1019 results about "Polymer thin films" patented technology

The invention discloses a preparation method of a degradable transparent conductive polymer film, and belongs to the technical field of film preparation. Preparing dispersion liquid I through graphene oxide quantum dots; preparing a dispersion liquid II from polyaniline nanofibers; dissolving pyrrole and toluenesulfonic acid in N, N-dimethylformamide to prepare a reaction solution, adding the dispersion liquid I and the dispersion liquid II, stirring, and adding ferric chloride hexahydrate to obtain a reaction solution; adjusting the pH value of the reaction solution to 1.5, and heating to obtain a polypyrrole solution; preparing cellulose acetate, polyvinyl alcohol and N, N-dimethylformamide to obtain a cellulose acetate solution; mixing the polypyrrole solution and the cellulose acetate solution, adding glutaraldehyde to obtain a mixed solution, and pouring the mixed solution into a mold to prepare a composite wet film; and putting the composite wet film into a hot-pressing forming machine for hot-pressing to generate the polymer film. The conductive polymer film prepared by the invention can be applied to the fields of supercapacitor electrode materials, electromagnetic shielding materials, flexible sensors and the like, and provides a new high-performance material choice for the development of related fields.

The invention relates to the technical field of petrochemical engineering, and discloses a temperature-resistant anti-swelling agent for fracturing and a preparation process thereof.The preparation method comprises the steps that glycerol triglycidyl ether and diethanol amine are subjected to a ring-opening reaction, a polyhydroxy tertiary amine monomer is obtained, then the polyhydroxy tertiary amine monomer and chloromethylated polystyrene are subjected to a quaternization reaction, and the temperature-resistant anti-swelling agent for fracturing is obtained. Quaternary ammonium salt groups of the anti-swelling agent and negative charges on the surface of clay form electrostatic interaction, and hydroxyl groups and the surface of the clay form hydrogen-bond interaction, so that the anti-swelling agent can be firmly adsorbed on the surface of the clay to form a layer of polymer film, the clay is prevented from being in contact with water, the phenomenon that the clay swells when encountering water is effectively inhibited, and the anti-swelling rate is very high. And the anti-swelling agent contains a heat-resistant polystyrene molecular chain, has excellent high temperature resistance, can maintain good structural stability at high temperature, still maintains high anti-swelling rate, and is suitable for a fracturing fluid system for high-temperature oil reservoir exploitation.

The invention belongs to the field of dielectric materials and dielectric energy storage, and particularly relates to a fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film and a preparation method thereof. The preparation method specifically comprises the following steps: adding fluorene polyester and polyaryletherurea into a solvent, fully dissolving to obtain a mixed solution, uniformly coating a substrate with the mixed solution, and then drying; and carrying out vacuum annealing on the dried film, and then carrying out curing treatment to strip the film from the substrate to obtain the fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film, thereby improving the charge-discharge efficiency and high discharge energy density of the polymer under high temperature and high field, and solving the problems of high electric leakage loss and low cost of the existing polymer film. And the charging and discharging efficiency is low.

The invention belongs to the technical field of two-dimensional materials, and particularly relates to a preparation method of a corner heterojunction. According to the preparation method, when the two-dimensional material sheet is prepared, based on the characteristics of smooth surface and high viscosity of the hydrophilic polymer layer, a large-area two-dimensional material can be stripped from the silicon substrate with the hydrophilic polymer film layer, the stripping process is clean, and the two-dimensional material is not damaged; when the corner heterojunction is prepared, an intermediate two-dimensional material or an active interface does not contact any polymer in the whole transfer process by adjusting the shape and size of a transfer medium based on a Van der Waals force pickup transfer method, so that the pollution of a heterogeneous interface is greatly reduced; the efficient and fast preparation of the Van der Waals heterostructure without polymer residues and bubbles on the interface is realized.

