The invention discloses a
high heat storage density stable thermochemical adsorption composite
heat storage material and a preparation method thereof, the
high heat storage density stable thermochemical adsorption composite
heat storage material comprises 54%-57% by
mass of mixed salt and 43%-46% by
mass of a porous material, the mixed salt comprises MgSO4 and MgCl2, the
mass ratio of MgSO4 to MgCl2 is 9: 1-6: 4, and the porous material is expanded
perlite modified by nano
alumina or a
silane coupling agent. The high-heat-storage-density stable thermochemical-adsorption composite
heat storage material provided by the invention is simple in preparation method, and the modified expanded
perlite is used as a carrier of the mixed hydrated salt; the obtained composite heat
storage material has excellent performance: the salt-containing load rate is 114-121%, the water
absorption rate is 1.2-1.28 g / g, the heat storage density is 1123.5-1208.6 kJ / kg, the heat storage temperature is 133.4-141.3 DEG C, the structural strength is 10.346-12.631 kPa, the
structural stability is 99.27-99.53%, and the stability is 79.7-83.3% after circulation for 30 times, that is, the composite heat
storage material is high in heat storage density, high in water
absorption rate, low in heat storage temperature, high in strength and not easy to scatter and fall off, and the composite heat
storage material is suitable for large-scale production. And the material also has relatively good
cycling stability.