494 results about "Hydrogen content" patented technology

The invention provides an acoustic coalescence elimination method for hydrogen bubbles in molten aluminum, and belongs to the technical field of molten aluminum bubble elimination. According to the method, sound field collaborative focusing is achieved by arranging a phase control array transducer set in a molten aluminum smelting furnace, primary gathered sound waves and efficient coalescence sound waves are applied in stages according to bubble size evolution in a double-frequency scanning mode, and the hydrogen bubbles in the molten aluminum are eliminated. A target frequency is dynamically adjusted in combination with a bubble resonance frequency optimization model to match the inherent frequency of a bubble, a sound-bubble coupling dynamic tracking system is used for monitoring bubble evolution triggering stage switching in real time, and a sound field focus point dynamically scans and covers a three-dimensional space area through phase delay control. A delay detection method is adopted to eliminate cavitation bubble interference and accurately measure the hydrogen content, sound intensity and frequency parameters are optimized according to a sound field parameter self-adaptive regulation and control model, and the technical problem that hydrogen bubbles in a molten aluminum deep area are difficult to be effectively driven by sound waves and cannot be fully coalesced and eliminated is solved.

The invention discloses a hydrogen embrittlement-resistant welding wire for tailor welding of ultrahigh-strength aluminum-silicon coating hot-formed steel and a welding method, and belongs to the technical field of metal materials. 5.0%-7.0% of Ni; 0.3%-0.6% of Mo; 0.08% to 0.12% of Nb; mo, Nb and C react to form Mo2C / NbC nanophase fixed free hydrogen; 0.05%-0.1% of V: carrying out a reaction to form VC nanophase fixed free hydrogen; 0.5% to 0.8% of La; 0.3%-0.5% of Ce; 0.1%-0.5% of Ti; according to the invention, hydrogen atoms diffused in the welding process can be captured, the hydrogen content in a welding seam is obviously reduced, and the diffusible hydrogen amount is reduced by more than 40% under the hydrogen capturing effect of retained austenite, so that the hydrogen-induced crack sensitivity is reduced by 70%.

The invention provides a method, a system and equipment for optimizing and regulating operating parameters of a hydrogen production system and a medium. The method comprises the following steps: acquiring current, operating pressure, temperature and alkali liquor flow of the hydrogen production system under various different working conditions; based on the current, the operation pressure and the temperature under various working conditions, the electrolysis efficiency of the hydrogen production system under the corresponding working conditions is determined; based on the operation pressure and the alkali liquor flow under various working conditions, determining the hydrogen content in oxygen of the hydrogen production system under the corresponding working conditions; and aiming at the temperature and the corresponding current under each working condition, maximizing the electrolytic efficiency as an optimization target, and carrying out constraint optimization on the operating pressure and the alkali liquor flow under the constraint condition that the hydrogen content in oxygen is smaller than or equal to a preset safety threshold value, so as to obtain the target operating pressure and the target alkali liquor flow under the corresponding current and temperature conditions. According to the method, the electrolysis efficiency can be maximized under the condition of ensuring that the hydrogen content in oxygen meets the safety threshold value.

A process for the production of hydrogen is described comprising the steps of: (i) reforming a gaseous mixture comprising a hydrocarbon and steam having a steam to carbon ratio in the range of 0.4:1 to 1.8:1, to in a reforming unit comprising an autothermal reformer to produce a reformed gas mixture, (ii) subjecting the reformed gas mixture to an isothermal water-gas shift reaction in an isothermal water-gas shift reactor using water as a heat exchange medium, thereby increasing the hydrogen content of the reformed gas mixture and producing a hydrogen-enriched reformed gas while raising steam, cooling at least some of the hydrogen-enriched reformed gas and separating condensed water therefrom to provide a de-watered hydrogen-enriched reformed gas, (iv) subjecting at least some of the de-watered hydrogen-enriched reformed gas to carbon dioxide separation by performing a reactive amine wash on the hydrogen-enriched reformed gas in a carbon dioxide separation unit to recover carbon dioxide gas and crude hydrogen gas, and (v) subjecting at least some of the crude hydrogen gas to purification in a hydrogen purification unit to produce a purified hydrogen gas and a tail gas, wherein a portion of the tail gas is recycled to the process.

A process for the production of hydrogen is described comprising the steps of: (i) subjecting a gaseous mixture comprising a hydrocarbon and steam to steam reforming in a reforming unit comprising an autothermal reformer to generate a reformed gas mixture; (ii) increasing the hydrogen content of the reformed gas mixture by subjecting it to one or more water-gas shift stages in a water-gas shift unit to provide a hydrogen-enriched reformed gas; (iii) passing the hydrogen-enriched reformed gas and an oxygen-rich gas to an oxidation unit containing an oxidation catalyst that converts carbon monoxide present in the hydrogen-enriched reformed gas to carbon dioxide, to form a carbon dioxide-enriched gas mixture; and (iv) passing the carbon dioxide-enriched gas mixture to a product separation unit to provide a hydrogen gas stream, a carbon dioxide gas stream and a by-product gas stream, wherein at least a portion of the by-product gas stream is compressed and recycled to one or more of the reforming unit, the water-gas-shift unit, the oxidation unit, and the product separation unit.

