2521 results about "Sulfate zinc" patented technology

The present invention is directed to a biocidal water treatment composition, water treatment apparatus, and method of treating water to reduce levels of pathogens. The composition contains sources of copper, zinc, and silver metal ions within a crosslinked polymer matrix. Examples of these ion sources include copper sulfate, zinc sulfate, and silver nitrate. An example of the crosslinked polymer matrix is crosslinked chitosan, which also serves to clarify the water and release the metal ions over time. The product is easy to manufacture, and allows the use of decreased halogen sanitizer, as well as decreased copper ion, thereby decreasing the likelihood of staining. The product simultaneously provides good bactericidal and algaecidal properties, despite low levels of copper ion and low chlorine levels.

A liquid fertilizer containing wood vinegar liquid or oxalic vinegar liquid and its production are disclosed. The liquid fertilizer consists of urea 1í½20.0%, potassium phosphate 1í½20.0%, potassium nitrate 1í½20.0%, lime nitrate 0.1í½10.0%, magnesium sulfate 0.1í½5.0%, ferrous sulfate 0.1í½5.0%, manganous sulfate 0.1í½5.0%, zinc sulfate 0.1í½5.0%, cupric sulfate 0.1í½5.0%, boron sand or boric acid 0.1í½2.0%, sodium molybdate or ammonium molybdate 0.1í½1.0%, plant hormone or plant regulator, rare earth element or humus acid or pesticide auxiliaries etc. The process is carried out by proportioning and mixing. It can improve bacterium inhibiting and plant growth regulating functions.

The invention discloses a special saline-alkali-soil improvement fertilizer prepared by modification with flue gas desulfurization gypsum and a preparation method thereof. The special improvement fertilizer comprises the following components in parts by weight: 40-80 parts of flue gas desulfurization gypsum, 1-3 parts of citric acid, 0.5-1.5 parts of magnesium sulfate, 1-5 parts of aluminum sulfate, 1-5 parts of ferrous sulfate, 10-30 parts of weathered coal, 10-20 parts of cattle manure or chicken manure, 1-5 parts of urea, 0.5-2.5 parts of ammonium sulfate, 1-3 parts of potassium sulfate, 1-3 parts of monoammonium phosphate, 0.1-0.5 part of zinc sulfate, 0.1-0.5 part of manganese sulfate and 3-10 parts of bentonite. The fertilizer is reasonable in design, provides an effective solution for inland saline-alkali soil of China, and has higher practical value and wide market prospects.

The invention relates to a preparation method for a zinc-iron-selenium-rich biological fertilizer and a usage, which belongs to the technical field of crop production. Water is added into pig manure, silkworm excrement, human excrement and colza cakes for a fermentation to get mother liquor of the biological fertilizer; zinc sulfate, green copperas, sodium selenite are added into the mother liquor for reactions to get zinc-iron-selenium-rich biological foliar fertilizer for the rice. The fertilizer is separately sprayed in the booting stage and the full heading stage of the rice, with an amount of 1000ml per mu. The function rice, with zinc content 19.4 to 28.7mg/kg, iron content 7.0 to 20.2mg/kg, and selenium content 0.08 to 0.15 mg/kg, measures up to the limit standards of zinc, iron, and selenium in the national food standards. Organic selenium accounts for more than 99% of the total selenium in the zinc-iron-selenium-rich function nutritive rice. The preparation method for the zinc-iron-selenium-rich biological fertilizer proves effective, economical, safe and non-polluted through twice foliage sprays with zinc-iron-selenium fertilizer for the rice as an experiment.

