3785 results about "Catalytic oxidation" patented technology

The invention discloses a preparation method of a fluorine-containing carbazole phosphonic acid compound, which solves the technical problems of harsh reaction conditions, high raw material price and low yield in the existing preparation process, 4-trifluoromethoxyaniline and 4-trifluoromethoxyiodobenzene are used as initial raw materials, and Ullmann reaction is performed under a solvent-free condition to obtain 4, 4 '-difluorocarbazole phosphonic acid. The preparation method comprises the following steps: taking 3, 4 '-bis (trifluoromethoxy) diphenylamine as a raw material, carrying out palladium acetate catalytic oxidation cyclization to obtain 3, 6-bis (trifluoromethoxy) carbazole, reacting the 3, 6-bis (trifluoromethoxy) carbazole with 2-bromoethyl dimethyl phosphonate to obtain N-(2-ethyl dimethyl phosphonate) 3, 6-bis (trifluoromethoxy) carbazole, and finally hydrolyzing to obtain the N-(2-ethyl phosphonate) 3, 6-bis (trifluoromethoxy) carbazole. The reaction process is simpler to operate, the yield is guaranteed, and the method is suitable for large-scale production. In the preparation method disclosed by the invention, a solvent is not required to be used in multiple steps, the reaction is performed under a solvent-free condition, and the preparation method is high in safety and environment-friendly.

The invention provides a zero-discharge treatment process for recycling production wastewater, and relates to the technical field of water treatment and recycling, and the zero-discharge treatment process comprises the following steps: S1, oxidizing and degrading COD through ozone and a Fenton reagent, and generating a flocculatable intermediate; s2, intercepting suspended matters by using a gradient aperture filter bed in a grading manner, and monitoring a dynamic membrane resistance coefficient delta Rm in real time to automatically trigger backwashing; s3, coupling an ultrafiltration reverse osmosis membrane to realize that the organic matter rejection rate eta is greater than or equal to 98%, and synchronously regulating and controlling flux and operation pressure by an online spectrometry; s4, regulating and controlling the current density by adopting a rotational flow electric flocculation reactor for directional crystallization to produce industrial salt with Cl <-> less than or equal to 50mg / L; and S5, based on the total dissolved solid recovery rate TR and the comprehensive energy consumption, establishing a multi-target optimization model for real-time parameter adjustment. According to the method, a membrane pollution early warning and backwashing dynamic response mechanism is constructed through cross-scale cooperative regulation and control of delta Rm and the retention rate eta, and a catalytic oxidation effect strengthening and electric crystallization parameter self-tuning technology is combined, so that the problem of cooperative optimization of high-salinity wastewater salt gradient separation and pollutant deep removal is solved.

A bias-free driven ion-based photoelectrochemical wastewater treatment system and method is disclosed. Through an ion-coupled photogenerated electron-assisted photocatalytic oxidation-reduction pathway, the system achieves efficient treatment of high-salinity wastewater. The system employs electron-ion receptor materials as the counter electrode, providing reaction sites to drive the coupling of photogenerated electrons and cation transfer. Additionally, the voltage generated by the system directly drives hole oxidation to produce strong oxidizing free radicals. Furthermore, this ion-based photoelectrochemical system demonstrates excellent degradation performance in high-concentration chloride media. This indicates that, in addition to cations (such as Na+) helping to accelerate the electron transfer rate, the presence of Cl− further enables efficient and sustainable wastewater treatment. The concept proposed in this invention emphasizes the potential for using abundant sodium chloride in seawater as an inexpensive additive for wastewater treatment.

The invention belongs to the technical field of CO catalytic oxidation, and particularly discloses a method for synthesizing a CuO / CeO2 catalyst through a rapid fluid mixing method and application thereof.The method comprises the steps that a copper salt solution A and a cerium salt solution B are put into a rapid fluid turbulence mixing reactor, the flow speed is controlled, a catalyst precursor is prepared after product treatment, the catalyst precursor is put into a muffle furnace, air is introduced for calcination, and the catalyst is prepared; and high selectivity and high conversion rate in CO oxidation reaction in a hydrogen-rich environment are realized. The method provided by the invention also improves the traditional MOF synthesis method, adopts water as a solvent, and reduces the synthesis conditions. The prepared catalyst has high conversion rate and selectivity, the CO conversion rate at 90 DEG C reaches 100%, and the corresponding selectivity is 100%.

