692 results about "Sulfate zinc" patented technology

The invention relates to the field of zinc ion batteries, in particular to a disaccharide eutectic gel electrolyte and a preparation method and application thereof. The preparation method of the disaccharide eutectic gel electrolyte comprises the following steps: firstly, adding disaccharide, choline compounds and zinc sulfate into deionized water, heating and uniformly stirring, then adding a polyacrylamide monomer as well as a thermal initiator and a cross-linking agent which are adaptive to a polymerization reaction with the monomer, and carrying out thermal initiation to form the disaccharide eutectic gel electrolyte. According to the invention, two additives, namely disaccharide and choline, are ingeniously introduced into the traditional gel electrolyte, and the two additives can form the stable disaccharide eutectic gel electrolyte together in the heating and stirring process. According to the innovative strategy, a polyacrylamide hydrogen bond network is enhanced, the cycle performance of the gel electrolyte battery is greatly improved, the configuration entropy of the system is increased due to introduction of the multi-component additive, the problem that an existing gel zinc battery is low in cycle performance is solved, and application of the gel zinc battery in a harsh temperature environment becomes possible.

The invention discloses a method for detecting antipsychotic drugs and metabolites thereof in a sample and a kit thereof, and relates to the technical field of biological detection.The kit comprises calibrators, quality control products, internal standard solutions and protein precipitators of 13 to-be-detected substances, and the protein precipitators comprise a zinc sulfate aqueous solution containing methanol, 13 analytes can be simultaneously detected, the separation degree of the to-be-detected substance is high, the detection time is short, the required sample size is small, and the method is suitable for TDM high-throughput detection of common antipsychotic drugs.

The invention discloses a copper surface micro-etching coarsening solution for a fine circuit as well as a preparation method and application of the copper surface micro-etching coarsening solution, and relates to the technical field of printed circuit board manufacturing. The copper surface micro-etching coarsening solution for the fine circuit is prepared from, by mass concentration, 60 g / L to 100 g / L of sulfuric acid, 40 g / L to 60 g / L of hydrogen peroxide, 0.5 g / L to 2 g / L of zinc sulfate, 10 g / L to 30 g / L of copper ions, 0.5 g / L to 1 g / L of pyridine heterocycle-containing Schiff base, 10 g / L to 100 g / L of ethyl alcohol, 1 g / L to 3 g / L of 2-mercaptobenzothiazole, 1 g / L to 5 g / L of methionine and 1 g / L to 5 g / L of polyacrylamide. According to the copper surface micro-etching coarsening solution, the 2-mercaptobenzothiazole and the methionine in the copper surface micro-etching coarsening solution can enable the copper surface to form a honeycomb structure under the low micro-etching amount, the zinc sulfate and the pyridine heterocyclic ring-containing Schiff base can form a composite film layer with copper ions on the surface of the honeycomb structure, and the interlayer binding force is improved.

The invention discloses a saline-alkali soil improvement and disease resistance double-effect controlled release fertilizer and a preparation method thereof. The fertilizer comprises 18-22% of biochar, 12-18% of furfural residues, 8-12% of cow dung compost and 6-10% of potassium humate. 5-7% of aluminum sulfate, 4-6% of sulfur and 3-5% of zeolite; the microbial inoculum comprises the following components in percentage by weight: 1.5 to 2.5 percent of saline-alkaline bacillus, 0.8 to 1.2 percent of bacillus subtilis and 0.8 to 1.2 percent 8-12% of a sodium polyacrylate coating, 4-6% of a sulfur coating and 1-3% of polyglutamic acid; 0.8 to 1.2 percent of humic acid chelated iron, 0.8 to 1.2 percent of algal polysaccharide and 0.8 to 1.2 percent of urease inhibitor; 0.8 to 1.2 percent of zinc sulfate, 0.5 to 1.0 percent of manganese sulfate and 0.5 to 1.0 percent of borax. The fertilizer can reduce the pH and conductivity of soil, increase the organic matter content of the soil and effectively improve the physicochemical properties of the soil, meanwhile, by adding the microbial agent, the disease resistance of crops can be effectively improved, the morbidity and disease index of the crops can be reduced, and nutrient release of the fertilizer has a sustained and controlled release characteristic; the initial release rate and the cumulative release rate of nitrogen are both lower than those of common chemical fertilizers, and the cumulative release rate of nitrogen is moderate within 60 days, so that the nutrient requirements of crops in different growth stages can be met.