The invention provides a boiler coal combustion-improving desulfurizing and denitrifying agent composition. The composition comprises the following raw materials in parts by weight: 2-7 parts of sodium carbonate, 1-3 parts of alumina, 2-8 parts of aluminium hydroxide, 2-5 parts of ferric trichloride, 2-6 parts of ferric oxide, 3-10 parts of potassium permanganate, 3-10 parts of potassium chlorate, 10-35 parts of activated attapulgite clay, 15-30 parts of urea, 2-4 parts of ammonium formate, 2-4 parts of ammonium chloride, 6-23 parts of ammonium acetate, 3-9 parts of manganese oxide, 9-12 parts of copper chloride, 1-3 parts of copper oxide, 2-4 parts of zinc sulfate, 1-3 parts of zinc nitrate, 7-18 parts of potassium dichromate, 1.0-1.5 parts of titanium dioxide, 0.5-1.0 part of barium molybdate, 0.5-1.5 parts of cobalt sulfate, 0.5-1.5 parts of vanadium pentoxide, 0.3-0.7 part of cerium oxide, 0.1-0.2 part of sodium dodecyl benzene sulfonate and 0.1-0.2 part of alkyl glyceryl ether. The composition is convenient to use, has stable properties, plays roles of combustion improving, desulfurization and denitrification, has coal saving rate of 8-25% and can remove fixed sulfur by 50-70%.

The invention discloses a technology of enhanced-dispersion partial selective and bulk flotation of lead and zinc sulfide ores under low and high alkalinity. During grading of the lead and zinc sulfide ores, sodium hexametahposphate is taken as a dispersion agent and directly added into a ball mill, the ores are ground till the ores with the size of 0.074mm account for 67%-70%, lime is taken as an adjusting agent, zinc sulfate and sodium sulfite are taken as inhibitors, dithiophosphate BA and diethyldithiocarbamate are taken as collectors, and selective flotation of part of lead minerals with good floatability can be performed under low alkalinity; then xanthate and the diethyldithiocarbamate are taken as collectors, and the flotation of the lead minerals is further performed under high alkalinity; copper sulfate is added in lead flotation tailings for activation, butyl xanthate is further taken as the collector for flotation of zinc blende and part of pyrite, and zinc-sulfur separation flotation is further performed on zinc-sulfur mixed concentrate; and sulfuric acid is added in zinc flotation tailings for activation, and the xanthate is taken as the collector for flotation of the remaining pyrite. By adopting the technology, the lead-silver recovery rate can be improved, the using amount of lime and sulfuric acid can be reduced, the circulating amount of middlings can be reduced, the ore dressing cost can be reduced and the grade of the concentrate can be improved.

This invention involves a mushroom cultivation material and production process, it belongs to the field of bio-engineering technology. This mushroom cultivation material contains Chinese crud drug residue 30 ~ 40 share, cotton shells 50 ~ 60 share, urea 1 ~ 2 share, wheat bran 5 ~ 7 share, potassium sulfate 0.5 to 1.5 share, calcium superphosphate 0.5 to 1.2 share, zinc sulfate, magnesium sulfate, borax, ferrous sulfate together for 0.4~1 share, calcined lime 0.5 to1.3 share. Because of using materials containing substances such as Chinese crud drug residue, the produced mushroom cultivation material of this invention has antibacterial effect. Through the implementation of the invention reached so no longer waste residue cause environmental pollution, reduce the factory heavy economic burden caused by the sewage problem.

The invention discloses a sustained-release compound fertilizer and a preparation method thereof. The sustained-release compound fertilizer is prepared from the following raw materials in parts by weight: 20 to 30 parts of urea, 30 to 40 parts of monoammonium phosphate, 5 to 10 parts of calcium superphosphate, 10 to 15 parts of potassium chloride, 1 to 2 parts of zinc sulfate, 1 to 2 parts of manganese sulfate, 2 to 3 parts of ferrous sulfate, 0.5 to 1.5 parts of borax, 3 to 5 parts of humic acid, 8 to 12 parts of modified clay and 4 to 6 parts of chitosan coating agent. The fertilizer has high sustained-release performance, double good functions of pest killing and water retention, high and long-lasting fertilizer efficiency and high nutrition utilization rate, a coating material is easy to degrade, pollution is completely avoided, the rapid growth of crops can be promoted, the stress resistance of the crops can be improved, the ecological balance of soil can be adjusted, the quality of agricultural products can be improved, and both production and income of the agricultural products are increased. Sources of the raw materials are extensive, and a production process is simple, convenient to operate, low in equipment investment, low in cost and applicable to industrial production, and has a broad market prospect.