The invention provides a flexible conductive substrate, a flexible conductive substrate preparation method and a flexible perovskite solar cell comprising the flexible conductive substrate. The flexible conductive substrate comprises a flexible substrate layer, a substrate buffer layer and a transparent conductive layer which are stacked from bottom to top. The substrate buffer layer is made of transparent metal oxide, and the thickness of the substrate buffer layer is 5-80 nm; the flexible conductive substrate adopts a composite flexible substrate structure, the polymer film is used as the flexible substrate layer, and the nanoscale substrate buffer layer formed by the transparent metal oxide is inserted between the flexible substrate layer and the transparent conductive layer, so that the surface stress distribution of the flexible substrate layer is effectively released / homogenized; and meanwhile, the connection strength between the flexible substrate layer and the transparent conductive layer is increased, so that the transparent conductive layer is not easy to desorb, and the photoelectric property and the mechanical quality of the ultrathin flexible perovskite solar cell prepared based on the novel flexible conductive substrate structure are remarkably improved.

In one aspect, a blank is formed of a substrate laminated with a thin polymer film layer. The blank includes fold lines and cutouts such that it is formable into a pack with a base that is fully sealed by the film layer, thereby solving the technical problem of packs formed from blanks where the bases include unsealed gaps or holes. In further aspects, a folded blank, packaging articles formed therefrom, and methods of manufacture are provided.

The invention discloses a method for preparing a flexible electrode layer by using laser-induced graphene and the flexible electrode layer. The method comprises the following steps: preparing a laser-induced graphene pattern on the surface of a polymer by using a carbon dioxide laser; and coating flexible photosensitive resin on the surface of the polymer with the laser-induced graphene pattern, carrying out ultraviolet curing, and peeling off the cured flexible photosensitive resin and the laser-induced graphene pattern from the polymer film to obtain the LIGG and flexible photosensitive resin double-layer structure. The graphene pattern induced by laser is quickly, simply and conveniently transferred to the flexible photosensitive resin substrate by adopting an ultraviolet curing method, and the flexible electrode layer which can be bent, can be patterned, has excellent conductivity and is provided with the LIGG and flexible photosensitive resin layer structure is obtained.

The invention relates to the technical field of organic materials, and discloses an organic long-afterglow material as well as a preparation method and application thereof. The compounds (I)-VI are rigid aromatic organic compounds containing heteroatoms O, S or N, can be applied to organic long-afterglow materials and serve as guest components of the long-afterglow materials. When a substance containing melamino-formaldehyde resin is used as a main component of the organic long-afterglow material, a cross-linked structure of the organic long-afterglow material can effectively prevent a phosphorescence quenching behavior of water and oxygen on guest molecules; the organic long-afterglow material is long in afterglow luminescence life, good in long-afterglow performance stability, high in phosphorescence quantum yield and high in luminescence efficiency; the polymer film prepared by taking the organic long afterglow material as the raw material can be excited by ultraviolet in sunlight, can generate response under extremely low ultraviolet intensity, and has ultraviolet detection potential.

The invention belongs to the technical field of three-dimensional micro-nano manufacturing, and discloses a three-dimensional composite film and a preparation method thereof.The method comprises the steps that a conductive functional structure is prepared on the surface of a prepared high-molecular polymer composite double-layer stress film; the high-molecular polymer composite double-layer stress film comprises a first high-molecular polymer film and a second high-molecular polymer film arranged on the surface of the first high-molecular polymer film, and the swelling ratio of the first high-molecular polymer film is different from that of the second high-molecular polymer film; the conductive functional layer is prepared on the surface of the second high-molecular polymer film; then cutting to obtain a planar composite double-layer stress film; and the planar composite double-layer stress film is subjected to swelling deformation in a solvent, and the three-dimensional composite film in a preset shape is obtained. According to the method, a stress difference introduction strategy based on a swelling mechanism is utilized, so that integrated curling forming manufacturing of the flexible polymer functional film is realized.

