2586 results about "Zirconium dioxide" patented technology

The invention provides a high selectivity catalyst used for catalyzing and completely oxidizing formaldehyde with low concentration at room temperature. The catalyst can catalyze formaldehyde completely so as to lead the formaldehyde to be converted into carbon dioxide and water at room temperature. In addition, the conversion rate of formaldehyde remains 100% within a long period of time, without complex auxiliary facilities such as light source, a heating oven and the like, and external conditions. The catalyst comprises three parts which are inorganic oxide carrier, noble metal component and auxiliary ingredient. Porous inorganic oxide carrier is one of cerium dioxide, zirconium dioxide, titanium dioxide, aluminium sesquioxide, tin dioxide, silicon dioxide, lanthanum sesquioxide, magnesium oxide and zinc oxide or the mixture thereof or composite oxide thereof, zeolite, sepiolite and porous carbon materials. The noble metal component of the catalyst is at least one of platinum, rhodium, palladium, gold and silver. The auxiliary ingredient is at least one of the alkali metals of lithium, sodium, kalium, rubidium and cesium. The loading of the noble metal component used in the catalyst of the invention is 0.1 to 10% according to weight converter of metal elements and the selective preference is 0.3 to 2%. The loading of the auxiliary ingredient is 0.2 to 30% according to weight converter of metal elements and the selective preference is 1 to 10%. When the loading of the auxiliary ingredient is lower than 0.2% or higher than 30%, the activity of the catalyst for catalyzing and oxidizing formaldehyde at room temperature is decreased remarkably.

The invention is directed to veneer ceramics for dental restorations of framework ceramics comprising yttrium-stabilized zirconium dioxide. It is the object of the invention to make possible a translucent veneer ceramic which has high flexural strength as well as excellent adhesion to the framework ceramic of yttrium-stabilized zirconium dioxide. According to the invention, this object is met in a veneer ceramic for dental restorations made of yttrium-stabilized zirconium dioxide which is produced from the following components:a)SiO258.0-74.0 percent by weightb) Al2O3 4.0-19.0 percent by weightc)Li2O  5.0-17.0 percent by weightd)Na2O 4.0-12.0 percent by weighte) ZrO2  0.5-6.0 percent by weight.

The invention discloses a calcium oxide-based ceramic core for casting titanium alloy and a manufacturing method of the calcium oxide-based ceramic core. The calcium oxide-based ceramic core comprises the following components by weight percent: 1.0-15.0% of zirconium dioxide, 0.5-10.0% of yttrium oxide, 0.05-0.1% of thorium oxide and the balance of calcium oxide, and the sum of the contents of the above the component is 100%. According to the ceramic core, the bending strength is 15-30Mpa at room temperature, the bending strength is 5-10Mpa at high temperature, the high-temperature deflection is 0.2-0.5%, the firing shrinkage ratio is 1-1.5%, and the porosity is 40-50%. Compared with the existing commercial alumina-based ceramic core and silicon oxide-based ceramic core, the calcium oxide-based ceramic core of the invention greatly reduces the reactivity with molten titanium, and has the advantages of high temperature resistance, easiness in core leach, low in cost and the like.

The invention discloses a supported noble metal catalyst for low-temperature catalytically oxidizing benzene series (benzene, methylbenzene and dimethylbenzene) gas to CO2 and H2O. Active components of the noble metal catalyst are: at least one of Pd, Pt, Ag, Au and Rh; carrier is at least one of active carbon, red mud, molecular sieve, aluminum sesquioxide, titanium dioxide, manganese dioxide, zirconium dioxide, silicon dioxide, cerium dioxide, lanthanum sesquioxide, cobalt oxide, magnesium oxide, zinc oxide, calcium oxide and cupric oxide. Under general pressure, in atmosphere ambient, in fixed bed reactor, with a space velocity range from 10,000 to 100,000h<-1> and at a temperature range from 110 to 210 DEG C, the catalyst can be used for directly oxidizing 100 to 800ppm benzene series gas to CO2 and H2O without byproduct, which shows good low-temperature catalytic activity. The catalyst of the invention has the advantages of simple preparation, lower complete oxidation temperature, immunity to H2O, good stability and high practical value.

