10207 results about "Ethyl ester" patented technology

Pitch multiplication is performed using a two step process to deposit spacer material on mandrels. The precursors of the first step react minimally with the mandrels, forming a barrier layer against chemical reactions for the deposition process of the second step, which uses precursors more reactive with the mandrels. Where the mandrels are formed of amorphous carbon and the spacer material is silicon oxide, the silicon oxide is first deposited by a plasma enhanced deposition process and then by a thermal chemical vapor deposition process. Oxygen gas and plasma-enhanced tetraethylorthosilicate (TEOS) are used as reactants in the plasma enhanced process, while ozone and TEOS are used as reactants in the thermal chemical vapor deposition process. The oxygen gas is less reactive with the amorphous carbon than ozone, thereby minimizing deformation of the mandrels caused by oxidation of the amorphous carbon.

A pharmaceutical composition contains cyclosporine as the active ingredient. More specifically, the composition is an orally administered pharmaceutical formulation in the form of a spontaneous emulsion comprising cyclosporine, ethanol ethyl oleate and polyoxyethylene glycerol trioleate. A method for preparing an orally administered pharmaceutical composition involves first dissolving cyclosporine in ethanol. Polyoxyethylene glycerol trioleate and an oil component are then added, mixed and diluted in an aqueous media to form a spontaneous emulsion.

A process for the selective production of ethyl acetate by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethyl acetate is disclosed and claimed. In an embodiment of this invention reaction of acetic acid and hydrogen over platinum and copper supported on silica selectively produces ethyl acetate in a vapor phase at a temperature of about 250° C.

The present invention provides, in one aspect, a substantially pure ethyl ester of N-[[5-methyl-2-(1-methylethyl)cyclohexyl]carbonyl]glycine. In another aspect, disclosed is a method for producing substantially pure ethyl ester of N-[[5-methyl-2-(1-methylethyl)cyclohexyl]carbonyl]glycine. In still another aspect, disclosed are various consumer products comprising the substantially pure ethyl ester of N-[[5-methyl-2-(1-methylethyl)cyclohexyl]carbonyl]glycine disclosed herein.

The invention discloses a method for preparing diethyl oxalate by CO coupling reaction. By applying a gas phase method, CO is coordinated with ethyl nitrite and is catalyzed by bimetallic supported catalyzer to couplingly generate crude diethyl oxalate, the reaction is a self-sealing circulation process, the CO gas mixed with the ethyl nitrite coming from a regeneration reactor is preheated and then enters into a coupling reactor, after the reaction, the gas is separated by condensation, so that the colorless and transparent condensed diethyl oxalate liquid is produced, and the uncondensed gas containing NO enters into the regeneration reactor to react with ethanol and oxygen in order to generate ethyl nitrite which is again circulated back to the coupling reactor for continuous use. The invention is carried out on the basis of previous laboratory research and under the background of industrial production and fulfils the continuous run examination of the bench scale test and pilot magnification under the condition of industrial operation, the temperature of the coupling reaction is low, and the concentration of products is increased. The method has the advantages of more energy saving, no pollution and high benefit. The total conversion rate of the CO generated by reaction is one hundred percent, and the selectivity of diethyl oxalate is over ninety six percent.

Methods and systems for the production of ethyl acetate are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and mixing of a carbonyl co-reactant (e.g. acetic acid, acetaldehyde) with ethanol. The high shear device may allow for lower reaction temperatures and pressures and may also reduce reaction time with existing catalysts.

