5726results about "Ceramicware" patented technology

The invention discloses a method of preparing aluminum oxide-silicon carbide compound porous ceramic by aluminum-silicon industrial waste residues. The primary raw materials comprise industrial waste residues, carbon powder, a pore forming substance and an adhesive. The aluminum oxide-silicon carbide compound porous ceramic is prepared by the following steps of mixing, drying, forming and sintering to obtain a final product. Treatment and high additional value utilization of the industrial waste residues are achieved. The prepared porous ceramic is remarkable in performance, and can be applied to the fields of filtration, sound isolation, heat isolation, fire fighting and the like. The method is simple in process flow and convenient for industrialized promotion; and the cost is good to control and the method has extreme economical value.

The invention discloses a fiber foamed concrete and a preparation method thereof. The fiber foamed concrete comprises the following raw materials in parts by weight: 5290 parts of cement, 4965 parts of water, 1.361 part of foaming solution, 1.2964 part of fly ash and 10 parts of fiber. The preparation method comprises the following steps: proportionally weighing the components; sequentially adding the cement and fly ash into a stirrer, proportionally weighing the water, uniformly stirring the mixture by the stirrer, and adding the fiber; preparing and adding the foaming solution; gradually adding the foam into the mixture, and continuously stirring until all the components are uniformly mixed; pouring the mixture into a mold on which lubricating oil is brushed, and curing in a curing chamber; after 24 hours, removing the mold; and respectively curing for 3 days, 7 days and 28 days for experimental detection. The fiber foamed concrete has the advantages of favorable thermal insulation property, favorable compression resistance and favorable bending resistance, and is applicable to a railway bed strengthening layer.

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

Systems and methods for forming an oxidation protection system on a composite structure are provided. In various embodiments, the oxidation protection system comprises a boron-glass layer formed on the composite substrate and a silicon-glass layer formed over the boron-glass layer. Each of the boron-glass layer and the silicon-glass layer include a glass former and a glass modifier. The boron-glass layer includes a boron compound comprising a mixture of boron carbide (B4C) powder and cubic boron nitride (BN) powder.

The invention relates to the technical field of material engineering, in particular to a preparation method and application of a light heat insulation cement aerogel material.The preparation method comprises the following steps that an adhesive is taken and dissolved in water, and then the solution is cooled to the room temperature; adding a dispersing agent into the solution, then adding cement, uniformly stirring, adding a hydrophobic component, and uniformly stirring; reinforcing fibers are added and evenly stirred, and the reinforcing fibers are at least one of polymer fibers, carbon fibers and glass fibers; adding the foaming component, and uniformly stirring; pouring the solution into a mold, performing freezing pore-forming by using liquid nitrogen, and recovering to room temperature after the freezing pore-forming is finished; and then drying to obtain the cement aerogel material after the drying is finished. The cement aerogel material prepared by the invention has excellent characteristics of high strength, light weight, non-flammability and the like, is used for a buffer layer of an explosion-proof tank, and can integrally improve the performance of the explosion-proof tank.

The invention discloses sound-insulation and heat-insulation building mortar and a preparation method thereof, and relates to the technical field of building materials, the sound-insulation and heat-insulation building mortar comprises, by weight, 42-48 parts of a cementing material, 15-25 parts of an auxiliary material, 17-22 parts of lightweight aggregate, 30-35 parts of a functional filler, and 1-2 parts of an additive; the cementing material is a mixture of sulphoaluminate cement and Portland cement; the auxiliary material is a mixture of fly ash and quartz sand, the lightweight aggregate is a mixture of 20-40-mesh hollow vitrified microbeads and 70-90-mesh hollow vitrified microbeads, and the mass ratio of the hollow vitrified microbeads to the hollow vitrified microbeads is 1: (2-3); the functional filler is a mixture of modified waste rubber particles and modified fibers; the additive is a mixture of a polycarboxylate superplasticizer and hydroxypropyl methyl cellulose ether. The mortar disclosed by the invention is good in thermal insulation performance and excellent in mechanical property, the method disclosed by the invention is simple to operate and low in cost, and the prepared mortar is excellent in performance.