The invention provides a preparation method and application of a selenium-enriched cadmium-resistant foliar fertilizer special for rice .The preparation method of the selenium-enriched cadmium-resistant foliar fertilizer special for the rice comprises the following steps that sodium selenite, zinc sulfate, manganese sulfate and ferrous sulfate are dissolved in water and prepared into an original mother liquid, wherein the concentration of sodium selenite ranges from 30 g/l to 60 g/l; the original mother liquid is mixed with an amino acid solution of which the mass concentration ranges from 15% to 20%, shaking chelating is conducted, and a chelating liquid is obtained; the chelating liquid and a single silicic acid aqueous solution are mixed to be uniform to be prepared into a mixed liquid; sodium alkyl benzene sulfonate is added, the mixture and filtrate obtained through saccharose alcohol fermentation are stirred at 25 DEG C to 35 DEG C for secondary chelating, and the selenium-enriched cadmium-resistant foliar fertilizer special for the rice is obtained .By means of the preparation method and application of the selenium-enriched cadmium-resistant foliar fertilizer special for the rice, 90% or above of inorganic selenium is converted into organic selenium such as selenomethionine and selenocystine, the poisoning risk is eliminated, the absorption conversion rate of selenium is increased, the raw material amount is reduced, the cost is reduced, and the rice has a good cadmium-resistant property.

Apparatus, materials, and methods for removing ammonia from fluid using metal hydroxides (e.g. zinc hydroxide) and metal cation loaded media (e.g. zinc loaded ion exchange resins); the metal hydroxides and metal cation loaded media may be regenerated with a weak acid (pK_a between 3 and 7). Alternatively, ammonia is removed from fluids by using H₂SO₄ and ZnSO₄ and metal cation loaded media; the metal cation loaded media may be regenerated with H₂SO₄ and ZnSO₄; the ammonia containing H₂SO₄ and H₂SO₄ may be concentrated as necessary to form (NH₄)₂SO₄.ZnSO₄.6H₂O (ammonium zinc sulfate hexahydrate) crystals. These crystals are removed from the mother liquor and heated to temperatures exceeding 200° C. releasing NH₃ and H₂O vapor upon the decomposition of the crystals.

The invention provides a pesticide compound which is a liquid preparation prepared from hydrogen peroxide, zinc sulfate and Chinese medicine, wherein the hydrogen peroxide and the zinc sulfate are adopted as active components and the Chinese medicine is adopted as the raw material, wherein every 100ml contains 1.0 to 5.0ml of hydrogen peroxide and 0.05 to 1.0g of zinc sulfate; and the amount of the Chinese medicine is 7 to 60g by the native medicine. The invention also provides a preparation method and the purposes of the pesticide compound. The pesticide compound follows the rules of a traditional Chinese medicine prescription, comprehensively considers the use cost, the environmental-friendliness, storage properties and other factors, is compounded, has the advantages of safety use, no environment pollution, strong killing power, good permeability and side scope of application, and is characterized by promoting the agricultural fruit resistance, speeding up wound healing, prolongingthe storage period and the like.

The invention relates to an aqueous culture method of anoectochilus. In the method, anoectochilus germchits are cleaned and sterilized, transplanted in a culture dish and cultured in a culture groove filled with an aqueous culture solution; each 10L of aqueous culture solution contains the following components: 650 to 800mg of calcium nitrate tetrahydrate, 50 to 60mg of ammonium nitrate, 280 to 350mg of potassium nitrate, 100 to 130mg of potassium dihydrogen phosphate, 350 to 380mg of magnesium sulfate, 0.5 to 0.8mg of potassium iodide, 2 to 5mg of manganese sulfate, 0.2 to 0.3mg of sodium molybdate, 0.1 to 0.2mg of cobalt chloride, 2 to 4mg of boric acid, 0.5 to 1mg of zinc sulfate, 0.3 to 0.5mg of copper sulfate and 3 to 5ml of iron salt solution, wherein the iron salt solution is prepared by mixing water, green vitriol and ethylenediamine tetraacetic acid disodium. The method has the advantages of lowering production cost, simplifying production process, improving the growth of anoectochilus plants and improving the survival rate of anoectochilus plants.

