467 results about "Polymer thin films" patented technology

The invention provides a flexible conductive substrate, a flexible conductive substrate preparation method and a flexible perovskite solar cell comprising the flexible conductive substrate. The flexible conductive substrate comprises a flexible substrate layer, a substrate buffer layer and a transparent conductive layer which are stacked from bottom to top. The substrate buffer layer is made of transparent metal oxide, and the thickness of the substrate buffer layer is 5-80 nm; the flexible conductive substrate adopts a composite flexible substrate structure, the polymer film is used as the flexible substrate layer, and the nanoscale substrate buffer layer formed by the transparent metal oxide is inserted between the flexible substrate layer and the transparent conductive layer, so that the surface stress distribution of the flexible substrate layer is effectively released / homogenized; and meanwhile, the connection strength between the flexible substrate layer and the transparent conductive layer is increased, so that the transparent conductive layer is not easy to desorb, and the photoelectric property and the mechanical quality of the ultrathin flexible perovskite solar cell prepared based on the novel flexible conductive substrate structure are remarkably improved.

This invention relates to a method for preparing a p-aminobenzenesulfonic acid blended nanofiltration membrane and its application. The invention aims to address the technical problem that existing polymer thin films struggle to simultaneously increase permeate flux while improving retention rate. This invention provides a nanofiltration membrane with high efficiency in separating cobalt and lithium ions and significantly enhanced permeate flux. It achieves this by doping p-aminobenzenesulfonic acid during the preparation of traditional TFC nanofiltration membranes, efficiently introducing sulfonic acid groups to promote the formation of an ordered nanochannel structure in the polyamide network, thereby increasing water flux. Simultaneously, the negative charge carried by the sulfonic acid groups enhances the overall electronegativity of the membrane, making it more effective against Co ions. 2+ The electrostatic adsorption capacity is significantly higher than that of Li + This enables efficient separation of cobalt and lithium ions. The nanofiltration membrane material provided by this invention can be widely used in the resource-based treatment of acid leaching wastewater from lithium cobalt oxide batteries, achieving efficient separation and recovery of cobalt and lithium, and improving economic benefits and resource utilization.

The invention belongs to the field of composite materials, and particularly relates to a nanofiber radiation refrigeration heat insulation film with a bionic multilayer structure. The device sequentially comprises a bionic anti-reflection layer, a solar spectrum reflection layer, a nanofiber porous heat insulation layer and an atmospheric window radiation layer from outside to inside, the bionic anti-reflection layer is a sub-wavelength nano bulge array simulating a moth eye structure and is formed on the outer surface of the solar spectrum reflecting layer; the solar spectrum reflecting layer is a polymer film doped with high-reflectivity nanoparticles; the nanofiber porous heat insulation layer is a porous membrane formed by interweaving polymer nanofibers prepared by an electrostatic spinning technology; the atmospheric window radiation layer is a functional layer formed by coating or blending high-emissivity inorganic nanoparticles on the inner surface of the nanofiber porous heat insulation layer; the film integrates bionic antireflection, high sunlight reflection, efficient heat radiation and physical heat insulation, and efficient, stable and flexible daytime radiation refrigeration is achieved.

The invention relates to a high-temperature-resistant polymer binder and a preparation method thereof. The binder is composed of a mixture of resin containing a siloxane unit polyimide main chain and an epoxy group side chain and tannic acid. Wherein the main chain containing siloxane and imide units endows the adhesive with excellent heat-resistant stability, excellent processability and excellent adhesion with glass and ceramic materials, and the adhesive can be cured at room temperature through the epoxy side group; the mixed tannic acid can form strong interface bonding with a polymer film and a metal material through a multiple hydrogen bond network, so that the tannic acid has important application prospects in the fields of semiconductor packaging, thermal interface materials and the like.

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.

The utility model relates to the field of electromagnetic shielding films, in particular to an electromagnetic shielding film, which comprises a multi-layer composite structure and is characterized in that the electromagnetic shielding film is formed by compounding at least four layers of materials, namely a base material layer 1, a conductive grid layer 2, an electromagnetic absorption layer 3 and a protective layer 4 in sequence; the base material layer 1 adopts a light high-strength polymer film as a substrate and has excellent flexibility and mechanical strength; the conductive grid layer 2 is located on the base material layer 1, is of a grid structure formed by fine metal wires or high-conductivity polymer fibers, is formed through a precise weaving or printing technology and is used for guiding and dispersing electromagnetic wave energy; the technical problem that the service life and the shielding effect of the electromagnetic shielding film are affected due to the fact that the electromagnetic shielding film is prone to abrasion, scraping and the like in the long-term use process is solved.

