828 results about "Polymer thin films" patented technology

The invention discloses a preparation method of a degradable transparent conductive polymer film, and belongs to the technical field of film preparation. Preparing dispersion liquid I through graphene oxide quantum dots; preparing a dispersion liquid II from polyaniline nanofibers; dissolving pyrrole and toluenesulfonic acid in N, N-dimethylformamide to prepare a reaction solution, adding the dispersion liquid I and the dispersion liquid II, stirring, and adding ferric chloride hexahydrate to obtain a reaction solution; adjusting the pH value of the reaction solution to 1.5, and heating to obtain a polypyrrole solution; preparing cellulose acetate, polyvinyl alcohol and N, N-dimethylformamide to obtain a cellulose acetate solution; mixing the polypyrrole solution and the cellulose acetate solution, adding glutaraldehyde to obtain a mixed solution, and pouring the mixed solution into a mold to prepare a composite wet film; and putting the composite wet film into a hot-pressing forming machine for hot-pressing to generate the polymer film. The conductive polymer film prepared by the invention can be applied to the fields of supercapacitor electrode materials, electromagnetic shielding materials, flexible sensors and the like, and provides a new high-performance material choice for the development of related fields.

The invention relates to the technical field of petrochemical engineering, and discloses a temperature-resistant anti-swelling agent for fracturing and a preparation process thereof.The preparation method comprises the steps that glycerol triglycidyl ether and diethanol amine are subjected to a ring-opening reaction, a polyhydroxy tertiary amine monomer is obtained, then the polyhydroxy tertiary amine monomer and chloromethylated polystyrene are subjected to a quaternization reaction, and the temperature-resistant anti-swelling agent for fracturing is obtained. Quaternary ammonium salt groups of the anti-swelling agent and negative charges on the surface of clay form electrostatic interaction, and hydroxyl groups and the surface of the clay form hydrogen-bond interaction, so that the anti-swelling agent can be firmly adsorbed on the surface of the clay to form a layer of polymer film, the clay is prevented from being in contact with water, the phenomenon that the clay swells when encountering water is effectively inhibited, and the anti-swelling rate is very high. And the anti-swelling agent contains a heat-resistant polystyrene molecular chain, has excellent high temperature resistance, can maintain good structural stability at high temperature, still maintains high anti-swelling rate, and is suitable for a fracturing fluid system for high-temperature oil reservoir exploitation.

The invention belongs to the field of dielectric materials and dielectric energy storage, and particularly relates to a fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film and a preparation method thereof. The preparation method specifically comprises the following steps: adding fluorene polyester and polyaryletherurea into a solvent, fully dissolving to obtain a mixed solution, uniformly coating a substrate with the mixed solution, and then drying; and carrying out vacuum annealing on the dried film, and then carrying out curing treatment to strip the film from the substrate to obtain the fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film, thereby improving the charge-discharge efficiency and high discharge energy density of the polymer under high temperature and high field, and solving the problems of high electric leakage loss and low cost of the existing polymer film. And the charging and discharging efficiency is low.

The invention belongs to the technical field of two-dimensional materials, and particularly relates to a preparation method of a corner heterojunction. According to the preparation method, when the two-dimensional material sheet is prepared, based on the characteristics of smooth surface and high viscosity of the hydrophilic polymer layer, a large-area two-dimensional material can be stripped from the silicon substrate with the hydrophilic polymer film layer, the stripping process is clean, and the two-dimensional material is not damaged; when the corner heterojunction is prepared, an intermediate two-dimensional material or an active interface does not contact any polymer in the whole transfer process by adjusting the shape and size of a transfer medium based on a Van der Waals force pickup transfer method, so that the pollution of a heterogeneous interface is greatly reduced; the efficient and fast preparation of the Van der Waals heterostructure without polymer residues and bubbles on the interface is realized.