Improved compositions comprise a polymer and carbon fibers, such as nanotubes. In some embodiments, the carbon fibers, e.g., nanotubes, can be mechanically blended or incorporated into the polymer, while in some embodiments carbon nanotubes also may be covalently bonded to the polymer to form corresponding covalent materials. In particular, the polymer can be covalently bonded to the side walls of the carbon nanotubes to form a composite with particularly desirable mechanical properties. Specifically, the bonding of the polymer to the nanotube sidewall can provide desirable mechanical properties of the composite due to the orientation relative to other types of association between the nanotubes and the polymer. The processing of the nanotubes can be facilitated by the dispersion of the nanotubes in an aqueous solution comprising a hydrophylic polymer, such as ethyl vinyl acetate. A dispersion of nanotubes can be combined with a polymer in an extrusion process to blend the materials under high shear, such as in an extruder. In general, various articles can be formed that take advantage of the properties of the composite materials incorporating a polymer and carbon fibers, such as carbon nanotubes.

PCT No. PCT/CN97/00004 Sec. 371 Date Sep. 17, 1998 Sec. 102(e) Date Sep. 17, 1998 PCT Filed Jan. 20, 1997 PCT Pub. No. WO97/25968 PCT Pub. Date Jul. 24, 1997The invention relates to a tooth-whitening varnish composition, comprising 6-20% of carbamide peroxide, 2-9% of film forming agent and 77-88% of volatile organic solvent, based on the total weight of the composition. The volatile organic solvent is selected from ether, ethylacetate, ethyl alcohol, or acetone. The film forming agent is artificial or natural material selected from cellulose, polyvinyl, butyral, coumarone resin or shellac. The composition can rapidly form films on dry tooth surfaces, and a remarkable tooth-whitening effect can be obtained.

Process for converting synthesis gas to ethanol, including the steps of 1) introducing synthesis gas, together with methyl ethanoate and/or ethyl ethanoate, into an alcohol synthesis unit to produce methanol and ethanol, 2) separating the methanol from the ethanol of step 1, 3) introducing methanol, from step 2, together with CO, into a carbonylation unit in the presence of a methanol carbonylation catalyst, to produce ethanoic acid, and 4) introducing ethanoic acid, from step 3, together with methanol and/or ethanol, into an esterification unit to produce methyl ethanoate and/or ethyl ethanoate. In step 5), methyl ethanoate and/or ethyl ethanoate, produced in step 4, are fed into the alcohol synthesis unit of step 1, and in step 6) ethanol from step 2 is recovered.

A process for hydrogenating acetic acid to form of ethyl acetate and mixtures of ethyl acetate and ethanol. The hydrogenation is done in the presence of catalyst, preferably on a support that optionally includes a support modifier.

A composition comprising purified water using ozonation, ionization, or distillation or any combination thereof wherein alcohol may be substituted for, or combined with water at least one emollient including but not limited to chitosan, and aloe vera gel, individually or in any combination; an oil component with spf boosting agents including but not limited to; ethyl macadamiate, non-toxic silicone oil and essential oils, butter milk, waxes impregnated with inorganic sun-block or sunscreen agent and organic/inorganic micronized particles, wood powder and bentonite clay, keratin, either individually or in any combination; at least one inorganic sun-block or sunscreen agent including any metal oxide, glass microsphere, silica and silica compound, and optionally metal oxide pigments with particles that are micronized, submicronized, nanoparticle sized, or otherwise individually or in any combination that can be homogenized in either a water phase, a water-aloe phase, an oil phase or any phase of said composition; at least one emulsifier wherein said emulsifier includes but is not limited to a phospholipid and/or liposome or an aloe vera gel or an ester of coconut oil individually or in any combination, for emulsifying the water, water-aloe, or oil phase in combination with an homogenizer; where any of components are preferably mixed with an homogenizer and where an appropriate thickening agent including but not limited to xanthan gum, carageenan, either individually or in any combination is added as required.

Certain applicator liquids and application techniques are described, which can be used to form nanotube films or fabrics of controlled properties. An applicator liquid for preparation of a nanotube film or fabric includes a controlled concentration of nanotubes dispersed in ethyl lactate. The controlled concentration is sufficient to form a nanotube fabric or film of preselected density and uniformity.

