1639results about "Specific gas purification/separation" patented technology

One ozone concentrating chamber is provided therein with a part of a cooling temperature range where ozone can be selectively condensed or an oxygen gas can be selectively removed by transmission from an ozonized oxygen gas, and a part of a temperature range where condensed ozone can be vaporized, and condensed ozone is vaporized by moving condensed ozone with flow of a fluid or by gravitation to the part where condensed ozone can be vaporized, whereby the ozonized oxygen gas can be increased in concentration. Such a constitution is provided that a particle material 13 for condensation and vaporization filled in the ozone concentrating chambers 11 and 12 has a spherical shape of a special shape with multifaceted planes on side surfaces, or an oxygen transmission membrane 130 capable of selectively transmitting an oxygen gas in an ozone gas is provided.

An electrical current generating system is disclosed that includes a fuel cell operating at a temperature of at least about 250° C. (for example, a molten carbonate fuel cell or a solid oxide fuel cell), a hydrogen gas separation system or oxygen gas delivery system that includes a compressor or pump, and a drive system for the compressor or pump that includes means for recovering energy from at least one of the hydrogen gas separation system, oxygen gas delivery system, or heat of the fuel cell. The drive system could be a gas turbine system. The hydrogen gas separation system or the oxygen gas delivery system may include a pressure swing adsorption module.

A process for the separation / recovery of gases is described where the desired component to be separated from the gaseous mixture is present in low / very low molar amount and / or low / moderate pressure, the process comprising contacting the gaseous mixture with a separation membrane unit containing high permeability / medium selectivity membranes which separate the feed stream into a permeate stream, enriched in the desired component and at a lower pressure and a retentate stream lean in the desired component and at a higher pressure. The retentate stream is made to convey its pressure to the permeate stream which then is directed to an adsorption PSA unit for further purification of the permeate stream so that the effluent stream from the PSA unit which contains the purified component has a purity of up to 99.90%. The process is useful for separating hydrogen from refinery off gases such as FCC gases and can also be applied to other gases such as helium and any other valuable gases present in gaseous streams in low to very low molar contents and low to moderate pressures.

A reactor comprising: a hollow shell defining a hermetic enclosure; a plurality of tube sheets disposed within said hermetic enclosure, a first one of said plurality of tube sheets defining a first chamber; at least one reaction tube each having a first end and an opposing second end, said first end being fixedly attached and substantially hermetically sealed to one end of said plurality of tube sheets and opening into said first chamber, the second end being axially unrestrained; each of said reaction tubes is comprised of an oxygen selective ion transport membrane with an anode side wherein said oxygen selective ion transport membrane is formed from a mixed conductor metal oxide that is effective for the transport of elemental oxygen at elevated temperatures and at least a portion of said first and second heat transfer sections are formed of metal; each of said reaction tubes includes first and second heat transfer sections and a reaction section, said reaction section disposed between said first and second heat transfer sections; a reforming catalyst disposed about said anode side of said oxygen selective ion transport membrane; a first process gas inlet; a second process gas inlet; and, a plurality of outlets.

A solid state membrane for a reforming reactor is disclosed which comprises at least one oxygen anion-conducting oxide selected from the group consisting of hexaaluminates, cerates, perovskites, and other mixed metal oxides that are able to adsorb and dissociate molecular oxygen. The membrane adsorbs and dissociates molecular oxygen into highly active atomic oxygen and allows oxygen anions to diffuse through the membrane, to provide high local concentration of oxygen to deter formation and deposition of carbon on reformer walls. Embodiments of the membrane also have catalytic activity for reforming a hydrocarbon fuel to synthesis gas. Also disclosed are a reformer having an inner wall containing the new membrane, and a process of reforming a hydrocarbon feed, such as a high sulfur-containing diesel fuel, to produce synthesis gas, suitable for use in fuel cells.

An electrical generating system consists of a fuel cell, and an oxygen gas delivery. The fuel cell includes and anode channel having an anode gas inlet for receiving a supply of hydrogen gas, a cathode channel having a cathode gas inlet and a cathode gas outlet, and an electrolyte in communication with the anode and cathode channel for facilitating ion exchange between the anode and cathode channel. The oxygen gas delivery system is coupled to the cathode gas inlet and delivers oxygen gas to the cathode channel. The electrical current generating system also includes gas recirculation means couple to the cathode gas outlet for recirculating a portion of cathode exhaust gas exhausted from the cathode gas outlet to the cathode gas inlet.

