536 results about "Copper oxide" patented technology

The invention discloses a copper-silicon catalyst as well as a preparation method and application thereof, and the copper-silicon catalyst comprises the following components in percentage by weight: 43-79wt% of silicon dioxide; the content of copper oxide is 15-35 wt%; the content of the auxiliary agent A is 3-10 wt%; the auxiliary agent B accounts for 3-12 wt%; the auxiliary agent A comprises one or more of alkali metal or alkaline earth metal oxides; and the auxiliary agent B comprises one or more of VB to VIIB group metal oxides. The raw materials of the catalyst are cheap and easy to obtain, the reaction condition is mild, the catalyst is environment-friendly, and the prepared catalyst is small in copper species particle size, high in dispersity, high in conversion rate and selectivity and good in stability.

The invention discloses a self-cleaning composite piezoelectric ceramic membrane as well as a preparation method and application thereof, and belongs to the field of composite ceramic membranes. The technical problem that an existing ceramic membrane separation technology is poor in biomembrane pollution resisting effect is solved. According to the preparation method, the barium titanate ceramic membrane is firstly prepared to serve as the base membrane, then the copper oxide one-dimensional nanostructure is loaded on the piezoelectric ceramic substrate, and the base membrane has a large membrane surface area and can be combined with more catalysts, so that more active sites are provided for catalytic reaction; according to the composite membrane, the hydrophilicity, the anti-pollution performance and the piezoelectric catalysis self-cleaning performance of the membrane are remarkably improved, and pollutants in water can be quickly and effectively separated, so that the flux and the anti-pollution performance of the membrane are improved.

The invention belongs to the field of PET (polyethylene glycol terephthalate) plastic waste treatment, and particularly relates to preparation of a copper oxide-nickel hydroxide core-shell structure catalytic material and application of the copper oxide-nickel hydroxide core-shell structure catalytic material to preparation of high-added-value formic acid by upgrading electro-catalysis PET plastics, and the preparation method comprises the following steps: (1) placing a copper conductive substrate in an alkali etching mixed solution for alkali etching treatment, obtaining a conductive substrate on which a Cu (OH) 2 precursor grows; (2) placing the conductive substrate on which the Cu (OH) 2 precursor grows in a muffle furnace for heat treatment to obtain a conductive substrate on which CuO nanowires grow; and (3) placing the conductive substrate on which the CuO nanowire grows in a hydrothermal kettle, and obtaining the CuO-coated Ni (OH) 2-x core-shell structure catalyst through a hydrothermal method.

The invention provides a method for co-processing multi-source copper-based waste through copper concentrate, and relates to the field of metal smelting. The copper concentrate and the copper-based waste are subjected to first mixing, and a mixture is obtained; under the oxygen-containing atmosphere, the mixture is smelted, and matte and smelting slag are obtained; the matte and the silicon-based slag former are subjected to first blowing to obtain first blowing slag; carrying out second mixing on the first converting slag and a reducing agent, and carrying out second converting to obtain crude copper; the copper concentrates comprise copper sulfide concentrates and copper oxide concentrates. Copper concentrate matte smelting and copper-based waste pyrogenic smelting are combined together, the problems that the copper-based waste smelting scale is small, and furnace burning is caused by overburning are solved, and the problem that a slag former is additionally added in copper concentrate matte smelting is solved. Through collaborative smelting, valuable metals such as copper, gold and silver enter matte, iron, aluminum and silicon in the copper-based waste enter smelting slag, and a silicon-based slag former and a reducing agent are added when the matte is blown, so that the slagging function is realized, and the valuable metals in the waste are recovered.

The invention relates to the technical field of industrial wastewater treatment, and discloses a treatment method for grinding fluid wastewater of a grinder, which comprises the following steps: pretreatment and demulsification, multi-stage chemical purification, biochemical deep treatment, deep purification and recycling, and sludge treatment. A specific supported heterogeneous catalyst is adopted in the multi-stage chemical purification step, nano zero-valent iron and copper oxide composite active components constructed on the surface of the catalyst can enhance the generation efficiency and stability of free radicals in the advanced oxidation process, and a composite coagulant with an optimized ratio in the coagulating sedimentation step is cooperated, so that the purification efficiency of the high-grade oxidation process is improved. An efficient continuous removal system for heavy metal ions and refractory organic pollutants is formed; meanwhile, in the pretreatment step, the demulsifier is composed of specific components, through the synergistic effect of all the components, rapid demulsification of the emulsified oil phase in the grinding fluid wastewater is achieved, favorable conditions are created for subsequent deep treatment, and therefore the purification efficiency and operation stability of the technology are overall improved.