The invention provides a preparation method of triazine structure containing benzoxazine intermediate, which sequentially includes: (1) performing synthetic reaction of aldehyde compound and amine compound at a molar ratio of at least 1:1 which includes adding aldehyde compound and solvent of at least one of clean water, methanol, ethanol, isopropanol, and ethyl acetate into a reactor at the room temperature under the normal pressure to obtain mixed solution with aldehyde mass concentration of no greater than 95%, adding amine compound while stirring, and reacting at 0-100 DEG C under the normal pressure for at least 15 minutes to obtain the reactant liquor; (2) pouring into the cleaning solution, stirring and cleaning, and filtering to collect solid substance, or directly filtering the reactant liquor to collect the solid substance; and (3) drying the solid substance obtained in step (2) at 30-100 DEG C.

Porous polymeric membranes including Halar (poly (ethylene chlorotrifluoroethylene)) and related compounds and the methods of production thereof which avoid the use of toxic solvents. Preferred solvents, coating agents and pore forming agents are citric acid ethyl ester or glycerol triacetate. The membranes may be in the form of a hollow fibre or flat sheet, and may include other agents to modify the properties of the membrane, such as the hydrophilic/hydrophobic balance. Leachable agents may also be incorporated into the membranes.

The invention relates to two synthetic methods of 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine and a salt substitute thereof. The first synthetic method comprises the following steps of: obtaining a final product through the steps of cyclodehydration, hydrogenation, coupling, saponification, recrystallization and the like by using epsilon-benzoyloxycarbonyl-L-lysine and p-nitryl monoethyl fumarate as starting materials. The second synthetic method comprises the following steps of: obtaining the final product through the steps of cyclodehydration, coupling, saponification, recrystallization and the like by using N-6-trifluoroacetyl-L-lysine and the p-nitryl monoethyl fumarate (or p-nitryl monoethyl fumarate acyl chloride) as the starting materials. Meanwhile, the salt substitute of the 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine can also be generated by directly carrying out substitution reaction on the 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine as a reaction product and corresponding salt.

The invention relates to a preparation method of a super-hydrophobic cellulose material with a micro-nano structure. The method comprises the following steps: (1) adding ethyl orthosilicate and functionalized siloxane into an ethanol system containing deionized water to obtain a dispersion liquid of functionalized silica particles A in the presence of ammonium hydroxide serving as a catalyst; with the dispersion liquid of functionalized silica particles A as seeds, sequentially adding the ethyl orthosilicate, the functionalized siloxane, the deionized water, the ammonium hydroxide and the ethanol so as to obtain a dispersion liquid of functionalized silica particles B; (2) performing ultrasonic dispersion on the two types of functionalized silica particles in dimethylformamide, then adding a hydrophobic polymer and a low surface energy additive into the system and evenly stirring so as to form white dispersion liquid; and (3) coating the white dispersion liquid obtained in the step (2) on a natural cellulose material in a direct spraying manner or a spin coating manner so as to obtain the super-hydrophobic cellulose material with the micro-nano structure. The coating material has strong scouring resistance and acid-alkali resistance besides the excellent hydrophobic property.

The invention discloses a preparation method for a Beta zeolite molecular sieve with a hierarchical porous structure. Ethyl orthosilicate is used as a silicon source, sodium metaaluminate is used as an aluminum source, hexaammonio cationic quaternary ammonium surfactant is used as a template, and then the hierarchical porous zeolite molecular sieve containing meso pores and Beta zeolite micropores is prepared by using a hydro-thermal synthesis process under an alkaline condition. According to the invention, the hexaammonio cationic quaternary ammonium surfactant is used as a Beta zeolite structure guiding agent and generates micropores, aggregation of hydrophobic long-chain alkyl groups on the surfactant forms the meso pores, so the prepared Beta zeolite molecular sieve has both meso pores and the crystalline micropores. The structure with both the meso pores and the micropores enables defects of a single pore structure to be avoided and mass transfer efficiency to be improved, and the Beta zeolite molecular sieve has a wide application prospect in aspects of macro-molecular catalysis, adsorption, separation, etc.