A method of generating electrical power in which a synthesis gas stream generated in a gasifier is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

An exothermic reaction and an endothermic reaction are thermally combined in a reactor having at least one oxygen selective ion transport membrane that provides the exothermic reaction with oxygen from an oxygen-containing gas such as air. The thermal requirements of the endothermic reaction are satisfied by the exothermic reaction. Dependent on the reactor design employed, the exothermic and endothermic reactions may be gaseously combined.

A method for maintaining the temperature of an oxygen-selective ion transport membrane within a desired temperature range includes providing an ion transport reactor with the oxygen-selective ion transport membrane. An oxygen-donating feed gas is delivered to a cathode side at a first temperature, at a first rate, and at a first oxygen partial pressure and a reactant gas is supplied to an anode side at a second temperature and a second rate. A physical condition is then established within the ion transport reactor that favors the transport of elemental oxygen through the oxygen selective ion transport membrane as oxygen ions. One or more process variables are then regulated to maintain the temperature of the oxygen selective ion transport membrane within the desired range.

The present invention relates generally to a pharmaceutical packaging for increasing the product shelf life, reducing discoloration, and reducing degradation of pharmaceuticals by reducing the oxygen level present in the pharmaceutical package. The pharmaceutical package comprises a substantially oxygen impermeable container, at least one oxygen scavenging element disposed in the container, and at least one packaged pharmaceutical product disposed in the oxygen impermeable container.

An integrated gasification combined cycle system. In one embodiment (FIG. 2) a system (200) includes an ion transport membrane air separation unit (210) for producing oxygen-enriched gas (209) and oxygen-depleted air (227), a gasification system (5) for generating syngas with the oxygen-enriched gas (209), a gas combustor (234) for reacting the syngas (224), and a subsystem configured to provide a first stream of air to the combustor (234) at a first pressure and to provide a second stream of air to the air separation unit (210) at a second pressure greater than the first pressure. The subsystem includes a compressor (230) having multi-pressure outlets (203, 204).

A portable oxygen concentrator includes a pressure swing absorption system defined by a relatively rigid housing adapted to generate a flow of oxygen enriched gas and a battery adapted to provide power to the pressure swing absorption system. The oxygen concentrator has a total weight of less than about 10 lbs, has a maximum flow of 100% O2 equivalent gas of about 0.9 lpm, has a total volume less than about 800 in3, and gas a battery life of at least about 8 hours. The present invention also using a liquefaction or transfill system in combination with such an oxygen concentrator.

A method and apparatus for reacting a hydrocarbon containing feed stream by steam methane reforming reactions to form a synthesis gas. The hydrocarbon containing feed is reacted within a reactor having stages in which the final stage from which a synthesis gas is discharged incorporates expensive high temperature materials such as oxide dispersed strengthened metals while upstream stages operate at a lower temperature allowing the use of more conventional high temperature alloys. Each of the reactor stages incorporate reactor elements having one or more separation zones to separate oxygen from an oxygen containing feed to support combustion of a fuel within adjacent combustion zones, thereby to generate heat to support the endothermic steam methane reforming reactions.

Gas supplying method and system in which effective component gas in exhaust gas can be separated and purified efficiently to be resupplied regardless of variation in the flow rate or composition of the exhaust gas and consumed gas can be replenished efficiently. In a method for collecting exhaust gas discharged from a gas using facility, separating / purifying effective component gas contained in the exhaust gas and supplying the effective component gas thus obtained to the gas using facility, the exhaust gas discharged from the gas using facility is added with a replenishing gas of the same components as the effective component gas before the effective component gas is separated and purified.

The present invention relates to the selective separation of carbon dioxide (“CO2”) from methane (“CH4”) in streams containing both carbon dioxide and methane utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from natural gas streams preferably for sequestration of at least a portion of the carbon dioxide present in the natural gas.

A hydrogen-electricity co-production (HECP) system utilizes a fuel cell to produce hydrogen, electricity, or a combination of both hydrogen and electricity. In a first mode, the fuel cell performs an electrochemical reaction by reacting a hydrogen-containing fuel with oxygen to produce electricity, water and heat. In a second mode, the fuel cell utilizes heat released by an electrochemical reaction of the fuel cell to reform a hydrogen-containing fuel to produce hydrogen rich gas. In a third mode, both hydrogen and electricity are co-produced by the fuel cell. The HECP system can control an amount of hydrogen and / or electricity produced and switch between modes by varying an electrical load on the system.

PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is equal to or less than about 14 kcal / mole at water loadings less than about 0.05 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec−1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.

A method and apparatus for producing high purity argon by combined cryogenic distillation and adsorption technologies is disclosed. Crude argon from a distillation column or a so-called argon column is passed to a system of adsorption vessels for further purification. Depressurization gas from adsorption is introduced back, in a controlled manner, to the distillation column and / or a compressor or other means for increasing pressure. Particulate filtration and getter purification may optionally be used.

Gas supplying method and system in which effective component gas in exhaust gas can be separated and purified efficiently to be resupplied regardless of variation in the flow rate or composition of the exhaust gas and consumed gas can be replenished efficiently. In a method for collecting exhaust gas discharged from a gas using facility, separating / purifying effective component gas contained in the exhaust gas and supplying the effective component gas thus obtained to the gas using facility, the exhaust gas discharged from the gas using facility is added with a replenishing gas of the same components as the effective component gas before the effective component gas is separated and purified.

The invention discloses a full-temperature-range pressure swing adsorption gas separation, refinement and purification method.By means of the difference of the temperatures and pressures of different raw material gases and the difference of the adsorption separation coefficients and physical chemistry properties of all components in the raw material gases in the temperature range of 80-200 DEG C and the pressure range of 0.03-4.0 MPa, the adsorption or desorption regeneration operation of the pressure swing adsorption circulation process is adjusted by coupling all separation methods, the adsorption theory that the pressure or temperature swing adsorption separation process is only limited to the adsorption and desorption regeneration circulation operation through pressure or temperature changes is expanded, and therefore all raw material gases are separated, refined and purified by achieving the energy gradient utilization in the gas separation, refinement and purification process and achieving the circulation operation, where adsorption, desorption and regeneration are easily matched and balanced, in the moderate to low cold and moderate to high temperature pressure swing adsorption separation process, and it is changed that a traditional adsorption method is only limited to the auxiliary effect of refinement and purification, and adsorption becomes the basic separation unit operation just as important as refinement, absorption and extraction separation.

Apparatus and method for removal of particles and VOC from an airstream, in which particles carried by the airstream are charged by a corona ionizer and then collected by an electrically enhanced filter downstream of the ionizer. A catalytic filter downstream of the electrically enhanced filter removes VOC as well as ozone generated by the ionizer.

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

An adsorbent for separating nitrogen from a mixed gas of oxygen and nitrogen is MSC wherein an oxygen and nitrogen separation ratio α and a ratio (t95 / t50) of a time t50 required for adsorbing 50% of the oxygen equilibrium adsorption amount and a time t95 required for adsorbing 95% of the oxygen equilibrium adsorption amount satisfy the inequality(t95 / t50)<0.4×(α−24)α≧35.The amount of adsorbent used with respect to a predetermined amount of nitrogen generated can be reduced since a method is carried out which uses this adsorbent to produce nitrogen by separating nitrogen from the mixed gas of oxygen and nitrogen by means of a PSA method. By this method, it is possible to reduce the cost of the apparatus and reduce and miniaturize the scale of the apparatus, and the power consumption amount can be reduced.

A fuel cell system with fuel processor for integration with a marine vessel propulsion system. The system includes an auto thermal reactor that is the fuel processor for producing hydrogen from a fuel source. The fuel source is preferably ethanol or biodiesel or a mixture thereof, but can also be a sulfur containing fuel like petrodiesel of JP-8. The system further includes a gas-water shift reactor for further production and concentration of the hydrogen from the auto thermal reactor output. The system also includes a hydrogen permeable membrane separator for generating suitable quantities of essentially pure hydrogen to the fuel cell. The system also includes an oxygen permeable membrane separator for concentrating oxygen and reducing nitrogen to improve the partial pressure of hydrogen in subsequent fuel processing steps. The system contemplates the use of a Polymer Electrolyte Membrane (PEM) fuel cell. The system minimizes preheating of catalysts or other components to the extent just needed to initiate the fuel processor. To that end, heat sources and sinks of the system and associated usage systems are matched so as to minimize heat collection, storage and distribution systems. Water is recycled within the system to the extent necessary to maintain a water balance in the fuel processor and the fuel cell stack(s). The system includes cooling of the fuel cell stack(s) and integrated heat recovery with exothermic and endothermic catalysts. The fuel processor / fuel cell system components are configured to conform to and take advantage of the available space and limitations, such as the space constraints and opportunities associated with a marine vessel.