13398results about How to "Avoid secondary pollution" patented technology

The present invention discloses a decelerated centrifugal dust removing apparatus for a dust cleaner. It comprises a cylinder, a conical cylinder and a dust collector box connected in the given order from the upper part to the lower part, as well as an air outlet pipe and an air inlet pipe on the cylinder body. The conical cylinder has a small upper end and a large lower end. In the conical cylinder, on the lower part of the air outlet pipe (under the air outlet pipe) there is an umbrella-shaped reflector in the center of which is provided a hole for air returning. Between the periphery of the umbrella reflector and the side wall is provided an annular gap for the falling down of dust. The apparatus features small loss of air flow pressure, good effectiveness of air suction, high quality of dust filtering, and low noise. With the apparatus, the secondary pollution of the cleaned air can be effectively prevented, and it is especially suitable for use in a secondary stage filtering system of the dust cleaner and for separating small and fine dust particles.

The invention provides a full-component resource reclamation method for waste positive electrode materials of lithium ion batteries. The method comprises the following steps: 1) separating active substances and aluminum foils in waste positive electrode materials of lithium ion batteries by using an aqueous solution of fluorine-containing organic acid and carrying out liquid-solid-solid separation so as to obtain leachate, the lithium-containing active substances and the aluminum foils; 2) respectively carrying out high temperature roasting and impurity removal with alkali liquor on the lithium-containing active substances; 3) respectively carrying out recovery of the fluorine-containing organic acid through addition of acid and distillation, deposition of impurity ions through addition of alkali and ammonium carbonate coprecipitation on the leachate so as to prepare nickel-cobalt-manganese carbonate ternary precursor; and 4) carrying out component regulation on a mixture of the treated active substances and the nickel-cobalt-manganese carbonate ternary precursor, adding lithium carbonate in a certain proportion and carrying out high temperature solid phase sintering so as to prepare a lithium nickel cobalt manganese oxide ternary positive electrode material. The method provided in the invention has the following advantages: the application scope of the method is wide; separation efficiency of the lithium-containing active substances and the aluminum foils is high; short-flow direct re-preparation of positive electrode materials in waste lithium ion batteries is realized; and the method is applicable to large-scale resource reclamation of waste lithium ion batteries.

The invention relates to a pest-proof disease-resistant organic fertilizer and a preparation method thereof, belonging to the technical field of organic fertilizers. Tobacco waste and oil tea pulp are utilized as main raw materials to develop a method of the pest-proof disease-resistant organic fertilizer. The invention breaks through the limitations of harmful substances and single product effect due to addition of chemical materials in the traditional organic fertilizer. The pest-proof disease-resistant organic fertilizer is prepared from the following raw materials: tobacco waste, oil tea pulp, organic substances, a poising agent and a microbial inoculant. The preparation method of the organic fertilizer comprises the following steps: crushing tobacco straws, tobacco stems, tobacco powder, oil tea pulp and organic substances, spraying the poising agent and microbial inoculant, mixing, carrying out pool stack fermentation and strip stack fermentation, screening and granulating to obtain the insect-proof disease-resistant organic fertilizer. The high-efficiency biological insect-inhibiting factors contained in the organic substances containing massive mycoprotein can effectively inhibit and kill pests and pathogenic bacteria, and solve the problem of environmental pollution caused by the pesticide fertilizer.

Monocrystalline silicon solaode chemical etching, washing, drying method and integral processor belong to technique field of chemical etching technique and washing. It characterized in that it not only includes water, acid, alkali, but also ultrasonic participates in etching and washing course: it includes following steps: (1) ultrasonic washes and heats in advance, (2) ultrasonic removes damnification layer, (3) ultrasonic makes herbs into wool, (4) ultrasonic rinses, (5) washing with acid to counteract, (6) ultrasonic rinses, (7) cutting water, (8) hot enthalpy to dry. Positive effects of the invention are: adopting ultrasonic to etch and wash, liquid of making wool can be acted with silicon piece, similar coarseness degree can be generated on surface, perfect pyramid pattern can be obtained; it also eliminates kalium, natrium ion from alkalescent solution, and extends service life of silicon piece; pollution can be decreased, energy consumption and water source can be saved greatly, it is a practical invention.