A non-aqueous electrolyte secondary battery comprising a negative electrode, a positive electrode and an electrolyte having a lithium salt dissolved in a non-aqueous solvent characterized in that said non-aqueous solvent contains a vinylethylene carbonate compound represented by the general formula (I) in an amount of from 0.01 to 20% by weight is subject to minimized decomposition of the electrolyte and can provide a high capacity as well as exhibits excellent storage properties and cycle life performance.

wherein R¹, R², R³, R⁴, R⁵ and R⁶ each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.

The present invention discloses a method for preparing low density silica aerogel under normal pressure. The method comprises: mixing tetraethoxysilane, water and ethanol according to a volume ratio of 1:0.5-19:1-29, adding an acid to adjust the pH value to 3-4, carrying out catalysis hydrolysis, adding an alkali to adjust the pH value to 6-6.5, carrying out catalysis gelating for 8-10 min to obtain a wet gel, aging the wet gel for 6-36 h at a room temperature, adding n-hexane to carry out solvent replacement for 6-36 h, immersing in a trimethylchlorosilane and n-hexane mixed solution to carry out hydrophobic modification for 12-15 h, adopting a n-hexane washing solution to remove the modification solution, placing into a muffle furnace to heat to a temperature of 30-250 DEG C, drying, and finally cooling to a room temperature to obtain the silica aerogel. Test results show that the density of the SiO2 aerogel is 50-80 kg/m<3> and is significantly lower than the density of the SiO2 aerogel prepared under the normal pressure dry condition in most of the public reports.

An application of 2-cyno-3-amino-3-ethyl phenylacrylate in preventing and controlling plant diseases and eliminating the petes which are caused by fusarium, uredinale, gray mold, etc. A synergistic agricultural chemical containingsaid compounds is also disclosed.

The invention discloses an organic-inorganic hybrid super-hydrophilic coating as well as a preparation method and an application thereof. The preparation method comprises: firstly carrying out hydrolysis condensation polymerization by a sol-gel method with ethyl orthosilicate used as a precursor, hydrochloric acid used as a catalyst, ethanol used as a solvent, a silane coupling agent used as a modifier and a proper amount of water to obtain a modified silica sol, then carrying out free radical polymerization on the modified silica sol and reactive hydrophilic monomers to obtain an organic-inorganic hybrid material, and carrying out solvent replacement to obtain an aqueous organic-inorganic hybrid super-hydrophilic coating. The coating is coated on plastics, glass or metal substrates through dipping or brushing to form a coating layer, the coating layer has a contact angle with water less than 5 degrees, the adhesion force with the substrates of level-0 and the hardness greater than 6H, and water drops can spread out quickly on the coating layer.

An integrated process is described for producing biodiesel from oleaginous seeds, preferably castor bean seeds, comprising a transesterification reaction where the seeds themselves react with anhydrous ethyl alcohol in the presence of an alkaline catalyst. The resulting ethyl esters are then separated by decantation and neutralized and used as fuel for diesel engines, co-solvents for diesel and gasoline mixtures with anhydrous or hydrated ethyl alcohol. The solid fractions may be used as fertilizers, for feeding cattle and as a raw material for producing ethyl alcohol.

