers (if any) are typically integrated into the feed stream cooling scheme to provide at least a portion of the refrigeration needed to condense the desired components for subsequent fractionation in the distillation column. In the process disclosed, the tower reboiling scheme is modified to use one or more tower liquid distillation streams from a point higher in the column than is used in the conventional reboiling scheme, providing colder stream(s) for the reboiler(s) that allow more effective cooling of the feed streams and thereby improve the efficiency with which the desired components are recovered. In addition, the tower liquid streams withdrawn from a higher point in the column contain larger quantities of the more volatile components, which when vaporized provide better stripping of undesirable components like carbon dioxide without reducing the recovery of the desired components. The heated distillation stream is returned to a lower point on the fractionation tower that is separated from the withdrawal point by at least one theoretical stage.

Methods of sequestering carbon dioxide (CO2) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.

The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO2 circulating fluid. Fuel derived CO2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

A low or no pollution engine is provided for delivering power for vehicles or other power applications. The engine has an air inlet which collects air from a surrounding environment. At least a portion of the nitrogen in the air is removed. The remaining gas is primarily oxygen, which is then routed to a gas generator. The gas generator has inputs for the oxygen and a hydrocarbon fuel. The fuel and oxygen are combusted within the gas generator, forming water and carbon dioxide. The combustion products are then expanded through a power generating device, such as a turbine or piston expander to deliver output power for operation of a vehicle or other power uses. The combustion products are then passed through a condenser where the steam is condensed and the carbon dioxide is collected or discharged. A portion of the water is routed back to the gas generator. The carbon dioxide is compressed and delivered to a terrestrial formation from which return of the CO2 into the atmosphere is inhibited.

A process for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is cooled and is thereafter expanded to the fractionation tower pressure and supplied to the fractionation tower at a lower mid-column feed position. A distillation stream is withdrawn from the column below the feed point of the stream and is then directed into heat exchange relation with the tower overhead vapor stream to cool the distillation stream and condense at least a part of it, forming a condensed stream. At least a portion of the condensed stream is directed to the fractionation tower at an upper mid-column feed position. A recycle stream is withdrawn from the tower overhead after it has been warmed and compressed. The compressed recycle stream is cooled sufficiently to substantially condense it, and is then expanded to the pressure of the fractionation tower and supplied to the tower at a top column feed position. The quantities and temperatures of the feeds to the fractionation tower are effective to maintain the overhead temperature of the fractionation tower at a temperature whereby the major portion of the desired components is recovered.

A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. In recent years, the preferred method of separating a hydrocarbon gas stream generally includes supplying at least portions of the gas stream to a fractionation tower having at least one reboiler, and often one or more side reboilers, to supply heat to the column by withdrawing and heating some of the tower liquids to produce stripping vapors that separate the more volatile components from the desired components. The reboiler and side reboilers (if any) are typically integrated into the feed stream cooling scheme to provide at least a portion of the refrigeration needed to condense the desired components for subsequent fractionation in the distillation column. In the process disclosed, the tower reboiling scheme is modified to use one or more tower liquid distillation streams from a point higher in the column than is used in the conventional reboiling scheme, providing colder stream(s) for the reboiler(s) that allow more effective cooling of the feed streams and thereby improve the efficiency with which the desired components are recovered. In addition, the tower liquid streams withdrawn from a higher point in the column contain larger quantities of the more volatile components, which when vaporized provide better stripping of undesirable components like carbon dioxide without reducing the recovery of the desired components. The heated distillation stream is returned to a lower point on the fractionation tower that is separated from the withdrawal point by at least one theoretical stage.

The present invention relates to methods for separating and recovering ethane, propane and heavier components from a feed gas, e.g. raw natural gas or a refinery or petroleum plant gas stream or a petrochemical plant gas stream. These methods employ a common new concept which is the use of the turbo-expander shaft compressor to generate the reflux requirement for the cryogenic absorber or distillation columns. The power of the turbo-expander which is absorbed by the shaft compressor is always high enough so that reflux generation by a specific gas compression through the expander shaft compressor and subsequent cooling, condensation and sub-cooling can always be easily maintained. The present invention allows for higher cryogenic absorber pressure and a lower demethanizer / de-ethanizer column pressure thus eliminating the common cryogenic pump at absorber bottom. The present invention ultimately results in a lower residue compression and utilities consumption. The present invention as such allows for a higher 99+% recovery of NGL from the feed gas stream.

An oxy-combustor is provided to combust oxygen with gaseous low heating value fuel. A compressor upstream of the combustor compresses the fuel. The combustor produces a drive gas including steam and carbon dioxide as well as other non-condensable gases in many cases, which pass through a turbine to output power. The drive gas can be recirculated to the combustor, either through the compressor, the oxygen inlet or directly to the combustor. Recirculation can occur before or after a condenser for separation of a portion of the water from the carbon dioxide. Excess carbon dioxide and steam is collected from the system. The turbine, combustor and compressor can be derived from an existing gas turbine with fuel and air / oxidizer lines swapped.

