350results about "Aqueous electrolytes" patented technology

The invention discloses an electrolyte for an aqueous manganese-based battery. The electrolyte comprises an electrolyte, and the electrolyte comprises a manganese salt; the weak acid is used for regulating and controlling proton dynamic release of the positive electrode / electrolyte interface to realize on-demand supply of protons of the positive electrode / electrolyte interface; and a solvent, wherein the solvent is deionized water; the PH range of the electrolyte is 2.0-3.5, and the electrolyte can realize on-demand supply of protons of a positive electrode / electrolyte interface in the charging and discharging process of the aqueous manganese-based battery, and promotes efficient and reversible deposition and dissolution reaction of a positive active substance manganese dioxide. According to the invention, the proton on-demand supply electrolyte is constructed by utilizing dynamic dissociation equilibrium of weak acid, so that on-demand supply of protons in the MnO2 dissolving process is realized, complete electrochemical dissolution of MnO2 is promoted, and generation of'dead manganese 'is inhibited, so that the cycling stability of the battery and the utilization efficiency of active substances are remarkably improved. The invention also discloses an aqueous manganese-based battery for realizing on-demand supply of protons and application of the aqueous manganese-based battery in the field of secondary energy storage.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention relates to the technical field of water-based energy storage batteries, in particular to a two-phase electrolyte for a water-based zinc ion battery and a preparation method of the two-phase electrolyte, and the two-phase electrolyte comprises soluble zinc salt, water and quaternary ammonium nitrate; the soluble zinc salt comprises one of zinc trifluoromethanesulfonate, zinc bis (trifluoromethylsulfonyl) imide, zinc acetate, zinc sulfate and zinc chloride, and the molar concentration of the soluble zinc salt is 1-5 mol / L; the quaternary ammonium nitrate is one or more than two of tetramethylammonium nitrate, tetraethyl ammonium nitrate, tetrabutyl ammonium nitrate, hexadecyl trimethyl ammonium nitrate and octadecyl trimethyl ammonium nitrate, and the molar concentration of the quaternary ammonium nitrate is 1-3 mol / L. The preparation method is simple, convenient and efficient, the reversibility of the zinc anode is optimized, the method is crucial for promoting the design of a practical water-based zinc ion battery, and the application of the zinc-based battery in the field of energy storage is further accelerated.

The invention discloses a zinc-bromine flow battery electrolyte, a negative electrode cosolvent and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, the negative electrode cosolvent of the zinc-bromine flow battery electrolyte is a carboxyl-containing butenoic acid substance, the butenoic acid substance is used as the cosolvent, and zinc is induced to preferentially deposit on a (002) plane by modifying a solid-liquid interface, so that the zinc-bromine flow battery electrolyte is obtained. And the deposition process of zinc is converted from an irregular form which tends to form a dendritic crystal shape and a moss shape into a deposition layer which tends to form a flat and compact deposition layer which is parallel to the substrate. The highly uniform zinc deposition fundamentally and effectively inhibits the formation and growth of zinc dendrites, and greatly improves the stability of the negative electrode and the cycle life of the battery. Chlorides improve ionic conductivity to reduce internal resistance, and sodium acetate buffer inhibits hydrogen evolution on stable pH; and synergistic optimization of positive and negative components ensures efficient reaction. And moreover, the raw materials are easy to obtain, the preparation is simple and convenient, the industrialization threshold is reduced, and the large-scale energy storage requirement is met.

The present disclosure relates to organic electrolyte solutions including organic electrolytes (e.g., aromatic imides, ferrocenes, spiro fused compounds, or cyclopropenium compounds), and redox flow batteries and systems including the same.

The present disclosure relates to organic electrolyte solutions including organic electrolytes (e.g., aromatic imides, ferrocenes, spiro fused compounds, or cyclopropenium compounds), and redox flow batteries and systems including the same.

This invention relates to a biomass-based gel electrolyte membrane, its preparation method, and its application. The method includes preparing regenerated cellulose using a sol-gel method, adding sodium alginate and zinc chloride solution, and rapidly constructing a biomass-based composite gel electrolyte with a dual-network structure through metal ion coordination crosslinking. The biomass-based gel electrolyte membrane is obtained by adsorbing an aqueous electrolyte onto a gel membrane with a dual-network structure. This gel electrolyte membrane is then assembled with a zinc anode and a vanadium pentoxide cathode to obtain a zinc-ion battery. This invention features a simple method, readily available and inexpensive raw materials, easy product molding, convenient operation and control, and is conducive to industrial production. The prepared composite gel electrolyte membrane has a dual-network structure, exhibiting good stability, liquid retention capacity, and ionic conductivity, and demonstrates excellent cycle capacity and lifespan when applied to aqueous zinc-ion batteries.