The invention discloses a comprehensive treatment system and treatment method for industrial wastewater containing organic fluorine, electrocatalytic oxidation is carried out through an electrocatalytic oxidation reactor in a physicochemical treatment area, the toxicity of the wastewater containing fluorine is effectively reduced, chain scission is carried out on fluorine-containing organic matter macromolecules, the biodegradability of the wastewater containing fluorine is improved, and the treatment effect is good. The fluorine removal reaction sedimentation tank and the calcium removal reaction sedimentation tank are sequentially adopted to effectively remove most fluorine ions and excessive calcium ions, so that the fluorine ion concentration of the fluorine-containing wastewater reaches 10 mg / L, the biological reaction area and the rear fluorine removal guarantee area are arranged at the rear end, the fluorine ion concentration of effluent is further reduced, fluorine removal is effective, operation is easy and convenient, and the cost is low.

The invention belongs to the technical field of electrocatalytic oxidation, and particularly relates to an electrocatalytic active anode film capable of efficiently producing active chlorine and a preparation method and application of the electrocatalytic active anode film. Porous foam titanium is used as a base material, a surface oxidation layer is removed through acidification pretreatment, a titanium dioxide nanotube array grows on the base material in situ through two times of anodic oxidation to serve as a middle layer, and the binding force of the catalyst and the substrate is effectively improved; meanwhile, Ti < 4 + > in TiO2 is partially converted into Ti < 3 + > through a cathode reduction method, so that the conductivity of the material can be enhanced; furthermore, a RuO2 catalytic layer capable of reducing the chlorine evolution potential is loaded on the titanium dioxide nanotube array, so that the electrocatalytic activity is improved. The prepared anode film has a porous structure, and when the anode film is applied to a Flow-through system, the yield of active chlorine and the contact oxidation efficiency of pollutants on an interface of the anode film are improved, and the problem of mass transfer limitation is solved. The electrocatalytic active anode film can realize high-efficiency decoloration of printing and dyeing wastewater under the conditions of no addition of chemicals and low energy consumption.

The invention discloses a nickel-containing etching wastewater treatment process, which belongs to the technical field of environmental protection, and comprises a raw water regulating tank, a pH pre-regulating tank, a heterogeneous catalytic oxidation tower, a neutralization coagulation tank, an inclined tube sedimentation tank and a clean water tank which are connected in sequence. According to the process, under the neutral condition, a catalyst loaded with cobalt manganese oxide is used for activating sodium hydrogen persulfate, high-activity sulfate free radicals are generated, a Ni-EDTA complex structure is fractured in a targeted mode, free nickel ions are released in situ, organic ligands are synchronously mineralized, and the adding amount of sodium hydrogen persulfate is dynamically adjusted through a clean water pool closed-loop control system; and high-purity nickel hydroxide precipitate is generated through alkaline precipitation and coagulation, so that efficient solid-liquid separation is realized. The treatment process disclosed by the invention is compact in flow and stable in operation, effectively solves the problems of difficult complex breaking, low nickel removal efficiency, high sludge toxicity, difficult resource recovery and the like when the EDTA complex nickel wastewater is treated by a traditional method, realizes closed-loop recovery of nickel resources, and has the remarkable advantages of low cost, high efficiency and environmental friendliness.

The invention belongs to the technical field of catalytic oxidation of carbon-containing industrial waste gas, and particularly relates to a Pd catalyst for catalytic combustion of carbon-containing waste gas as well as a preparation method and application of the Pd catalyst. The invention provides a Pd catalyst for catalytic oxidation of carbon-containing industrial waste gas such as CO and volatile organic pollutants VOCs. The Pd catalyst is obtained by compounding an amorphous CeO2 nano-cluster with a TiO2 substrate (marked as cCeO2 / TiO2) and indirectly regulating the form of Pd through gradient regulation of the content of the amorphous CeO2 nano-cluster by a sol-gel method on the basis of strong interaction of Pd and Ce species. The Pd catalyst prepared by the invention shows excellent low ignition temperature, high performance and certain universality in the catalytic combustion process of carbon-containing industrial waste gases such as CO and low-chain VOCs (Volatile Organic Compounds). In addition, the method for preparing the Pd catalyst is simple to operate and mild in condition, and has great industrial application potential and value.