The invention discloses a foam cement-based sound absorption material with an adjustable and controllable pore structure and a preparation method of the foam cement-based sound absorption material, and belongs to the technical field of building functional materials. Aiming at the problems of insufficient pore structure regulation and control, limited sound absorption performance and high cost of a traditional cement-based sound absorption material, P.O42.5R Portland cement is used as a basis, a physical-chemical synergistic foaming method and a three-stage gradient temperature control freeze-drying process are combined through the synergistic effect of a composite foaming agent, a microporous structure regulator and a composite pore forming agent, and the sound absorption material is prepared. Precise regulation and control of pores from the nm level to the mm level are achieved, and an interconnected pore channel network with the high open porosity is formed. The density of the obtained material is 200-1000 kg / m, the porosity is 60-90%, the aperture coverage range is 2 nm-6 mm, the open porosity is 70-85%, the 28d compressive strength is 1.83-14.56 MPa, the average sound absorption coefficient in the frequency range of 250-2000 Hz is 0.12-0.62, and the noise reduction coefficient is 0.14-0.64. The composite material has the characteristics of adjustable pore structure, light weight, high strength, broadband sound absorption, low cost and good durability, and is suitable for the noise control fields of building walls, traffic facilities and the like.

The invention relates to the field of building materials, and discloses a multifunctional foamed ceramic sound insulation and heat preservation material for buildings. Comprising the following raw materials in parts by weight: 42 to 48 parts of pottery clay tailings, 14 to 16 parts of fly ash, 10.5 to 12 parts of crushed stone materials, 2.8 to 3.2 parts of a silicon carbide foaming agent, 0.7 to 0.8 part of a borax fluxing agent, 7 to 8 parts of paraffin / silicon dioxide phase change microcapsules, 0.5 to 1.0 part of graphene, 2.0 to 2.5 parts of nano iron powder, 0.05 to 0.5 part of nano silver, 1.0 to 1.5 parts of photocatalytic titanium dioxide and 0.3 to 0.4 part of a fluorosilane coupling agent. A stable matrix structure is constructed through the argil tailings, the fly ash and the crushed stone materials, the silicon carbide foaming agent and the borax fluxing agent reduce the heat conductivity coefficient, the sound insulation performance is improved, the material is endowed with the antibacterial ability through nano-silver and photocatalytic titanium dioxide, indoor sanitation is guaranteed, and a super-hydrophobic layer is constructed through the fluorosilane coupling agent.

A porous refractory in the K2O—SiO2—B2O3 system is formed by chemical direct foaming by heating to over 600° C., resulting in adherent black or white foam. The foam can function as highly porous thermal insulation, a high or low thermal emissivity surface, as a sealant for deteriorated refractory surfaces, as a filler for pockmarks / holes / gaps or as a bonding agent for parts with large gaps between them.

According to the mullite castable preparation method based on comprehensive utilization of the secondary aluminum ash nonferrous smelting slag, components are regulated and controlled by controlling the molar ratio of Al2O3 to SiO2, so that porous light mullite stably falls into a mullite phase region, and generation of excessive corundum phases is avoided. PMMA microspheres, corn flour, carbonized rice husks and SiO2 coated calcium carbonate composite pore-forming agent systems are adopted, and a layered slurry formula, gradient slip casting and segmented sintering processes are combined, so that the porosity and strength distribution are accurately regulated and controlled, and low-temperature sintering and amorphous phase change control are realized. By optimizing the grading of the porous light mullite aggregate and adding the homologous fine powder, the bonding strength and compressive strength of the castable are improved. And finally, the surface of the castable is coated with a compact mullite coating, so that the porosity is reduced, and the erosion resistance, corrosion resistance and stripping resistance are remarkably improved. The obtained castable has the advantages of light weight, high temperature resistance, high strength, low cost and excellent thermal stability and erosion resistance.

The invention discloses a preparation process of a fireproof lightweight thermal-insulation cement-based mortar material, which comprises the following steps: (1) placing porous lightweight aggregate in a sodium silicate solution for standing, and drying the obtained aggregate to obtain pretreated thermal-insulation aggregate; (2) uniformly mixing silica fume, calcium silicate powder, calcium hydroxide powder and water to form slurry; mixing the pretreated thermal insulation aggregate with the slurry, separating, airing the aggregate, and curing to obtain the primary thermal insulation aggregate. And (3) spraying water on the primary thermal insulation aggregate for wetting, then spraying ethanol containing a silane coupling agent, and airing to obtain the modified thermal insulation aggregate. And (4) uniformly mixing Portland cement, the modified thermal insulation aggregate, basalt fiber and a water reducing agent as raw materials, adding water, and uniformly stirring to obtain the mortar material. According to the invention, the water absorption rate of the porous lightweight aggregate is reduced, so that the adverse effect of the high water absorption characteristic of the aggregate on the mechanical properties of the mortar material is effectively reduced.