The invention discloses a high-cycle-performance aqueous battery, which comprises an aqueous electrolyte, a negative electrode, a first positive electrode and a second positive electrode, wherein the first positive electrode and the second positive electrode are positioned on two sides of the negative electrode, and a first diaphragm and a second diaphragm are respectively arranged between the first positive electrode and the negative electrode and between the second positive electrode and the negative electrode; the battery is provided with an electromagnetic valve, the electromagnetic valve is electrically connected with the first positive electrode and the second positive electrode to control switching of the positive electrodes in the charging and discharging loop, and every time discharging and charging circulation are completed, the electromagnetic valve switches the electrode connection relation, and the first positive electrode and the second positive electrode are alternately connected into the charging and discharging loop. Switching of the two positive electrodes in the aqueous battery is accurately controlled through the electromagnetic valve, a positive-negative battery structure is formed in real time, the double positive electrodes alternately perform lithium removal-lithium intercalation reaction, excessive Li intercalation or insufficient positive electrode reduction caused by long-term charging and discharging of a single positive electrode is avoided, the structural stability of the positive electrode material is improved, and the service life of the battery is prolonged. The cycle life and the electrochemical performance stability of the aqueous battery are obviously improved.

The invention discloses a chloride ion battery for realizing bromine / chlorine synergistic chemistry and a preparation method thereof, and belongs to the technical field of redox batteries. The chloride ion battery takes graphite paper coated with vanadium pentoxide and graphite as a positive electrode, wherein the mass ratio of the vanadium pentoxide to the graphite is (0.5: 1)-(2: 1); zinc foil is used as a negative electrode, and an electrolyte is a mixed aqueous solution of tetramethylammonium chloride and lithium bromide. A double-halogen system of a V2O5-graphite composite positive electrode is adopted, chlorine species are chemically stabilized through the action of bromine, BrCl is generated in the charging process to inhibit Cl2 formation, and meanwhile, the intercalation energy barrier of chlorine is reduced; according to the salt-in-water electrolyte based on tetramethylammonium chloride, an electrochemical window is expanded to 3.0 V, and BrCl hydrolysis is effectively inhibited. The high-voltage halogen ion battery prepared by the method can realize a 2.3 V discharge platform, provides a specific capacity of 600mAh g <-1 >, has a capacity retention rate of 90% after 200 cycles, and opens up a safe development path for the high-voltage halogen ion battery without toxic gas emission. In addition, the battery system is simple in structure and has remarkable cost benefits.

The invention relates to the technical field of all-vanadium redox flow batteries, and discloses a supported electrolyte of all-vanadium redox flow battery positive and negative electrolyte and a preparation method thereof, and the supported electrolyte comprises an aqueous solution containing vanadium ions, sulfonate ions, sulfate ions and phosphonic acid groups. The sulfonic acid group (-SO3H) has strong polarity and high ionization degree, after the sulfonic acid group (-SO3H) is mixed with the phosphonic acid group (-PO3H2) and sulfuric acid, the ionic environment of the electrolyte can be optimized, the activation energy of V (II) / V (III) and V (IV) / V (V) electricity on electron transfer is reduced, and compared with an existing sulfuric acid supported electrolyte, the reversibility of electrochemical reaction is remarkably improved, and the electrochemical activity of the electrolyte is enhanced; meanwhile, phosphonic acid groups have high complexing ability, can form stable chelates with vanadium ions and can form complexing-dispersing synergy with sulfonic acid groups, the solubility of the vanadium ions is improved, and agglomeration and crystallization of the vanadium ions are inhibited.