The utility model specifically discloses an odor wet oxidation treatment device, which comprises: a gas conveying unit, which is used for collecting and conveying odor gas; the wet-type catalytic ozonation unit is communicated with the gas conveying unit and is used for carrying out primary treatment on the malodorous gas so as to remove part of malodorous substances in the malodorous gas; the chemical oxidation unit is communicated with the wet-type catalytic ozonation unit and is used for further treating the malodorous gas subjected to primary treatment so as to remove residual malodorous substances in the malodorous gas; and the gas discharge unit is communicated with the chemical oxidation unit and is used for collecting the purified malodorous gas and discharging the malodorous gas outwards. According to the device, the wet ozone catalysis unit and the chemical oxidation unit are coupled, so that water-soluble and water-insoluble components in the malodorous substances can be effectively treated, and the device is small in occupied area and does not generate hazardous wastes. Therefore, the device has the characteristics of low cost and small pollution, and can better adapt to subsequent treatment of malodorous gas in industrial enterprises.

The invention belongs to the technical field of biological dyes, and discloses a bio-based melanin precursor compound, bio-based melanin as well as a preparation method and application of the bio-based melanin precursor compound and the bio-based melanin. The invention provides a bio-based melanin precursor compound 4-[5-(2, 2-diaminoethyl)-2, 3-dihydroxyphenyl]-1H-indole-5, 6-diphenol, and a preparation method of the bio-based melanin precursor compound. The bio-based melanin precursor compound is stable in chemical property and easy to store. And the catalyst can be used as a raw material to efficiently synthesize bio-based melanin through a catalytic oxidation reaction. The process for preparing the bio-based melanin is simple, mild, high in yield and suitable for large-scale industrial production. The bio-based melanin prepared by the invention has good application performance during dyeing, does not generate harmful substances, and is safe and environment-friendly.

The invention relates to the technical field of industrial wastewater treatment, in particular to a heterogeneous catalytic oxidation process and system for treating organic wastewater. The heterogeneous catalytic oxidation system for treating the organic wastewater comprises an acid adjusting unit, a booster pump, a catalytic oxidation reaction unit and a pH callback pipeline mixer which are communicated in sequence, the catalytic oxidation reaction unit comprises a plurality of heterogeneous catalytic oxidation reactors which are connected in series, and the treatment temperatures and the treatment pressures of the heterogeneous catalytic oxidation reactors are sequentially reduced along the flowing direction of wastewater. The heterogeneous catalytic oxidation reactors connected in series in the system provided by the invention do not need to be pressurized step by step, are simple and efficient, and have feasibility. The heterogeneous catalytic oxidation reactors are adopted, so that the loss of the catalyst can be avoided, the continuous addition of the catalyst is not needed, the operation cost is reduced, meanwhile, the function of configuring different catalysts in each stage of heterogeneous catalytic oxidation reactor can be realized, and the degradation degree of organic matters and the precise regulation and control of each stage of target products are realized.

The invention relates to the technical field of organic fertilizer preparation and waste recycling, in particular to a food industrial park wastewater recycling and sludge resourceful treatment method which comprises the following steps: step 1, dynamically partitioning wastewater and cooperatively separating grease, monitoring the conductivity and turbidity of wastewater at water outlets of all workshops in real time, and dynamically dividing wastewater load grades according to monitored values; step 2, coupling biological treatment and carbon source circulation, inputting the effluent in the step 1 into an anaerobic reactor according to a real-time COD load ratio, adding a sludge glycolysis solution as a carbon source supplement, and dynamically adjusting the adding amount based on the ratio of volatile fatty acid to alkalinity; step 3, catalytic oxidation-membrane coupling advanced treatment: carrying out catalytic ozonation on aerobic effluent through sludge-based activated carbon, and adjusting the filling amount of a catalyst in a stepped manner along with characteristic parameters of organic matters in the effluent; 4, directional glycolysis of the sludge and closed-loop utilization of products. Through monitoring and dynamic adjustment, the problems of high energy consumption, low treatment efficiency, resource waste and the like in a traditional wastewater treatment method are effectively solved.

