111results about "Zinc-halogen accumulators" patented technology

The invention discloses a zinc-iodine battery positive electrode material based on corn straw shell derived porous carbon and a preparation method of the zinc-iodine battery positive electrode material. According to the material, corn straw shells serve as the sole carbon source, an indigenous nitrogen-doped biomass charcoal carrier with a hierarchical pore structure is prepared through pre-carbonization and KOH activation processes, and the material is characterized in that the specific surface area is larger than or equal to 1500 m < 2 > / g, and the micropore proportion is larger than 90%. The iodine is loaded on the carrier (the iodine content is greater than or equal to 45wt%) through a vacuum sublimation method to form the indigenous nitrogen-doped biomass charcoal / iodine composite material. According to the positive electrode material, through the synergistic effect of physical confinement and pyridine nitrogen chemical adsorption, the multi-iodide shuttle effect is effectively inhibited, so that the capacity retention rate of the zinc-iodine battery is greater than or equal to 93% after 40000 cycles under the current density of 2A g <-1 >, and the capacity retention rate is greater than 45% under the rate of 10A / g. The method has double benefits of agricultural waste resource utilization and high-performance energy storage device development.

The invention belongs to the technical field of zinc battery electrolyte, and discloses application of pyridine hydrochloride as an electrolyte additive in stabilizing a zinc negative electrode and realizing four-electron transfer of a zinc-iodine secondary battery. The hydrochloride containing the pyridine structure is used as an electrolyte additive, molecules of the pyridine structure are adsorbed on the surface of the zinc negative electrode to form a shielding layer, the deposition / stripping reversibility of the zinc negative electrode is improved, stabilization of the zinc negative electrode can be achieved, and the problems of zinc dendritic crystal, corrosion and hydrogen evolution are solved. Meanwhile, molecules with pyridine structures can activate and stabilize I- / I0 / I < + > four-electron redox reaction, inhibit I < + > hydrolysis side reaction and improve the energy density and cycling stability of the zinc-iodine battery. The problem of poor electrochemical deposition / stripping reversibility of a zinc negative electrode and the problem of poor stability of positive valence I < + > species of an iodine positive electrode of a four-electron transfer reaction are solved. The electrolyte containing the additive is low in cost, simple in method, easy to produce and high in practical value.

The invention discloses a two-phase electrolyte, a preparation method thereof and a liquid energy storage battery system, and belongs to the technical field of electrochemical energy storage. According to the invention, a liquid-liquid double-phase electrolyte is composed of a water-phase electrolyte and an organic-phase electrolyte, wherein the organic-phase electrolyte contains a coupling system of 1-(methyl-decyl)-3-methylimidazolium bromide, tris (methyl-decyl) methyl ammonium bromide and (10-octadecyl) alkyl trimethyl ammonium bromide in a molar ratio of (5-7): (2-4): 1. During charging, positive electrode bromide ions are subjected to an oxidation reaction to generate a bromine simple substance, and meanwhile, the bromine simple substance and a coupling system of the quaternary ammonium bromide compound and the bromine complexing agent provided by the invention form a stable polybromine complex product, so that the polybromine complex product is prevented from being migrated into a water-phase electrolyte, and the purpose of improving the stability of the water-phase electrolyte in the absence of a diaphragm is achieved. The self-discharge reaction of bromine is significantly inhibited at a high temperature exceeding the boiling point temperature of bromine, the coulombic efficiency and energy efficiency of the liquid energy storage battery are improved, the system cost is reduced, and the long-term cycle stability of the liquid energy storage battery is improved.

The invention relates to the field of nano materials and electrochemical technology materials, in particular to a melamino-formaldehyde / MXene composite material, a derived carbon material thereof, a preparation method and application. According to the preparation method disclosed by the invention, MXene is taken as a substrate, and protonated melamine formaldehyde molecules are inserted into MXene layers through an electrostatic self-assembly effect, so that the melamine formaldehyde / MXene composite material is synthesized; and carrying out high-temperature calcination on the basis to prepare the melamine formaldehyde / MXene composite material derived carbon material. According to the invention, active sites for adsorption and catalytic conversion of iodine species are provided while self-stacking of MXene is solved, and the melamine formaldehyde / MXene composite material is used as the positive electrode material of the aqueous zinc-iodine battery, so that the iodine species can be effectively anchored, and the active sites for catalytic conversion of iodine are fully provided; the reversibility and the structural stability of the electrode reaction are enhanced, so that the electrochemical performance of the battery is greatly improved.