The invention relates to a compound oxide carrier and a preparation method, and belongs to the filed of catalyst preparation, wherein the compound oxide carrier is prepared by compounding gamma-aluminum oxide, silicon dioxide and zirconium dioxide. The method comprises the following steps: co-precipitating precursors of the aluminum oxide, the silicon dioxide and the zirconium dioxide with alkali solution, adding surfactant into the mixture to improve the pore structure and acidity and alkaline, then washing, filtering and roasting the obtained sediment at high temperature to obtain compound oxide powder, and finally extruding and molding the compound oxide powder to obtain the carrier. The pore structure and the acidity and the alkaline of the obtained carrier have wide adjustable ranges, the specific surface of the carrier is 200 to 500 m<2> per gram, the pore volume thereof is 0.4 to 1.2 milliliters per gram, and the total acid amount of NH3-TPD is 0.2 to 0.8mmol / g. The carrier prepared by the method is suitable for preparing hydrogenation catalysts of petroleum fractions.

The invention discloses a bimetal methanation catalyst for the removal of micro carbon monoxide from a hydrogen-rich gas and a preparation method thereof. The bimetal methanation catalyst contains active components, namely nickel oxide and ferric oxide, loaded on an oxide carrier and an assistant, wherein the assistant is at least one element selected from the main group I, the main group II, the subgroup I, the subgroup III, the subgroup VI and the subgroup VIII of the periodic table, and the oxide carrier is alumina, titanium dioxide, zirconium dioxide and silicon dioxide or a mixture thereof. The catalyst of the invention can allow the micro carbon monoxide to be removed from the hydrogen-rich gas at a relatively low temperature and has the advantages of low load, high activity, relatively low cost and wide application prospect.

The invention provides a fluid cement for medical use for bone reconstruction, in particular for filling the vertebral body, and a binary composition which is intended for the preparation of such a cement. The invention also provides a device for conditioning the binary composition, and a method of preparing a bone cement from a binary composition. The fluid cement according to the invention comprises: a) approximately 60% to 85% by weight of a polymer comprising a polymethylmethacrylate and a methylmethacrylate monomer and b) approximately from 15 to 40% by weight of a radio-opaque composition. Preferably, the radio-opaque composition comprises a radio-opacifier, such as barium sulfate and zirconium dioxide, in a mixture with a calcium phosphate, for example apatite hydroxide.

The invention discloses a preparation method of a self-cleaning ceramic nanometer glass antireflective coating material and a coating preparing technique thereof. The reflection deducting coating is formed by coating a composite of amorphous porous silicon dioxide and one or a plurality of titanium dioxide, zirconium dioxide, tin dioxide, ceria, yttria, and the like on the surface of photovaltic glass or common float glass, the reflection deducting coating coated on the surface of the glass has the characteristics of self-cleaning effect, high ceramic hardness and wear resistance. surface antistatic property of dust protection, aging resistance and zero-decrement, can be used for 25 years; and within 250nm-2500nm, the degree of transparency of the photovoltaic glass coated with the reflection deducting coating can be improved by 2.5%-3.5%, and the degree of transparency of the common glass coated with the reflection deducting coating can be improved by 2.8%-3.8%. The nanometer antireflective coating material provided by the invention is a water-based paint, the three wastes are not generated in the preparing course, the preparation method is simple, and the cost is low; and the coating preparing technical process is low in requirement and simple and easy to operate, the energy is saved, thereby being suitable for industrial production in large scale.