The invention provides a wormwood planting fertilizer and application thereof, and belongs to the technical field of agricultural planting. The wormwood planting fertilizer is prepared from the following components in parts by weight: 10 to 15 parts of humic acid, 5 to 8 parts of amino acid, 2 to 3 parts of wormwood extract A, 3 to 5 parts of wormwood extract B, 15 to 20 parts of nitrogen-phosphorus-potassium compound fertilizer, 0.01 to 0.03 part of sodium selenite, 0.02 to 0.05 part of zinc sulfate, 0.3 to 0.5 part of cellulose nanocrystal, 0.01 to 0.03 part of malic acid and 0.1 to 0.2 part of sodium alginate. By means of the two-dimensional design that components synergistically enhance absorption and the planting process is matched with the growth rhythm, the problems that in traditional fertilization, nutrients are unbalanced, the selenium and zinc utilization rate is low, and pest and disease damage prevention and control are difficult are solved, efficient absorption of wormwood on microelements, accurate supply of nutrients and reduction of the pesticide use amount are achieved, and the yield of the wormwood is increased. The yield and the medicinal quality are synergistically improved.

The invention discloses a zinc sulfate solution impurity removal method based on a three-section countercurrent purification process, and belongs to the technical field of hydrometallurgy. Heating the zinc sulfate solution containing impurities to 60-70 DEG C in a first-section reaction tank, reacting for 30-60 minutes, adding the second-section pressure filter residue, and performing pressure filtration to obtain a first-section purified solution and a first-section pressure filter residue; the first-section purified liquid is transferred into a second-section reaction tank, zinc powder and third-section filter residues are added, the adding amount of the zinc powder is 0.8-2 times of the theoretical amount of the zinc powder needed for metal cadmium replacement, the temperature is increased to 70-80 DEG C, a reaction is conducted for 60-90 min, and second-section purified liquid and second-section filter residues are obtained after filter pressing; the second-section purified liquid is transferred into a third-section reaction tank, zinc powder is supplemented, the adding amount is 180-300 times of the theoretical amount of the zinc powder needed for metal cobalt replacement, the temperature is increased to 80-90 DEG C, a reaction is conducted for 90-120 min, and third-section purified liquid and third-section filter pressing residues are obtained after filter pressing; and returning the third-section press-filter residue to the second-section reaction tank, returning the second-section press-filter residue to the first-section reaction tank, and reversely recycling. The method has the advantages of sufficient reaction kinetics, high utilization rate of zinc powder, low zinc content in purified slag, simple process, deep impurity removal, low consumption and high efficiency.

The invention provides a poly-like flocculation flotation method for micro-fine particle galena and micro-fine particle sphalerite. The method comprises the following steps: firstly, mixing to-be-treated ore samples containing micro-fine particle galena and micro-fine particle sphalerite with the particle sizes of less than or equal to 20 microns with water to obtain to-be-treated ore pulp, then sequentially adding zinc sulfate, diethyldithiocarbamate, polyoxyethylene, polyaluminum chloride and a foaming agent, and carrying out air inflation flotation and foam scraping to obtain galena concentrate and tailings. ZnSO4 is adsorbed on the surface of the micro-fine-particle sphalerite in advance and generates a synergistic effect with polyaluminum chloride added subsequently, and N, N '-diethyldithiocarbamate is adsorbed on the surface of the micro-fine-particle galena in advance and generates a synergistic effect with polyoxyethylene added subsequently, so that galena hydrophobic floccules and sphalerite hydrophilic floccules with proper apparent particle sizes are formed; on one hand, the flotation recovery rate of the micro-fine particle galena can be increased, and on the other hand, mechanical entrainment of the micro-fine particle sphalerite can be reduced, so that the flotation separation efficiency of the micro-fine particle lead zinc ore can be effectively improved.