The invention relates to an iodine-loaded positive electrode for a zinc-iodine battery and a preparation method and application of the iodine-loaded positive electrode, and belongs to the technical field of positive electrode materials for zinc-iodine batteries. The preparation method of the iodine-loaded positive electrode for the zinc-iodine battery comprises the following steps: mixing an iodine-loaded carbon material, conductive carbon black, a polysaccharide binder and deionized water in proportion, grinding into slurry, uniformly coating a current collector with the slurry, and drying to obtain the iodine-loaded positive electrode for the zinc-iodine battery. As the polysaccharide binder is rich in a large number of active functional groups (hydroxyl, carboxyl and the like), dissolution of active iodine and a shuttle effect of polyiodide can be inhibited through a chemical adsorption effect, corrosion to a zinc negative electrode caused by attenuation of battery capacity and shuttle of the polyiodide is avoided, and the polysaccharide binder has a good application prospect in the zinc-iodine battery.

The invention relates to an electrolyte for synergistically stabilizing positive electrode iodine multi-electron reaction through four-combination zinc salt and a high-surface-capacity zinc-iodine soft package battery. The electrolyte comprises the four-combination zinc salt and water, in the electrolyte, the total concentration of zinc ions in the four combinations of zinc salts is 2 + / -0.2 mol / L; the four-combination zinc salt is a four-combination zinc salt; the SO4 < 2-> in the electrolyte buffers the pH value of a system, so that side reaction of a negative electrode is reduced; cH3COO <-> can be cross-linked with I3 <->, so that shuttling of polyiodide is inhibited, and reversibility of a two-electron reaction is enhanced; bromide ions Br <-> in the electrolyte are chemically combined with I < + > through isohalogen to excite four-electron reaction; the trifluoromethanesulfonate OTf <-> with strong electronegativity surrounds the positive electricity I < + > by virtue of an ion atmosphere effect, so that active water molecule attack hydrolysis failure is avoided, a synergistic stable positive electrode iodine multi-electron reaction is realized, and the high-surface-capacity zinc-iodine soft package battery is beneficial to promoting the development of the zinc-iodine battery to practical application.

The invention relates to an aqueous zinc-iodine battery electrolyte containing an amino acid additive and a preparation method and application thereof, and belongs to the technical field of aqueous zinc-iodine batteries. The preparation method of the aqueous zinc-iodine battery electrolyte containing the amino acid additives comprises the following steps: fully stirring and mixing zinc salt, D-penicillamine and deionized water according to a certain proportion to obtain the aqueous zinc-iodine battery electrolyte containing the amino acid additives. The amino acid-containing additive D-penicillamine used in the invention is preferentially coordinated with I-, and due to the lack of free I-in the reaction, the generation of polyiodide and the dissolution of I2 are inhibited, so that the shuttle effect is inhibited; the amino acid-containing additive D-penicillamine also participates in a Zn < 2 + > solvation sheath layer, so that the tendency of desolvation and Zn < 2 + > migration is improved, and the generation of zinc negative electrode byproducts is inhibited; in addition, the aqueous zinc-iodine battery electrolyte containing the amino acid additive D-penicillamine is simple in preparation method and low in cost.

The invention discloses a preparation method of a Zr-MOF nano material, which comprises the following steps: adding deionized water into a reaction mixture consisting of zircon salt, 4 ', 4', 4 ', 4'-(ethylene-1, 1, 2, 2-tetraalkyl) tetra ([1, 1 '-biphenyl]-4-carboxylic acid), an acid regulator and an organic solvent to form a mixed solution, heating and reacting in a high-pressure reaction kettle, and cooling to room temperature to obtain the Zr-MOF nano material. And centrifugally collecting and cleaning a product, and drying in a dark place to obtain the Zr-MOF nano material. According to the application of the Zr-MOF nano material in the water-based zinc-iodine battery, the Zr-MOF nano material and iodine are prepared into a composite material, then the composite material is prepared into electrode slurry, the surface of a stainless steel mesh is coated with the electrode slurry, and the electrode slurry is dried to serve as an electrode plate of the water-based zinc-iodine battery. The preparation process is simple, Zr-MOF nano-materials with different structures can be obtained by adjusting the deionized water content of the system, and the Zr-MOF nano-materials can be applied to an electrode plate of an aqueous zinc-iodine battery to improve the cycle performance of the battery.

