The invention relates to the field of efficient utilization of tail gas waste heat, and specifically discloses a high-efficiency tubular heat exchanger device based on surface modification. The devicecomprises a cylinder body, an oil drain wire net, an oil receiving device, a self-rotation turbulence inner component, a bearing, a self-rotation turbulence inner component fixing shaft and a self-rotation turbulence inner component lower supporting plate; an air inlet and the oil receiving device are arranged at the bottom end of the cylinder body, the oil drain wire net and the self-rotation turbulence inner component are arranged above the air inlet; an air outlet is formed in the upper end of the cylinder body; and oleophobic and hydrophobic layers are arranged on the inner wall of the cylinder body and the surface of the self-rotation turbulence inner component. According to the device, oil-containing coking substances in the air can be filtered through the oil drain wire net, the coking substances can be collected by the oil receiving device, so that the part, entering the cylinder body to be adhered, of the oil-containing coking substances are reduced; the self-rotation turbulence inner component, under drive of air flows, carries out self-rotation to increase the disturbance of fluids, to improve the flushing effect of the air on a heat exchange surface, so that the scaleis effectively inhibited, and the heat exchange efficiency is improved; and the oleophobic and hydrophobic layers can prevent the oil-containing coking substances from being adhered, and the heat exchange efficiency is continuously improved.