The invention discloses a method for preparing a vanadium electrolyte by electrochemistry-ultrasonic synergistic reduction of a waste vanadium catalyst in the technical field of solid waste resource utilization, which comprises the following steps of: roasting the waste vanadium catalyst by NaOH and leaching by sulfuric acid, applying 80Hz pulse current by adopting a titanium-based lead dioxide anode and a graphite cathode in a three-chamber electrolytic bath, synchronously starting a 25kHz and 300W ultrasonic field for synergistic reduction, and controlling the reaction temperature to be 35 + / -2 DEG C until the V < 5 + > concentration is less than 0.05 g / L; and then adding a chitosan-tea polyphenol composite stabilizer, and concentrating through a PVDF (Polyvinylidene Fluoride) ultrafiltration membrane to obtain electrolyte with the vanadium concentration of 1.8 mol / L, wherein the molar ratio of V < 4 + > to V < 3 + > is 1: 1.2, Fe < 3 + > is less than 15 ppm, and Al < 3 + > is less than 10 ppm. In the process, the vanadium recovery rate reaches 95.2%, the energy consumption is 2.8 kWh / kg vanadium and is reduced by 65% compared with that of a traditional process, and the cycle life of the electrolyte is prolonged to 1200 times or above.

The invention relates to an electrolyte for synergistically stabilizing positive electrode iodine multi-electron reaction through four-combination zinc salt and a high-surface-capacity zinc-iodine soft package battery. The electrolyte comprises the four-combination zinc salt and water, in the electrolyte, the total concentration of zinc ions in the four combinations of zinc salts is 2 + / -0.2 mol / L; the four-combination zinc salt is a four-combination zinc salt; the SO4 < 2-> in the electrolyte buffers the pH value of a system, so that side reaction of a negative electrode is reduced; cH3COO <-> can be cross-linked with I3 <->, so that shuttling of polyiodide is inhibited, and reversibility of a two-electron reaction is enhanced; bromide ions Br <-> in the electrolyte are chemically combined with I < + > through isohalogen to excite four-electron reaction; the trifluoromethanesulfonate OTf <-> with strong electronegativity surrounds the positive electricity I < + > by virtue of an ion atmosphere effect, so that active water molecule attack hydrolysis failure is avoided, a synergistic stable positive electrode iodine multi-electron reaction is realized, and the high-surface-capacity zinc-iodine soft package battery is beneficial to promoting the development of the zinc-iodine battery to practical application.

An activatable dressing of the present disclosure comprises a biocompatible battery including a magnesium-based (Mg) anode; a silver / silver chloride-based (Ag / AgCl) cathode; and a sodium chloride (NaCl) impregnated separator disposed between the anode and cathode in a dry state, the separator comprising an inlet pad configured for introduction of a water-based fluid to the separator for activation of the battery. The activatable dressing further comprises stimulation electrodes electrically coupled to the Mg anode and Ag / AgCl cathode.

The invention discloses an organic composite electrode material, a preparation method thereof and a photo-assisted charging ammonium ion battery. The organic composite electrode material is obtained by compounding 2, 6-di [1-(pyrene-3, 4, 9, 10-tetraformyl diimine)] anthraquinone and reduced graphene oxide, and the organic composite electrode material is prepared by compounding the 2, 6-di [1-(pyrene-3, 4, 9, 10-tetraformyl diimine)] anthraquinone and the reduced graphene oxide. According to the invention, the photo-assisted charging strategy and the aqueous ion battery are combined, the ammonium ions are used as the charge carrier of the aqueous photo-assisted charging battery for the first time by virtue of the rapid dynamic characteristic of the ammonium ions in the aqueous electrolyte, and the advantages of rapid ion transmission of the ammonium ions in the electrolyte are utilized; the problem that the photoelectric reaction rate and the electrochemical oxidation reduction rate in the aqueous photo-assisted rechargeable battery are not matched is solved, collaborative optimization of the photoelectric reaction rate and the electrochemical reaction rate is achieved, the charging and discharging efficiency and the energy utilization rate of the battery are remarkably improved, and a new thought is provided for the next generation of photo-storage integrated battery technology.

The invention relates to an aqueous zinc-iodine battery electrolyte containing an amino acid additive and a preparation method and application thereof, and belongs to the technical field of aqueous zinc-iodine batteries. The preparation method of the aqueous zinc-iodine battery electrolyte containing the amino acid additives comprises the following steps: fully stirring and mixing zinc salt, D-penicillamine and deionized water according to a certain proportion to obtain the aqueous zinc-iodine battery electrolyte containing the amino acid additives. The amino acid-containing additive D-penicillamine used in the invention is preferentially coordinated with I-, and due to the lack of free I-in the reaction, the generation of polyiodide and the dissolution of I2 are inhibited, so that the shuttle effect is inhibited; the amino acid-containing additive D-penicillamine also participates in a Zn < 2 + > solvation sheath layer, so that the tendency of desolvation and Zn < 2 + > migration is improved, and the generation of zinc negative electrode byproducts is inhibited; in addition, the aqueous zinc-iodine battery electrolyte containing the amino acid additive D-penicillamine is simple in preparation method and low in cost.

