The invention belongs to the technical field of diethyl oxalate production and specifically relates to an ethyl nitrite regeneration technological method and device used in a diethyl oxalate production process, which improve nitric oxide utilization rate in the regeneration process and reduce ethanol usage quantity. The device comprises a rotating packed bed, the gas inlet of the rotating packed bed is respectively connected with a nitrogen source, an oxygen source and a nitric oxide source, the liquid inlet is connected with an ethanol storage tank, the liquid outlet is connected with the inlet of an ethanol and water mixture storage tank, and the gas outlet is connected with a condenser I. The technological process comprises the following steps of: starting the rotating packed bed, carrying out contact reaction on nitric oxide, nitrogen, oxygen and absolute ethyl alcohol in the rotating packed bed to generate a gas phase and a liquid phase, condensing discharged gas phase and makingthe liquid phase flow into the ethanol and water mixture storage tank. The technological method has the advantages of high reaction efficiency, efficient utilization of all NO (nitric oxide) and little investment, and the device has the advantages of compact and simple structure, small size, convenience for operation, little energy consumption, simple processes, convenience for starting and stopping and the like.