A low or no pollution power generation system is provided. The system has an air separator to collect oxygen. A gas generator is provided with inputs for the oxygen and a hydrocarbon fuel. The fuel and oxygen are combusted within the gas generator, forming water and carbon dioxide. Water or other diluents are also delivered into the gas generator to control temperature of the combustion products. The combustion products are then expanded through at least one turbine or other expander to deliver output power. The combustion products are then passed through a separator where the steam is condensed. A portion of the water is discharged and the remainder is routed back to the gas generator as diluent. The carbon dioxide can be conditioned for sequestration. The system can be optimized by adding multiple expanders, reheaters and water diluent preheaters, and by preheating air for an ion transfer membrane oxygen separation.

A method for providing refrigeration such as to an insulated enclosure wherein a defined multicomponent refrigerant fluid undergoes a phase change coupled with Joule-Thomson expansion to generate refrigeration over a wide temperature range which may comprise from ambient to low temperatures.

A power plant including an air separation unit (ASU) arranged to separate nitrogen, oxygen, carbon dioxide and argon from air and produce a stream of substantially pure liquid oxygen, nitrogen, carbon dioxide and argon; a steam generator, fired or unfired, arranged to combust a fuel, e.g., natural gas, liquefied natural gas, synthesis gas, coal, petroleum coke, biomass, municipal solid waste or any other gaseous, liquid or solid fuel in the presence of air and a quantity of substantially pure oxygen gas to produce an exhaust gas comprising water, carbon dioxide, carbon monoxide, nitrogen oxides, nitrogen, sulfur oxides and other trace gases, and a steam-turbine-generator to produce electricity, a primary gas heat exchanger unit for particulate / acid gas / moisture removal and a secondary heat exchanger arranged to cool the remainder of the exhaust gases from the steam generator. Exhaust gases are liquefied in the ASU thereby recovering carbon dioxide, nitrogen oxides, nitrogen, sulfur oxides, oxygen, and all other trace gases from the steam generator exhaust gas stream. The cooled gases are liquefied in the ASU and separated for sale or re-use in the power plant. Carbon dioxide liquid is transported from the plant for use in enhanced oil recovery or for other commercial use. Carbon dioxide removal is accomplished in the ASU by cryogenic separation of the gases, after directing the stream of liquid nitrogen from the air separation unit to the exhaust gas heat exchanger units to cool all of the exhaust gases including carbon dioxide, carbon monoxide, nitrogen oxides, nitrogen, oxygen, sulfur oxides, and other trace gases.

A process for liquefying natural gas in conjunction with processing natural gas to recover natural gas liquids (NGL) is disclosed. In the process, the natural gas stream to be liquefied is taken from one of the streams in the NGL recovery plant and cooled under pressure to condense it. A distillation stream is withdrawn from the NGL recovery plant to provide some of the cooling required to condense the natural gas stream. The condensed natural gas stream is expanded to an intermediate pressure and supplied to a mid-column feed point on a distillation column. The bottom product from this distillation column preferentially contains the majority of any hydrocarbons heavier than methane that would otherwise reduce the purity of the liquefied natural gas, and is routed to the NGL recovery plant so that these heavier hydrocarbons can be recovered in the NGL product. The overhead vapor from the distillation column is cooled and condensed, and a portion of the condensed stream is supplied to a top feed point on the distillation column to serve as reflux. A second portion of the condensed stream is expanded to low pressure to form the liquefied natural gas stream.

The present invention concerns systems for storing energy and using the stored energy to generate electrical energy or drive a propeller (505). In particular, the present invention provides a method of storing energy comprising: providing a gaseous input, producing a cryogen from the gaseous input; storing the cryogen; expanding the cryogen; using the expanded cryogen to drive a turbine (320) and recovering cold energy from the expansion of the cryogen. The present invention also provides a cryogenic energy storage system comprising: a source of cryogen; a cryogen storage facility (370); means for expanding the cryogen; a turbine (320) capable of being driven by the expanding cryogen; and means (340, 350) for recovering cold energy released during expansion of the cryogen.

The present invention relates to an enhanced oil recovery process that is integrated with a synthesis gas generation process, such as gasification or methane reforming, involving combined capture and recycle of carbon dioxide from both processes.

Marine LNG carrier and method of operating the marine LNG carrier. The LNG carrier carries LNG in at least one tank. Gas composed of evaporated LNG within the at least one tank is removed. The gas is fed to at least one gas consuming prime mover of the LNG carrier. Power is provided with the at least one gas consuming prime mover. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.

An integrated air separation and oxygen fired power generation system includes an air separation unit and a gas turbine including an air compressor to provide compressed air for the air separation unit. The system further includes a gas turbine expander and at least one additional turbine to drive the air compressor, as well as at least one combustion unit to provide drive gas for expander and additional turbine(s). A portion of oxygen produced by the air separation unit is delivered to the combustor(s) to facilitate production of drive gas for use by the expander and additional turbine(s). Turbine inlet temperatures are controlled by recycling water or steam to the combustor(s).