The invention provides a closed-loop reaction continuous production process for producing pigment violet 23, which comprises the following steps: a) adding an NMP (N-Methyl Pyrrolidone) solvent into a 100L reaction kettle, starting and stirring to 30 DEG C, adding a reduzate, and stirring for 30 minutes; b) adding sodium carbonate after the step a), and continuously stirring for 30 minutes; c) slowly adding chloranil, keeping the temperature at 35-40 DEG C, and continuously reacting until the reaction is finished; d) transferring the material in the step c) to closed-loop reaction equipment, and controlling the feeding sequence, mode and complete reaction of each component by utilizing a multi-component reaction optimization technology to ensure the reaction of reactants and reduce the generation e of side reaction to the maximum extent; the adding sequence, the reaction environment, the pressure and the flow speed of reactants are accurately controlled in the reaction process, and the high yield and the high purity of the pigment purple 23 are guaranteed; f) continuously carrying out catalytic oxidation reaction in the closed loop by using a static mixer and a small amount of catalyst combination to obtain a product; by optimizing the continuous production process of the closed-loop reaction of the pigment violet 23, adopting a closed-loop reaction system, and performing continuous production and flow marking monitoring and control, the method disclosed by the invention achieves obvious good effects in a plurality of aspects; the production efficiency is improved, the product quality is guaranteed, the production cost is reduced, the environmental friendliness is improved, and the process stability is enhanced.

The invention relates to the technical field of industrial production wastewater treatment, and particularly provides a resource utilization method of calcium chloride high-salt water containing high-concentration organic matters. The method comprises the steps of pretreatment, wet catalytic oxidation, salt type conversion, softening filtration, deep oxidation, nanofiltration purification and targeted adsorption, no residual mother liquor exists, no secondary pollution is generated, organic matters in effluent are stable and reach the standard, the water quality and water quantity fluctuation resistance is high, heterogeneous and homogeneous catalysts are combined for catalysis, and the purification effect is good. According to the method, the sodium chloride solution is used as a raw material, the homogeneous catalyst is recycled, in addition, most of salt in the homogeneous catalyst is also recycled, resource reutilization is fully achieved, the treatment cost is reduced, and the treated sodium chloride solution can be used as primary saline water for subsequent ion membrane electrolysis.

The invention relates to a metal additive modified Pt-loaded CeO2 catalyst, preparation and application thereof in CO oxidation, and belongs to the technical field of industrial catalysis. The preparation process of the catalyst mainly comprises the following steps: respectively dissolving cerium salt, platinum salt and auxiliary metal salt in deionized water to prepare corresponding precursor solutions; then, mixing the three solutions, and dropwise adding ammonia water under a stirring condition until yellow precipitates are generated; and finally, drying and washing the precipitate, and calcining the solid powder in a proper atmosphere to obtain the assistant metal modified Pt / CeO2 catalyst. La, Pr, Nd or Sm auxiliary metal is introduced into the Pt / CeO2 catalyst, so that the CO catalytic oxidation performance of the catalyst can be improved, and the poisoning resistance of the catalyst in an SO2-containing environment can be enhanced. The method has important significance in the actual industrial application, especially in the catalytic oxidation process under the condition of treating complex flue gas.

The invention relates to the technical field of industrial wastewater treatment, and discloses an efficient two-stage reverse osmosis petroleum coke water treatment system, which comprises pretreatment execution ends, a reverse osmosis core end, a concentration regeneration end and an intelligent control end which are commonly configured with a data feedback module. A step-by-step mechanism is established at the initial stage of wastewater treatment, quartz sand is adopted to intercept large-particle suspended solids, activated carbon is adopted to adsorb and degrade organic matters, softening resin is adopted to replace and remove scaling ions, ozone is adopted to catalyze, oxidize and decompose refractory pollutants, an oxidation-reduction potential dynamic regulation and control mechanism is innovatively introduced, and the dosage of an oxidizing agent is automatically regulated according to water quality and chemical quality; by means of the design, the blocking problem caused by high-hardness waste water is solved, the membrane is prolonged, the solution period is stably solved, the chemical cleaning frequency and agent consumption are reduced, a pollution early warning and closed response linkage mechanism is constructed, membrane damage caused by manual intervention delay is avoided, and the service life of membrane elements is prolonged and reduced.

The invention discloses a method for leaching precious metal through catalytic oxidation of thiosulfate, which comprises the following steps: mixing a copper-containing catalytic system-thiosulfate solution with a precious metal-containing material, and carrying out leaching reaction to obtain a precious metal leachate; wherein a copper-containing catalytic system in the copper-containing catalytic system-thiosulfate solution is a copper-iminodiacetic acid complex. The precious metal is extracted by adopting a copper-iminodiacetic acid catalytic system, the leaching rate of the precious metal and the consumption of thiosulfate can be considered, the leaching effect is remarkably superior to that of an existing copper ammonia system, and industrial application is easy to achieve.