A nutritional growth promoter for multi-stem ginseng belongs to the agricultural technology field. The invention solves the problem of changing ginseng from single-stem to multi-stem. The invention can be prepared according to the weight percentages as follows: B9 0.10%-0.40%, chito-oligosaccharides 0.30%-1.00%, compound amino acid 0.50%-1.50%, monopotassium phosphate 0.10%-0.20%, ferrisulphas 0.02%-0.08%, boric acid 0.05%-0.15%, manganous sulfate 0.05%-0.15%, copper sulfate 0.02%-0.08%, zinc sulfate 0.10%-0.20%, ammonium molybdate 0.05%-0.10%, and water 100.0%. B9, chito-oligosaccharides, compound amino acid, monopotassium phosphate, ferrisulphas, boric acid, manganous sulfate, copper sulfate, zinc sulfate, and ammonium molybdate are respectively dissolved in little water, and then mixed with the rest water to prepare nutrient solution which is used in foliage spraying. The nutritional growth promoter is used for cultivating multi-stem ginseng with increased production and improved quality.

The invention provides a plant nutrient solution which consists of the following components: potassium nitrate, urea, ammonium nitrate, magnesium sulphate, ammonium dihydrogen phosphate, calcium nitrate, manganese sulfate, zinc sulfate, ferric citrate, boric acid, sodium molybdate, sodium iodide, folic acid, asparagine and deionized water. According to the invention, the plant nutrient solution is comprehensive in nutrition, has no poisonous substance, cannot pollute the environment after being used, cannot cause harm to human body, and is free from undesirable odor. Through the adoption of the plant nutrient solution to cultivate foliage plants such as monstera deliciosa and rohdea japonica without soil, the leaf color is dark green, the growth is vigorous, death is hard, and compared with the conventional plant nutrient solution in the market, the growth rate is increased by 20%.

The invention discloses a soil improvement biofertilizer and a preparation method of the soil improvement biofertilizer. The soil improvement biofertilizer is characterized by being prepared from the following raw materials in parts by weight: 200-350 parts of turf, 100-150 parts of clay, 5-10 parts of composite microbial agent, 5-7 parts of polyacrylamide, 60-80 parts of ammonium sulfate, 50-65 parts of monopotassium phosphate, 70-80 parts of calcium chloride, 20-25 parts of sodium borate, 15-25 parts of zinc sulfate, 20-25 parts of acetic acid, 2-3 parts of 1,2,3-glycerol, 6-10 parts of sodium gluconate, 80-100 parts of oyster shell powder and 9-12 parts of a soil conditioner. The soil conditioner contains a jade component which is beneficial to a human body by crop absorption; meanwhile, toxic heavy metal elements in soil can be effectively adsorbed and solidified; absorption of the heavy metal elements by the crops is reduced; and the crop yield can be increased. A plurality of microorganisms with the effects of fixing nitrogen, and resolving phosphor and potassium are added to the fertilizer, so that improvement of the soil structure is facilitated, and the yield and the quality of the crops are improved.

The invention provides an organic-inorganic composite biological fertilizer pesticide special for soybean. The organic-inorganic composite biological fertilizer pesticide is prepared from the following materials in parts by weigh: 40-50 parts of household garbage, 30-40 parts of mushroom slag, 20-25 parts of vinasse, 15-20 parts of humic acid, 10-13 parts of monocalcium phosphate, 12-14 parts of urea, 10-12 parts of potassium nitrate, 10-12 parts of quail feather, 20-24 parts of modified sepiolite, 3-4 parts of quispualis indica, 3-4 parts of stone-like omphalia, 4-6 parts of broom cypress fruit, 4-6 parts of rhizome nardostachyos, 4-6 parts of radix euphorbiae lantu, 0.1-0.2 part of boric acid, 0.05-0.1 part of sodium molybdate, 1-1.5 parts of zinc sulfate, 0.7-1.0 part of manganese sulfate, 5-7 parts of magnesium sulfate, 1-2 parts of nitrogen-fixing bacteria preparation and 3-5 parts of wintergreen oil. According to the invention, multiple organic wastes are mixed and then fermented so as to be changed into green organic fertilizer, environmental pollution is reduced, fermenting organic matter are mixed with inorganic fertilizer, and Chinese herbal medicine juice with insecticide function is added, therefore, the nutrition is more complete, and the sterilizing effect is increased. By applying the fertilizer, the quality of the soybean can be effectively improved, the soybean has green leaves and more flowers, the flowering period is prolonged, and the yield is improved.