The invention discloses high-toughness enamel glaze. The enamel glaze is prepared from the following components in parts by weight: 40-50 parts of silicon dioxide, 15-25 parts of titanium dioxide, 5-15 parts of potassium oxide, 10-20 parts of sodium oxide, 1-5 parts of lithium oxide, 2-4 parts of calcium fluoride, 6-12 parts of vanadium pentoxide, 1-3 parts of tungsten carbide and 5-10 parts of aluminum oxide and zirconium dioxide. According to the enamel glaze, by means of the composition, the toughness of the enamel glaze can be greatly improved, meanwhile, the defect that ceramic cracks arecaused due to collision can be overcome, and therefore, the enamel glaze has a wide application prospect.

The invention relates to the technical field of solar photovoltaic glass and provides an antireflective coating solution, which comprises the following components in percentage by volume: 80.0-95.0% of silicon dioxide sol, 0.1-8.0% of titanium dioxide sol, 0.1-5.0% of zirconium dioxide sol, 0-3.0% of cerium dioxide and / or magnesium oxide and / or aluminum oxide sol, 0.1-3.6% of stabilizer, 0.1-3.8% of surface finishing agent, 0-8.0% of volatilization control agent, and 0.2-4.5% of processing assistants. The invention also provides a preparation method of the antireflective coating solution, photovoltaic glass prepared by adopting the antireflective coating solution, and a preparation method of the photovoltaic glass.

The invention relates to a phosphorus fixing film applied to diffusive gradients in thin-films measurement technology. A fixing film and dispersion film superposed structure is arranged in the diffusive gradients in thin-films measurement technology, ions pass through a dispersion film in a dispersion way and is captured by a fixing film immediately to form the linear gradient distribution on the dispersion film. The phosphorus fixing film capturing phosphorus ions is characterized by using zirconium dioxide powder and acrylamide as raw materials, the raw materials are uniformly mixed to form mixed solution according to the weight volume ratio of 1:1.5-1:4, the mixed solution is slowly infused into a clearance of two glass plates clamping a u-shaped plastic sheet, the glass plates are placed for 2-4h horizontally at lower temperature of 10-15 DEG C after bubbles are removed, the temperature is risen to 30-35 DEG C after the zirconium dioxide powder is freely settled so as to enable the mixed solution to be gelated to form a film, the film has higher absorption capacity ratio to phosphate radicals than the prior iron film material by at least 4 times under the condition that the pH value is 5-9, so the analysis requirement of the DGT technology to phosphorus in different environment media is completely met.

This invention relates to the field of electric power generation by direct transformation of the chemical energy of gaseous fuel to electric power by means of high-temperature solid oxide fuel cells. The invention can be used for the fabrication of miniaturized thin filmed oxygen sensors, in electrochemical devices for oxygen extraction from air and in catalytic electrochemical devices for waste gas cleaning or hydrocarbon fuels conversion. The technical objective of the invention is the production of a low-cost electrode-electrolyte pair having an elevated electrochemical efficiency as the most important structural part of a highly efficient, economically advantageous and durable fuel cell. Furthermore, the invention achieves additional objectives. The achievement of these objectives is exemplified with two electrode-electrolyte pair designs and their fabrication methods, including with the use of a special organogel.

The invention relates to a sulfur-tolerant methanation catalyst and its preparation method, and relates to a sulfur-tolerant methanation catalyst which can be used under a wide operation condition particularly at high temperature and its preparation method, and the sulfur-tolerant methanation catalyst contains a carrier and an active component loaded on the carrier. The carrier is selected from alumina, silica, zirconium dioxide, active carbon or molecular sieve, the active component comprises a molybdenum oxide taken as a main active component, a cobalt oxide taken as a first auxiliary agent; and a zirconium oxide, a cerium oxide or a lanthanum oxide, or a mixture composed of at least two above oxides which is taken as a second auxiliary agent. The invention also discloses the preparation method of the sulfur-tolerant methanation catalyst which is composed of a dipping step, a drying step and a calcining step.