The invention discloses a copper oxide modified bismuth vanadate photocatalyst as well as a preparation method and application thereof, and belongs to the technical field of photocatalytic reduction of carbon dioxide. The method comprises the following steps: synthesizing a BiVO4 monomer through a hydrothermal method, then mixing and stirring the BiVO4 monomer and a Cu-MOF precursor solution, carrying out electrostatic adsorption compounding, then carrying out calcination treatment to convert Cu-MOF into CuO, loading the CuO on the surface of BiVO4, forming a p-n heterojunction, and preparing the CuO / BiVO4 composite photocatalyst. According to the catalyst, separation of photon-generated carriers is effectively promoted by constructing a heterojunction, the CO2 adsorption and activation capacity is enhanced, and the CO2 photocatalytic reduction performance is remarkably improved; experiments show that the CO yield of the prepared catalyst reaches 36.77 [mu] mol.g <-1 >. H <-1 > in a reaction for 5 hours, which is about 5.7 times that of pure BiVO4, and the catalyst has good stability; the method is simple in process, low in cost and suitable for efficient photocatalytic reduction of CO2 to prepare fuel.

The invention relates to a method and a system for recovering hydrogen in mixed gas by using a pressure swing adsorption and membrane separation method. The method comprises the following steps: S1, preliminary impurity removal: carrying out multi-layer adsorption impurity removal on mixed gas containing silane, disilane and hydrogen, and cooling to 22-28 DEG C; s2, pressure swing adsorption: feeding the mixed gas subjected to primary impurity removal into a pressure swing adsorption device, wherein an adsorbent in the adsorption device is modified activated carbon which is activated at high temperature and is loaded with 3-5% of copper oxide on the surface; s3, membrane separation and adsorption: the mixed gas passing through the pressure swing adsorption device enters a filter and a dryer, and finally passes through a membrane separation device, silane and disilane are collected on the enrichment side of the membrane separation device for further purification, and hydrogen is collected on the permeation side of the membrane separation device for further purification. According to the invention, a process of combining pressure swing adsorption and a membrane separation method is adopted, the advantages of the two technologies are fully exerted, and efficient separation of silane, disilane and hydrogen is realized.

The invention discloses a layered nano-porous copper loaded cuprous oxide / copper oxide nanowire composite material as well as a preparation method and application thereof. The material is a thin strip and comprises an amorphous substrate thin strip, multiple layers of nano-porous copper covering an amorphous substrate and a cuprous oxide / copper oxide two-component heterojunction nanowire loaded on the surface of the nano-porous copper. The preparation method comprises the following steps: firstly, freely dealloying an amorphous ribbon, and adding PVP (Polyvinyl Pyrrolidone) into dealloying corrosive liquid to generate layered nano-porous copper; then, copper hydroxide nanowires grow on the surface of each layer of nano-porous copper in situ through the anodic oxidation technology; and finally, converting the copper hydroxide into cuprous oxide / copper oxide nanowires with different component proportions by regulating and controlling the temperature by adopting a heat treatment process. The prepared composite material has a larger specific surface area and more active sites, and has unique structure and performance advantages in the field of photocatalytic degradation of organic dyes.

The application discloses a preparation method and purification process of copper hydroxide, a certain amount of anhydrous copper sulfate is accurately weighed, and a certain volume of deionized water is added to prepare a solution with a certain concentration, a copper ammonia solution is prepared: slurry is prepared from circuit board sludge, screening is performed, ammonium bicarbonate or ammonium carbonate is added for reaction, and a copper ammonia solution containing carbonate or bicarbonate is obtained through purification; in addition, high-purity copper powder is added into concentrated ammonia water, concentrated hydrogen peroxide solution is slowly dropped into the concentrated ammonia water, and the dropping is continued until no large amount of bubbles is generated in the solution, and the solution is filtered to obtain a clear indigo blue solution. The production process adds the step of adding a stabilizer and stirring, guarantees the stable state of the copper hydroxide crystal, and enables the copper hydroxide crystal to remain unchanged into copper oxide for one year in an environment with a temperature as high as 60 degrees.