The invention relates to the technical field of building materials, and particularly discloses a lightweight high-strength waterproof gypsum board and a preparation method thereof, the lightweight high-strength waterproof gypsum board comprises alpha-type high-strength gypsum, phosphogypsum, gradient lightweight aggregate, hydrophobic fiber, temperature-sensitive waterproof capsule and the like. The preparation method comprises the following steps: preparing the hydrophobic fiber, the gradient lightweight aggregate and the temperature-sensitive waterproof capsule, dry-mixing the components, mixing the dry-mixed components with water to form slurry, and pouring and curing. Lightweight and high strength are realized through cooperation of the gradient lightweight aggregate and the hydrophobic fiber, and the temperature-sensitive waterproof capsule releases components to fill pores during curing, so that the problem of insufficient early-stage waterproof performance is solved; the prepared gypsum board has the advantages of light weight, high strength, good waterproofness and durability.

The invention relates to the technical field of concrete, and particularly discloses ultralow-density foam concrete and a preparation method thereof. The ultralow-density foam concrete is prepared from the following raw materials in parts by weight: 35 to 60 parts of cement, 15 to 25 parts of steel slag, 8 to 15 parts of lightweight aggregate, 1 to 3 parts of reinforced fiber, 0.5 to 1 part of a foaming agent, 0.1 to 0.3 part of a stabilizer, 0.3 to 0.5 part of a foaming aid and 30 to 70 parts of water, the foaming aid is at least one of aluminum powder, silica fume, calcium stearate and triethanolamine, and the foaming agent is one of an animal protein foaming agent and a rosin foaming agent; the foaming agent and the foaming aid are combined, a stable foam structure is formed in a concrete system, meanwhile, the phenomena of foam merging and foam breaking are reduced, formation of communicating holes is reduced while the foam hole structure is refined, the stability of foam concrete bubbles is improved, and foam collapse is reduced.

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.

The invention discloses an alumina-based catalytic ceramic membrane loaded with high-content ferric oxide as well as a preparation method and application of the alumina-based catalytic ceramic membrane, and belongs to the technical field of inorganic functional ceramic microfiltration membranes and preparation of the inorganic functional ceramic microfiltration membranes. The invention solves the problems that the catalytic action of the existing catalytic ceramic membrane is limited by low catalyst loading capacity, the preparation process is complicated, the cost is high and the like. When the aluminum oxide-based ceramic membrane is prepared, silicon dioxide is added to generate a liquid phase in the sintering process to promote sintering, the catalyst alpha-Fe2O3 is added into the ceramic powder before sintering, the ceramic membrane with the catalytic function is prepared in a one-step forming and co-sintering mode, the preparation process is simplified, and meanwhile the preparation cost is reduced. The content of alpha-Fe2O3 on the surface and in the ceramic membrane is increased, and Fe < 3 + > is utilized to activate crystal lattices to promote sintering. Along with the increase of the addition amount of alpha-Fe2O3, small pores are discharged in the sintering process, pore walls are shrunk, macropores are generated, the pore diameter of the ceramic membrane is gradually increased, and the permeation flux of the ceramic membrane is improved.

The invention provides nutritional moisturizing ceramsite as well as a preparation method, application and an application method.The method comprises the following steps: firstly, uniformly mixing sieved power plant fly ash with commercial cement, solid nutrition powder and coal gangue powder, and adding hydrogen peroxide to obtain porous ceramsite; the preparation method comprises the following steps: adsorbing a nutritional agent by porous ceramsite, wrapping the porous ceramsite with phosphorylated chitosan, carrying out hydroformylation and alkynylation, and reacting with the modified microcapsule to obtain the nutritional moisturizing ceramsite. The invention also provides an application of the nutritional moisturizing ceramsite in desertification soil improvement. According to the application method of the nutritional moisturizing ceramsite in desertification soil improvement, the nutritional moisturizing ceramsite is divided into large, medium and small ceramsite according to the particle size, and directly covers a desertification land to form a nutritional moisturizing ceramsite layer in a big-end-up form, a uniform form, an interlayer form, a mixed form or a uniform mixing form. The nutritional moisturizing ceramsite prepared by the invention can improve soil fertility and promote plant growth.