The invention provides a flexible conductive substrate, a flexible conductive substrate preparation method and a flexible perovskite solar cell comprising the flexible conductive substrate. The flexible conductive substrate comprises a flexible substrate layer, a substrate buffer layer and a transparent conductive layer which are stacked from bottom to top. The substrate buffer layer is made of transparent metal oxide, and the thickness of the substrate buffer layer is 5-80 nm; the flexible conductive substrate adopts a composite flexible substrate structure, the polymer film is used as the flexible substrate layer, and the nanoscale substrate buffer layer formed by the transparent metal oxide is inserted between the flexible substrate layer and the transparent conductive layer, so that the surface stress distribution of the flexible substrate layer is effectively released / homogenized; and meanwhile, the connection strength between the flexible substrate layer and the transparent conductive layer is increased, so that the transparent conductive layer is not easy to desorb, and the photoelectric property and the mechanical quality of the ultrathin flexible perovskite solar cell prepared based on the novel flexible conductive substrate structure are remarkably improved.

In one aspect, a blank is formed of a substrate laminated with a thin polymer film layer. The blank includes fold lines and cutouts such that it is formable into a pack with a base that is fully sealed by the film layer, thereby solving the technical problem of packs formed from blanks where the bases include unsealed gaps or holes. In further aspects, a folded blank, packaging articles formed therefrom, and methods of manufacture are provided.

This invention relates to a method for preparing a p-aminobenzenesulfonic acid blended nanofiltration membrane and its application. The invention aims to address the technical problem that existing polymer thin films struggle to simultaneously increase permeate flux while improving retention rate. This invention provides a nanofiltration membrane with high efficiency in separating cobalt and lithium ions and significantly enhanced permeate flux. It achieves this by doping p-aminobenzenesulfonic acid during the preparation of traditional TFC nanofiltration membranes, efficiently introducing sulfonic acid groups to promote the formation of an ordered nanochannel structure in the polyamide network, thereby increasing water flux. Simultaneously, the negative charge carried by the sulfonic acid groups enhances the overall electronegativity of the membrane, making it more effective against Co ions. 2+ The electrostatic adsorption capacity is significantly higher than that of Li + This enables efficient separation of cobalt and lithium ions. The nanofiltration membrane material provided by this invention can be widely used in the resource-based treatment of acid leaching wastewater from lithium cobalt oxide batteries, achieving efficient separation and recovery of cobalt and lithium, and improving economic benefits and resource utilization.

The invention belongs to the field of composite materials, and particularly relates to a nanofiber radiation refrigeration heat insulation film with a bionic multilayer structure. The device sequentially comprises a bionic anti-reflection layer, a solar spectrum reflection layer, a nanofiber porous heat insulation layer and an atmospheric window radiation layer from outside to inside, the bionic anti-reflection layer is a sub-wavelength nano bulge array simulating a moth eye structure and is formed on the outer surface of the solar spectrum reflecting layer; the solar spectrum reflecting layer is a polymer film doped with high-reflectivity nanoparticles; the nanofiber porous heat insulation layer is a porous membrane formed by interweaving polymer nanofibers prepared by an electrostatic spinning technology; the atmospheric window radiation layer is a functional layer formed by coating or blending high-emissivity inorganic nanoparticles on the inner surface of the nanofiber porous heat insulation layer; the film integrates bionic antireflection, high sunlight reflection, efficient heat radiation and physical heat insulation, and efficient, stable and flexible daytime radiation refrigeration is achieved.

The invention relates to a high-temperature-resistant polymer binder and a preparation method thereof. The binder is composed of a mixture of resin containing a siloxane unit polyimide main chain and an epoxy group side chain and tannic acid. Wherein the main chain containing siloxane and imide units endows the adhesive with excellent heat-resistant stability, excellent processability and excellent adhesion with glass and ceramic materials, and the adhesive can be cured at room temperature through the epoxy side group; the mixed tannic acid can form strong interface bonding with a polymer film and a metal material through a multiple hydrogen bond network, so that the tannic acid has important application prospects in the fields of semiconductor packaging, thermal interface materials and the like.

