The present application relates to a kind of purification method of
nitric oxide gas, comprising the following steps: crude
nitric oxide gas is imported into extraction column, and the extraction phase obtained after extraction is imported into resolution column for temperature resolution;
Nitric oxide gas resolved is imported into
ethanol absorption
tower after alkali washing
tower and condenser;Again imported into the adsorption
tower filled with 13X
molecular sieve;After adsorption, the gas is collected into product collection
bottle, and the purity of more than 99.99%
nitric oxide product is obtained.The present application uses
ferrous sulfate solution as extractant, extracts refined nitric
oxide, realizes the efficient extraction of nitric
oxide by the coordination reaction of
ferrous ion and nitric
oxide in the purification process, then uses
ethanol as absorbent, utilizes the
significant difference in
solubility of nitric oxide and
nitrous oxide in
ethanol, can selectively absorb the
nitrous oxide impurity difficult to remove, finally uses 13X
molecular sieve to further remove
nitrous oxide, which is beneficial to reduce
disproportionation reaction and improve product purity.