The present invention belongs to the technical field of porous materials. Disclosed are a fiber porous carbon material, a porous graphite, and a preparation method therefor and the use thereof. The preparation method for the fiber porous carbon material comprises: subjecting a mixture of carbon fibers and a carbonizable and graphitizable organic precursor substance to cold pressing, controlling the density after cold pressing to be 0.7-1.0 g / cm3 or controlling the pressure intensity of cold pressing forming to be 2-80 MPa, and sequentially carrying out carbonization and graphitization after forming, wherein the average length of the carbon fibers is 50-350 μm. The porous material prepared by means of the method has relatively high air permeability, also has a relatively small pore diameter, a relatively uniform pore diameter distribution, a relatively high bending strength and a relatively low heat conductivity coefficient, and can improve the growth quality of silicon carbide crystals when being applied to the growth of the silicon carbide crystals.

The invention belongs to the technical field of nano porous materials, discloses a high-strength and low-thermal-conductivity SiC-TiO2 nanofiber aerogel and a preparation method thereof, and aims to solve the problems of insufficient structural stability, shear strength and high-temperature thermal conductivity of traditional ceramic aerogel. TiO2 nanorods are introduced onto a SiC nanofiber membrane by adopting an in-situ growth technology, and the high-strength and low-thermal-conductivity SiC-TiO2 nanofiber aerogel is prepared. And constructing the SiC nano composite fiber membrane into the layered porous ceramic nanofiber aerogel with a multilevel structure by combining a layer-by-layer stacking method with a directional freezing casting technology. TiO2 nanorods growing on the surface of the SiC fiber in situ serve as a secondary structure, so that the overall mechanical performance of the material is enhanced; the TiO2 nanorods have specific high infrared light reflection and scattering capabilities, so that the transmittance of the aerogel material to radiation is reduced, and the thermal radiation conduction in a high-temperature environment is effectively reduced. In addition, a silica sol binder is introduced between layers of the aerogel multilevel structure, stable bonding points are formed between fibers after calcination, and the mechanical stability is improved.

The invention provides a sintered hollow batten for buildings and a preparation method, and belongs to the technical field of novel wall materials, the sintered hollow batten for buildings comprises the following raw materials: high-calcium fly ash, construction waste recycled aggregate, clay, sulphoaluminate cement, a foaming agent, reinforced fibers and an additive; wherein the particle size of the construction waste recycled aggregate is 0.5-5mm, and the construction waste recycled aggregate is subjected to plasma activation treatment; a nano TiO2 photocatalytic coating is loaded on the surface of the construction waste recycled aggregate; the reinforced fibers are composite fibers of basalt fibers and polypropylene fibers, and the mass ratio of the basalt fibers to the polypropylene fibers is (1: 1)-(1: 2). According to the sintered hollow batten for the building, the building waste recycled aggregate subjected to plasma activation treatment is adopted, and the nano titanium dioxide photocatalytic coating is loaded, so that the bonding strength of the aggregate is greatly improved, and the hollow batten is endowed with the function of degrading pollutants such as formaldehyde.

The invention belongs to the technical field of phase-change ceramic fiber aerogel, and discloses high-temperature phase-change heat-insulation ceramic fiber aerogel and a preparation method thereof.The preparation method comprises the steps that polycarbosilane and polyvinylpyrrolidone are added into an organic solvent to be mixed and stirred till the polycarbosilane and the polyvinylpyrrolidone are completely dissolved, and a precursor solution is obtained; dispersing a high-temperature phase change microcapsule into the precursor solution, and stirring until the high-temperature phase change microcapsule is uniformly dispersed to obtain a spinning solution; a ceramic precursor fiber membrane is obtained through electrostatic spinning, and the high-temperature phase-change heat-insulation ceramic fiber aerogel is obtained through cross-linking curing and sintering. The thermal conductivity of the high-temperature phase-change heat-insulation ceramic fiber aerogel is adjustable between 0.03 W / (m.k) and 0.05 W / (m.k), the phase-change temperature ranges from 550 DEG C to 600 DEG C, and the phase-change enthalpy value ranges from 400 J / g to 500 J / g. Compared with traditional ceramic aerogel, the aerogel can regulate and control the environment temperature, is more resistant to high temperature and safer, and has wide application in the field of high-temperature heat insulation of aviation power batteries.