Thin polymer films may comprise a first polymer layer comprising poly(vinylidene fluoride); a second polymer layer comprising poly(vinylidene fluoride); and a nanofiller-polymer layer interposed between the first polymer layer and the second polymer layer, the nanofiller-polymer layer comprising poly(methyl methacrylate) and nanosheets dispersed in the poly(methyl methacrylate); the nanosheets comprising mica nanosheets and / or hexagonal boron-nitride nanosheets; wherein 50-99% of the nanosheets in the nanofiller-polymer layer are oriented parallel to a width dimension of the first polymer layer.

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.

The invention belongs to the field of polymer films, and discloses a polyvinylidene fluoride film based on cross-linking reaction and a preparation method and application thereof, and the preparation method comprises the following steps: mixing cyclohexanone, polyvinylidene fluoride and polyoxyethylene diamine to obtain a mixed solution; curing the mixed solution into a film to obtain a blended polyvinylidene fluoride film; and carrying out cross-linking reaction on the blended polyvinylidene fluoride film to obtain a cross-linked polyvinylidene fluoride film, and culturing the cross-linked polyvinylidene fluoride film at 150-165 DEG C to obtain the polyvinylidene fluoride film with high gamma crystal form content. Through detection and comparison, in the polyvinylidene fluoride film based on the cross-linking reaction, the gamma-phase crystal content is obviously increased, and the alpha-phase crystal content is obviously reduced. The method is simple in process and convenient to operate, polyvinylidene fluoride is endowed with the capacity of obtaining gamma crystals at a low temperature in a short time, and the method can be widely applied to the fields of pressure sensors, lithium ion batteries, automobile motors, high-temperature-resistant thermistor devices and the like.

Proposed is a method for forming an electroless plating electrode through selective cross-linking layer formation using a laser, specifically, the method includes forming a selective cross-linking layer by sintering a water-soluble polymer thin film layer, which is formed on a substrate by coating, to form a patterned shape thereon using a laser, followed by forming a precise metal pattern by electroless-plating the selective cross-linking layer with copper, nickel, or other metals. The method offers a simple manufacturing process, cost efficiency, and flexibility in manufacturing without being limited by the shape of a substrate, thereby patterns may be formed on various substrates. A catalyst material for electroless plating is mixed with a polymer material to directly cross-link the substrate. Thus, durability is improved but also an electrode may be formed with a substrate by electroless plating simply and in a short time due to use of only a single material.

The utility model relates to the field of electromagnetic shielding films, in particular to an electromagnetic shielding film, which comprises a multi-layer composite structure and is characterized in that the electromagnetic shielding film is formed by compounding at least four layers of materials, namely a base material layer 1, a conductive grid layer 2, an electromagnetic absorption layer 3 and a protective layer 4 in sequence; the base material layer 1 adopts a light high-strength polymer film as a substrate and has excellent flexibility and mechanical strength; the conductive grid layer 2 is located on the base material layer 1, is of a grid structure formed by fine metal wires or high-conductivity polymer fibers, is formed through a precise weaving or printing technology and is used for guiding and dispersing electromagnetic wave energy; the technical problem that the service life and the shielding effect of the electromagnetic shielding film are affected due to the fact that the electromagnetic shielding film is prone to abrasion, scraping and the like in the long-term use process is solved.

In a system and a method for reprocessing ultra-high molecular weight polymer film offcuts, the system comprises a feed device 202 and a comminution device 203. The feed device is configured to provide an ultra-high molecular weight polymer film offcut to the comminution device. The comminution device comprises at least one cutting screen, wherein the cutting screen comprises a plurality of screen openings and a plurality of cutting projections, wherein at least one cutting projection spans a cutting opening allocated to it, and wherein the comminution device is configured to generate relative motion between the cutting screen and the fed polymer film offcut in order to comminute the polymer film offcut.