This invention relates to a method for preparing a p-aminobenzenesulfonic acid blended nanofiltration membrane and its application. The invention aims to address the technical problem that existing polymer thin films struggle to simultaneously increase permeate flux while improving retention rate. This invention provides a nanofiltration membrane with high efficiency in separating cobalt and lithium ions and significantly enhanced permeate flux. It achieves this by doping p-aminobenzenesulfonic acid during the preparation of traditional TFC nanofiltration membranes, efficiently introducing sulfonic acid groups to promote the formation of an ordered nanochannel structure in the polyamide network, thereby increasing water flux. Simultaneously, the negative charge carried by the sulfonic acid groups enhances the overall electronegativity of the membrane, making it more effective against Co ions. 2+ The electrostatic adsorption capacity is significantly higher than that of Li + This enables efficient separation of cobalt and lithium ions. The nanofiltration membrane material provided by this invention can be widely used in the resource-based treatment of acid leaching wastewater from lithium cobalt oxide batteries, achieving efficient separation and recovery of cobalt and lithium, and improving economic benefits and resource utilization.

The invention belongs to the field of composite materials, and particularly relates to a nanofiber radiation refrigeration heat insulation film with a bionic multilayer structure. The device sequentially comprises a bionic anti-reflection layer, a solar spectrum reflection layer, a nanofiber porous heat insulation layer and an atmospheric window radiation layer from outside to inside, the bionic anti-reflection layer is a sub-wavelength nano bulge array simulating a moth eye structure and is formed on the outer surface of the solar spectrum reflecting layer; the solar spectrum reflecting layer is a polymer film doped with high-reflectivity nanoparticles; the nanofiber porous heat insulation layer is a porous membrane formed by interweaving polymer nanofibers prepared by an electrostatic spinning technology; the atmospheric window radiation layer is a functional layer formed by coating or blending high-emissivity inorganic nanoparticles on the inner surface of the nanofiber porous heat insulation layer; the film integrates bionic antireflection, high sunlight reflection, efficient heat radiation and physical heat insulation, and efficient, stable and flexible daytime radiation refrigeration is achieved.

The invention relates to a high-temperature-resistant polymer binder and a preparation method thereof. The binder is composed of a mixture of resin containing a siloxane unit polyimide main chain and an epoxy group side chain and tannic acid. Wherein the main chain containing siloxane and imide units endows the adhesive with excellent heat-resistant stability, excellent processability and excellent adhesion with glass and ceramic materials, and the adhesive can be cured at room temperature through the epoxy side group; the mixed tannic acid can form strong interface bonding with a polymer film and a metal material through a multiple hydrogen bond network, so that the tannic acid has important application prospects in the fields of semiconductor packaging, thermal interface materials and the like.

Thin polymer films may comprise a first polymer layer comprising poly(vinylidene fluoride); a second polymer layer comprising poly(vinylidene fluoride); and a nanofiller-polymer layer interposed between the first polymer layer and the second polymer layer, the nanofiller-polymer layer comprising poly(methyl methacrylate) and nanosheets dispersed in the poly(methyl methacrylate); the nanosheets comprising mica nanosheets and / or hexagonal boron-nitride nanosheets; wherein 50-99% of the nanosheets in the nanofiller-polymer layer are oriented parallel to a width dimension of the first polymer layer.

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.

The invention relates to the field of sewage treatment, and provides double-layer anaerobic bacteria-algal-bacterial symbiotic immobilized particles as well as a preparation method and application thereof. The double-layer anaerobic bacteria-algal-bacterial symbiotic immobilized particle sequentially comprises a PAN (polyacrylonitrile) fiber particle, an anaerobic bacteria layer, a polymer film, an algal-bacterial symbiotic layer and a calcium alginate gel layer from inside to outside. The preparation method comprises the following steps: modifying PAN fiber particles to enable the PAN fiber particles to carry positive charges, and putting the modified PAN fiber particles into an anaerobic bacteria solution for dipping adsorption; coating a PVDF (Polyvinylidene Fluoride) solution to form a polymer film, so as to obtain PAN (Polyacrylonitrile) fiber particles for immobilizing anaerobic bacteria; soaking in a mixed solution of an algal-bacterial symbiotic suspension and sodium alginate, taking out, putting into a calcium chloride solution, and cross-linking and hardening to form gel. Anaerobic microorganisms and aerobic microorganisms in the immobilized particles are subjected to regional division and immobilization, and the inner-layer anaerobic microorganisms and the outer-layer aerobic microorganisms play a greater role in different regions of a carrier by virtue of a physiological synergistic effect among the microorganisms, so that carbon, nitrogen and phosphorus in sewage are deeply removed.