The present application relates to the technical field of flexible sensor, and discloses a flexible large-strain sensor, a preparation method and application, aiming to solve the problems of small range, poor adhesion of traditional sensors in large-strain monitoring of solid engine grain and other soft materials, and poor signal linearity and repeatability, complex preparation process and high cost of existing flexible sensors. A polymer film is used to make a flexible insulating substrate; a conductive film is prepared on the flexible insulating substrate to form a composite film layer structure; according to a preset pattern of the conductive film, laser etching and scribing are performed on the conductive film according to a first type of vector track, only penetrating the conductive film, to divide out strain resistance and other resistance, forming an off-axis serpentine structure; according to a preset pattern of the flexible insulating substrate, laser etching and scribing are performed on the composite film layer structure according to a second type of vector track, penetrating the composite film layer structure, to etch out the flexible insulating substrate of the sensor; lead-out wires are welded on the lead-out electrodes and encapsulated to obtain the flexible large-strain sensor.

The present disclosure relates to the technical field of film material, and particularly to a polymeric polyphenol-modified polymer film, a preparation method thereof and a metallized polymer film. According to the present disclosure, corona treatment is performed to a surface of a polymer layer, so that a polar modifying liquid can uniformly coat the surface of the polymer layer, thereby forming a modification layer tightly combined with the polymer layer. Thus, the low-polarity polymer layer surface can be imparted with a durable high polarity. Consequently, the polymer layer is capable of being stably and tightly bonded to a material layer with high polarity and high surface tension, such as a metal layer, for a long period of time, effectively broadening the application scenarios for non-polar polymer substrate layers. By controlling the concentrations of the polyphenolic compound and the cross-linking agent in the modifying liquid, the modification layer formed by a cross-linking reaction can have a suitable cross-linking density and an adequate number of hydroxyl groups, thereby further effectively and stably enhancing the long-term polarity and surface tension of the polymer layer. The preparation method is simple and easy to operate, cost-effective, efficient, and easy to scale up.

The invention discloses a flexible temperature sensor of an ultrahigh-conductivity Cu-LIG composite electrode and a preparation method of the flexible temperature sensor. A polymer film is used as a flexible substrate and a carbon source precursor of a device, and a super-hydrophilic LIG electrode with a patterned structure is prepared on the surface of the flexible film through a laser processing technology; the preparation method comprises the following steps: further implementing Ag catalytic nano particle formation treatment on the surface of an LIG electrode, subsequently generating a compact Cu sheet layer on the LIG surface by using an in-situ chemical self-deposition technology under the action of Ag catalytic nano particles, forming a Cu-LIG up-and-down laminated composite electrode structure, and realizing the preparation of the sensor by virtue of packaging of an external connecting circuit. The temperature sensor has the advantages of high resistance temperature coefficient, fast dynamic response performance, wide temperature sensing range and the like.

The present invention relates to a polyamide resin in which an average particle size of individual crystals measured by a small-angle X-ray scattering apparatus is 8.0 nm or less, and a polymer film and resin laminate using the same.

The invention discloses an ultraviolet-resistant and high-temperature-aging-resistant photovoltaic cable structure which comprises a cable conductor, and a buffer layer, an insulating layer, a shielding layer and a sheath layer which are sequentially arranged on the outer side of the cable conductor. The insulating layer is formed by co-extruding a heat-conducting buffer layer, a main insulating layer and a reflection isolating layer, and the heat-conducting buffer layer is provided with a heat-conducting channel along the axial direction; the shielding layer comprises a main body shielding layer and a thermal insulation layer. Silver-plated copper wires are embedded in the thermal insulation layer. Lotus-leaf-like bionic protrusions are arranged on the outer surface of the sheath layer, and a shape memory polymer film is embedded in the sheath layer. The cable conductor is made of high-purity oxygen-free copper and is spirally twisted, a ceramic composite coating is coated outside the cable conductor, and the buffer layer is a polytetrafluoroethylene film. According to the structure, through cooperation of multi-layer composite design and functional materials, the effects of rapid heat dissipation, improvement of temperature resistance and aging resistance, effective blocking of ultraviolet rays, enhancement of structural stability and the like are achieved, the problems that an existing photovoltaic cable is poor in weather resistance, insufficient in heat conduction and prone to structure failure are solved, and the photovoltaic cable can be widely applied to outdoor scenes such as photovoltaic power stations and the like.

