4results about How to "Reduce purification costs" patented technology

This invention discloses the application of a Ni-based catalyst in the anti-CO poisoning hydrogenation reaction of a liquid organic hydrogen support, aiming to solve the technical problem of CO poisoning in existing LOHC hydrogenation catalysts. It uses CO-containing crude hydrogen as the hydrogen source to achieve the hydrogenation reaction. The Ni-based catalyst has an M / Ni reverse-phase structure, using hydrogen-dissociated metallic Ni as the support, and loading nano-metal oxide M as the supported phase to construct reverse-phase interfacial active sites. The metal M is a combination of Zr and Al, with the molar fraction of the supported phase metal M ranging from 10% to 25% based on 100% of all metals in the catalyst. The catalyst preparation method of this invention is simple and easy to implement, possessing a non-traditional supported reverse-phase structure. When applied to the anti-CO poisoning hydrogenation reaction, it exhibits superior activity compared to traditional supported catalysts. Furthermore, the reaction system is clean, safe, and reproducible, allowing for effective recycling and making it suitable for industrial production, showing promising application prospects.

This application discloses a multi-module combined aquaculture water purification method and system, relating to the field of water purification technology. The method includes: acquiring the rated aquaculture load and module distribution information of multiple aquaculture modules; determining the initial connection topology between the multiple water purification modules through a priori empirical model; collecting real-time monitoring data from the multiple aquaculture modules and calculating the real-time water quality load; optimizing water purification parameters based on simulation analysis; and controlling the aquaculture water purification in the target scenario based on the optimized water purification parameter results. This solves the technical problem of traditional aquaculture water purification methods being unable to dynamically adjust according to the actual load and distribution characteristics of different aquaculture modules, leading to low purification efficiency.

This invention relates to the field of organic compound preparation technology, specifically a method for preparing 11-triglycerides of carbonate via low-temperature acylation. This method uses glycerol and undecanoyl chloride as raw materials, employing a synergistic system of a "composite acid-binding agent + Lewis acid catalyst," and combines in-situ dehydration technology and a stepwise heating strategy in a dual-solvent environment to achieve efficient synthesis. The specific steps include: under nitrogen protection, dissolving glycerol in a dichloromethane-toluene dual solvent, adding a composite acid-binding agent of pyridine and N,N-diisopropylethylamine, anhydrous zinc chloride catalyst, and 4A molecular sieve for in-situ dehydration; dropwise adding undecanoyl chloride at a low temperature of 5-10°C, followed by sequential heating to 30°C for 2-3 hours and then reacting at 50°C for 12-16 hours; and post-processing using a combined process of filtration-multi-stage extraction-membrane separation-column chromatography. This invention provides mild reaction conditions, effectively suppresses side reactions, produces high-purity products, increases molar yield, and reduces solvent toxicity and purification costs.

This invention belongs to the field of heterocyclic pharmaceutical intermediate synthesis technology, specifically disclosing a method for synthesizing N-alkoxycarbonyl-4-amino-4-alkylpiperidine. Using N-alkoxycarbonylpiperidine-4-carboxylate as the starting material, the target product is obtained through a four-step reaction involving alkylation, hydrolysis, amidation, and Hoffmann rearrangement. This invention, through the adaptation and control of the substrate, synthetic route, and synthetic conditions, can solve the problems existing in the substrate-based synthetic route, thereby improving product yield and quality. The method described in this invention achieves a total yield of ≥60% of the target product, with key impurities all <0.1%. The process is safe and controllable, suitable for both laboratory-scale and industrial-scale production.