The invention relates to the technical field of zinc-iodine battery electrolyte, in particular to aqueous zinc-iodine electrolyte as well as a preparation method and application thereof. The aqueous zinc-iodine battery electrolyte contains an additive and a zinc salt, the molar concentration of the additive is 0.15 M to 0.8 M, and the additive is selected from one or more of triethylamine hydrochloride, 1-butyl-1-methylpyrrolidine chloride, 1, 3-dimethylimidazole chloride, pyridine hydrochloride, aniline hydrochloride, guanidine hydrochloride and 1-ethyl-3-methylimidazole chloride. The method can directionally regulate and control zinc negative electrode deposition and iodine positive electrode reaction kinetics, realizes four-electron reversible conversion, promotes uniform deposition of zinc ions and inhibits side reactions during charging, inhibits multi-iodide shuttle and I < + > hydrolysis during discharging, and has wide application prospects in the zinc-iodine battery electrolyte industry.

The invention belongs to the technical field of zinc-iodine batteries, and particularly relates to doped polyaniline, a preparation method thereof and a zinc-iodine battery. The preparation method comprises the following steps: in an acidic environment, mixing substituted aniline, aniline and an oxidizing agent to obtain a mixed solution, and carrying out oxidative polymerization reaction to obtain doped polyaniline; wherein a substituent group of the substituted aniline is an electron withdrawing group; the number of the substituent group is 1; the molar ratio of the substituted aniline to the aniline is (5-25): 100; the positive electrode material in the zinc-iodine battery prepared from the doped polyaniline has high specific capacity and cycling stability.

The invention provides a dry-process low-temperature pulse iodine positive electrode preparation method and a battery, and relates to the technical field of iodine positive electrode preparation, the iodine positive electrode preparation method comprises the following steps: mixing elemental iodine with activated carbon to obtain a carbon-iodine composite material, then putting the solid powdery carbon-iodine composite material, a conductive agent and polytetrafluoroethylene into a high-speed stirrer, and stirring at a high speed; and sequentially carrying out constant-speed intermittent pulse stirring, speed-reducing pulse stirring and speed-increasing pulse stirring, and finally rolling to obtain the iodine positive electrode. According to the stirring operation, the temperature rise effect in the high-speed stirring process is inhibited, the mixture obtained after polytetrafluoroethylene fiberization is obtained through low-temperature pulse stirring, the surface of the prepared iodine positive plate is smooth and flat, the cracking phenomenon does not exist, the shearing force is regulated and controlled through low-temperature pulse stirring, mechanical disturbance is weakened, and the iodine positive plate has the good application prospect. And the temperature is reduced to inhibit thermal desorption of iodine molecules, so that the damage to the iodine adsorption effect of porous carbon is reduced, and the mechanical strength and electrochemical performance of the electrode are remarkably improved.

This invention provides a modified positive electrode structure, a zinc-vanadium battery, and a method for preparing the same. [Solution] The zinc-vanadium battery comprises a modified positive electrode structure (including a positive electrode and a modified layer), a separator, a negative electrode, and an aqueous electrolyte. The positive electrode contains titanium. The modified layer is located on the positive electrode and contains 70-95 parts by weight of vanadium-based material, 3-45 parts by weight of conductive agent, and 3-45 parts by weight of binder. The separator is located on the modified layer. The negative electrode contains zinc and is located on the separator. The positive electrode, modified layer, separator, and negative electrode are all in the aqueous electrolyte. In the X-ray diffraction pattern of the vanadium-based material measured by XRD using CuKα1 rays, the peak intensity at 2θ=8°±1.0° is I8, and the peak intensity at 2θ=20°±1.0° is I 20 In that case, I8 and I 20 The ratio (I8 / I 20 ) is 0 <I8 / I 20 The condition ≤ 1.4 is satisfied. Furthermore, a modified cathode structure, a method for preparing the modified cathode structure, and a method for preparing a zinc-vanadium battery are also provided.

The invention discloses a water-based binder, a zinc-iodine battery positive pole piece and a preparation method and application of the zinc-iodine battery positive pole piece. The preparation method of the water-based binder comprises the following steps: mixing polyethyleneimine, methyl iodide and a solvent, and carrying out graft polymerization reaction to obtain the water-based binder. The aqueous binder provided by the invention can keep excellent electrochemical stability in an aqueous electrolyte, so that the assembled zinc-iodine battery has long cycle performance; the preparation method of the aqueous binder provided by the invention is simple and environment-friendly, is more suitable for industrial large-scale production, and has a wide industrial application prospect.

A battery module (400) that is a static, open pool single cell battery which may have electrode elements (442, 443) of the same polarity spaced apart but electrically connected in parallel to one another and suspended from a common bus into a common electrolyte pool (405), in addition to a battery box (400) that receives a plurality of electrode elements into the common electrolyte pool for the open pool battery. The electrode elements (442, 443) are alternating cathode elements (442) and anode elements (443). A method for manufacture of the battery module is also described.