The invention relates to a fiber-enhanced Al2O3-SiO2 aerogel efficient heat isolation composite material and a preparation method thereof. The composite material is prepared from the following ingredients in percentage by mass: 25 percent to 90 percent of Al2O3-SiO2 aerogel base bodies, 5 percent to 45 percent of enhanced fiber and 5 percent to 30 percent of light-shielding agents, wherein the light shielding agents are zirconium dioxide or zirconium silicate. The highest use temperature of the prepared material can reach 1200 DEG C; good heat insulation performance is realized in the range of 25 DEG C to 1200 DEG C.

The invention relates to a kind of hydroxyl apatite - zirconia compound biology ceramic material and its producing method, belonging to biology medical material producing technological field. The invention makes zirconia as substance central layer, on its upper and lower surfaces, respectively spread mix middle layer of zirconia and hydroxyl apatite mixed as per different proportion, on the most outside spread a surface layer of pure hydroxyl apatite, to form a kind of gradient nappe structure; in steel mould, at pressure of 10 - 30 MPa, dry press to molding, then at high temperature of 1500 - 1600 Deg. C, sinter without pressure, then can get hydroxyl apatite - zirconia compound biology ceramic material. The compound material produced by the method of the invention, its anti-bending strength is 900 - 1100 MPa, its fracture toughness (KIC) is 7 - 10 MPaíñm1 / 2, its roughness is 0.5 - 5.0 micron; the compound material has good biology compatibility, so can meet the requirement of load bearing planting body of different parts of human body.

The invention provides a novel bactericide, which consists of tourmaline, transition metal and / or oxide thereof, and a carrier. The tourmaline is powder of (Na, Ca) (Mg, Fe)3B3Al6Si6(O, OH, F)31, and accounts for 5 to 80 percent by weight of the bactericide; the transition metal and / or the oxide thereof by the weight of the metal elements account for 0.1 to 50 percent of the weight of the bactericide; and the carrier is one or a mixture of titanium dioxide, silicon dioxide, aluminum oxide, zeolite, zinc oxide, ferric oxide, zirconium dioxide, sepiolite, porous ceramics and active carbon. The bactericide does not need to add a power supply or a light source but can kill microbes such as bacteria, virus and mildew in the air, has the characteristics of small resistance, high sterilization speed and no pollution, and can be widely applied to air sterilization for an air purifier, an air conditioner and a concentrated air-conditioning ventilation system.

An article of manufacture and a process for making the article by generating corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and / or zirconium dioxide using direct and alternating current on anodes comprising aluminum and / or titanium. Optionally, the article is coated with additional layers, such as paint, after deposition of the ceramic coating.

By using a catalyst formed by carrying a noble metal such as platinum, palladium, rhodium, iridium, or ruthenium, and an element from the 2B and 3B families such as zinc, gallium, or indium, on a basic metal oxide carrier, such as cerium dioxide or zirconium dioxide, or a catalyst formed by carrying similar noble metal and an alkali metal, such as sodium, potassium, or cesium, or an alkaline earth metal such as magnesium, calcium, or barium on a similar carrier, methanol can be water vapor reformed with a high efficiency while the carbon monoxide concentration in the obtained hydrogen-containing gas can be simultaneously kept at a low level.

The invention relates to a nanoscale heat insulating material, comprising the following components in weight percent: 5-95% of nanoscale silicon dioxide powder, 5-50% of nanoscale or micro-sized zirconium dioxide powder or zirconium silicate powder and / or silicon carbide powder, 3-15% of reinforced fibre and adding the solvent to 100%. The invention is characterized by easily-obtained raw materials, simple production, low cost and the like, no need of special device; as for the prepared nanoscale heat insulating material, the density is 100-500Kg / m3, the heat conduction coefficient is 0.030-0.055W / mK at 800 DEG C and is much lower than that of the ceramic fibre with the heat conduction coefficient being 0.12-0.20W / mK at 800 DEG C, thus being an excellent nanoscale heat insulating material with broad application prospect and being widely applied to each aspect of heat insulating and energy saving fields of high temperature heat insulation, low temperature heat insulation, cold insulation and the like.