The invention relates to the technical field of flexible sensors, discloses a flexible large-strain sensor, and a preparation method and application thereof, and aims to solve the problems that a traditional sensor is small in measuring range, poor in fitting performance and high in reliability in large-strain monitoring of soft materials such as solid engine grains. And the problems of poor signal linearity and repeatability, complex preparation process and high cost of the existing flexible sensor are solved. Manufacturing a flexible insulating substrate by adopting a polymer film; preparing a conductive film on the flexible insulating base to form a composite film layer structure; according to a preset pattern of the conductive film, laser etching scribing is carried out on the conductive film according to the first type of vector trajectory, only the conductive film is penetrated, a strain resistor and other resistors are segmented, and an off-axis snakelike structure is formed; according to a preset pattern of the flexible insulating substrate, laser etching scribing is carried out on the composite film layer structure according to a second type of vector trajectory, the composite film layer structure is penetrated, and the flexible insulating substrate of the sensor is etched; and welding a leading-out wire on the leading-out electrode and packaging to obtain the flexible large-strain sensor.

The present application belongs to the technical field of polymer dielectric energy storage material, and discloses a preparation method of a full-organic small-molecule composite polymer film and a product. The preparation method comprises the following steps: mixing a mixed solution of PVDF and PMMA with a PE EU solution to form a pre-preparation solution; casting the pre-preparation solution on a substrate and heating and drying, and then heat treating in a vacuum environment to obtain the required composite polymer film. The present application also discloses the product prepared by the above preparation method. Through the present application, the problems of low discharge energy density and charge-discharge efficiency of ferroelectric-based polymer films are solved.

The invention discloses an ionic gel flexible pressure film sensing array and a preparation method thereof. The sensing array comprises two layers of patterned flexible electrodes, an ionic gel unit array containing a surface microstructure and a patterned isolation layer. The ionic gel layer and the isolation layer are located on the same plane, each ionic gel unit is surrounded by the isolation layer unit structure, the two layers of electrodes respectively cover the upper side and the lower side, the ionic gel is in contact with an electrode conductive region, and the isolation layer is in contact with a non-conductive region. The preparation method comprises the following steps: performing laser etching and patterning processing on the flexible electrode; preparing a mask with a hollow pattern and covering the mask to the first electrode; imprinting on the polymer film to prepare a microstructure mold; dropwise adding liquid ionic gel into the mold, and pressing and curing the first electrode covered with the mask to form an ionic gel unit array; and bonding the isolation layer and the two layers of electrodes. The preparation method is low in cost, simple, flexible, thin in device thickness, wide in measuring range, high in sensitivity and signal-to-noise ratio, resistant to sensitive layer crosstalk and suitable for various pressure detection scenes.

The invention discloses a conjugated polymer film with electrical properties and tensile stability simultaneously improved, and a preparation method and application thereof, and belongs to the technical field of flexible electronic materials. The preparation method comprises the following steps: placing the conjugated polymer film in a solution formed by mixing an electrolyte and a dopant, and soaking for 30-60 seconds to complete ion exchange doping, thereby obtaining the conjugated polymer film with various carrier transport channels. The strategy of increasing the types of carrier transmission channels is adopted, and two main transmission channels of a crystal phase and an accumulation region are formed in the conjugated polymer film through an ion exchange doping method, so that the conjugated polymer film can maintain the electrical property at a high proportion under a stretching external field, and the electrical property of the conjugated polymer film is improved under the same stretching strain. And the tensile stability of the conductivity is far higher than that of a conjugated polymer film which only takes a crystal phase or an accumulation region as a carrier transmission channel.

