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1343 results about "Cyclic process" patented technology

Cyclic process: When a system returns to its original state after completing a series of changes, then it is known that a cycle is completed. This process is known as cyclic process. In a cyclic process the initial and the final state is same.

Method for preparing diethyl oxalate by coupling CO

The invention discloses a method for preparing diethyl oxalate by CO coupling reaction. By applying a gas phase method, CO is coordinated with ethyl nitrite and is catalyzed by bimetallic supported catalyzer to couplingly generate crude diethyl oxalate, the reaction is a self-sealing circulation process, the CO gas mixed with the ethyl nitrite coming from a regeneration reactor is preheated and then enters into a coupling reactor, after the reaction, the gas is separated by condensation, so that the colorless and transparent condensed diethyl oxalate liquid is produced, and the uncondensed gas containing NO enters into the regeneration reactor to react with ethanol and oxygen in order to generate ethyl nitrite which is again circulated back to the coupling reactor for continuous use. The invention is carried out on the basis of previous laboratory research and under the background of industrial production and fulfils the continuous run examination of the bench scale test and pilot magnification under the condition of industrial operation, the temperature of the coupling reaction is low, and the concentration of products is increased. The method has the advantages of more energy saving, no pollution and high benefit. The total conversion rate of the CO generated by reaction is one hundred percent, and the selectivity of diethyl oxalate is over ninety six percent.
Owner:TIANJIN UNIV

Anode or cathode pole piece of lithium ion battery and coating method thereof

The present invention relates to a lithium-ion battery anode or cathode pole piece and a spreading method of the anode pole piece or the cathode pole piece, wherein, the anode pole piece and the cathode pole piece consists of a foil, a conducting adhesive thin layer and an electrode active material layer in turn; the thickness of the conducting adhesive thin layer is five to ten microns. The electrode pole piece is made in the procedures that a layer of conducting adhesive thin layer in the thickness of five to ten microns are pre-coated on the surface of the foil before the sizing agent is spread, so that a conducting adhesive thin layer having good adhesive force, good conductivity and compact structure is formed on the surface of the foil. Then the electrode active material sizing agent is spread on the conducting adhesive thin layer, and is dried under an appropriate temperature to produce a required pole piece. The present invention can reduce the surface of the foil, and can improve the wetting quality of the sizing agent, thereby improving the adhesion performance of the anode material and the collecting body (aluminum foil) so as to reduce the powder-dropping of the battery during the cycling process, and to prolong the cycling service life of the battery; moreover, the present invention can reduce the content of the adhesive agent in the sizing agent, and improve the utilization rate of the active substance, and the method of the present invention does not produce negative influence on the performance of the battery.
Owner:CENT SOUTH UNIV

Polymer lithium ion battery and diaphragm thereof

The invention belongs to the technical field of polymer lithium ion batteries, in particular to a diaphragm for the polymer lithium ion battery. The diaphragm comprises a multihole base material, wherein an inorganic substance coating layer and an organic substance coating layer are coated on at least one surface of the multihole base material; and the organic substance coating layer is in island-type and / or linear distribution and coated on the surface of the multihole base material and / or the inorganic substance coating layer. Compared with the prior art, due to the inorganic substance coating layer, the diaphragm can keep relatively high heat stability and mechanical performance, so that the lithium ion battery has high safety performance; the organic substance coating layer has high imbibition swelling capacity, and an interface has high stability, so that the manufactured lithium ion battery has perfect mechanical performance; due to the distribution characteristic of the organic substance coating layer, spaces are provided for charging and discharging processes of a pole piece and a circulation process; and the problem of deformation of the polymer lithium ion battery is well solved. Furthermore, the invention also discloses a polymer lithium ion batter with the diaphragm.
Owner:NINGDE AMPEREX TECH +1

Modified diaphragm and preparation method and application therefor

The invention discloses a modified diaphragm. The modified diaphragm comprises a diaphragm substrate, and an electronic conductive coating layer and an inorganic hard coating layer positioned on the two surfaces of the diaphragm substrate respectively, wherein the electronic conductive coating layer is a mixed coating layer with graphene and a porous carbon material; and the inorganic hard coating layer is a nitrogen-carbon material coating layer, a nitrogen-silicon material coating layer, a carbon-boron material coating layer or a silicon-carbon material coating layer. The preparation method comprises the steps of uniformly coating the two surfaces of the diaphragm substrate with the electronic conductive coating layer and the inorganic hard coating layer respectively, and drying the two surfaces respectively obtain the modified diaphragm. The modified diaphragm has high diffusion and absorption capacity for an organic electrolyte, high ionic conductivity, and an obvious adsorption and blocking effect on poly-sulfur-lithium; in addition, the modified diaphragm can further restrain a shuttle effect, prevent battery short-circuit, effectively restrain the growth of negative electrode metal lithium dendrites in a cyclic process, prevent from punching the diaphragm, and protect the lithium negative electrode, so that the problem that the diaphragm is punched after dendrites formation is solved, and the safety performance of the battery is improved.
Owner:CENT SOUTH UNIV
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