The invention relates to the technical field of dyes, in particular to an acid black dye with
green light and a preparation method thereof.The preparation method comprises the steps that a front color base I and a front color base II are synthesized firstly, then the front color base I and
chromic oxide are complexed to obtain a reaction solution I, then the front color base II is added into the reaction solution I, and the acid black dye with the
green light is prepared. The preparation method is simple and environment-friendly, a dye
compound A, a dye compound B, a dye
compound C and a dye compound D are formed by complexing a front color base I, a front color base II and
chromium ions, and then the adding amount proportion of the front color base I, the front color base II and the
chromium ions is adjusted; the ratio of the dye
compound A to the dye compound B to the dye
compound C to the dye compound D is adjusted, the green and full acid black dye is prepared, and the obtained acid black dye with
green light is excellent in color fastness.