The present invention relates to laser welded articles and methods thereof.SOLUTION: The method includes laminating laser-weldable polymeric film layers including at least one colored film layer and at least first and second uncolored film layers, directing a laser beam of a first wavelength at the laminate, and moving the laser beam along a first welding path. The laser beam impinges on the colored film layer and locally heats and welds the colored film layer and the first uncolored film layer to one another along a first welding path. Next, a laser beam of a second wavelength different from the first wavelength is directed at the laminate and moved along a second welding path offset from the first welding path. The laser beam impinges on the second unpigmented layer to locally heat and weld the second unpigmented layer and the first unpigmented layer together along a second welding path.SELECTED DRAWING: Figure 4

Mechanically and piezoelectrically anisotropic polymer fibers may be formed by spinning a polymer solution or gel that includes a high molecular weight crystallizable polymer and a liquid solvent. The solvent may be configured to interact with the polymer to facilitate chain alignment and, in some examples, create a higher crystalline content within the spun fibers. The polymer solution may also include a low molecular weight additive. The high and low molecular weight polymers may each be characterized by a bimodal molecular weight distribution where the molecular weight of the additive is less than the molecular weight of the crystallizable polymer. The polymer(s) and the additive(s) may be independently selected from vinylidene fluoride, trifluoroethylene, chlorotrifluoroethylene, hexafluoropropene, vinyl fluoride, etc. The spun fibers may be oriented, annealed, poled, and woven or laminated to form a polymer thin film having a high elastic modulus and a high electromechanical coupling factor.

The present invention relates to a polymer composition comprising an ethylene-based polymer and a polylactic acid. Such polymer composition exhibits desirably good melt fracture prevention properties, in particular in production of polymer films.

Embodiments of this disclosure relate to a method for selectively depositing polysilicon after forming a fluid polymer film to protect a substrate surface within a feature. A first silicon (Si) layer is deposited by physical vapor deposition (PVD). A fluid polymer film is formed on the first silicon (Si) layer on the bottom. A portion of the first silicon (Si) layer is selectively removed from the top surface and at least one side wall. The fluid polymer film is removed. In some embodiments, a second silicon (Si) layer is selectively deposited on the first silicon (Si) layer to fill the feature. In some embodiments, the remaining portion of the first silicon (Si) layer on the bottom is oxidized to form a first silicon oxide (SiO₂) on the bottom. x ) forms a layer, and a silicon (Si) layer or a second silicon oxide (SiO) layer x The ) layer is the first silicon oxide (SiO x It is deposited on top of layers.

The application relates to the field of flexible sensing fabric, and discloses a flexible piezoelectric ultrasonic fiber transducer and a preparation method and application thereof, the preparation method comprising the following steps: laminating two films A and B in the order of ABABA, wherein A is a non-conductive high polymer film, and B is a conductive high polymer film; laminating the films through hot pressing to obtain a hot-stretching preform which is internally coated with a piezoelectric ultrasonic circuit structure; fixing the hot-stretching preform in a low-temperature polymer drawing tower, feeding a wire through hot stretching to obtain the flexible piezoelectric ultrasonic fiber transducer. The flexible piezoelectric ultrasonic fiber transducer is prepared by coating a piezoelectric ultrasonic circuit system with a flexible non-conductive high polymer film, the non-conductive high polymer film can be used as a matching layer and a backing layer of the ultrasonic transducer system while serving as a coating layer, is non-toxic and harmless, has certain flexibility and stretchability, is wear-resistant, has good elasticity, and is easy to process and prepare.

A liquid crystal polymer film that includes: a liquid crystal polymer; and an inorganic filler, wherein a relative permittivity of the liquid crystal polymer film is 5 to 10, and an average value of distances between barycentric coordinates of particles of the inorganic filler in the liquid crystal polymer film is 0.5 μm to 2.0 μm.

The present invention relates to a method of preparing a polymer film using chemical vapor deposition using sulfur as an initiator (sCVD) capable of manufacturing a polymer film through polymerization of sulfur and a monomer using gas-phase sulfur as an initiator. In the manufactured polymer film, any of various monomers and sulfur can be polymerized into a copolymer, and it is possible to manufacture a polymer film having a high content of sulfur, an excellent refractive index, and excellent transmittance.

This invention relates to the application of electromagnetic shielding composite materials, specifically to an electromagnetic shielding composite film with a gradient structure and its preparation method. Using a polymer film as the core layer, electromagnetic functional layers are sequentially deposited on both sides of the polymer core layer, and a carbon fiber felt is composited on at least one side, resulting in an electromagnetic shielding composite film with excellent electromagnetic shielding performance. The gradient multilayer structure design of this invention utilizes the principles of impedance mismatch at different interfaces and the skin effect to effectively improve the multiple reflections of electromagnetic waves between different functional layers. Furthermore, the type of polymer core layer can be changed according to different needs; using a polymer-based high-barrier film as the core layer can yield a high-barrier electromagnetic shielding packaging film that combines high barrier properties with high electromagnetic shielding.