Disclosed are a preparation method and application of heterogeneous Fenton-like catalyst. The preparation method includes the steps of firstly, dissolving complexing agent and metal salt in distilled water to respectively prepare complexing agent and metal salt solutions; secondly dropwise adding the metal salt solution into the complexing agent solution under the action of a magnetic mixer, and mixing for 20-60 after dropwise addition to obtain metal complex solution; and thirdly, impregnating activated carbon fiber in the metal complex solution for 1-24h, and subjecting taken-out activated carbon fiber to distilled water washing and drying to obtain the heterogeneous Fenton-like catalyst. The preparation method is simple, and conditions are mild. Environment-friendly hydrogen peroxide is used as oxidant, no extra ultraviolet light or even visible light is needed, and the heterogeneous Fenton-like catalyst is capable of efficiently degrading organic pollutants such as dye within a wide pH range of 2-10. The heterogeneous Fenton-like catalyst is well repeatable, and secondary pollution of the homogeneous Fenton reagent caused by iron ions is avoided.

The invention discloses composite hydrogel for adsorption of metal ions and a preparation method thereof. The hydrogel comprises, by weight, 5-95 parts of polyvinyl alcohol, 5-95 parts of chitosan, 0.1-20 parts of modified graphene oxide and 2-6 parts of sodium alginate, the weight ratio between the polyvinyl alcohol and the chitosan is (5: 95)-(95: 5), modified graphite oxide includes modified graphene oxide modified by dopamine and/or modified graphene oxide modified by ferroferric oxide, all components are uniformly mixed in a certain sequence, and the composite hydrogel is obtained under special conditions. The composite hydrogel for adsorption of the heavy metal ions and the preparation method thereof have the advantages that high speed, high efficiency, high adsorption capacity and high selectivity are achieved, the adsorption effect on the heavy metal ions is remarkable, meanwhile, the preparation process is simple, and the operability is high.

The invention discloses a neutral inorganic composite material for dehydration, solidification and modification of high water content sludge. The composite material comprises a powdery mixture consisting of the following components in part by weight: 100 parts of water hardened solidifying material consisting of hydrated gypsum and magnesium oxide, 80 to 120 parts of inorganic water absorption ash material, 20 to 40 parts of inorganic substance aid hardened material, 1 to 10 parts of high polymer coagulant and 1 to 5 parts of modifying functional agent. After being treated by the neutral inorganic composite material, the solidified sludge has high compressive strength; the pH of the lixivium is neutral, and meanwhile, harmful substances such as heavy metal and the like in the sludge can be effectively solidified; the treated sludge meets the requirement of landfill soil, soil for earthwork or soil for greening and farmlands; and the neutral inorganic composite material can be widely applied to the dehydration, solidification and modification of the high water content sludge such as sludge from waterworks, dredged bottom mud of rivers and lakes, residual building soil and the like.

The invention relates to a biomass magnetic carbon material for degrading organic dye. The material is prepared by mixing a biological raw material and an iron precursor at a ratio of (2-20kg):1kg. Meanwhile, the invention also discloses a preparation method of the biomass magnetic carbon material. The biomass magnetic carbon material provided by the invention is cheap and efficient and has double effects of adsorption catalysis and degradation; serving as an efficient catalyst in a process of constructing a Fenton-like system for treating high-concentration wastewater, the biomass magnetic carbon material has high catalytic activity in thoroughly oxidizing and degrading organic dye; the degradation effect is better than that of a ferrous ion homogeneous catalysis reaction and a Fenton-like reaction taking ferroferric oxide as a catalyst.

A haydite is prepared from the fly ash (20-80 Wt%) generated by burning garbage and clay (rest) through mixing, granulating, and high-temp calcining at 1000-1400 deg.C.

A process for preparing sulfuric acid from used alkylating sulfuric acid by high-temp cracking includes such steps as heating to 1000-1100 deg.C, cracking, acid washing for cleaning, converting twice by contact method, and absorbing twice to obtain qualified sulfuric acid for reuse. It has high recovering rate.

The invention discloses a thermal desorption method for contaminated soil, which comprises the following steps of: performing thermal desorption on the contaminated soil at the temperature of between 400 and 650 DEG C; incinerating gaseous contaminant-containing flue gas which is discharged by the thermal desorption step at the temperature of between 750 and 1,200DEG C; and performing afterheat utilization and tail gas treatment on the incinerated flue gas. When the thermal desorption method is used for treating the contaminated soil, the destruction and removal efficiency for the organic contaminants in the contaminated soil is over 99 percent, the tail gas meets the emission standard, and the possible secondary pollution in the process of treating the contaminated soil is stopped, so that the effective innocent treatment is realized and the original reutilization property of the soil is maintained.