The invention belongs to the technical field of energy storage system device materials, and particularly relates to a modified silk amino acid-based gel electrolyte as well as a preparation method and application thereof. The method comprises the following steps: S1, uniformly mixing and stirring 15 to 30g of acrylamide, 50 to 60g of zinc sulfate heptahydrate, 0.1 to 1g of silk amino acid and 100g of water; adding 5mL to 10mL of ethanol, and uniformly shaking; then sequentially adding a proper amount of N-N methylene bisacrylamide and a photoinitiator, and continuously stirring until the solution is clear to obtain an electrolyte; s2, dropwise adding the prepared electrolyte into a polytetrafluoroethylene (PTFE) plate, and covering the polyurethane fiber membranes obtained by electrostatic spinning on the two sides; and carrying out light curing under ultraviolet irradiation to obtain the modified silk amino acid (M-SAA) gel electrolyte. According to the invention, silk amino acid (SAA) is introduced to construct a compact protective film with a beta folding structure, so that zinc dendrite growth and side reaction are inhibited, and the stability of the zinc negative electrode of the battery and the cycle performance of the battery are improved.

The invention discloses an environment-friendly composite tree wound healing agent and a preparation method and application thereof, and belongs to the technical field of garden maintenance, the environment-friendly composite tree wound healing agent comprises the following raw materials by weight: 40-70 parts of a film forming substrate, 10-20 parts of an active component, and 10-20 parts of a functional auxiliary agent; the film-forming substrate is prepared from the following raw materials in parts by weight: 10 to 20 parts of chitosan, 20 to 30 parts of modified starch and 10 to 20 parts of vegetable wax; the active component is prepared from the following raw materials in parts by weight: 0.1 to 0.5 part of indolebutyric acid, 5 to 10 parts of tea tree essential oil, 3 to 5 parts of radix scutellariae extract, 1 to 2 parts of zinc sulfate and 0.5 to 1 part of boric acid; the functional additive comprises the following raw materials in parts by weight: 2-5 parts of nano titanium dioxide, 3-5 parts of a thickening agent and 5-10 parts of a humectant; the positive effect is achieved on tree wound healing.

The invention discloses an electrolyte for regulating interface reaction based on an organic anion mediated gradient ion pump, and belongs to the field of zinc metal batteries. The electrolyte for regulating and controlling the interface reaction based on the organic anion mediated gradient ion pump comprises a mixed aqueous solution of zinc salt electrolyte and organic anion salt, the zinc salt electrolyte is selected from any one of zinc sulfate, zinc chloride, zinc acetate or zinc trifluoromethanesulfonate; an organic chain in the organic anion salt is of a Janus structure, the organic chain contains hydroxyl and alkyl with hydrophobic end chain parts, the problems that an interfacial film of an existing aqueous zinc metal battery solid electrolyte is prone to failure, a zinc negative electrode is poor in stability, and side reaction is serious are solved, the high-reversibility and long-life zinc deposition / stripping process is achieved through multiple effects of the organic salt additive, and the service life of the solid electrolyte is prolonged. The overall performance of the zinc metal battery is improved.