According to the aqueous electrolyte, the preparation method and the aqueous metal ion battery provided by the invention, the zinc salt, the deionized water and the additive are mixed to obtain the electrolyte, and the additive comprises the carbamido-containing organic molecules, so that a double-electric-layer structure on the surface of zinc metal can be changed, an energy barrier in a stripping process can be reduced, and a zinc metal negative electrode can be regulated and controlled to be stripped uniformly; the battery is promoted to show stable cycle performance under high current and high capacity; meanwhile, the electrolyte containing the carbamido organic molecule additive optimizes the surface state of the zinc metal negative electrode and ensures the advantages of high ionic conductivity, low cost and environmental protection of the pure water system electrolyte; besides, the aqueous electrolyte provided by the invention can be applied to the rechargeable aqueous zinc ion battery, realizes long cycle life under high current density and deposition capacity, and has wide application prospects.

The invention discloses a universal water-based zinc-based battery electrolyte additive and a battery preparation method, and particularly relates to the technical field of water-based zinc-based secondary batteries, the universal water-based zinc-based battery electrolyte additive is a nitroimidazole organic matter, contains an imidazole ring and a nitryl group, and is characterized in that the nitroimidazole organic matter is a nitroimidazole organic matter; the high-electronegativity zinc ion electrode has one or more functional groups of methyl, hydroxyl, carboxyl, carbonyl, imino, sulfo and halogen, nitryl can be reduced to form imino or imidazole is subjected to ring opening to form an azo compound in the electrochemical process, and high-electronegativity sites can be adsorbed on the surface of the electrode or interact with zinc ions. Nitrogen sites with high electronegativity can be adsorbed to the surface of the zinc negative electrode, contact between water and the zinc negative electrode is isolated, a hydrogen evolution reaction and a corrosion side reaction are limited, the electrochemical environment of an electrode interface is stabilized, and the electrolyte additive can promote 3D diffusion of zinc ions, reduce the critical nucleation size of zinc deposition and inhibit growth of zinc dendrites.

The disclosure provides batteries that have long-duration or long-lifetime for energy storage applications. In one aspect, the disclosure provides perylene diimide molecules that are water soluble and can be used as energy storage materials. In operation, the perylene diimide molecules are oxidized in an anode chamber and the electrons released in the oxidation process flow to the cathode chamber where they reduce a molecule in the cathode chamber. The perylene diimide molecules in accordance with many embodiments are highly compatible with polymeric materials that are inexpensive and easy to process, hence allowing for significantly reduced manufacturing costs.

The invention belongs to the technical field of flexible energy storage devices, and discloses a flexible wearable solid-state zinc battery based on a poly-zwitter ion hydrogel electrolyte and a preparation method thereof. According to the flexible wearable solid-state zinc battery, a poly-zwitterionic hydrogel electrolyte is used as an electrolyte, a current collector is coated with a zinc powder dispersion liquid to serve as a flexible negative electrode, and the current collector is coated with a vanadium-based or manganese-based material dispersion liquid to serve as a flexible positive electrode. The poly-zwitterionic hydrogel electrolyte is prepared by copolymerizing a zwitterionic monomer, an acrylate monomer, a lithium salt and a photoinitiator and soaking in a zinc salt solution, has the characteristics of good mechanical properties, high ionic conductivity, wide electrochemical window and the like due to the unique structure, and can be applied to special environments such as stretching, curling, bending and the like. The preparation process is simple in route, has excellent electrochemical and mechanical properties, is large in specific capacity, is beneficial to large-scale industrialization, and has a good application prospect in flexible electronic equipment, wearable equipment and skin equipment.

A zinc / bromine flow battery comprises an electrolyte. The electrolyte comprises an active substance, a supporting electrolyte, and an additive. The additive is selected from at least one of 1-ethyl-3-methylimidazolium bromide, 1-ethyl-3-methylimidazolium chloride, 1-carboxymethyl-3-methylimidazolium bromide, and 1-carboxymethyl-3-methylimidazolium chloride. The use of the additive can regulate the deposition morphology of zinc and suppress zinc dendrites, and can also inhibit the diffusion of bromine on the positive electrode side, thereby improving the coulombic efficiency of the battery. Moreover, the complex product formed by the additive complexed with bromine does not produce solids during long-term cycling, whereas the complex product of conventional MEP in the later stage of battery cycling forms solids which are unevenly distributed on the electrode surface, reducing the voltage efficiency of the battery and shortening the service life of the battery.

