The invention relates to a coal bed gas deoxidation catalyst as well as a preparation method and the application thereof. The coal bed gas deoxidation catalyst takes one or the combination of severalplatinum group noble metals, i.e. Pd, Pt, Ru, Rh and Ir, as main catalyzing active components and takes one or the combination of several alkali metal/alkaline-earth metal oxides, i.e. Na2O, K2O, MgO,CaO, SrO and BaO, and multi-element compound oxides of CeO2, lanthanide series rare earth elements, i.e. Pr, Nd, Sm, Eu, Gd, and the like, or/and transition elements, i.e. Y, Zr, La, and the like, or/and gamma-Al2O3 as auxiliary catalysts, and the catalyzing components are loaded on an inert carrier in a coating way so as to prepare an integral catalyst. The coal bed gas deoxidation catalyst hasthe advantages of low igniting temperature, stable combustion process, high activity, long service life, and the like, is suitable for the methane catalyzing and combustion process taking coal bed gasdeoxidation purification as a purpose and can also be extensively applied to the catalyzing and combustion process of CO and low-carbon hydrocarbon under fuel-rich and oxygen-poor reducing atmosphere.