The invention relates to a ceramic wave-transmitting material and preparing method thereof, wherein the material is prepared from sub-micron high purity silicon nitride, boron nitride, zirconium dioxide and nano silica flour through batching, homogeneously mixing by means of supersonic wave and chemical dispersion method, forming through cold isostatic compaction method, and high-sintering in nitrogen atmosphere.

The invention provides a high temperature resistance infrared radiation pottery dope, which belongs to the thermal engineering field. The dope is a mixture of the following materials in mass share: 200 mesh zirconium dioxide 10, 200 mesh zircon quartz sand 20, 300 mesh feldspar 10, 300 mesh cerium oxide 7, 300 mesh manganese sesquioxide 15, 300 mesh manganic oxide 3, 600 mesh titanium dioxide 2, 200 mesh alumina 10, 400 mesh graphite 10, 400 mesh boron nitride 3 and 200 mesh carborundum 10. The graphite and boron nitride in the dope are of lubricating and anti-bonding functions, the carborundum is of wear resistance function, the manganic oxide, titanium dioxide and alumina are of strong infrared ray emission and the dope mad of zirconium dioxide, zircon quartz, feldspar and cerium oxide has good compact structure and strong fire-proof and the manganese sesquioxide can catalyze C, S and N for conversion. Therefore, the invention is applicable for use in dynamic furnaces such as coal dust furnace, boiling furnace and fluidized bed furnace.

The invention discloses a scrubbable attapulgite photocatalyst spraying liquid. The main points of the technical scheme are that ingredients consist of high-viscosity attapulgite clay, acidified attapulgite clay, nano-titanium dioxide, white carbon black, nano-silver-loaded antibacterial powder, nano-magnesium oxide, nano-zirconium dioxide, nano-aluminium oxide, nano-zinc oxide, polyvinyl alcohol, polyethylene glycol, polydimethylsiloxane and water. The scrubbable attapulgite photocatalyst spraying liquid is prepared by stirring, dispersing, emulsifying and grinding the ingredients first, and then, dispersing again, homogenizing, grinding, and canning. The scrubbable attapulgite photocatalyst spraying liquid is suitable for being sprayed on the surface of a building or a decorative material, can continuously adsorb and degrade pollutants, such as formaldehyde, ammonia and benzene, under the irradiation of light, and has extremely good functions of sterilizing, deodorizing, preventing mould, preventing pollution, self-cleaning and purifying air. A thin film which is formed by spraying the scrubbable attapulgite photocatalyst spraying liquid on the surface of the building or the decorative material can present a saturated state after being used for a long time, and can be scrubbed with a cleaning rag.

The catheter includes a tubular body made from a composition including a ceramic, such as zirconium dioxide.

The invention provides a compound modified titanium and preparation method thereof. The compound modified titanium comprises a kernel and an envelop layer coated on the kernel; wherein the kernel is titanium oxide, the envelop layer is composed of inorganic film coated on the kernel and organic film coated on the inorganic film, the inorganic film has two layers at least, the layer close to the kernel contains at least one of silicon dioxide and aluminium oxide, the layer far away from the kernel is coated outside the layer close to the kernel, and the layer far away from the kernel contains zirconium dioxide. In the preparation method of compound modified titanium provided by the invention, the organic envelop liquid adopts surfactant, coupling agent and water emulsion, so that the binding force of titanium oxide of the organic film after being coated by inorganic envelop is high, and dispersity of titanium in oily system is improved.

An article of manufacture and a process for making the article by generating corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and / or zirconium dioxide using direct and alternating current on anodes comprising aluminum and / or titanium. Optionally, the article is coated with additional layers, such as paint, after deposition of the ceramic coating.