The invention discloses an extracting polyphenol, theanine, tea polysaccharide and tea pigment method from tea, which is characterized by the following: using deionized water for lixiviating tea at constant temperature with continuous flow upstream at multi-speed; adopting microstrainer to dislodge the foreign matter of raffinate; using hyperfiltration for putting-off pectin and protein; concentrating by hyperfiltration and dehydration; extracting tea polyphenol by acetic acid ethyl ester and recovering dissolvant; stripping caffeine of extracting extract phase, pesticide residue and dissolvant by CO2 supercritical fluid; getting tea polyphenol by low-temperature nitrogen spray-drying; using alcohol separation and low temperation vacuum drying by hyperfiltration trapped fluid to prepare tea polysaccharide; separating alcohol recrystallization by basic copper carbonate and hydrogen sulfide to get theanine; using enzymatic oxidation and alkaline air to oxygenate remain polyphenols substance of liquid phantom; getting tea pigment by hyperfiltration dehydration compression and vacuum drying; merging caffeine form carbon dioxide above-critical fluid and caffeine from carrene; recovering dissolvent; using deionized water for washing; obtaining caffeine by recrystallization vacuum drying.

The present invention relates to an acrylic pressure sensitive adhesive composition comprising (meth)acrylic copolymers including alkyl(meth)acrylic acid ester monomer having 1˜12 carbon atoms of alkyl group, characterized in that the gel content is 10˜55%, the swelling ratio is 30˜110, the weight average molecular weight of sol eluted from the adhesive by ethyl acetate is at least 800,000, the molecular weight distribution is 2.0˜7.0; and a polarizer and a liquid crystal display comprising the above composition show excellent durability under a high temperature and humidity condition, and can improve the light leakage phenomenon and provide excellent operability at the time of manufacturing polarizer by effectively providing high modulus and stress release property.

The LixMn2O4 powder for cathode active material of a lithium secondary battery of the present invention is prepared by a method of comprising the steps of mixing an acetate aqueous solution using Li acetate and Mn acetate as metal precursors, and a chelating agent aqueous solution using PVB, GA, PAA or GC as a chelating agent; heating the mixed solution at 70 DIFFERENCE 90 DEG C. to form a sol; further heating the sol at 70 DIFFERENCE 90 DEG C. to form a gel precursor; calcining the produced gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours under atmosphere. The cathode active material, LixMn2O4 powder for a lithium secondary battery in accordance with the present invention has a uniform particle size distribution, a high crystallinity and a pure spinel-phase, and a particle size, a specific surface area, a lattice of a cubic structure and the like can be controlled upon the preparing conditions. The present invention also provides a method of preparing LiNi1-xCoxO2 powder, which comprises the steps of providing a gel precursor using PAA as a chelating agent and hydroxide, nitrate or acetate of Li, Co and Ni as metal precursors; heating the gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours to form a powder. The LixMn2O4 and LiNi1-xCoxO2 powder of the present invention can be used for a cathode active material of a lithium secondary battery such as a lithium ion battery or lithium polymer battery.

The invention relates to a method for extracting dihydromyricetin, ampelopsis grossedentata amylase and ampelopsis grossedentata polyphenol from ampelopsis grossedentata. The method comprises the following processing steps of: (a) crushing raw materials: drying and crushing fresh ampelopsis grossedentata stem leaves; (b) leaching: extracting with hot water and centrifugally collecting supernatant fluid; (c) concentrating: decompressing and concentrating the supernatant fluid I, cooling, standing still and centrifugally collecting precipitate and supernatant fluid II; (d) extracting dihydromyricetin: recrystallizing and drying the precipitate in vacuum to obtain dihydromyricetin; (e) alcoholizing: decompressing and concentrating the supernatant fluid II, depositing in alcohol and centrifugally collecting a precipitate and supernatant fluid III; (f) extracting crude polysaccharides: purifying the precipitate, drying in vacuum or spraying and drying to obtain ampelopsis grossedentata amylase; and (g) extracting ampelopsis grossedentata polyphenol: decompressing and concentrating the supernatant fluid III, extracting with ethyl acetate, concentrating and drying to obtain ampelopsis grossedentata polyphenol or absorbing with AB-8 resin, eluting with distilled water, eluting with ethanol and collecting eluate, concentrating and drying in vacuum to obtain ampelopsis grossedentata polyphenol. The method has the advantages of low cost, higher product yield and environmental protection, is suitable for industrial continuous production and can comprehensively develop and utilize ampelopsis grossedentata resources and improve the economic benefits.