The invention discloses a straw mushroom culture medium and a method for circularly cultivating straw mushrooms. The straw mushroom culture medium comprises 70 to 90 weight percent of Chinese medicament dreg, 10 to 30 weight percent of straws and a production increasing agent with the dose of 5 to 10 kg/m<3>, wherein the production increasing agent is prepared by mixing the following components in percentage by weight: 0.006 to 0.01 percent of vitamin B1, 15 to 20 percent of superphosphate, 40 to 60 percent of quick lime, 1.5 to 2 percent of magnesium sulfate, 0.2 to 0.4 percent of zinc sulfate, 0.2 to 0.3 percent of boric fertilizer, 0.2 to 0.4 percent of triacontanol and 22 to 37 percent of starch. By the straw mushroom culture medium and the method for circularly cultivating the straw mushrooms, resources can recycled; energy is saved due to short fermentation time of the medium; the medium can increase yield of the straw mushroom, can improve the quality of the straw mushroom and can increase the flavonoid content of the straw mushrooms; and by the multi-time circularly cultivating method, the utilization ratio of the medium is increased and production cost is reduced.

The invention relates to compound premix feed for laying hens, which comprises 3 to 9 kg of manganous sulfate, 3 to 7 kg of zinc sulfate, 3 to 7 kg of ferrous sulfate, 0.6 to 1.4 kg of copper sulphate, 12 to 18 kg of choline chloride, 7 to 11 kg of lysine, 26 to 34 kg of methionine, 1.6 to 2.4 kg of phytase, 400 to 461 kg of calcium carbonate, 80 to 120 kg of calcium hydrophosphate, 300 to 360 kg of fish meal, 45 to 75 kg of common salt, 0.20 to 0.44 kg of vitamin A, 0.06 to 0.14kg of vitamin D3, 0.52 to 1.12 kg of vitamin E, 0.047 to 0.1 kg of vitamin K3, 0.026 to 0.056 kg of vitamin B1, 0.177 to 0.33 kg of vitamin B2, 0.078 to 0.145 kg of vitamin B6, 0.025 to 0.058 kg of vitamin B12, 0.02 to 0.03 kg of folic acid, 0.008 to 0.018 kg of biotin, 0.3 to 0.674 kg of nicotinic acid, 0.11 to 0.245 kg of calcium pantothenate, and 1.2 to 3.83 kg of rice hull powder. The laying hens fed by the premix feed have high laying rate, and keep long period of peak time of laying eggs reaching 6-9 months. The ratio of the feed to the egg is as low as 2.0-2.1:1.

The invention relates to a chelated liquid fertilizer containing multiple types of plant alcohols and medium trace elements, which is applied in the field of agriculture and forestry. The liquid fertilizer consists of the following main materials in parts by weight: 80-450 parts of soluble plant alcohols, 1-10 parts of calcium nitrate, 0.5-3.5 parts of zinc sulfate, 0.1-2.5 parts of manganese sulfate, 0.5-5 parts of magnesium sulfate, 0.1-2.5 parts of ferrous sulfate, 0.03-0.08 part of cobalt chloride, 0.01-0.05 part of ammonium molybdate and 0.2-1.0 part of boric acid. The pH value of the liquid fertilizer is adjusted to be neutral with slightly stronger acidity by adding an appropriate amount of water. The liquid fertilizer contains the multiple types of plant alcohols and has the capabilities of activating the biological activity of crops and enhancing the adsorption to the medium trace elements of the crops and the antioxidation of the crops; and the medium trace elements are capable of promoting the healthy growth of the crops and correcting the nutritional deficiency symptom of the crops. The liquid fertilizer has the characteristics of simple processing technology, low production cost, high fertilizer efficiency and the like; the liquid fertilizer is suitable to serving as a toot system and leaf top application for fruit trees, vegetables and field corps, and is particularly suitable to supplying medium trace element nutrition to the leaves or fruits during the late growth period of the fruit trees. The liquid fertilizer with multiple elements is extensive in application.