A method for recovering MnO2 from the anode material of a wasted lithium manganate oxide battery comprises the following steps of firstly obtaining an anode active material by pre-disposing assembled anode sheets with alkaline solution, etc., subsequently taking the anode active material as a raw material and obtaining a Lambda-MnO2 by soaking the raw material in an inorganic acid or a normal-pressure acid, or obtaining an Alpha-/Beta-/Gama-MnO2 by soaking the raw material in a hydrothermal acid. The method has simple process, little used acid and convenient separation and purification; the obtained various crystal-type MnO2 with large specific surface area and porous structure can be applied directly to be as a catalyst for synthesizing ester compound or disposable battery anode material of Li/MnO2 or electrode material of a super-capacitor.

The invention relates to the technical field of air filtering, in particular to a graphene material coating and a preparing method thereof, and further relates to an a air filtering device and system based on the graphene material coating. The preparing method of the graphene material coating includes the following steps that S1, slurry-dispersion raw liquid is prepared, wherein a dispersing agent and a bonding agent are added into a solvent, and the mixture is stirred to generate the slurry-dispersion raw liquid; S2, a graphene surface coating is formed, wherein graphene powder is added into the slurry-dispersion raw liquid, the mixture is stirred to allow slurry to be even to be applied to the surface of a carrier, drying is carried out, and the graphene-material-coating finished product is obtained. By means of the graphene material coating and the preparing method thereof, the adsorption rate of hazardous substances in gas can be increased, and secondary pollution caused by unfirm adsorption is avoided.

The invention relates to algae-enhanced urea and a production method thereof. According to the invention, a fertilizer is produced through steps that: natural algae and urea are adopted as raw materials; algae is subject to microbe fermentation, and is subject to processes such as extraction and press-filtration, such that an algae enhancing liquid is prepared; molten urea solution and the algae enhancing liquid are granulated in an urea granulating tower, such that the algae-enhanced urea provided by the invention is obtained. With the algae-enhanced urea, soil urease activity can be substantially inhibited. The algae-enhanced urea has an enhanced fertilizer releasing-retarding effect. With the algae-enhanced urea, a utilization rate of fertilizer is improved by 5-10%, and agricultural cultivation can be simplified; nutrient loss can be reduced; secondary pollution can be avoided; and agricultural production cost can be reduced. The algae-enhanced urea is advantaged in wide raw material source, convenient transportation, and convenient application. With the algae-enhanced urea, mechanical working can easily be carried out. Therefore, the algae-enhanced urea has a wide prospect in production.

The invention provides a method for producing baking-free bricks by using phosphorous gypsum based cementitious material to solidify yellow phosphorous slags. 1) The raw materials and formula of the invention are as follows: (1) the phosphorous gypsum cementitious material: 40-60 parts of phosphorous gypsum, 0-30 parts of yellow phosphorous slags, 0-30 parts of pulverized fuel ash, 0-5 parts of blast furnace slag, 10-15 parts of calcined lime, and 0-10 parts of carbide slag; (2) the mateirals of the baking-free brick green bodies: 100 parts of phosphorous gypsum cementitious material, 150-300parts of yellow phosphorous slags raw materials, 2-4 parts of activator, 0.2-1 part of auxiliary agent, and 10-40 parts of water. 2) The preparation method: the baking-free bricks are produced throughthe steps of treating raw materials, mixing the solution with additive, preparing brick blanks and moulding and conserving. In the production process of the invention, no organic matter is added, thus completely avoiding the pollution problems of toxic substance caused by degradation of organic materials, and the release of additive and volatilization of residues, and having the advantages of lowcost, good physical property, high production efficiency, saving of energy consumption and non environmental pollution.

The invention relates to a chemical oxidation remediation method for organism-contaminated soil and a remediation device. The device comprises an oxidant pot, a catalyst pot, a chelating agent pot, aflexible pipe, an electric valve, a control apparatus, a valve switch, a pump, a flow valve, a reactor, a stirrer, a stirrer switch, a sealing cover, a liquid inlet pipe, an exhaust pipe, a gas-liquidseparating apparatus and a tail gas treating apparatus. The method comprises the following steps: placing contaminated soil into the reactor; firstly injecting 0.03-0.4mol/ (kg soil) of citric acid into the reactor through the chelating agent pot; then adding 0-0.4mol/ (kg soil) of catalyst ferrous sulfate in the catalyst pot, and adding water to be dissolved to prepare 0.5mol/l of catalyst; injecting the catalyst into the reactor by the pump; pumping 1-2mol/(kg soil) of oxidant hydrogen peroxide into the reactor; and fully stirring the three preparations and the contaminated soil by the stirrer in the reactor to oxidize and degrade polycyclic aromatic hydrocarbon in the soil, and the removal rate of pollutants in the soil exceeds 80 percent. The invention has high efficiency on organics-contaminated soil remediation and can not cause secondary pollution to the soil.