This invention provides an amino-modified copper-silicon catalyst, its preparation method, and its application, belonging to the field of catalyst technology. The copper oxide particles in the copper-silicon catalyst provided by this invention have a small particle size and high dispersibility on the silica surface, which can significantly improve the catalytic activity of the copper-silicon catalyst, thereby improving the selectivity of ethanol in the hydrogenation of diethyl oxalate. Example results show that, at 180℃ and a hydrogen-to-ester ratio of 25, the copper-silicon catalyst provided by this invention achieves a diethyl oxalate conversion rate of 96.66% and an ethanol selectivity of 84.72% for diethyl oxalate. Furthermore, after 270 hours of stable reaction, the diethyl oxalate conversion rate still reaches 94.7%, and the ethanol selectivity still reaches 66.29%, indicating that the copper-silicon catalyst does not show significant deactivation.

The invention relates to a catalyst for preparing cyclododecanone through cyclododecanol dehydrogenation and a preparation method and application thereof. The catalyst component comprises copper, zinc, zirconium, sodium, calcium, aluminum and iron; the catalyst is prepared from the following components in percentage by mass in an oxide form: 40 to 65 weight percent of copper oxide, 10 to 21 weight percent of zinc oxide, 10 to 30 weight percent of zirconium oxide, 5 to 20 weight percent of sodium oxide, 1 to 5 weight percent of calcium oxide, 0.5 to 1.5 weight percent of aluminum oxide and 0.05 to 0.5 weight percent of iron oxide. In one embodiment, according to the preparation method of the catalyst provided by the invention, water vapor is added during roasting in a nitrogen environment, so that the release speed of carbon dioxide is controlled, and formation of carbon deposition in the roasting process is reduced. The catalyst can solve the problem of low selectivity caused by low dehydrogenation reaction conversion rate and many by-product cyclododecene, and has the characteristics of high strength, good hydrothermal resistance, long service life and the like.

Provided in the present application are a copper grid line and the use. The copper grid line comprises a grid line body portion and a grid line peripheral portion, wherein the grid line peripheral portion is located on both sides of the grid line body portion, and the width of the grid line peripheral portion on either side does not exceed 15%-50% of the width of the grid line body portion; the median particle size of a copper powder in the grid line peripheral portion is less than the median particle size of a copper powder in the grid line body portion. Since a dense structure can be formed at the grid line peripheral portion, the contact area between the copper grid line and the surface of a cell is increased, and the adhesion of the copper grid line is improved, such that moisture and oxygen are prevented from penetrating through the interface between the copper grid line and the underlying cell to oxidize the copper powder in the body portion of the copper grid line, thereby reducing the bulk resistivity of the grid line and the contact resistance between the grid line and the cell.

The application relates to the development and technical field of electrocatalysts, and discloses a benzothiadiazole modified single-atom zirconium-doped metal copper electrode material and a preparation method and application thereof. The preparation method comprises the following steps: dissolving inorganic copper salt and inorganic zirconium salt, adding the inorganic copper salt and the inorganic zirconium salt into an alkaline solution, and performing hydrothermal reaction to obtain a single-atom zirconium-doped copper oxide precursor; dissolving benzothiadiazole, adding the benzothiadiazole into a dispersion solution of the single-atom zirconium-doped copper oxide precursor to obtain a mixed solution; spraying the mixed solution on a polytetrafluoroethylene film substrate loaded with copper nanoparticles to obtain a benzothiadiazole modified single-atom zirconium-doped copper oxide precursor electrode material; and performing electrochemical reduction treatment on the benzothiadiazole modified single-atom zirconium-doped copper oxide precursor electrode material to obtain a benzothiadiazole modified single-atom zirconium-doped metal copper electrode material. The electrode material is applied to an electro-reduction carbon dioxide reaction as a working electrode, exhibits excellent electro-reduction CO2 performance in an acidic environment, and realizes high-value-added C 2+ product with high selectivity.

The invention relates to the development of low-cost functionalised copper (II) hydroxide (f-Cu(OH)2) electrodes for energy storage technologies and electrochemical devices. By means of surface functionalisation using high-energy X-rays, the energy storage capacity of the material is increased and an environmentally friendly production process is provided. The electrodes produced by this method can be used in applications such as supercapacitors, portable electronic devices, and renewable energy systems.