In a first aspect, a coating solution includes a soluble polymer and a crosslinking precursor. The soluble polymer includes an imide group. The crosslinking precursor includes a first amine group that is either reactive or passivated towards crosslinking and one or more additional amine groups, wherein the one or more additional amine groups has been passivated towards crosslinking such that the crosslinking precursor can be chemically converted, thermally converted, photo-converted or dissociated to form at least two reactive amines. In a second aspect, a process for forming a polymer film includes: (a) casting a coating solution, (b) activating the crosslinking precursor using an external stimulus to form at least two reactive amines and crosslink the polymer, and (c) drying the polymer film. The coating solution includes a soluble polymer, including an imide group, and a crosslinking precursor.

The present application relates to the technical field of flexible sensor, and discloses a flexible large-strain sensor, a preparation method and application, aiming to solve the problems of small range, poor adhesion of traditional sensors in large-strain monitoring of solid engine grain and other soft materials, and poor signal linearity and repeatability, complex preparation process and high cost of existing flexible sensors. A polymer film is used to make a flexible insulating substrate; a conductive film is prepared on the flexible insulating substrate to form a composite film layer structure; according to a preset pattern of the conductive film, laser etching and scribing are performed on the conductive film according to a first type of vector track, only penetrating the conductive film, to divide out strain resistance and other resistance, forming an off-axis serpentine structure; according to a preset pattern of the flexible insulating substrate, laser etching and scribing are performed on the composite film layer structure according to a second type of vector track, penetrating the composite film layer structure, to etch out the flexible insulating substrate of the sensor; lead-out wires are welded on the lead-out electrodes and encapsulated to obtain the flexible large-strain sensor.

The present disclosure relates to the technical field of film material, and particularly to a polymeric polyphenol-modified polymer film, a preparation method thereof and a metallized polymer film. According to the present disclosure, corona treatment is performed to a surface of a polymer layer, so that a polar modifying liquid can uniformly coat the surface of the polymer layer, thereby forming a modification layer tightly combined with the polymer layer. Thus, the low-polarity polymer layer surface can be imparted with a durable high polarity. Consequently, the polymer layer is capable of being stably and tightly bonded to a material layer with high polarity and high surface tension, such as a metal layer, for a long period of time, effectively broadening the application scenarios for non-polar polymer substrate layers. By controlling the concentrations of the polyphenolic compound and the cross-linking agent in the modifying liquid, the modification layer formed by a cross-linking reaction can have a suitable cross-linking density and an adequate number of hydroxyl groups, thereby further effectively and stably enhancing the long-term polarity and surface tension of the polymer layer. The preparation method is simple and easy to operate, cost-effective, efficient, and easy to scale up.

Systems and methods for enabling higher uniform performance and higher voltage operation for micro-OLED displays, manufacturing a meniscus lens including thermo-forming a functional optical layer and printing a lens element over the formed functional optical layer, using a hybrid process used to form a functionalized lens having a controlled surface profile, modeling the polarization properties of a human eye using a polymer thin film, and improving optical sparce eye-tracking by collecting an optical output signal from each detector through a corresponding optical fiber, and determining a gaze direction of a user's eye based on the electrical signal may be disclosed.

The present disclosure provides embodiments of processes and methods for stabilizing self-assembled monolayers (SAMs). In the present disclosure, a cyclic vapor deposition process is used to selectively deposit a polymer thin film on a SAM structure formed on a target material. The polymer thin film selectively deposited on the SAM structure stabilizes the SAM structure by: (a) healing defects in the SAM structure and providing blanket coverage over the target material surface, (b) preventing migration of SAM-forming molecules to neighboring non-target surfaces, and (c) increasing the thickness and rigidity of the SAM structure. In one embodiment, sequentially pulsed initiated chemical vapor deposition (spiCVD) is used to selectively deposit the polymer thin film on the SAM structure.