The invention discloses a fermentation process of citric acid residues, and relates to the technical field of organic acid fermentation. The fermentation process comprises the following steps: mixing and crushing citric acid residues and wheat bran according to a mass ratio of (4-5): 1 to obtain a mixed material; spraying an ammonia water solution, a magnesium sulfate solution and a zinc sulfate solution into the mixed material, adjusting the pH value to 5.0-5.5, sterilizing, adding a urea solution and a basic nutrient solution, and uniformly mixing to obtain slurry; aspergillus niger and saccharomycopsis fibuligera are mixed according to the spore number ratio of 100: 1, then sterile water is added, the mixture is stirred to be uniform, and bacterial liquid with the spore concentration of 1 * 10 < 7 >-5 * 10 < 7 > / mL is obtained; spraying the bacterial liquid to the surface of the slurry, performing aerobic culture for 40-48 hours under the conditions that the temperature is 30-35 DEG C and the humidity is 80-85%, then cooling to 25-30 DEG C, reducing the humidity to 70-75%, spraying methanol at the same time, and performing sealed culture for 5-6 days; performing drying; and the acid yield and the nutrient substance yield in the finally obtained fermentation product are obviously improved.

A toothpaste comprising: i) zinc sulfate heptahydrate; ii) glycine; iii) a silica abrasive; iv) greater than 20% by weight of water; wherein the weight ratio of zinc sulfate heptahydrate to glycine is 1: 3 to 2: 1.

The invention discloses a carbide slag fly ash concrete aerated block and a preparation method thereof, and belongs to the technical field of resource utilization of building materials and solid waste. The aerated block comprises the following raw materials: carbide slag, fly ash, gypsum, Portland cement, aluminum powder paste, a nano core-shell structure calcium-aluminum-silicon polymer and a zwitterionic foam-stabilizing polymer, the raw materials have a specific weight part range. Wherein the nano core-shell structure calcium-aluminum-silicon polymer is prepared by dispersing fly ash in water to form slurry, reacting the slurry with sodium silicate and a sodium metaaluminate solution in sequence, then adding calcium nitrate and a zinc sulfate solution for continuous reaction, and carrying out separation, washing, drying and grinding; the zwitterionic foam-stabilizing polymer is prepared by polymerizing a monomer in a solvent, precipitating and separating out, quaternizing, activating carboxyl crosslinking, dialyzing and purifying, and freeze-drying. All the steps relate to process parameters such as dry mixing time, stirring time, curing temperature, pressure and time, and the performance of the aerated block is improved through component optimization and preparation process improvement.

The invention provides a hydrated eutectic electrolyte as well as a preparation method and application thereof. The electrolyte comprises water-soluble zinc salt, deionized water and a deep eutectic solution, the deep eutectic solution is formed by mixing zinc perchlorate and a polar deep eutectic solvent and performing deep eutectic crystallization. The electrolyte has the characteristics of low water activity, low freezing point and efficient induction of uniform deposition of zinc, can be compatible with an iodine-loaded positive electrode and can inhibit dissolution of iodine, and the characteristics are beneficial to inhibition of hydrogen evolution reaction, polyiodine shuttling and other side reactions in the battery circulation process, promote uniform deposition of zinc, protect the integrity of an iodine electrode, and improve the electrochemical performance of the battery. The stable operation of the zinc-iodine battery is ensured; the electrolyte is a zinc sulfate solution containing a ZnClO4 / dimethyl sulfoxide deep eutectic solvent, the solution is combined with free water to form a eutectic structure, the eutectic structure participates in construction of a Zn < 2 + > ion solvation shell, extra intramolecular hydrogen bonds are introduced for the electrolyte, meanwhile, hydrogen bonds among water molecules are weakened, so that the internal energy of the electrolyte is enhanced, the freezing point is reduced, and the flowability is improved.

