This invention discloses a method and
system for targeted deep desulfurization of
syngas for
integrated gasification combined cycle (IGCC) power generation, belonging to the field of gas purification. The process includes pretreatment to remove impurities, removal of most inorganic
sulfur using an
alkanolamine solution, and graded treatment of the
syngas through an Al2O3 layer, a pre-sulfurized NiMoS / CoMoS catalyst layer, and a
zinc oxide layer in a fine desulfurization
tower. GC-SCD technology is used to trace the
sulfur form and optimize the process. The deactivated catalyst is regenerated by low-temperature coking and resulfurization. The pre-sulfurization catalyst uses TiO2-Al2O3 as a carrier, with TiO2 accounting for 5-15 wt%, and the
catalytic hydrolysis conditions are 100-140℃ and 1.5-2.2 MPa. This invention achieves targeted conversion of organic
sulfur under mild conditions, inhibits the formation of thiols and sulfides, and the catalyst is regenerable. The total sulfur in the treated
syngas is ≤0.1 ppm, making it suitable for ultra-deep purification of IGCC and
coal chemical syngas, with high desulfurization efficiency and low operating costs.