The invention discloses a purpose of heavy metal sludge, an acid pellet and a preparation method and a purpose thereof. The invention takes stainless steel cold-rolling heavy metal sludge as a raw material for preparing the acid pellet of the sludge. The acid pellet of the sludge is mainly prepared by the following raw materials by weight percent: 5-50 percent of stainless steel cold-rolling heavy metal sludge, 30-70 percent of iron ore concentrate, 2-8 percent of composite binding agent, 4-15 percent of carbon powder and 10-30 percent of water. The preparation method of the acid pellet of the sludge comprises the main steps of pretreatment of raw materials, mixing of raw materials, pelletizing and roasting. The acid pellet of the sludge is used as a raw material of a blast furnace. The invention solves the problems that the prior art can not effectively treat and comprehensively utilize the stainless steel cold-rolling heavy metal sludge.

The invention discloses carboxymethyl cellulose of wheat straw. The wheat straw is crushed and subjected to pretreatment with dilute alkali, bleaching and alkalization, and then reacts with chloroacetic acid before being etherified so as to obtain the carboxymethyl cellulose of the wheat straw; and the carboxymethyl cellulose of the wheat straw is subjected to graft copolymerization together with acrylic acid to obtain a carboxymethyl cellulose-based polymer adsorbent. The adsorbent is applied to the treatment of wastewater containing heavy metal ions, has high adsorbability and large adsorption capacity and ensures high metal ion removal rate. After treatment, the adsorbent has high stability and can completely meet the requirements of heavy-metal wastewater treatment; and the treated wastewater is clear and transparent without odor and can meet the national emission standard. The invention has the advantage that the resources of raw materials are wide, the cost is low, the use of waste is realized, and secondary pollution caused by burning of the wheat straw is avoided, thus being conducive to environmental protection.

The invention relates to a method for recovering rare earth from waste rare earth luminescent material, comprising the following steps: collection of waste rare earth luminescent material, including quick identification on rare earth fluorescent lamp and dismantling and breaking of the rare earth fluorescent lamp, breaking of a CRT display, and peeling and collection of the waste rare earth luminescent material and a glass matrix; pretreatment on the waste rare earth luminescent material, including demercuration oxidation precipitation, alkali fusion and acidolysis; extraction separation of rare earth elements to obtain rare earth chloride enrichment; extraction purification of the rare earth elements to obtain high-purity rare earth chloride; precipitation separation of the rare earth elements to obtain oxalate rare earth or carbonic acid rare earth precipitates; and sintering of the oxalate rare earth or carbonic acid rare earth precipitates to obtain high-purity-level rare earth oxide. The method realizes separation of rare earth elements including Ce, Eu, Tb and Y from impurity elements including Mg, Ba, Ca and the like and complete separation and recovery of light, mediate and heavy rare earth elements, and purification is carried out to obtain the high-purity rare earth oxide, so that the resources are comprehensively recycled, the process flow is reasonable, economic and practical, the rare earth recovery rate is high and the added value of the product is high.

The invention discloses a deep treatment method for cyanide-containing waste water of a tailings pond in the gold industry. The process adopts an ozone oxidation method, a catalytic oxidation method and a biological treatment method to collectively deeply treat the cyanide-containing waste water of the tailings pond in the gold industry. Through the combination of the three methods, a good treatment effect on the cyanide, thiocyanate, arsenic and heavy metals is good, the content of the cyanide after being treated is less than or equal to 0.05mg/L, the content of ammonia and nitrogen after being treated is less than 1mg/L, and other pollutants after being treated can meet the requirement of the ground surface water grade-B water quality standard. The method is used for treating the cyanide-containing waste water of the tailings pond in the gold industry, the treatment effect on the cyanide, the COD, As and heavy metals is good, the heavy metals such as the gold and silver as well as other metal resource can be recovered, and the secondary pollution caused by the ammonia and nitrogen can be avoided. By adopting the deep treatment method for the cyanide-containing waste water of the tailings pond, a good environment, a good economic benefit and a good social benefit can be achieved.