The invention relates to the technical field of organic fertilizers, in particular to a special fruit-promoting and quality-improving organic fertilizer for camellia oleifera trees and a preparation process thereof, and the special fruit-promoting and quality-improving organic fertilizer is prepared from the following raw materials: composted chicken manure, camellia oleifera shell powder, fulvic acid, chitosan oligosaccharide, double-layer coated slow-release particles, a soil conditioner, a microbial agent and zinc sulfate. After the potassium feldspar powder is activated by citric acid, the effectiveness of potassium is remarkably improved, and the inner layer modified whey protein film preferentially obstructs water contact and delays the release of potassium in the initial stage, so that the problem of excessive growth of branches and leaves is avoided; the outer polyethylene glycol-glycerol copolymer film has a temperature-sensitive characteristic, can respond to soil humidity and temperature changes, is gradually degraded and accelerates potassium release, so that the high-potassium requirement in a grease synthesis critical period is met; the double-film barrier structure effectively reduces early loss of potassium, ensures continuous potassium supply in later fruit expansion and grease accumulation stages, and remarkably reduces the risk of fruit drop caused by insufficient potassium.

The invention relates to the technical field of low-zinc composite active agents, in particular to a low-zinc efficient composite active agent for blended rubber and a preparation method thereof.The preparation method comprises the following steps that zinc acetate, zinc nitrate, zinc sulfate and urea are mixed to prepare nano-zinc oxide, and the nano-zinc oxide is modified with polypropylene glycol to obtain modified nano-zinc oxide; mixing and stirring a dispersing agent, stearic acid, modified nano zinc oxide, multi-walled carbon nanotubes and magnesium oxide under the protection of inert gas to prepare a blend, and curing and molding the blend through a condensation granulation process to obtain the low-zinc high-efficiency composite activator for blended rubber. The prepared low-zinc efficient composite active agent for the blended rubber shortens the vulcanization time of the blended rubber, is excellent in dispersity and enhances the mechanical properties, including tensile strength and elongation at break, of the blended rubber, and in addition, the preparation method is simple and convenient to operate and low in cost and has a good industrial application prospect.

The invention discloses a combined preparation for improving rice quality and application thereof, and belongs to the technical field of crop planting. The combined preparation is prepared from the following raw materials in parts by weight: radix angelicae sinensis, radix paeoniae alba, rhizoma atractylodis macrocephalae, fructus forsythiae, oyster mushroom bran, needle mushroom bran, a microbial agent, ammonium nitrate, potassium nitrate, ammonium molybdate, DTA-6, zinc sulfate and monopotassium phosphate. The microbial agent is prepared from bacillus megatherium, pseudomonas putida, serratia marcescens and saccharomycetes. The combined preparation for improving the rice quality is prepared by taking natural Chinese herbal medicines, fungus chaff, microbial strains and a plant growth regulator as raw materials. The combined preparation is rich in polysaccharide, amino acid, chitosan oligosaccharide and other components and active microbial agents, and can promote the growth and development of rice and improve the quality of rice. The combined preparation provided by the invention provides a new technical thought for rice quality improvement.

The invention relates to the technical field of graphene modification, and particularly discloses a preparation method of zinc borate modified graphene, which comprises the following steps: ultrasonically dispersing graphene in water to obtain 0.5-1g / L graphene dispersion liquid; adding a dispersing agent, a 0.08-0.12 mol / L borax aqueous solution and ethanol into the graphene dispersion liquid, uniformly mixing, and then dropwise adding a 0.08-0.12 mol / L zinc sulfate aqueous solution under the stirring action; then carrying out a reaction through microwave heating at the temperature of 50-70 DEG C under the power of 100-300 W for 20-30 min; after the reaction is finished, filtering, washing and drying to obtain zinc borate modified graphene. According to the preparation method of the zinc borate modified graphene, provided by the invention, a uniform, complete and compact shell layer can be formed on the surface of the graphene through in-situ self-assembly, so that the surface of the graphene is textured, and the dispersion uniformity and dispersion stability of the graphene in an oil phase system are improved.