The invention relates to the field of mine mining, and discloses a mine efficient mining intelligent ventilation system which comprises an intelligent monitoring module, the intelligent monitoring module is installed in a mine, environment information in the mine is collected, and the collected information is transmitted to a central control module; the intelligent monitoring module is connected with a central control module, and the central control module is the core of the whole system, receives parameter information transmitted by the intelligent monitoring module, and controls the ventilation equipment module to start according to the parameter information. According to the air purification module, various treatment modes including multi-stage filtration, oxygen supplement, catalytic oxidation, chemical spraying, adsorbent purification, catalytic combustion and the like are adopted for different harmful gases. Therefore, the system can effectively remove various pollutants in mine air, air quality is improved, and health and safety of workers are guaranteed.

The invention discloses a sewage treatment system and method based on combination of ultrasonic micro-electrolysis and catalytic oxidation, and relates to the technical field of environmental protection, and the method comprises the following steps: sewage is pretreated by generating active free radicals through ultrasonic enhanced micro-electrolysis, and then enters a catalytic oxidation unit to be deeply mineralized together with ozone; the ultrasonic power, the ozone adding amount and the reflux ratio are dynamically adjusted through the fluid circulation and intelligent control unit; and the tail water is fed back through online monitoring to reach the standard. The system integrates an ultrasonic micro-electrolysis module, a catalytic oxidation module, an intelligent control module and an automatic backwashing module, and realizes closed-loop optimized operation. The method solves the problems of low treatment efficiency of refractory organic matters, strong drug dependence, easy damage of equipment, poor adaptability and the like in the prior art, obviously improves the COD removal rate to 95% or above, reduces the energy consumption by 20%, does not need additional drugs, is suitable for high-difficulty wastewater treatment of printing and dyeing, pharmacy and the like, and has the advantages of high efficiency, stability, low consumption and engineering.

The invention belongs to the technical field of herbicides, and particularly relates to a preparation method of pyroxasulfone. According to the method, an intermediate is mixed with a solvent, a catalyst and an oxidizing agent, pyroxasulfone can be prepared through oxidation, and the catalyst is any one or a mixture of two of magnesium oxide and tetramethylpiperidone. The pyroxasulfone preparation method has the beneficial effects that the yield of pyroxasulfone can be more than or equal to 95% through catalytic oxidation reaction including the solvent, the catalyst and the oxidizing agent; the catalyst has the advantages of economy and high efficiency, and certainly cannot cause heavy metal harm.

The invention discloses a low-temperature multi-effect evaporation-based impurity salt treatment process method, and relates to the technical field of industrial waste salt treatment in the chemical industry. According to the scheme, firstly, impurity salt is dissolved and then pretreated by a fluorine removal tank and a multi-medium filter, and pretreated saline water is obtained; then, organic matters and dissolved substances are removed through a catalytic oxidation and nanofiltration device, and a monovalent salt solution and a divalent salt solution are separated out; then, the monovalent salt solution is subjected to reverse osmosis concentration and then enters a low-temperature multi-effect evaporation system for sodium chloride crystallization, and the divalent salt solution is subjected to catalytic oxidation and then enters low-temperature multi-effect evaporation for sodium sulfate crystallization. And finally, the mother liquor subjected to low-temperature multi-effect evaporation is refluxed and retreated, and resources are further concentrated. According to the invention, the waste salt treatment efficiency is effectively improved by optimizing the chemical addition of the sedimentation tank. By adopting a low-temperature multi-effect evaporation technology, the energy efficiency is optimized, the energy loss is reduced, the crystallization efficiency is improved, and the resource recovery rate is increased. And a mother liquor backflow retreatment mechanism reduces waste liquid discharge and reduces environmental burden.

The present invention relates to a catalytically active material, the preparation thereof, and the use of the catalytically active material, e.g. in the catalytic oxidation of CO to CO2 or in the catalytic hydrogenation of alkyne. The catalytically active material comprises a support5 comprising a metal oxide, and atomically dispersed noble metal on the surface of the support, wherein the metal oxide is selected from TiO2, CeO2, ZnO, SnO2, Ga2O3, In2O3, ZrO2, and Fe2O3, the noble metal is selected from Pt, Pd, Rh, and Au, and the catalytically active material is obtainable by a method comprising a step of non-thermal plasma treatment in the presence of O2.