An amphoteric ion exchange separator for a redox battery according to various embodiments of the present invention may comprise a polymer matrix into which a zwitterionic functional group having a quaternary ammonium group and a sulfonic acid group is introduced.

Provided is a fluoride ion secondary battery having a capacity larger than that of a conventional one. The fluoride ion secondary battery has a negative electrode including zirconium fluoride as a negative electrode active material. The zirconium fluoride may be in the form of particles with an average particle size of 100 nm or less, and the negative electrode may have a zirconium fluoride content of less than 50 % by mass. The negative electrode active material may further include metallic zirconium, which may be in the form of particles with an average particle size of 75 μm or less. The negative electrode may have a metallic zirconium content of 8% by mass or less.

Provided herein are phosphorus battery electrolyte additive chemicals for use in aqueous batteries that prevent self-discharge in the form of corrosion and hydrogen evolution, which increases the efficiency and extends the shelf-life of the batteries.

An electrolyte composition for a Zn-MnO2 electrochemical device said electrolyte composition comprising water, a zinc salt, and a combination of additives, wherein the combination of additives comprises an organic additive and an additive of formula (I), its use and an electrochemical device comprising said electrolyte.

A cathode electrode of a Zinc Bromine Static Battery (ZBSB) apparatus. The cathode electrode comprises 80-90% by weight of a mixture of a quaternary ammonium salt fused with activated carbon to form a salt-fused activated carbon component. The cathode electrode further comprises 5-12% by weight of super P carbon. Furthermore, the cathode electrode comprises 1-5% by weight of a binder. The salt-fused activated carbon component, super P carbon, and the binder are mixed together to form the cathode electrode.

An embodiment of the present disclosure is a composite material comprising: about 35 wt% to about 70 wt% of at least one polyethylene polymer; about 25 wt% to about 55 wt% of at least one graphite filler; and at least 50 square meters per gram (m 2 and about 2 wt % to about 15 wt % of a carbon powder filler having a BET surface area of ​​at least 0.94 grams per cubic centimeter (g / cm 3 ). 3 ), a melt flow rate (MFR) of at least 10 grams per 10 minutes (g / 10 min) measured at 190° C. and 21.6 kilograms (kg), and an environmental stress crack resistance (ESCR) of at least 500 hours. The composition has a volume electrical resistivity of less than 5 ohm-centimeters (ohm-cm) and an MFR of at least 4 g / 10 min measured at 280° C. and 21.6 kg.

The present invention relates to the assembly of a negatively charged dendrite-inhibiting ionomer membrane for aqueous rechargeable zinc metal batteries (AZMB) made by crosslinking sulfonated polyvinyl alcohol (PVS) and polyvinyl alcohol (PVA).

This invention provides a modified positive electrode structure, a zinc-vanadium battery, and a method for preparing the same. [Solution] The zinc-vanadium battery comprises a modified positive electrode structure (including a positive electrode and a modified layer), a separator, a negative electrode, and an aqueous electrolyte. The positive electrode contains titanium. The modified layer is located on the positive electrode and contains 70-95 parts by weight of vanadium-based material, 3-45 parts by weight of conductive agent, and 3-45 parts by weight of binder. The separator is located on the modified layer. The negative electrode contains zinc and is located on the separator. The positive electrode, modified layer, separator, and negative electrode are all in the aqueous electrolyte. In the X-ray diffraction pattern of the vanadium-based material measured by XRD using CuKα1 rays, the peak intensity at 2θ=8°±1.0° is I8, and the peak intensity at 2θ=20°±1.0° is I 20 In that case, I8 and I 20 The ratio (I8 / I 20 ) is 0 <I8 / I 20 The condition ≤ 1.4 is satisfied. Furthermore, a modified cathode structure, a method for preparing the modified cathode structure, and a method for preparing a zinc-vanadium battery are also provided.

An electrolyte of a static zinc-based battery, includes zinc bromide in a molar concentration ranging from 1.5 M to 3.0 M, a mixture of two or more quaternary ammonium salts as a bromine complexing agent in a range of 30% to 55% of the molar concentration of the zinc bromide, a glycol based anti-freezing agent in molar concentration ranging from 0.1 M to 2.0 M; and one or more additional supporting ionic conducting agents selected from a group comprising of zinc chloride, potassium chloride, magnesium chloride, lithium chloride, calcium chloride, or a combination thereof. Each of the one or more additional supporting ionic conducting agents or their combination is in a molar concentration ranging from 0.5 M to 2 M.