The invention relates to the technical field of self-thermal-insulation mortar, in particular to self-thermal-insulation mortar and a preparation method thereof. Comprising the following components: Portland cement, a gradient graphene aerogel skeleton, metal organic framework nanoparticles, photo-thermal-phase change coupling microcapsules, magnetic field orientation Fe3O4 nanosheets, self-repairing microcapsules, silicon carbide nanowire aerogel, a water reducing agent and a fiber reinforced material. The gradient graphene aerogel skeleton, the photo-thermal-phase change coupling microcapsules and other materials with excellent thermal insulation performance are introduced, and a multi-layer thermal insulation structure is constructed. The gradient graphene aerogel skeleton has extremely low heat conductivity coefficient and high porosity, and can effectively prevent heat transfer; the photo-thermal-phase change coupling microcapsules can absorb and release a large amount of heat in the phase change process, and the heat preservation effect of the mortar is further improved.

The invention discloses a layered pore structure geopolymer based on combination of multi-stage low-temperature in-situ polymerization and an ice template method and a preparation method of the layered pore structure geopolymer. The preparation method comprises the following steps: preparing geopolymer slurry; performing one-way freezing on the slurry to form a frozen green body containing a directionally arranged ice crystal template; before the frozen green body is subjected to freeze drying to remove an ice crystal template, specific multi-stage low-temperature in-situ polymerization treatment is carried out, and the treatment comprises at least two different low-temperature heat preservation stages which are sequentially carried out within the temperature range of-10 DEG C to + 5 DEG C, and the temperature of the low-temperature heat preservation stages is gradually increased; and then the treated green body is subjected to freeze drying and maintenance. According to the method, the multi-stage low-temperature in-situ polymerization step aiming at the reaction characteristics of the geopolymer is introduced before the ice crystal template is removed, so that the problems of low mechanical property and unstable pore structure of the geopolymer prepared by a traditional ice template method are solved, and the mechanical strength and structural integrity of the product are remarkably improved; meanwhile, a good layered pore structure and pore channel connectivity are kept.

The invention discloses a method for preparing porous tantalum carbide ceramic by combining a template method with a carbon thermal reduction method, and relates to the field of carbide porous ceramic materials. The invention discloses a method for preparing porous tantalum carbide ceramic by combining a template method with a carbon thermal reduction method, which comprises the following steps of: dipping a polyurethane foam template with rough pore rib surfaces in tantalum-containing reaction slurry, rolling to extrude redundant slurry, and repeating dipping-pressing for multiple times; drying the polyurethane foam template with the rough hole rib surface after dipping treatment to obtain a tantalum carbide preform; placing the tantalum carbide preform in a high-temperature furnace, vacuumizing, heating by a gradient heating program, preserving heat, sintering, and cooling to obtain porous tantalum carbide ceramic; the method is easy to operate, the porosity of the porous ceramic can be regulated and controlled, carbon impurities left on the template can be removed, and therefore the filtering performance of the tantalum carbide porous ceramic is controlled, the purity of the porous ceramic is improved, and industrial large-scale production can be achieved.

Preparation methods for multi-sheet porous ceramic matrices (10, 20, 30, 40) and an atomization core thereof. The preparation method for the multi-sheet porous ceramic matrices (10, 20, 30, 40) comprises: (1) the preparation of ceramic powders, involving: weighing a plurality of groups of components in parts by weight, comprising 25-55 parts of an aggregate, 5-40 parts of a pore former, 5-19 parts of a sintering aid, and 5-35 parts of a powder dispersing agent; (2) the preparation of casting ceramic slurries, involving: weighing a plurality of groups of components in parts by weight, comprising 40-65 parts of each group of ceramic powder, 30-50 parts of a solvent, 0.1-3 parts of a slurry dispersing agent, 1-8 parts of a plasticizer, and 1-10 parts of a binder; (3) the preparation of ceramic green bodies, involving: respectively making the plurality of groups of casting ceramic slurries into a plurality of groups of sheet-like ceramic green bodies by means of a casting process; and (4) the preparation of multi-sheet porous ceramic matrices (10, 20, 30, 40), involving: vertically stacking a plurality of ceramic green bodies of different groups and / or the same group in sequence and then laminating same into an integral body, then feeding same into a furnace for de-binding and sintering, and finally cutting same into required shapes to obtain the multi-sheet porous ceramic matrices (10, 20, 30, 40).