The invention provides a cyanide breaking agent and method for treating alkaline cyanide-containing wastewater. The cyanide breaking agent is a combination of an oxidizing agent, a Fe3O4 ZIF-8 core-shell magnetic catalyst and PDMS-hydrophobic silicon dioxide composite liquid. Through a catalytic oxidation-adsorption integrated method, the reaction path is shortened, efficient removal of cyanide is realized, the effluent is far lower than 0.5 mg / L specified by the national standard, a recyclable product is obtained, and the risk of secondary pollution caused by HCN or heavy metal precipitation is reduced; non-photocatalytic nanoscale Fe3O4-ZIF-8 core-shell magnetic catalyst particles are combined with PDMS-hydrophobic silicon dioxide composite liquid to cooperate with an oxidizing agent, the process that cyanide is converted into non-toxic products through integrated two-stage oxidation is promoted, and meanwhile the content of ammonia nitrogen in wastewater is further reduced by combining modified activated carbon.

The invention discloses a high-efficiency purification process for removing COD (Chemical Oxygen Demand) of desulfurization wastewater by an electrocatalytic oxidation method, and relates to the technical field of environmental protection, and the high-efficiency purification process comprises the following steps: reducing initial COD of wastewater through sulfite oxidation pretreatment, removing heavy metal ions through heavy metal chemical precipitation, and degrading organic matters through electrocatalytic oxidation advanced treatment. Ozone is used for synergistically strengthening and realizing cyclic utilization of oxygen resources; according to the method, the current density of electrocatalytic oxidation is dynamically regulated and controlled, a matching section group is determined by constructing a current density-COD change curve, dividing sections and constructing a section matching model, then a current density group is constructed, a benefit stable value and an efficient judgment value are obtained through quantitative analysis, and the optimal current density is determined; and an electrode prediction model is constructed to predict the expected service life of the electrode by using a long-short-term memory network algorithm. The desulfurization wastewater OD can be efficiently purified, the current density is optimized, and the service life of the electrode is predicted.

The utility model discloses a plug-flow type electrocatalytic oxidation industrial wastewater treatment device which comprises a box body, a water inlet is formed in one end of the box body, a water outlet is formed in the other end of the box body, an oxidizing agent is filled in the box body, a plurality of cathode plates are arranged at the top and the bottom in the box body, a mounting plate is horizontally arranged in the box body, and an anode plate is hinged to the mounting plate. The anode plates are located between the adjacent cathode plates, and turning guide plates are hinged between the anode plates and the cathode plates on the same side; a driving assembly and a moving assembly are arranged outside the box, one end of the mounting plate penetrates out of the box and then is connected with the moving assembly, and the driving assembly is suitable for driving the moving assembly to drive the mounting plate to horizontally move. When the anode plate moves, the direction-changing guide plate is driven to move so as to disturb wastewater, so that the wastewater is in a flowing state all the time and sequentially flows through the polar plates, the contact with the cathode plate and the anode plate is increased, the electro-catalysis effect is improved, the wastewater is quickly and uniformly mixed with an oxidizing agent, and the oxidation effect is greatly enhanced.

The invention relates to the field of sewage treatment, in particular to a sewage treatment device based on electro-Fenton reaction catalytic oxidation, which comprises a treatment tank and an anode ring arranged at the top of the treatment tank, a plurality of arc-shaped cathode plates are arranged at equal intervals in the circumferential direction of the bottom of the cathode ring, an anode column is coaxially arranged at the center of the cathode ring, and a circular groove is formed in the upper end of the anode column. A plurality of air supply holes are formed in the inner wall of the circular groove; the anode column is provided with a cleaning mechanism for cleaning the arc-shaped cathode plates and the anode column, the cleaning mechanism comprises a horizontal ring which is arranged on the anode column in a sliding manner and can move back and forth along the axis of the anode column, and the horizontal ring is provided with a plurality of arc-shaped through grooves for the arc-shaped cathode plates to pass through; and a mixing mechanism for mixing electrolytes electrolyzed on the arc-shaped cathode plates and the anode columns is also arranged on the horizontal ring. According to the sewage treatment device, adhered impurities can be removed, meanwhile, the reaction speed between electrolytes can be increased, and the sewage treatment efficiency is improved.