The invention discloses a method for manufacturing a high thermal shock ultra-temperature zirconium dioxide product at low temperature. The manufacturing method is to use electric-melting high-purity zirconium dioxide fine powder with granularity less than 47mum (using one of Y2O3, (CaO+Y2O3), (CaO+MgO) and (MgO+Y2O3) as a stabilizing agent) as a substrate, Y2O3 fine powder with granularity less than 5mum as an additive, one of ZrO2 collosol and ZrOCl solution or combination of one of lignosulphonate and phenolic resin with the ZrOCl solution as a bonding agent to fire the product after milling, forming and drying at a temperature ranging from 1,630 to 1,700 DEG C. Heavy and light high purity zirconium dioxide products which are manufactured by the method have high thermal shock stability, high compressive strength, good high temperature stability, strong impermeability and erosion resistance, good thermal insulation effect and the like, and can be used in a high temperature environment over 2,200 DEG C for long time; and the manufacturing method has the advantages of simple manufacturing process, easy industrial popularization and application and the like.

The invention discloses calcium barium zirconate titanate base piezoceramics and a preparation method thereof. The chemical formula of the calcium barium zirconate titanate base piezoceramics is (1-x-y)BaTiO3-xCaTiO3-yBaZrO3, wherein x is greater than 0 and smaller than 0.5, y is greater than 0 and smaller than 0.5, and both x and y are molar fractions. The preparation method comprises the following steps: mixing barium carbonate, calcium carbonate, titanium dioxide and zirconium dioxide according to the stoichiometric proportion (1-x-y)BaTiO3-xCaTiO3-yBaZrO3 (x is greater than 0 and smaller than 0.5, y is greater than 0 and smaller than 0.5, and both x and y are molar fractions), ball-milling, calcining, ball-milling for the second time, granulating, moulding, removing the binder, high-temperature sintering and the like so as to finally prepare the calcium barium zirconate titanate base piezoceramics with high piezoelectric performance. The method greatly enhances the piezoelectric performance of the lead-free piezoceramic system and the technical stability of the material, so that the lead-free piezoceramics in the barium titanate system achieve the practical level in the aspectsof components and technique.

The invention discloses a basic glaze for ink jet printing, a preparation method of the basic glaze, and a ceramic tile. The basic glaze for the ink jet printing comprises the following chemical components by weight percentage: 2.0-3.0% of igloss, 13.0-17.0% of aluminium oxide, 64.0-69.0% of silicon dioxide, 0.05-0.2% of ferric oxide, 0.3-0.9% of calcium oxide, 3.0-6.0% of magnesium oxide, 1.4-2.0% of potassium oxide, 1.4-2.0% of sodium oxide, 0.03-0.10% of titanium oxide, 5.0-10.0% of zirconium dioxide and hafnium oxide, 0.01-0.2% of lithium oxide, and 0.1-2.0% of zinc oxide. The basic glaze for the ink jet printing is free from such defects as deformation, bubbles, pin holes, sewage suction and poor color when an ink jet printing technique is used, and a fabricated product has good color, the surface of a glazed tile is fine and smooth, and the product quality and effect can be improved.

The invention discloses transparent nanometer zirconium dioxide liquid phase dispersoid, and a preparation method and application thereof. The dispersoid comprises liquid phase media and nanometer zirconium dioxide particles, wherein the nanometer zirconium dioxide particles are uniformly dispersed into liquid phase media; the solid content of the dispersoid is 1 weight percent to 50 weight percent; the one-dimensional dimension of the nanometer zirconium dioxide particles is 1 to 12nm; the liquid phase media are water, organic solvents, a mixture of water-soluble organic solvents and water, or a mixture of different organic solvents. The nanometer zirconium dioxide in the product has high crystallinity degree; the particle diameter is small; the distribution is uniform; any surfactant is not contained; the purity is high; the dispersion effect is good; no sedimentation occurs after the still standing for 6 months or longer. The product prepared by the method does not need any treatment, and is directly the transparent nanometer zirconium dioxide liquid phase dispersoid; any substance does not need to be added for dispersion assistance; the problems of easy agglomeration, poor dispersibility and poor optical performance of the composite material are solved; higher application performance and wider application ranges are given to the product.