The invention belongs to the field of polymer films, and discloses a polyvinylidene fluoride film based on cross-linking reaction and a preparation method and application thereof, and the preparation method comprises the following steps: mixing cyclohexanone, polyvinylidene fluoride and polyoxyethylene diamine to obtain a mixed solution; curing the mixed solution into a film to obtain a blended polyvinylidene fluoride film; and carrying out cross-linking reaction on the blended polyvinylidene fluoride film to obtain a cross-linked polyvinylidene fluoride film, and culturing the cross-linked polyvinylidene fluoride film at 150-165 DEG C to obtain the polyvinylidene fluoride film with high gamma crystal form content. Through detection and comparison, in the polyvinylidene fluoride film based on the cross-linking reaction, the gamma-phase crystal content is obviously increased, and the alpha-phase crystal content is obviously reduced. The method is simple in process and convenient to operate, polyvinylidene fluoride is endowed with the capacity of obtaining gamma crystals at a low temperature in a short time, and the method can be widely applied to the fields of pressure sensors, lithium ion batteries, automobile motors, high-temperature-resistant thermistor devices and the like.

Proposed is a method for forming an electroless plating electrode through selective cross-linking layer formation using a laser, specifically, the method includes forming a selective cross-linking layer by sintering a water-soluble polymer thin film layer, which is formed on a substrate by coating, to form a patterned shape thereon using a laser, followed by forming a precise metal pattern by electroless-plating the selective cross-linking layer with copper, nickel, or other metals. The method offers a simple manufacturing process, cost efficiency, and flexibility in manufacturing without being limited by the shape of a substrate, thereby patterns may be formed on various substrates. A catalyst material for electroless plating is mixed with a polymer material to directly cross-link the substrate. Thus, durability is improved but also an electrode may be formed with a substrate by electroless plating simply and in a short time due to use of only a single material.

The utility model relates to the field of electromagnetic shielding films, in particular to an electromagnetic shielding film, which comprises a multi-layer composite structure and is characterized in that the electromagnetic shielding film is formed by compounding at least four layers of materials, namely a base material layer 1, a conductive grid layer 2, an electromagnetic absorption layer 3 and a protective layer 4 in sequence; the base material layer 1 adopts a light high-strength polymer film as a substrate and has excellent flexibility and mechanical strength; the conductive grid layer 2 is located on the base material layer 1, is of a grid structure formed by fine metal wires or high-conductivity polymer fibers, is formed through a precise weaving or printing technology and is used for guiding and dispersing electromagnetic wave energy; the technical problem that the service life and the shielding effect of the electromagnetic shielding film are affected due to the fact that the electromagnetic shielding film is prone to abrasion, scraping and the like in the long-term use process is solved.

In a system and a method for reprocessing ultra-high molecular weight polymer film offcuts, the system comprises a feed device 202 and a comminution device 203. The feed device is configured to provide an ultra-high molecular weight polymer film offcut to the comminution device. The comminution device comprises at least one cutting screen, wherein the cutting screen comprises a plurality of screen openings and a plurality of cutting projections, wherein at least one cutting projection spans a cutting opening allocated to it, and wherein the comminution device is configured to generate relative motion between the cutting screen and the fed polymer film offcut in order to comminute the polymer film offcut.

In a first aspect, a coating solution includes a soluble polymer and a crosslinking precursor. The soluble polymer includes an imide group. The crosslinking precursor includes a first amine group that is either reactive or passivated towards crosslinking and one or more additional amine groups, wherein the one or more additional amine groups has been passivated towards crosslinking such that the crosslinking precursor can be chemically converted, thermally converted, photo-converted or dissociated to form at least two reactive amines. In a second aspect, a process for forming a polymer film includes: (a) casting a coating solution, (b) activating the crosslinking precursor using an external stimulus to form at least two reactive amines and crosslink the polymer, and (c) drying the polymer film. The coating solution includes a soluble polymer, including an imide group, and a crosslinking precursor.