The invention relates to a spherical hydrotalcite phase desulfurization adsorbent as well as a preparation method and application thereof, the preparation method comprises the following steps: mixing an iron source, a nickel source and organic carboxylate, and then carrying out hydrothermal carbonization reaction to obtain the spherical hydrotalcite phase desulfurization adsorbent. The nickel source and the iron source are selected as the raw materials, hydroxide radicals of laminates and carbonate ions between the laminates of the prepared hydrotalcite phase desulfurization adsorbent can increase the alkalinity of the surface of the desulfurization adsorbent and improve the adsorption capacity to hydrogen sulfide, and meanwhile, the hydrotalcite phase desulfurization adsorbent can react with hydrogen sulfide in a catalytic oxidation manner, so that the removal efficiency is improved. Organic carboxylate is selected as a hydrothermal auxiliary agent, carboxylate radicals can chelate metal ions through multidentate coordination to form a stable complex, so that the nucleation rate of hydrotalcite is delayed, the particle size uniformity is improved, meanwhile, a carbon coating layer is generated through hydrothermal carbonization, and pores in the carbon coating layer and pores in hydrotalcite can form hierarchical pore channels, so that the composite material is prepared. The mass transfer efficiency is synergistically improved, so that the adsorption capacity of the adsorbent is improved.

The multi-component condensation, adsorption and catalytic oxidation device comprises a condensation, adsorption and catalytic oxidation device body, and the condensation, adsorption and catalytic oxidation device body is composed of a catalytic combustion furnace, a catalytic fan, a buffer, a carbon tank, a waste gas fan, a condenser and a heat exchanger which are arranged in a machine shell; a functional mechanism is arranged outside the catalytic combustion furnace, and a cleaning structure for cleaning the filter plate is arranged on the filter cartridge. And a second synchronous structure is arranged between the rotating shaft and the rotating fan. The device has a three-stage condensation link for recovering and treating volatile organic compounds, a knocking plate and a piston pump are respectively driven to work through a second synchronous structure, a diaphragm pump is used for pumping water, and water mist sprayed by a spray head adsorbs impurities in flue gas and precipitates at the bottom of a filter cartridge; the filtered flue gas enters the volatile organic matter equipment to be treated, and the knocking plate can knock the filter plate when moving up and down in a reciprocating manner, so that the filter plate is prevented from being blocked.

The invention discloses stable silicon dioxide microspheres as well as a preparation method and application thereof. Mixing a sodium silicate diluent and an organic acid aqueous solution to form colloidal particles, and carrying out a sol-gel reaction to obtain silica sol; the preparation method comprises the following steps: in an air environment, throwing silica sol into water under stirring to form microspheres, injecting inorganic acid into the water at the same time, then injecting a sodium silicate diluent for reaction, and then adjusting the pH value of the system to 6-7; and aging, washing, drying and roasting to obtain the silicon dioxide microspheres. The preparation method comprises the following steps: mixing a sodium silicate diluent and an organic acid aqueous solution by an acid mixing method, granulating by air to form microspheres, and finally injecting inorganic acid to quickly remove heat, reduce pressure drop and maintain the state of the microspheres, thereby obtaining the stable silicon dioxide microspheres. The porous silicon dioxide microsphere with larger surface area and pore volume is obtained, has better catalytic performance when being used as a catalytic oxidation carrier, and has the advantages of high conversion rate and high stability.

The invention relates to the field of 3D printing and catalytic materials, and discloses a method for preparing a manganese-based catalyst through 3D printing, the prepared catalyst and application, the method comprises the following steps: (1) mixing a photosensitive resin mixed solution with ceramic powder to obtain photosensitive ceramic slurry, and carrying out 3D printing to obtain a printing blank; (2) degreasing and sintering the printing green body to obtain a 3D printing ceramic carrier; and (3) coating the surface of the 3D printing ceramic carrier with the slurry containing the manganese oxide, and roasting to obtain the manganese-based catalyst. According to the method, effective preparation of the manganese-based catalyst is achieved in a coating mode, the coating method is easy and convenient to operate and suitable for batch production, the carrier prepared in a 3D printing mode has a communicated pore channel structure, active components are fully distributed on the surface of the carrier, and the catalytic oxidation activity of the catalyst is improved.