The invention relates to the field of fertilizers, in particular to a stable fertilizer for nitrogen fixation and emission reduction of a rice field and a preparation method of the stable fertilizer. The fertilizer core comprises the following components: 28-32 parts of ammonium sulfate, 4-6 parts of monoammonium phosphate, 8-12 parts of potassium sulfate, 0.15-0.50 part of a composite nitrification inhibitor, 1-3.5 parts of zinc sulfate monohydrate and 1-2 parts of borax; wherein the composite nitrification inhibitor is obtained by mixing 3, 4-dimethyl-pyrazole phosphate and a phenylboronic acid-phosphoryl compound in a mass ratio of (2-7): 1. The fertilizer product has a scientific and reasonable formula, the long-acting nutrient content and the trace element substance composition are reasonable, the controlled release function is achieved, nutrients needed by rice growth can be met, the fertilizer utilization rate is increased, and the yield and the quality are improved.

The invention discloses an amino acid water-soluble fertilizer and a preparation process thereof, and relates to the technical field of water-soluble fertilizer preparation. The nutrient solution is prepared from the following raw materials: 35 to 45 parts of compound amino acid, 8 to 12 parts of monopotassium phosphate, 3 to 4 parts of potassium sulfate, 1.5 to 2 parts of disodium calcium ethylenediamine tetraacetate, 1.2 to 1.8 parts of EDTA (Ethylene Diamine Tetraacetic Acid) chelated magnesium, 0.3 to 0.7 part of chelated zinc, 0.1 to 0.3 part of zinc sulfate, 2 to 3 parts of citric acid-monopotassium phosphate buffer solution, 2 to 3 parts of algal polysaccharide, 0.5 to 1 part of mannitol, 2 to 4 parts of potassium fulvate, 1 to 2 parts of chitosan oligosaccharide and 0.5 to 1 part of nano silicon dioxide. 0.5-1 part of polyaspartic acid; 1-2 parts of a dispersing agent; the compound amino acid raw materials comprise 60-70% of fish scale protein water-soluble amino acid and 30-40% of bamboo shoot protein water-soluble amino acid; the amino acid water-soluble fertilizer provided by the invention can effectively improve the nutrient absorption efficiency of crops and promote the growth of the crops.

The invention discloses a method for jointly recovering zinc and cadmium from zinc-cadmium slag of zinc hydrometallurgy. The method comprises the following steps: S1, carrying out acid leaching on the zinc-cadmium slag and adding zinc powder for replacement; s2, sponge cadmium is subjected to vacuum melting; s3, adding clear water and calcium oxide into the cadmium alkaline residues for wet grinding, filtering to obtain clear liquid and filter residues, and returning sodium hydroxide obtained after the clear liquid is evaporated and crystallized to S2; s4, the filter residues are subjected to reduction roasting, recyclable zinc-cadmium smoke dust, calcium oxide residues and sulfur trioxide are obtained, the calcium oxide residues are returned to S3, sulfuric acid is prepared from sulfur trioxide, and a part of sulfuric acid is returned to S1; the other part of sulfuric acid enters the next step; s5, the smoke dust is dissolved with sulfuric acid, a sulfuric acid solution containing zinc and cadmium is obtained, then zinc powder is added for replacement, and sponge cadmium and a zinc sulfate solution are obtained; the sponge cadmium returns to S2, and the zinc sulfate returns to S1. According to the method, the cadmium alkaline residue treatment product can be effectively recycled and utilized, the cadmium alkaline residue treatment cost is reduced, no cadmium element flows out of the process to cause environmental pollution, and the method is an environment-friendly process method.

The invention discloses a method for removing arsenic and recovering copper and zinc from scrap copper smelting smoke dust, which comprises the following steps: carrying out first-stage acid leaching on the scrap copper smelting smoke dust to obtain first-stage leaching liquid and first-stage leaching slag; second-stage acid leaching is conducted on the first-stage leaching residues, second-stage leaching liquid and second-stage leaching residues are obtained, and the second-stage leaching liquid is returned to the first-stage acid leaching; zinc oxide is added into the first-section leaching solution to adjust the first-section leaching solution to a preset pH value, then iron powder is added to replace copper in the mixed leaching solution, and copper sponge and a replaced solution are obtained; zinc oxide is added into the replaced liquid to adjust the replaced liquid to a preset pH value, then ferrous sulfate heptahydrate is added, oxygen is introduced for oxidation arsenic precipitation, and arsenic precipitation residues and arsenic precipitation liquid are obtained; and adding zinc oxide into the arsenic-precipitated liquid to adjust the arsenic-precipitated liquid to a preset pH value for neutralization and purification to obtain neutralized and purified residues and a zinc sulfate solution, and returning the neutralized and purified residues to the second-stage acid leaching. According to the method, the valuable elements of arsenic, copper and zinc can be thoroughly separated, and arsenic precipitation caused in the zinc stannate decomposition process can be avoided.