The invention discloses a soil improving synergistic saline-alkali resistant water soluble fertilizer and a preparation method thereof. The waste liquid generated in the amino acid fermentation production process is taken as a carrier, and added with active humic acid prepared from decomposed coal or brown coal or peat rich in humic acid, and then the mixture is thoroughly and proportionally mixed with water soluble nitrogen fertilizer, water soluble phosphatic fertilizer, water soluble potassic fertilizer, and macroelements and microelements such as copper sulfate, borax, zinc sulfate and ferrous sulfate; and then the final mixture is subjected to spray drying, separation and collection treatment, so that a powdery material is obtained; and as a result, the soil improving synergistic saline-alkali resistant water soluble fertilizer is formed. The soil improving synergistic saline-alkali resistant water soluble fertilizer provided by the invention is low in cost, low in investment, low in energy consumption, small in floor area, energy-saving, environment-friendly and free of pollution; zero emission of amino acid waste liquid and deep processing of the decomposed coal, the brown coal and the peat are realized and pollution on the environment is reduced; the waste is well utilized and changed into things of value; besides, the soil improving synergistic saline-alkali resistant water soluble fertilizer is good in water solubility, free of residue, rich in nutrition, high in active organic matter content and high in safety; and furthermore, the soil improving synergistic saline-alkali resistant water soluble fertilizer achieves the effects or improving the soil and resisting saline and alkali, and is obvious in synergia and wide in uses.

The invention discloses a metallurgical process for recovering metal copper, lead, zinc and tin from copper refining waste slag, which uses waste liquid of zinc electrolysis with sulfuric acid or waste liquid of zinc electrolysis to perform the acid leaching; more than 95% of the zinc and copper are in the solution, the Fe 2+ in the solution is less than or equal to 1.5g/L; then the copper slag is used for removing chlorine; when the Cl- in the solution is less than or equal to 1.0g/L, the solution is sent to a copper electro-deposition; the electro-deposition decopperization can produce copper piece or copper powder; the decopperization neutralization is to add calcine or zinc oxide for neutralizing acid when the Cu2+ in the solution is less than or equal to 1.0g/L; lime is used for adjusting the pH value to 5.2-5.4; after purifying and removing residue of the zinc sulfate solution, the solution is sent to the zinc electro-deposition for producing zinc piece; the lean and tin pyrometallurgical purification is that, after more than 98% of lead and tin is sent to the acid leaching residue, the material of the acid leaching residue is balled and sent to a smelting furnace, so as to produce lead-tin alloy; the lead-tin alloy is directly sent to a vacuum fractionation furnace for purifying the lead and tin product; sulfur dioxide in the tail gas is absorbed by ammonia, so as to obtain ammonium sulphate product. The process is to extract copper and zinc joint wet process and to purify lead and tin by pyrometallurgical method; the process flow is effectively shortened, the metalrecovery rate and the resource utilization rate are both largely increased, and there is no secondary pollution in the process.

The invention provides bacillus subtilis DLD2 bacterial strain which is preserved in a China general microbiological culture collection center (CGMCC), the serial number is CGMCC NO.3222. The invention further provides a multi-functional biological agent formula and a preparation method thereof; fermentation broth, fulvic acid, zinc sulfate and other components of the bacillus subtilis DLD2 are formulated for preparing the multi-functional biological agent formula which is used for improving soil and continuous cropping resistance; the biological agent has the following functional effect: (1) bio-control microorganisms are utilized to prevent harmful flora from infecting plant and killing pathogenic bacteria, induce the plant to generate disease resistance and prevent seedling withering and rotting; (2) by utilizing synergia effect of formulation of the bacillus subtilis, fulvic acid and zinc sulfate, the root system growth can be induced, plant regeneration and root regeneration are realized, soil hardening is broken, granular structure is formed, no deep tillage is realized, moisture holding and soil moisture conservation is realized, fertilizer damage is relieved and soil fertility is improved.