The invention discloses modified garnet ceramic powder, a PVDF (polyvinylidene fluoride)-based composite solid electrolyte, a solid-state battery as well as a preparation method and application of the solid-state battery. The modified garnet ceramic powder comprises ceramic powder and a modified interface layer coating the outer side of the ceramic powder, the thickness of the modified interface layer is 4-8 nm; the ceramic powder is garnet ceramic electrolyte powder; the modified interface layer is a polymer film polymerized on the surface of the ceramic powder; and the polymer film is made of polycyanoethyl cellulose. According to the modified garnet ceramic powder, cyanoethyl cellulose and a garnet ceramic electrolyte are coordinated and polymerized, so that the interface structure of garnet and a PVDF-based polymer is regulated and controlled, side reactions are inhibited, interface contact is better, electrochemical stability is achieved, ion transmission is faster, and the comprehensive performance of the composite electrolyte is improved.

The invention discloses preparation and application of a poly-anthraquinone thiophene film, the prepared film material can be used as a novel electrochromic material, and belongs to the field of intelligent discoloration, and the anthraquinone thiophene material is simple in synthetic route, mild in condition and low in cost. A novel D-A type monomer is synthesized by taking anthraquinone as an electron acceptor and thiophene derivatives as electron donors, and the monomer can be used for preparing a polymer film through electrochemical polymerization.

The present application relates to the technical field of flexible sensor, and discloses a flexible large-strain sensor, a preparation method and application, aiming to solve the problems of small range, poor adhesion of traditional sensors in large-strain monitoring of solid engine grain and other soft materials, and poor signal linearity and repeatability, complex preparation process and high cost of existing flexible sensors. A polymer film is used to make a flexible insulating substrate; a conductive film is prepared on the flexible insulating substrate to form a composite film layer structure; according to a preset pattern of the conductive film, laser etching and scribing are performed on the conductive film according to a first type of vector track, only penetrating the conductive film, to divide out strain resistance and other resistance, forming an off-axis serpentine structure; according to a preset pattern of the flexible insulating substrate, laser etching and scribing are performed on the composite film layer structure according to a second type of vector track, penetrating the composite film layer structure, to etch out the flexible insulating substrate of the sensor; lead-out wires are welded on the lead-out electrodes and encapsulated to obtain the flexible large-strain sensor.

The present invention belongs to the field of the design and preparation of electromagnetic shielding materials. Disclosed are a modularized full-spectrum efficient electromagnetic shielding flexible fabric and a preparation method therefor. The preparation method of the present invention comprises the following steps: (1) subjecting a fabric to a metal deposition treatment by using a magnetron sputtering system, so as to obtain a flexible conductive fabric A; (2) subjecting the surface of a polymer thin film to a metal deposition treatment by using a vacuum coating technology, so as to obtain a high-toughness conductive thin film B; (3) uniformly mixing a carbon-based wave-absorbing material, a polymer and a solvent, and curing the mixture, so as to obtain a wave-absorbing layer C having a certain thickness; and (4) subjecting the functional modules obtained in step (1), step (2) and step (3) to specific permutation, combination and packaging, so as to obtain a modularized full-spectrum electromagnetic shielding flexible composite fabric.

The invention relates to a preparation process and method for preparing core-shell nanoparticles and a polymer (PVP) film on a substrate of a common glass slide, wherein the core-shell nanoparticles are coated with tungsten-doped vanadium dioxide nanoparticles on the surface of silicon dioxide, and the process sequentially comprises the following steps of: pretreating a silicon dioxide and tungsten-doped vanadium dioxide core-shell structure and preparing a PVP mixed solution; the method comprises the basic operation procedures of ethanol dispersion of the core-shell structure, PVP dispersion, setting of stirring parameters, spin-coating parameters, drying parameters and the like. The invention also relates to an application of the core-shell nanoparticles and a polymer (PVP) film which are prepared on a substrate of a common glass slide and are coated with tungsten-doped vanadium dioxide nanoparticles on the surface of silicon dioxide in the fields of intelligent windows, infrared stealth, energy-saving glass and radiation refrigeration in the aspects of adjustable transmittance and adjustable radiation capability. The problems that a traditional vanadium dioxide nanoparticle film is low in visible light transmittance, poor in near-infrared modulation capacity, reverse in infrared radiance and the like are solved.