The invention relates to the technical field of non-ferrous metal beneficiation, in particular to a flotation reagent composition for recycling micro-fine particle copper sulfide from copper oxide acid leaching residues and a beneficiation method of the flotation reagent composition. The flotation reagent composition for recovering copper sulfide from copper oxide acid leaching residues is characterized by comprising a collecting agent, a hydrophobic agglomeration agent and a foaming agent, and the collecting agent is ethyl thioacetate; the hydrophobic agglomeration agent is prepared from octadecyl triethoxy silane and kerosene; and the foaming agent is selected from terpilenol, methyl isobutyl carbinol or sec-octanol. The ethyl thioacetate serving as a collecting agent is stable in chemical property in an acid environment, weak in gangue mineral collecting capacity and good in selectivity in the copper sulfide mineral flotation process, and therefore the grade and the recovery rate of obtained copper sulfide concentrate are higher.

The application discloses a method for improving oxidation defects of copper lines in metal damascene integrated etching, which comprises the following steps: according to a metal damascene integrated etching process menu, forming a damascene structure with a groove and a hole connected below the groove in an interlayer dielectric layer, and exposing a surface of a lower copper layer below the bottom of the hole; performing an in-situ ashing step; inserting a pretreatment step to reduce copper oxide formed on the surface of the lower copper layer exposed below the bottom of the hole in the in-situ ashing step into copper; and continuing to perform other subsequent steps in the process menu. The application can avoid the generation of copper missing cavities below the bottom of the hole, and further causes the defects of open circuit, effectively improves the yield of wafers, and has the advantages of simple realization, low cost and remarkable effect.

The invention relates to absorbent paper as well as a preparation method and application thereof. The method comprises the following steps: pulping plant fiber pulp, adding sodium bicarbonate for pretreatment, and washing to obtain pretreated paper pulp; adding a dispersing agent, a wet strength agent and a composite antibacterial component into the pretreated paper pulp, and uniformly mixing to obtain mixed paper pulp; the composite antibacterial component is prepared from chitosan, polylysine and a modified copper oxide dispersion liquid; feeding the mixed paper pulp into a rotary screen paper machine to produce upper-layer single-layer wrinkling base paper, then compounding the upper-layer single-layer wrinkling base paper with lower-layer single-layer semi-forming base paper on which the macromolecular water-absorbent resin particles are scattered, and then drying to obtain the water-absorbent paper. The antibacterial rate of the absorbent paper on various pathogenic bacteria is larger than or equal to 99.5%, the antibacterial rate is still larger than or equal to 97% after 20 times of water washing, and the absorbent paper is high in water absorption speed, stable in physical performance, safe, environmentally friendly, controllable in cost, capable of being widely applied to the fields of hygienic products, medical dressings, food packaging and the like, simple in preparation process and suitable for industrial production.

This invention discloses a copper-based catalyst supported on macroporous alumina, its preparation, and its application. The macroporous alumina-supported copper-based catalyst comprises a macroporous alumina support and copper oxide and lanthanum oxide supported on its surface. The macroporous alumina-supported copper-based catalyst is particulate with a specific surface area of ​​250-500 μm. 2 / g, pore volume 1.0~2.0 cm³ 3 The copper-based catalyst supported on macroporous alumina has an average pore size of 16-30 nm. The content of each component in the catalyst, expressed as a mass percentage, is as follows: macroporous alumina support 79%-98.9%, copper oxide 0.1%-6%, and lanthanum oxide 1%-15%. The macroporous alumina-supported copper-based catalyst of this invention exhibits high catalytic activity and selectivity for higher alcohols in the ethanol-to-higher alcohol reaction, particularly showing higher selectivity for C6-C10 fatty alcohols.

The invention discloses a copper oxide tailing treatment method based on a ferric iron-sulfuric acid leaching system, which comprises the following steps: S1, pretreatment: copper oxide tailing ore pulp is fed into a two-section closed circuit ore grinding system, and the ore pulp after ore grinding is preheated to complete low-temperature activation before entering a leaching reactor; s2, low-temperature-gradient-dynamic leaching is conducted, specifically, the preheated ore pulp is pumped into a leaching reactor, and temperature control, Fe and acidity dynamic control and parameter regulation and control in the leaching process are conducted in the leaching process; and S3, solid-liquid separation is conducted, slurry obtained after leaching is completed is pumped into an automatic plate-and-frame filter press, obtained filter cakes are conveyed to a tailing pond, leachate is conveyed to an SX-EW workshop to be treated, and cathode copper is prepared. According to the method, copper oxide is fully leached, gangue acid consumption is reduced by 60-70%, and meanwhile waste heat in the reaction process, acid barren liquor obtained after leaching and waste water are effectively utilized.