The invention relates to the technical field of crop cultivation. In particular to a rice leaf fertilizer and a fertilizing method and application thereof. The rice leaf fertilizer is prepared from the following components in percentage by weight: 10 to 20 percent of chitin derivative, 5 to 15 percent of compound amino acid, 5 to 10 percent of composted livestock and poultry manure, 5 to 15 percent of fulvic acid, 1 to 3 percent of zinc sulfate, 0.5 to 2 percent of borax, 0.2 to 0.5 percent of potassium silicate, 0.1 to 0.5 percent of polyether modified siloxane, 0.05 to 0.1 percent of rhamnolipid, 0.1 to 0.15 percent of betaine, 1 to 2 percent of sodium alginate and the balance of water. By applying the foliar fertilizer in drought and salt stress environments, the content of beta-glucan in rice is increased, the rice foliar fertilizer disclosed by the invention not only can be popularized for planting rice in northern drought regions in China, but also the planted rice has higher beta-glucan content, and has a health assisting effect on diabetics with limited starch consumption.

The invention provides a collaborative recovery method for directionally converting SO2 into waste tire cord steel wires, and belongs to the technical field of solid waste recycling. According to the collaborative recovery method provided by the invention, the granular waste tire cord steel is roasted in an SO2 / O2 / N2 mixed atmosphere and an air atmosphere in sequence, and then the valuable metal components copper, zinc and iron in the waste tire cord steel wire are directionally converted into copper sulfate, zinc sulfate and iron oxide through further leaching and magnetic separation processes. According to the method, efficient recovery and resource utilization of valuable metal components of copper, zinc and iron in the waste tire cord steel wires are achieved, an innovative solution is provided for high-value utilization of the waste tire cord steel wires, and the method has good application prospects and social and ecological benefits.

The invention relates to a copper sulfate-free copper-zinc sulfide ore flotation separation method, and relates to the technical field of mineral flotation separation. The method comprises the following steps: obtaining copper-zinc sulfide ore pulp; by taking ethionine ester as a collecting agent and lime as an inhibitor, carrying out copper-zinc bulk flotation on the copper-zinc sulfide ore pulp to obtain copper-zinc bulk concentrate and discardable tailings; zinc sulfate serves as an inhibitor, the copper-zinc bulk concentrate is subjected to regrinding treatment, and copper-zinc bulk concentrate pulp is obtained; copper flotation is conducted on the copper-zinc bulk concentrate pulp, and copper concentrate and copper tailing pulp are obtained; with ethionine ester as a collecting agent, the copper tailing ore pulp is subjected to sphalerite activation under the condition of aeration stirring, and activated sphalerite ore pulp is obtained; and carrying out flotation on the activated sphalerite by using lime as an inhibitor to obtain zinc concentrate. The scheme provided by the invention has the advantages that heavy metal pollution is avoided, the mineral separation cost is reduced, and the process adaptability is high.