The invention relates to the technical field of electrochemical energy storage batteries, in particular to a zinc-iodine battery positive electrode composite material as well as a preparation method and application thereof. The zinc-iodine battery positive electrode composite material comprises a chitosan-derived nitrogen self-doped porous carbon material and active iodine, and the chitosan-derived nitrogen self-doped porous carbon material is prepared by taking KOH as a pore-foaming agent and chitosan as a carbon source and a nitrogen source through sol-gel, freeze drying and high-temperature carbonization processes. By introducing the chitosan-derived nitrogen self-doped porous carbon material, the performance of the zinc-iodine battery is remarkably improved.

Improved systems and methods for balancing a state of charge (SOC) of a plurality of batteries are disclosed. For example, a system may include multiple battery strings (301, 302) connected in parallel to one another through a common bus (340). Each battery string may include a power converter (321, 322) and multiple battery modules (311A...312C) connected in series. The power converter may be configured to regulate the combined power output of the battery modules. Each battery module may include multiple relays (461...464) that may be controlled to discharge, charge, and / or bypass that battery module. Collectively, the power converters of the battery strings and the relays of the battery modules may be controlled to balance the battery strings with one another and to balance the battery modules within each of the battery strings.

An electrolyte composition for a Zinc metal electrochemical device said electrolyte composition comprising water, a zinc salt, and an additive of formula (I), its use and an electrochemical device comprising said electrolyte.

The invention relates to a strong coordination type electrolyte with simple components, and belongs to the technical field of zinc-iodine battery electrolyte additives, and the electrolyte only contains zinc sulfate, an additive and water; the additive comprises any one of tetramethyl guanidine hydrochloride, betaine hydrochloride, sodium bromide, trimethyl ammonium bromide and trimethyl sulfoxide bromide. According to the electrolyte, hydrolysis failure of the electrolyte is inhibited by means of a strong coordination mode and efficient complexing I < + >, only a low-concentration single additive component is needed, and the electrolyte also keeps the advantage of high ionic conductivity of a water-based electrolyte and can accelerate substance transmission in a thick electrode, so that relatively high coulombic efficiency and cycling stability are realized under high iodine surface loading capacity; the invention also provides an ampere-hour level four-electron zinc-iodine soft package battery with high surface capacity, which can break through the performance bottleneck of the existing zinc-iodine battery in the aspect of practical application.

The invention relates to a high-energy-density aqueous zinc-iodine battery and an efficient electrolyte additive, and belongs to the field of energy storage devices, and the high-energy-density aqueous zinc-iodine battery comprises zinc salt and an electrolyte additive capable of stabilizing I, the electrolyte additive is a halogenated organic compound, the molecule of the halogenated organic compound comprises at least one halogen atom and at least one polar group selected from nitro, carbonyl, imino, sulfo or hydroxyl, and the number of carbon atoms of the compound is 1-10. According to the high-energy-density aqueous zinc-iodine battery and the efficient electrolyte additive, the specific halogenated organic matter additive is introduced into the electrolyte, so that the four-electron conversion reaction mechanism (I / I / I) of iodine is successfully activated and stabilized, the discharge capacity of a traditional zinc-iodine battery is increased to 422.9 mAh g or above from about 182.9 mAh g, the specific capacity is doubled, and the energy consumption is reduced. And the energy density of the water-based zinc-iodine battery is obviously improved.

The application discloses a kind of bottle-in-bottle structure silver porous carbon composite material as zinc iodine battery positive carrier and its preparation and application in zinc iodine battery positive electrode.The bottle-in-bottle structure silver porous carbon composite material Ag@KJ600 is synthesized by ultrasonic immersion method, dried, calcined, ground with I2 in argon protection environment, sealed and heated for 12 hours to obtain Ag@KJ600 / I2.When the composite material is used as iodine positive carrier, it can chemically adsorb polyiodide formed during the cycle process, inhibit the shuttle effect of polyiodide, and further reduce the corrosion of negative zinc and the loss of active material.Ag@KJ600 / I2 active material can be applied to zinc iodine battery iodine positive electrode, and excellent electrochemical performance is shown.

Improved systems and methods for balancing a state of charge (SOC) of a plurality of batteries are disclosed. For example, a system may include multiple battery strings connected in parallel to one another through a common bus. Each battery string may include a power converter and multiple battery modules connected in series. The power converter may be configured to regulate the combined power output of the battery modules. Each battery module may include multiple relays that may be controlled to discharge, charge, and / or bypass that battery module. Collectively, the power converters of the battery strings and the relays of the battery modules may be controlled to balance the battery strings with one another and to balance the battery modules within each of the battery strings.