This invention pertains to the field of glucose detection and discloses a copper-based MOF nanofiber membrane, its preparation method, and its application. The copper-based MOF nanofiber membrane is prepared by a method comprising the following steps: (1) adding a polyvinyl alcohol solution to a copper acetate solution to form a spinning solution; (2) electrospinning the spinning solution to obtain a copper-based nanofiber membrane; (3) calcining the copper-based nanofiber membrane in an air atmosphere to obtain a copper oxide fiber membrane; (4) mixing the copper oxide fiber membrane with an organic ligand, adding a solvent, and performing a hydrothermal reaction to obtain a copper-based MOF nanofiber membrane. The copper-based MOF nanofiber membrane prepared by this invention, as an electrode material for an enzyme-free glucose sensor, can improve conductivity, sensitivity, and anti-interference performance. Furthermore, the preparation method is simple and can be mass-produced.

The present invention relates to a copper oxide powder having a specific surface area of at least 25.0 m 2 / g to 70.0 m 2 / g, a crystallite size of not more than 150.0 Angstrom (A), and a chlorine content of less than 200 ppm, and a process for the production of the copper oxide powder.

This application relates to a copper-aluminum brazed terminal block and its manufacturing method, belonging to the field of power fittings technology. It consists of an aluminum-based terminal block with a copper sheet welded to it. The flux used in the welding is a high-performance, non-corrosive copper-aluminum flux composed of the following components: potassium fluoroaluminate, cesium ammonium fluoride, 1-butyl-3-methylimidazolium tetrafluoroborate, potassium fluorotitanate, and nano-copper oxide. The process involves chemically stripping the dense alumina film using highly active fluorine species released from a pure fluorinated ionic liquid, achieving film removal and avoiding the thermal effects of high temperatures. Secondly, a nano-titanium transition layer is generated in situ through a liquid-phase displacement reaction of potassium fluorotitanate on the nascent aluminum surface, achieving a qualitative change in joint strength from mechanical interlocking to intrinsic metallurgical bonding. Finally, the elimination of chlorine and the presence of a self-cleaning mechanism prevent the flux from absorbing moisture and hydrolyzing or causing electrochemical corrosion, thus ensuring long-term reliability and durability of the joint under harsh environments while achieving good connection performance.

The application discloses a copper oxide nanowire loaded silver monatomic catalyst, a preparation method and application thereof, and comprises a substrate, CuO nanowires and metal Ag monatomic atoms loaded on a CuO nanowire electrode layer; the substrate is a commercial copper foam, and the substrate is used for providing a copper source and preparing an array material of the metal Ag monatomic atoms on the CuO nanowires. The application adopts the above-mentioned copper oxide nanowire loaded silver monatomic catalyst, the preparation method and the application thereof, through silver monatomic atom modification, copper-silver metal interaction jointly regulates an intermediate product in an adsorption electrocatalytic reduction process, excellent electrocatalytic nitrophenol reduction performance is obtained, and the application is suitable for environmental pollution treatment and pharmaceutical synthesis development fields.

The invention discloses a metal oxide composite sodium ferric sulfate positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of sodium ion battery positive electrode materials. The metal oxide composite sodium ferric sulfate positive electrode material comprises the following raw materials in parts by mass: 1-20 parts of sodium sulfate, 2-40 parts of ferrous sulfate, 0.05-1 part of an antioxidant, 0.05-1 part of a carbon source and 0.01-2 parts of metal oxide, the metal oxide is at least one of ferrous oxide, ferric oxide, ferroferric oxide, manganese oxide, manganese dioxide, cobalt oxide, cobaltosic oxide, cobaltic oxide, vanadium monoxide, vanadium dioxide, vanadium trioxide, vanadium pentoxide, nickel oxide and copper oxide. The invention also discloses a preparation method and application of the metal oxide composite sodium ferric sulfate positive electrode material. The method provided by the invention can solve the problems of low conductivity and specific capacity of the existing sodium ferric sulfate positive electrode material, and has the advantages of low cost, strong process adaptability and wide application prospect.

The invention provides a regenerated graphite negative electrode material and a preparation method and application thereof, and belongs to the field of regenerated graphite negative electrode materials. The preparation method of the regenerated graphite negative electrode material provided by the invention comprises the following steps: mixing a negative electrode active substance in a waste battery with an acid solution, carrying out acid leaching, and then carrying out first filtration to respectively obtain an acid leaching solution containing copper ions and waste graphite; mixing the copper ion-containing pickle liquor with alkali liquor, carrying out precipitation reaction, and then sequentially carrying out second filtering and drying to obtain copper oxide; mixing the waste graphite, the copper oxide and asphalt, and sequentially calcining and pickling to obtain a regenerated graphite negative electrode material; the mass ratio of the waste graphite to the copper oxide to the asphalt is 100: (8-12): (5-15). The regenerated graphite negative electrode material prepared by the preparation method provided by the invention has good specific capacity and cycling stability.