An optically anisotropic polymer thin film includes a crystallizable polymer and an additive configured to interact with the polymer (e.g., via π-π interactions) to facilitate chain alignment and, in some examples, create a higher crystalline content within the polymer thin film. The polymer thin film may be characterized by a bimodal molecular weight distribution where the molecular weight of the additive may be less than approximately 50% of the molecular weight of the crystallizable polymer. Example crystallizable polymers include polyethylene naphthalate, polyethylene terephthalate, polybutylene naphthalate, polybutylene terephthalate, as well as derivatives thereof. Example additives, which may occupy up to approximately 10 wt. % of the polymer thin film, include aromatic ester oligomers, aromatic amide oligomers, and polycyclic aromatic hydrocarbons, for example. The optically anisotropic polymer thin film may be characterized by a refractive index greater than approximately 1.7 and an in-plane birefringence greater than approximately 0.2.

The present disclosure provides a film for enhancing the growth of plants in the Cannabaceae family, the film being capable of blocking solar spectrum in the range 430-550 nm. The present disclosure also provides a single- or multi-layer plastic greenhouse film for enhancing cannabis plant growth, where the single- or multi-layer plastic greenhouse film (a) has at least one blue light blocking layer for blocking solar spectrum in the range of 430-500 nm; (b) has a high transmittance for red light in the solar spectrum in the range of 600-750 nm.

The application discloses a conjugated polymer material capable of realizing neutral state green / black-transparent electrochromic performance and a preparation method and application thereof. The conjugated polymer material (IV) is prepared through copolymerization of a cyclic ether modified p-dibromobenzene ring monomer (I), a thiophene derivative ProDOT monomer (II) and a D-A-D unit ProDOT-BTD-ProDOT coupling monomer (III). The electrochromic polymer thin film processed from the conjugated polymer material has application prospects in the fields of intelligent windows, intelligent glasses, displays, electronic paper and the like. In the material, the cyclic ether modified p-dibromobenzene ring monomer effectively reduces the oxidation potential of the conjugated polymer, improves the electrochromic performance of the black / green-transparent electrochromic thin film, and realizes stable and reversible conversion.

This polymer film 10 is characterized by comprising a first resin layer 11, a second resin layer 12, and a third resin layer, in that order. The polymer film is also characterized in that: the first resin film 11 forms one outermost layer of the polymer film 10; the first resin layer 11 includes a polyamide resin; the polyamide resin includes a copolymer polyamide that is a polycondensation product of diamine units and dicarboxylic acid units; the proportion of the number of aromatic diamine units to the total number of diamine units included in the polyamide resin that forms the first resin layer 11 is at least 75 mol%; the proportion of the number of isophthalic acid units to the total number of dicarboxylic acid units included in the polyamide resin that forms the first resin layer 11 is at least 22 mol%; the second resin layer 12 includes acid-denatured polypropylene; and the third resin layer 13 includes homopolypropylene.

The invention relates to the technical field of battery materials, and discloses a composite current collector and a preparation method and application thereof. The composite current collector comprises a first metal layer, a first transition layer, a polymer film base layer, a second transition layer and a second metal layer which are sequentially arranged from top to bottom, the surfaces of the two sides of the polymer film base layer are provided with micro-concave structures. The micro-concave structures are rhombic pits; the first transition layer and the second transition layer are made of metal oxides independently, and the surfaces of the two sides of the first transition layer and the second transition layer are provided with nanometer protruding structures; the height of the nano convex structure is 20 to 50 nm; the first metal layer and the second metal layer are made of metal conductive materials independently. The composite current collector provided by the invention has the characteristics of high interface bonding force and high conductivity.

The application discloses a liquid crystal polymer film, which is made of the following components by mass percentage: 50-70% of thermotropic liquid crystal molecule monomers, 25-35% of cross-linking agents, 1-10% of photo-initiators and 1-5% of photosensitive chiral agents. The liquid crystal polymer film is a flexible controllable and independent film forming device, has simple preparation process and convenient testing technology, and realizes multi-color and high saturation pattern through regulating and controlling the molecular arrangement and optical properties of the liquid crystal polymer film. The liquid crystal polymer film has excellent environmental stability and can keep stable performance under the change of humidity, pH and temperature, and is suitable for practical application in complex environment.