The present invention relates to a bioelectrochemical device for treating soy sauce wastewater and a preparation method thereof. The bioelectrochemical device comprises an anode chamber and a cathode chamber, wherein a columnar anode is disposed at the center of the anode chamber; a columnar cathode is disposed at the center of the cathode chamber; the space between the columnar anode and the anode chamber is filled with a modified conductive oxidizing filler; electroactive bacteria grow on the columnar anode and the modified conductive oxidizing filler, and the modified conductive oxidizing filler is metal-doped activated carbon. The metal-doped activated carbon is formed by mixing the activated carbon with a mixed solution of zinc sulfate and potassium sulfate, adsorbing the zinc sulfate and potassium sulfate onto the activated carbon, and then calcining the activated carbon to form corresponding metal oxides on the surface of the activated carbon. Due to the introduction of metallic potassium and metallic zinc, the metallic potassium and metallic zinc have electronic interaction and synergistic effects, thereby improving electronic conductivity and promoting degradation treatment of the soy sauce wastewater.

The invention relates to the technical field of agriculture, in particular to a zinc-rich cadmium-reducing leaf surface blocking and controlling agent as well as a preparation method and an application method thereof. According to the specific technical scheme, the zinc-rich cadmium-reducing leaf surface blocking and controlling agent is prepared from, by mass, 10%-20% of gamma-chitosan, 20%-30% of L-malic acid and 50%-70% of zinc sulfate. The technical problem that in the prior art, the cadmium content of brown rice cannot be reduced through a leaf surface blocking and controlling agent is solved.

The invention discloses a broad-spectrum combined medicine for treating liver cancer, which comprises purified water, tripterygium wilfordii alkaloid, tripterygium hypoglaucum alkaloid, chamaejasmine, gelsmium elegans alkaloid, xanthoxylin and various B medicines, and further comprises folic acid, vitamins, copper sulfate, zinc sulfate, manganese sulfate, yeast and penicillin sodium. Through the multi-component, multi-target and multi-path design, the medicine disclosed by the invention shows a potential effect of inhibiting the progress of liver cancer and good safety in cell experiments, animal models and human individual case observation. Cellular immunity and humoral immunity can be enhanced, the treatment cost is lower than that of a traditional treatment scheme, and no pain is caused during treatment.

The invention belongs to the technical field of electrochemical energy storage, and discloses an electrolyte for a zinc-bromine flow battery, a preparation method of the electrolyte and the zinc-bromine flow battery, raw materials of the electrolyte comprise the following components: zinc salt, potassium salt, an additive and a solvent; the potassium salt is a compound mixture of potassium bromide and potassium bromate; the additive comprises an organic complexing agent and an inorganic corrosion inhibitor; wherein the organic complexing agent comprises an organic zinc complexing agent and an organic bromine complexing agent; the organic zinc complexing agent is crown ether; the organic bromine complexing agent is imidazole bromine salt or pyridine bromine salt; the inorganic corrosion inhibitor is a compound of sodium molybdate, zinc sulfate, sodium dihydrogen phosphate and deionized water; growth of zinc dendrites can be remarkably inhibited, the energy density of the battery is improved, and escape of hydrogen bromide is effectively prevented, so that the performance and the stability of the zinc-bromine flow battery are comprehensively improved, the service life of the battery is prolonged, and the use cost and the safety risk of the battery are reduced.

The invention discloses a process for recovering zinc, nickel, cadmium, copper and chlorine in high-chlorine zinc slag. The process comprises the following steps: S1, four-stage reverse water washing; s2, removing impurities from water washing liquid; s3, concentrating and crystallizing the impurity-removed liquid; s4, leaching the washed mixed slag; s5, neutralizing the leachate to remove arsenic and iron; s6, replacing to remove copper, cadmium and nickel; and S7, concentrating and crystallizing the copper-cadmium-nickel-removed solution. According to the method, the technical bottleneck problem that the high-chlorine zinc slag is used for recovering zinc and discarding chlorine resources by applying a traditional zinc hydrometallurgy process technology is solved, and the environment-friendly process technology for recovering zinc and chlorine at low cost, producing ammonium chloride and zinc sulfate products and realizing zero emission of three wastes is realized. And meanwhile, valuable metals such as lead, cadmium and copper in the high-chlorine zinc slag are enriched and recycled.