The invention provides a composite electrolyte for a secondary metal battery as well as a preparation method and application of the composite electrolyte. The preparation method comprises the following steps: firstly, adding soluble zinc salt into deionized water to prepare an aqueous zinc salt electrolyte, gradually adding the amino acid additive after the pH value of the aqueous zinc salt electrolyte is stable, continuously stirring until the amino acid additive is completely dissolved, and standing to obtain the aqueous composite electrolyte containing the amino acid additive. Ammonium radicals of amino acids exist in the form of-NH4 or-NH3 +, and carboxyl exists in the form of-COOH or-COO-; the-NH3 < + > can be electrostatically adsorbed on the surface of the zinc negative electrode to change an electric double layer structure and prevent free water molecules from being adsorbed and electrolyzed, and the-NH4, the-COOH and the-COO <-> can change a hydrated zinc ion solvation structure and reduce the number of coordination numbers and active water molecules released in a desolvation process; the composite electrolyte is far better than an existing composite electrolyte obtained by using an amino acid additive, and the performance of a secondary zinc metal battery is effectively improved.

The present disclosure provides a vanadium electrolyte, a preparation method and use thereof. The method includes: adding sulfuric acid into vanadium-containing ore, and stirring to obtain a mixture; curing the mixture to obtain a clinker; leaching the clinker with water to obtain a vanadium-containing leaching solution; adding a first impurity-removing agent into the vanadium-containing leaching solution to obtain a first purified solution; adding an oxidizing agent, a ferric phosphate dihydrate seed crystal and a second impurity-removing agent into the first purified solution to obtain a second purified solution; adding a reducing agent and a flocculating agent into the second purified solution, and filtering a resultant solution to obtain a filtered solution; mixing the filtered solution with an extraction liquid to obtain a vanadium-supported organic phase; stripping the vanadium-supported organic phase to obtain a stripping liquid; and removing an organic phase from the stripping liquid to obtain the vanadium electrolyte.

Systems and methods of the various embodiments may provide bifacial sealed gas diffusion electrode (GDE) assemblies. In some embodiments, a bifacial sealed gas diffusion electrode (GDE) assembly includes active electrode layers on two opposing sides of the assembly. Various embodiments may provide architecture and / or sealing methods for GDE assemblies. In various embodiments, the GDE assemblies may be for use in devices. In various embodiments, the devices may be primary or secondary batteries. In various embodiments, these devices may be useful for energy storage. For example, bifacial sealed GDE assemblies of the various embodiments may form cathode electrodes (sometimes called air electrodes) of a battery, such as a metal-air battery.

The invention discloses a microphase separation hydrogel electrolyte with ion selectivity and a preparation method and application thereof. The electrolyte is prepared by constructing a microphase separation polymer network composed of a polyanionic polymer and an ion exchange group-containing polymer in a synergistic manner and inducing crosslinking by using metal ions. The formation of a continuous ion transmission channel in the hydrogel is realized. The technical problem that high ionic conductivity and high ionic transference number are difficult to obtain at the same time in a traditional hydrogel electrolyte is solved, spatial unwrapping and selective coordination of a polymer chain segment are induced through a microphase separation structure, and directional construction of an ion channel is achieved; and the ion conductivity of the electrolyte is remarkably improved, and meanwhile, the target ion transference number is further improved. The prepared hydrogel electrolyte has high mechanical stability, high ion flux and excellent ion selectivity, and can be widely applied to high-performance electrochemical devices such as batteries.

The invention discloses a zinc ion battery and a preparation method thereof, the zinc ion battery comprises a positive electrode, a negative electrode, a diaphragm and an electrolyte, and the zinc ion battery is characterized in that the positive electrode comprises a vanadium-based material, and the vanadium-based material comprises vanadium pentoxide intercalated by water molecules and metal ions and an MXene coating layer; the electrolyte comprises zinc salt, water and an additive, the additive comprises positive ions and negative ions, and the negative ions have the structure shown in the formula I. According to the zinc ion battery, water molecules and metal ions are used for intercalating vanadium pentoxide and coating MXene, and the water molecules and the metal ions are cooperatively used with the electrolyte with specific composition, so that ions can be quickly intercalated / deintercalated, the intrinsic conductivity of the material is enhanced, the structure of the material is stabilized, vanadium dissolution / metal ion dissolution at the positive electrode side can be prevented, and the service life of the zinc ion battery is prolonged. And the side reactions of interface hydrogen evolution and corrosion caused by decomposition of active water molecules on the zinc negative electrode side are synergistically inhibited. Through the comprehensive action of the factors, the zinc ion battery has excellent electrochemical performance.