A method and a plant for simultaneous production of a gas for injection into an oil field and production of methanol, dimethyl ether and / or other oxygenated hydrocarbons or production of higher hydrocarbons from natural gas is disclosed. An air separation unit (ATR) for production of pure nitrogen for injection and pure oxygen for production of synthesis gas (“syngas”) by authermal reformation of a natural gas is an essential part of the method and plant.

An electrical power system that can be used to interconnect a plurality of generators to a plurality to loads while being rated at less than a total power consumed. The system is preferably used to distribute power for a Liquefied Natural Gas (LNG) facility. The system broadly comprises a primary bus connected between the generators and the loads, such as electrical compressor motors used in the LNG facility. The generators and the loads are arranged along the primary bus in order to distribute the power from the generators to the loads, without overloading the primary bus.

Carbon dioxide is separated from a feed gas, preferably derived from flue gas from an oxyfuel combustion process, in a membrane separation system to produce separated carbon dioxide gas which is fed to the oxyfuel combustion process to improve the performance of the process.

The present invention relates to an enhanced oil recovery process that is integrated with a synthesis gas generation process, such as gasification or methane reforming, involving combined capture and recycle of carbon dioxide from both processes.

Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.

The invention is directed to a method of fueling gas turbines from natural gas reserves with relatively low methane concentrations. The invention uses such reserves to generate electric power. The invention permits the use of these reserves at significantly lower cost than by producing pipeline natural gas to fuel gas turbines to generate electric power. These reserves currently generally are used only after the removal of impurities to produce pipeline natural gas quality turbine fuel. The latter current technology is capital intensive, and at current natural gas prices, economically unattractive. The process of the invention can remove the impurities from the gas from the natural gas reserve necessary for protection of the environment, and leaves inert gasses in the fuel in an amount which will increase the output of a gas turbine for the generation of power by about 5 to about 20%.

A method for the production of the natural gas hydrate characterized by the steps of: combining natural gas and water to form a natural-gas water system and an agent adapted to reduce the natural gas-water interfacial tension to form a natural-gas water-agent system, allowing the natural gas-water-agent system to reach equilibrium at elevated pressure and ambient temperature and reducing the temperature of the natural gas-water-agent system to initiate the formation of the natural gas hydrate.

In a novel process for the production of particles or powders, a substance or mixture of substances to be treated is provided in a pressure vessel. A highly compressible fluid is dissolved under pressure in the substance or mixture of substances provided until a solution containing 5% to 90% by weight of said highly compressible fluid has formed. The melting point of said highly compressible fluid is at least around 40 K lower than the melting point of the substance or mixture of substances to be treated. The solution obtained by dissolving said highly compressible fluid in the substance or mixture of substances provided is adjusted to a temperature of up to around 50 K above or below the melting point under atmospheric pressure of the substance or mixture of substances to be treated and is then rapidly decompressed by means of a decompression device in such a way that the temperature falls, downstream of the decompression device, below the solidification point of the substance or mixture of substances to be treated and essentially all of the highly compressible fluid turns gaseous, whereby particles of the substance or mixture of substances provided form. Subsequently, the particles which have formed are removed from the stream of decompressed highly compressible fluid.

A process for the recovery of propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is cooled and / or expanded to partially condense it, then separated to provide a first vapor stream. The first vapor stream is directed into a contacting device whereby vapors and liquids are formed. The liquids are directed to a distillation column operating at lower pressure wherein a second vapor stream is separated to recover a product containing the major portion of the C3 components and heavier hydrocarbon components. The second vapor stream is directed into heat exchange relation with the vapors to cool the second vapor stream and condense at least a part of it, forming a condensed stream. At least a portion of the condensed stream is directed to the contacting device to intimately contact the first vapor stream; the remaining portion (if any) of the condensed stream can be supplied to the distillation column as its top feed. The quantities and temperatures of the feeds to the contacting device and the distillation column are effective to maintain the overhead temperatures of the contacting device and the distillation column at temperatures whereby the major portion of the desired components is recovered.

A method for the separation of a feed gas mixture comprising oxygen and nitrogen in which an oxidant gas and fuel are combusted in a combustion engine to generate shaft work and a hot exhaust gas, the feed gas mixture comprising oxygen and nitrogen is compressed, and the resulting compressed feed gas mixture is separated into two or more product gas streams with differing compositions. The shaft work of the combustion engine is utilized to provide at least a portion of the work required for compressing the feed gas mixture, one of the product gas streams by is heated by indirect heat exchange with the hot exhaust gas from the combustion engine, and the resulting heated product gas is work expanded to generate shaft work and yield an expanded product gas stream. The combustion engine may be a gas turbine combustion engine.

Methods of sequestering carbon dioxide (CO2) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.