The invention relates to a metallurgical treatment method of high-grade cobalt-containing copper sulfide concentrate, which comprises the following steps: carrying out first-stage presoaking on the cobalt-containing copper sulfide concentrate to obtain first-stage presoaking liquid and first-stage presoaking slag; grinding the first-stage presoaking residues until the particles of the first-stage presoaking residues are smaller than 200 meshes and account for 95 wt% or above, introducing oxygen, and performing second-stage presoaking to obtain second-stage presoaking liquid and second-stage presoaking residues; the copper grade of the cobalt-containing copper sulfide concentrate is 60 wt% or above. In the presoaking process, a large amount of copper oxide minerals and iron compounds are leached into a solution, so that the iron content in the presoaking residues is reduced, and generation of refractory substances such as copper ferrite is reduced; and compared with the raw ore amount, the ore amount is reduced by 40% or above, the follow-up recovery difficulty is remarkably reduced, and the leaching rate of the cobalt-containing copper sulfide concentrate is effectively increased.

The invention belongs to the technical field of catalysts, and particularly discloses a hydrodeoxygenation catalyst and a preparation method and application thereof. The catalyst contains a silicon-zirconium composite oxide carrier and a CuCo alloy loaded on the carrier, the molar ratio of silicon to zirconium in the silicon-zirconium composite oxide is (1-5): 1. The preparation method comprises the following steps: 1) preparing a precursor containing copper, cobalt, silicon and zirconium by adopting a sol-gel method; 2) roasting the precursor to obtain a copper oxide and a cobalt oxide which take the silicon-zirconium composite oxide as a carrier; and 3) carrying out reduction treatment on the material obtained in the step 2) to obtain the catalyst. The catalyst provided by the invention has high activity and alkane selectivity in hydrodeoxygenation reactions of various aldehyde ketone condensates, and can be used for hydrodeoxygenation reactions of aldehyde ketone condensation mixtures to produce aviation fuels.

A Cu x The preparation method of O / BNAD composite photocatalyst adopts a soft template method. Porous h-BN (p-BNNS) is prepared by high-temperature calcination of the precursor. Under low-temperature conditions, a diazotization reaction is used to generate p-BNNS diazonium salt, which is then coupled with an aromatic amine to obtain a porous boron nitride azo compound (p-BNAD) covalently linked by -N=N-azo bonds. Finally, copper oxide / boron azo nitride (Cu) is prepared by vacuum impregnation with copper salt. x This invention utilizes an O / BNAD composite photocatalyst for the efficient reduction of Cr(VI) and the inhibition of bacteria. Under simulated sunlight, Cu... x O / BNAD can effectively reduce Cr(VI) ions, with an apparent kinetic constant of 0.071 min. ‑1 The conversion rate is as high as 88.67%. Under visible light irradiation, it can effectively inhibit the reproduction of Gram bacteria, with an antibacterial rate of 98.0-99.9%.

This invention provides a method for producing copper nanowires that exhibits excellent selectivity and can be implemented with a simple configuration. [Solution] A method for producing copper nanowires, comprising the following step 1. Step 1: A mixture containing copper oxide (a), halogen ions (b), a nonionic polymer compound (c), alkyl quaternary ammonium ions (d), a reducing agent (e), and water (f) is heated to 50°C or higher to precipitate copper nanowires.

The invention relates to a copper microsphere and a preparation method and application thereof. The preparation method of the copper microspheres comprises the following steps that mixed powder containing copper oxide powder and graphite powder is subjected to first heat treatment in a reducing atmosphere, the copper oxide powder in the mixed powder is reduced into copper powder, and mixed copper powder is obtained; the mixed copper powder is subjected to second heat treatment, copper powder in the mixed copper powder is molten, and copper liquid is obtained; the molten copper is rapidly cooled to the temperature below the copper melting temperature, the molten copper is solidified into copper microspheres, the graphite powder is removed, and the copper microspheres are obtained; wherein the extremely fast cooling time is less than or equal to 5 ms. According to the preparation method, the sphericity degree of the copper microspheres can be effectively improved.