A method for improving the dimensional stability of a biodegradable film. The method includes providing a poly (hydroxyalkanoate)-based blown polymer film to a roll, feeding the poly (hydroxyalkanoate)-based blown polymer film to an annealing roll, and heating the blown film by contacting with the annealing roll at a temperature range of about 80 DEG C to about 150 DEG C for a predetermined period of time.

The present disclosure relates to the technical field of film material, and particularly to a polymeric polyphenol-modified polymer film, a preparation method thereof and a metallized polymer film. According to the present disclosure, corona treatment is performed to a surface of a polymer layer, so that a polar modifying liquid can uniformly coat the surface of the polymer layer, thereby forming a modification layer tightly combined with the polymer layer. Thus, the low-polarity polymer layer surface can be imparted with a durable high polarity. Consequently, the polymer layer is capable of being stably and tightly bonded to a material layer with high polarity and high surface tension, such as a metal layer, for a long period of time, effectively broadening the application scenarios for non-polar polymer substrate layers. By controlling the concentrations of the polyphenolic compound and the cross-linking agent in the modifying liquid, the modification layer formed by a cross-linking reaction can have a suitable cross-linking density and an adequate number of hydroxyl groups, thereby further effectively and stably enhancing the long-term polarity and surface tension of the polymer layer. The preparation method is simple and easy to operate, cost-effective, efficient, and easy to scale up.

The invention relates to a method for preparing a reversible adhesive flexible conductive film through aerosol jet printing. The method comprises the following steps: S1, preparing a phase transition polymer film; s2, preparing conductive ink; and S3, preparing the reversible adhesive flexible conductive film. According to the invention, the modulus change of the phase transition polymer is controlled by using temperature, and the phase transition polymer is used as a substrate of the conductive film, so that the conductive ink is completely transferred in an aerosol jet printing mode in a low-temperature and high-modulus state, and the adhesive and peelable conductive film is prepared; the method has a wide prospect in the application fields of electrophysiological signal monitoring, epidermal sensing, wearable electronics and the like.

Systems and methods for enabling higher uniform performance and higher voltage operation for micro-OLED displays, manufacturing a meniscus lens including thermo-forming a functional optical layer and printing a lens element over the formed functional optical layer, using a hybrid process used to form a functionalized lens having a controlled surface profile, modeling the polarization properties of a human eye using a polymer thin film, and improving optical sparce eye-tracking by collecting an optical output signal from each detector through a corresponding optical fiber, and determining a gaze direction of a user's eye based on the electrical signal may be disclosed.

The invention relates to a preparation method of a flexible film for dynamically adjusting infrared emissivity, and belongs to the technical field of dynamic adjustment of infrared radiation characteristics. The preparation method comprises the following operation steps: (1) uniformly mixing the basic component A and the reaction component B at room temperature; (2) defoaming the mixed solution, and pouring the mixed solution on a flat plate for self-leveling; (3) curing to obtain a polymer film; (4) stretching and fixing the polymer film, and sequentially plating an adhesion layer film and a functional layer film on the surface of the polymer film by using an electron beam evaporation coating technology; the functional layer film is made of a low-emissivity material; and (5) reducing the strain spontaneous release polymer film to an initial length to obtain the variable-emissivity flexible film with a wrinkle structure on the surface. The size and morphology change of the wrinkle structure changes the propagation path of the electromagnetic wave, and changes the area ratio of the high-emissivity material to the low-emissivity material, thereby changing the surface emissivity of the material. The infrared radiation temperature adjustment amplitude of the flexible film is 40 DEG C, and the flexible film has a good dynamic infrared camouflage function.