The present invention relates to a silicone microporous zeolite and the synthesis method of the silicone microporous zeolite, used to solve the problem that a frame structure of the microporous zeolite synthesized by the prior technology does not contain the silicone and to provide the microporous zeolite, in which the frame structure contains the silicone. The present invention contains the following mol relation: In the formula of (1/n) Al2O3: SiO2: (m/n) R, n is equal to 5-1000 and m is equal to 0.01-300. R is an alkyl, an alkane alkenyl or a phenyl. A solid nuclear magnetic map of Si29NMR is between -80ppm and +50ppm and includes at least one nuclear magnetic resonance spectral peak of Si29. A diffraction pattern of x-ray has a d-spacing maximum at the position of 11.14 plus or minus 0.05, 9.99 plus or minus 0.05, 9.74 plus or minus 0.05, 6.36 plus or minus 0.05, 5.99 plus or minus 0.05, 5.70 plus or minus 0.05, 5.57 plus or minus 0.05, 4.98 plus or minus 0.05, 4.26 plus or minus 0.05, 3.83 plus or minus 0.05, 3.75 plus or minus 0.05, 3.72 plus or minus 0.05, 3.65 plus or minus 0.05, 3.44 plus or minus 0.05, 3.32 plus or minus 0.05 angstrom and 3.05 plus or minus 0.05 angstrom. The microporous zeolite can serve as a sorbent or an activator component used in the transformation of the organic compounds.