The invention discloses a flexible temperature sensor of an ultrahigh-conductivity Cu-LIG composite electrode and a preparation method of the flexible temperature sensor. A polymer film is used as a flexible substrate and a carbon source precursor of a device, and a super-hydrophilic LIG electrode with a patterned structure is prepared on the surface of the flexible film through a laser processing technology; the preparation method comprises the following steps: further implementing Ag catalytic nano particle formation treatment on the surface of an LIG electrode, subsequently generating a compact Cu sheet layer on the LIG surface by using an in-situ chemical self-deposition technology under the action of Ag catalytic nano particles, forming a Cu-LIG up-and-down laminated composite electrode structure, and realizing the preparation of the sensor by virtue of packaging of an external connecting circuit. The temperature sensor has the advantages of high resistance temperature coefficient, fast dynamic response performance, wide temperature sensing range and the like.

The present invention relates to a polyamide resin in which an average particle size of individual crystals measured by a small-angle X-ray scattering apparatus is 8.0 nm or less, and a polymer film and resin laminate using the same.

The invention discloses an ultraviolet-resistant and high-temperature-aging-resistant photovoltaic cable structure which comprises a cable conductor, and a buffer layer, an insulating layer, a shielding layer and a sheath layer which are sequentially arranged on the outer side of the cable conductor. The insulating layer is formed by co-extruding a heat-conducting buffer layer, a main insulating layer and a reflection isolating layer, and the heat-conducting buffer layer is provided with a heat-conducting channel along the axial direction; the shielding layer comprises a main body shielding layer and a thermal insulation layer. Silver-plated copper wires are embedded in the thermal insulation layer. Lotus-leaf-like bionic protrusions are arranged on the outer surface of the sheath layer, and a shape memory polymer film is embedded in the sheath layer. The cable conductor is made of high-purity oxygen-free copper and is spirally twisted, a ceramic composite coating is coated outside the cable conductor, and the buffer layer is a polytetrafluoroethylene film. According to the structure, through cooperation of multi-layer composite design and functional materials, the effects of rapid heat dissipation, improvement of temperature resistance and aging resistance, effective blocking of ultraviolet rays, enhancement of structural stability and the like are achieved, the problems that an existing photovoltaic cable is poor in weather resistance, insufficient in heat conduction and prone to structure failure are solved, and the photovoltaic cable can be widely applied to outdoor scenes such as photovoltaic power stations and the like.

The invention relates to the technical field of flexible sensors, discloses a flexible large-strain sensor, and a preparation method and application thereof, and aims to solve the problems that a traditional sensor is small in measuring range, poor in fitting performance and high in reliability in large-strain monitoring of soft materials such as solid engine grains. And the problems of poor signal linearity and repeatability, complex preparation process and high cost of the existing flexible sensor are solved. Manufacturing a flexible insulating substrate by adopting a polymer film; preparing a conductive film on the flexible insulating base to form a composite film layer structure; according to a preset pattern of the conductive film, laser etching scribing is carried out on the conductive film according to the first type of vector trajectory, only the conductive film is penetrated, a strain resistor and other resistors are segmented, and an off-axis snakelike structure is formed; according to a preset pattern of the flexible insulating substrate, laser etching scribing is carried out on the composite film layer structure according to a second type of vector trajectory, the composite film layer structure is penetrated, and the flexible insulating substrate of the sensor is etched; and welding a leading-out wire on the leading-out electrode and packaging to obtain the flexible large-strain sensor.

The present application belongs to the technical field of polymer dielectric energy storage material, and discloses a preparation method of a full-organic small-molecule composite polymer film and a product. The preparation method comprises the following steps: mixing a mixed solution of PVDF and PMMA with a PE EU solution to form a pre-preparation solution; casting the pre-preparation solution on a substrate and heating and drying, and then heat treating in a vacuum environment to obtain the required composite polymer film. The present application also discloses the product prepared by the above preparation method. Through the present application, the problems of low discharge energy density and charge-discharge efficiency of ferroelectric-based polymer films are solved.