The application provides an organic small-molecule electrolyte additive and application, and relates to the technical field of batteries. The organic small molecule is a carbon-containing three-membered ring alcohol small molecule, specifically, cyclopropanol, and the content of the electrolyte additive is 1%-10% v / v. Due to the metastable three-membered ring structure in the molecular structure of cyclopropanol, the ring-opening reaction is easily generated in the charging and discharging process, the electrode / electrolyte interface structure is reshaped, and the electrochemical performance is improved. Compared with conventional isopropyl alcohol, the cyclopropanol of the application can achieve the effect that excellent electrochemical performance can be presented only by adding a small amount of additive. The cyclopropanol has water solubility and organic co-solubility, and can form a uniform solution, and can be used in monovalent to multivalent ion energy storage systems of lithium, sodium, potassium, zinc, calcium, magnesium, cadmium, tin, aluminum, iron and the like, and will not have a negative impact on the solubility of the electrolyte, maintaining the high ionic conductivity of the electrolyte, which is simple, low in cost and good in application prospect.

This invention provides a modified positive electrode structure, a zinc-vanadium battery, and a method for preparing the same. [Solution] The zinc-vanadium battery comprises a modified positive electrode structure (including a positive electrode and a modified layer), a separator, a negative electrode, and an aqueous electrolyte. The positive electrode contains titanium. The modified layer is located on the positive electrode and contains 70-95 parts by weight of vanadium-based material, 3-45 parts by weight of conductive agent, and 3-45 parts by weight of binder. The separator is located on the modified layer. The negative electrode contains zinc and is located on the separator. The positive electrode, modified layer, separator, and negative electrode are all in the aqueous electrolyte. In the X-ray diffraction pattern of the vanadium-based material measured by XRD using CuKα1 rays, the peak intensity at 2θ=8°±1.0° is I8, and the peak intensity at 2θ=20°±1.0° is I 20 In that case, I8 and I 20 The ratio (I8 / I 20 ) is 0 <I8 / I 20 The condition ≤ 1.4 is satisfied. Furthermore, a modified cathode structure, a method for preparing the modified cathode structure, and a method for preparing a zinc-vanadium battery are also provided.

This invention discloses a type of sodium titanate with a layered crystal structure, its preparation method, and its application in aqueous magnesium-ion batteries, belonging to the field of aqueous magnesium-ion battery technology. This invention uses sodium titanate with a layered crystal structure as the negative electrode material in aqueous magnesium-ion batteries. Due to its excellent chemical and structural stability, sodium titanate can achieve reversible magnesium deposition in aqueous magnesium electrolytes. 2+ Intercalation / extraction. This invention synthesizes Na via a hydrothermal method and a high-temperature annealing process. 2 Ti 2 O 5 And Na 2 Ti 3 O 7 Materials. In magnesium chloride electrolyte, both sodium titanate materials exhibit extremely low charge / discharge potentials (Na). 2 Ti 2 O 5 -1.3 to -0.6V vs. SCE; Na 2 Ti 3 O 7 (-1.5 to -1V vs. SCE) and good cycle stability. Furthermore, Na... 2 Ti 2 O 5 The half-cell exhibits a charge-discharge specific capacity of up to 213 mAh / g at a current density of 2 A / g, and maintains a high specific capacity of 150 mAh / g even at a high current density of 10 A / g. The sodium titanate of this invention is an ideal anode material for aqueous magnesium batteries, possessing both low cost and environmental friendliness, and shows great promise for application in the field of aqueous magnesium-ion energy storage.

The instant invention relates to an electrolyte solution for a battery, the solution comprising an additive selected from the group consisting of polyquaternized polymers; the invention further relates the use of such additive and a battery comprising said additive.

A separator for a zinc ion battery, a method for preparing same, and a zinc ion battery including same are provided. The separator includes a separator substrate including a fiber material and a filler dispersed in the fiber material in a form of particles, wherein the filler is an ammonium phosphate salt.