A ceramic membrane, and a process for producing a ceramic membrane. In the process for the production of a ceramic membrane the ceramic membrane is produced by additive manufacturing. The ceramic membrane comprises a membrane portion comprising pores. A nano-and / or micro-particle is formed in-situ from a nano- and / or micro-particle precursor during the additive manufacturing process and / or post-processing step. The ceramic membrane comprises the in-situ formed nano- and / or micro-particle, or residue thereof, arranged within the pores of the membrane portion. Also described is a water treatment module including the ceramic membrane.

The invention discloses a porous ceramic filter for liquid magnesium alloy purification and a preparation method thereof, and the porous ceramic filter comprises the following raw materials in percentage by mass: 70-85wt% of ceramic particles, 8-15wt% of multi-element oxide system microcrystalline glass brazing filler metal and the balance of a binder, al2O3-B2O3-SiO2-MgO-CaO multi-element oxide system microcrystalline glass brazing filler metal is adopted, under the condition of air atmosphere high-temperature calcination, a compact reaction layer containing a low-melting-point glass phase, an aluminum oxide phase, a magnesium aluminate spinel phase, a calcium aluminosilicate phase, a borate phase and a silicate phase is generated on the surfaces of ceramic particles of a porous ceramic filter through a chemical reaction; the magnesium alloy filter has high strength and good high-temperature stability, and the problems that the filter loses efficacy and magnesium alloy melt is polluted due to the fact that the filter is eroded by magnesium alloy liquid are effectively solved.

The invention relates to the technical field of porcelain, in particular to porous antioxidant composite porcelain and a preparation method thereof, and the preparation method comprises the following steps: weighing the following raw materials in parts by weight: 35-40 parts of clay, 10-15 parts of aluminum oxide, 6-10 parts of an aluminum nitride-doped modified homogenizing agent, 5-9 parts of kaolin and 5-8 parts of a sodium silicate blender. According to the porous anti-oxidation composite porcelain, clay is adopted as a matrix, aluminum oxide and kaolin are added to be matched with an aluminum nitride modified homogenizing agent and a sodium silicate blender, the raw materials are blended and synergized, compression molding is performed, and finally homogenizing sintering is performed, so that the porous anti-oxidation composite porcelain is obtained. The porous performance, the high-temperature oxidation resistance and the mechanical bending strength performance of the obtained composite porcelain are harmoniously improved, and meanwhile, the stability effect of the product is remarkable under different degrees of corrosion conditions.

The invention relates to a preparation method of alumina porous ceramic for an electrostatic chuck, which successfully obtains porous ceramic with uniform pore structure, adjustable porosity and aperture, small density and high strength by optimizing technological parameters such as freeze drying and taking ice crystals generated by water as a template. Aluminum oxide powder, a plasticizer, a dispersing agent, a binder, a defoaming agent, a thickening agent and the like are adopted as main raw materials, the formula of the slurry is adjusted, and the flowability, formability and stability of the slurry are improved. In addition, by doping the sintering aid, the porous ceramic also has good dielectric strength and compressive strength. The method not only can provide excellent thermal management performance, but also is simple in process, wide in raw material source, low in cost and environment-friendly, and provides a high-performance porous ceramic material with potential application potential for electrostatic chucks and the like.

The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.

The invention provides a design method of a freeze-thaw sensitive composite material for 3D printing. The design method comprises the following steps: S1, selecting a matrix material with differentiated heat conductivity coefficient, thermal expansion coefficient and specific heat capacity; s2, doping microcapsule phase change materials with different phase change temperatures and latent heat values into the matrix material; s3, reinforced fibers are selectively added, and the cementation effect between the base materials is changed; s4, 3D printing process parameters are determined, wherein the 3D printing process parameters comprise the layer thickness, the filling density and the temperature; s5, permutation and combination are performed according to different base materials, microcapsule phase change materials and reinforced fibers and proportions thereof, corresponding freeze-thaw sensitive composite materials are manufactured through 3D printing with different process parameters, corresponding physical and mechanical property tests are performed, a freeze-thaw sensitive-process-performance database is established according to physical and mechanical property test results, and the freeze-thaw sensitive composite material is obtained. And obtaining a mapping relationship among different parameters for subsequent further material development.