The invention discloses a nanosilicon dioxide modified polyurethane elastomer and a preparation method thereof. The preparation method comprises the steps of enabling polyether glycol, isocyanate and micromolecular dihydroxy alcohol to be subjected to addition polymerization reaction to prepare a polyurethane prepolymer as a component A; uniformly mixing a chain extender, ethyl silicate and a silane coupling agent, carrying out in-situ hydrolysis on ethyl silicate to form nanosilicon dioxide particles, performing surface hydrophobicity modification on the nanosilicon dioxide particles by using the silane coupling agent, and removing a solvent in the mixture to obtain a component B; uniformly mixing the component A and the component B according to a certain ratio, degassing, pouring and carrying out vulcanization molding to obtain the nano-modified polyurethane elastomer. By using the preparation method, the uniform dispersion of silicon dioxide particles in polyurethane is realized, the enhancement effect of nanoparticles is sufficiently taken, the prepared polyurethane elastomer is obtained by crosslinking the nanosilicon dioxide particles, and the heat resistance and chemical stability of the polyurethane elastomer can be remarkably improved; in addition, the nanosilicon dioxide modified polyurethane elastomer can meet the requirements of a sealing element for mechanical strength, wear resistance, high elasticity and oil resistance and has a wide market prospect.

The comprehensive process of extracting tea polysaccharide, tea polyphenol, theanine and coffine from tea includes the following steps: water or organic solvent extraction of tea powder under the action of microwave, concentration, precipitation and water dissolving the extract liquid, salt separating to eliminate protein and separation in gel column and drying to obtain tea polysaccharide; chloroform extraction of the raffinate, ethyl acetate extraction of the chloroform raffinate and drying to obtain tea polyphenol; No. 732 cationic exchange resin extraction of the ethyl acetate raffinate, concentration, crystallization and drying to obtain theanine; and crystallizing and drying the chloroform extract liquid to obtain coffine. The present invention has the advantages of short extraction time, high extraction rate, less loss of active matter, etc.

The invention relates to the technical field of lithium ion electrolytes, and in particular relates to a lithium-ion battery electrolyte with both high and low temperature performances. The electrolyte comprises lithium hexafluorophosphate, mixed organic solvents, filming additives, additives for improving the dielectric constant and the low temperature infiltration capability, and a lithium salt type additive, wherein the mixed organic solvents comprise a carbonic ester solvent and a linear carboxylic ester solvent; the linear carboxylic ester solvent in the mixed organic solvents is one or a mixture of more than two of ethyl propionate, propionic acid n-propyl ester, n-propyl acetate, acetic acid n-butyl ester and isobutyl acetate; and the additives for improving the dielectric constant and the low temperature infiltration capability are one or a mixture of more than two of fluoro ethylene carbonate, difluoro ethylene carbonate and 4-trifluoromethyl ethylene carbonate. A battery prepared from the lithium-ion battery electrolyte with both high and low temperature performances is long in service life, and both the good low temperature discharge performance of the battery is ensured, and the storage performance of the battery at the high temperature of 60 DEG C is effectively considered.

A fluoride POSS acrylic resin block copolymer resin and its synthesis are disclosed. The molecular-weight of copolymer Mn is 20000-60000, Mn/Mw is 1.1-1.5, contact angle between coating and water is 85-120degree. The process is carried out by adding components into reactor to obtain methyl acrylate performed polymer with Br end capping, reacting with CuBr, PMDETA and F-POSS, removing catalyst from reactant, depositing while filtering by methanol, vacuum drying to constant weight to obtain the final product. The polymer powders can be dissolved into acetic ether, acetone, 1,2-dichloroethane, dioxane and cyclohexanone or their mixtures, then it can be used for coating or filming.