To provide a laminate that is useful as a temporary support for producing a large-area, high-definition, flexible electronic device, has a stably low adhesive strength between a heat-resistant polymer film and an inorganic substrate even in a case of a large surface area, and has few blister defects.SOLUTION: There is provided a laminate, comprising: an inorganic substrate; a silane coupling agent layer including an amino group; and a heat-resistant polymer film in the stated order, the laminate being characterized in that an elemental nitrogen component ratio in an inorganic-substrate-side peel surface after peeling the heat-resistant polymer film from the inorganic substrate at 90° is greater than 3.5 atomic% and 11 atomic% or less.SELECTED DRAWING: None

The application discloses a kind of concrete crack self-repairing agent suitable for marine corrosion conditions, including component one and component two;The component one, component two are all core-shell structure;The outer shell of component one is polymer film;Inner layer includes the following components by mass percentage: 20%-30% barite powder, 50%-60% magnesium source, 20%-30% cement;The outer shell of component two is polymer film;Inner layer includes the following components by mass percentage: 20-30% barite powder, 5-10% microbial powder, 20-30% glucose, 20%-40% aluminum source, 10%-30% low-alkali cement.The repairing agent of the application is continuous grading solid particle pellet, and the fine aggregate of concrete is replaced with equal mass.By the synergistic effect of microbial mineralization and metal mineral hydration, the filling of concrete crack space and the solidification of invasive crack corrosion ions are realized, especially suitable for marine corrosion environment.

The invention discloses an ionic gel flexible pressure film sensing array and a preparation method thereof. The sensing array comprises two layers of patterned flexible electrodes, an ionic gel unit array containing a surface microstructure and a patterned isolation layer. The ionic gel layer and the isolation layer are located on the same plane, each ionic gel unit is surrounded by the isolation layer unit structure, the two layers of electrodes respectively cover the upper side and the lower side, the ionic gel is in contact with an electrode conductive region, and the isolation layer is in contact with a non-conductive region. The preparation method comprises the following steps: performing laser etching and patterning processing on the flexible electrode; preparing a mask with a hollow pattern and covering the mask to the first electrode; imprinting on the polymer film to prepare a microstructure mold; dropwise adding liquid ionic gel into the mold, and pressing and curing the first electrode covered with the mask to form an ionic gel unit array; and bonding the isolation layer and the two layers of electrodes. The preparation method is low in cost, simple, flexible, thin in device thickness, wide in measuring range, high in sensitivity and signal-to-noise ratio, resistant to sensitive layer crosstalk and suitable for various pressure detection scenes.

The invention relates to the technical field of composite material preparation, in particular to a preparation method of a polymer film / hydrogel composite material with a wrinkled surface. The preparation method of the polymer film / hydrogel composite material with the wrinkled surface comprises the steps that hydrogel comprises a first surface and a second surface which are oppositely arranged, the first surface adheres to a substrate, the second surface is coated with a polymer solution, and the polymer film / hydrogel composite material is obtained through light curing treatment and drying treatment in sequence; and soaking the polymer film / hydrogel composite material in water to obtain the polymer film / hydrogel composite material. By controlling the raw materials, the hydrogel thickness, the soaking treatment time and the like, the fold wavelength and amplitude of the polymer film / hydrogel composite material can be accurately regulated and controlled, and the requirements of different application scenes can be met.

The invention relates to the technical field of coating preparation, particularly discloses polymer elastomer resin as well as a preparation method and application thereof, and aims to solve the problem that a polymer film layer is in a crack state due to film shrinkage in an ultralow-temperature state. The polymer elastomer resin with a low-polarity and high-confusion-degree structure is prepared, so that the condition that a film is not broken due to film shrinkage in an ultralow-temperature state of a polymer is ensured, and the integrity of a coating film in an ultralow-temperature environment is ensured; the prepared polymer elastomer resin, isocyanate and a catalyst are mixed and react to prepare the coating, and the coating not only has good ultralow temperature resistance, hydrophobicity and ultraviolet resistance, but also has excellent adhesiveness on the surfaces of low-surface-tension metals such as stainless steel and aluminum alloy.