The invention discloses an alkaline water electrolysis hydrogen production operation boundary evaluation method considering hydrogen content constraint in oxygen, and relates to the technical field of water electrolysis hydrogen production. The method comprises the following steps: analyzing a generation mechanism of gas crossing in an alkaline water electrolytic cell, according to steady-state and dynamic models of HTO gas crossing caused by diaphragm permeation and alkaline liquor mixed circulation in the electrolytic cell, and based on structural parameters represented by the volume of a gas-liquid separator and operating parameters such as working pressure, temperature, electrolyte circulation flow and the like of the electrolytic cell; the method comprises the following steps: analyzing the influence of different parameters on HTO impurity accumulation, quantifying the sensitivity coefficient of each parameter on HTO accumulation, predicting an HTO accumulation trajectory through a model, determining the safe operation range of different parameters, determining the safe operation boundary of alkaline water electrolysis hydrogen production, and constructing a parameter priority regulation and control method based on sensitivity ranking under a given operation condition. And pressure-flow-temperature parameters are determined for cooperative adjustment under the dynamic working condition, and the HTO concentration overrun risk is inhibited in real time.

The invention discloses a laboratory adsorption gas calculation method based on isothermal adsorption-nuclear magnetic resonance combined measurement, and relates to the technical field of exploration geophysics. According to the invention, on the basis of isothermal adsorption-nuclear magnetic resonance combined measurement experiment, 23MHz nuclear magnetic resonance experiment is utilized; nuclear magnetic signal conversion of bound water-adsorbed state methane is carried out through nuclear magnetic resonance T2 spectrums of coal rocks with different water saturations and T2 spectrums measured through a coal rock isothermal adsorption-nuclear magnetic resonance combined measurement experiment to obtain the hydrogen content of the adsorbed state methane, then the amount of substance of the adsorbed state methane is obtained, and finally the volume of the adsorbed state methane is obtained. The method comprises the following steps: firstly, measuring and determining the content of bound water in the coal rock by adopting a 25mm sample tube and the current minimum nuclear magnetism callback interval, then carrying out bound water-adsorbed gas nuclear magnetism signal conversion on the sample tube used in an isothermal adsorption-nuclear magnetism combined measurement experiment to obtain the hydrogen content of the adsorbed gas, further obtaining the amount of substance of the adsorbed gas, and finally obtaining the volume of the adsorbed gas.

The application provides a crystallizer protection slag for casting high-hydrogen-content medium-carbon steel liquid steel and application thereof, wherein the chemical composition of the crystallizer protection slag has the following mass percentages: SiO2: 25-32%, CaO: 29-36%, Al2O3: 1-4%, MgO: 3-6%, Na2O: 7-12%, F: 6-10%, C 总 : 3-6%, MnO: 2-4%, Li2O: 0.5-1%, and the rest is other inevitable impurities. The crystallizer protection slag can significantly reduce the occurrence rate of crystallizer sticking alarm emergency speed reduction and the occurrence rate of leakage during continuous casting when used for casting high-hydrogen-content medium-carbon steel liquid steel. Thus, the high-hydrogen-content medium-carbon steel liquid steel can be directly subjected to continuous casting without additional dehydrogenation treatment, the production efficiency is improved, and the production cost is solved.

The invention belongs to the technical field of titanium welding wire preparation, and discloses a preparation method of a low-cost low-hydrogen titanium welding wire. The method comprises the following steps: preparing a titanium alloy wire rod; under the room temperature condition, multi-pass continuous cold drawing operation is conducted on the titanium alloy wire rod, a plurality of drawing dies are detachably installed on the same continuous drawing machine or a plurality of continuous drawing machines connected in series, so that a wire material continuously passes through the multiple drawing dies at a time to complete multi-pass deformation, and the wire rod is subjected to continuous cold drawing. The pass deformation of the multi-pass continuous cold drawing is designed to be a starting stage, a middle stage and a final stage, and the single-pass deformation of the starting stage and the single-pass deformation of the final stage are smaller than the single-pass deformation of the middle stage; in the middle stage process or after the middle stage process, on-line annealing treatment is carried out on the wire, and on-line annealing is carried out under argon protection; and the wire material subjected to online annealing treatment is subjected to polishing and lower breaking or close arrangement treatment, and a titanium alloy welding wire finished product is obtained. The titanium welding wire prepared through the method is low in hydrogen content, high in preparation efficiency and low in cost.

This invention provides a boronene-coated sodium-ion battery cathode material and its preparation method, wherein the general chemical formula of the cathode material is Na[Ni]. a Fe b Mn c O2@BL (0 < a < 1, 0 < b < 1, 0 < c < 1, a + b + c = 1). This cathode material is uniformly coated with borene, effectively improving its air stability. The preparation method first involves growing a monolayer of borene on a copper surface using chemical vapor deposition, then obtaining a borene film using a wet transfer process. Finally, the borene film is mixed with the cathode material, vacuum-sealed, and sintered in a muffle furnace, ensuring the borene film is firmly coated onto the cathode material surface. This technology fully utilizes the unique cage-like structure, good conductivity, and high hydrogen content of borene materials. Introducing a borene coating layer onto the cathode material surface not only enhances its air stability but also improves its cycle life, rate performance, and energy density.

The invention relates to a method for determining the hydrogen content in an exhaust tract (130) of a hydrogen internal combustion engine (100) and to a hydrogen internal combustion engine (100) that has combustion chambers (110) and an oxygen sensor (140), which is provided in the exhaust tract (130) of the hydrogen internal combustion engine (100) and is designed to generate an oxygen signal that is representative of the oxygen content in the exhaust gas of the hydrogen internal combustion engine (100). The method according to the invention has the steps of determining a specified operating mode of the hydrogen internal combustion engine (100) during which substantially no combustion processes of an air-hydrogen mixture take place within the combustion chambers (110); receiving an oxygen signal from the oxygen sensor (140) in the specified operating mode of the internal combustion engine (100); and determining the hydrogen content in the exhaust gas of the hydrogen internal combustion engine (100) at least partly on the basis of the oxygen signal received from the oxygen sensor (140).

The invention provides a control method and device of an alkaline electrolyzed water system, an MPC controller optimizes hydrogen flow and auxiliary power supply power in real time through a prediction model in each control period to obtain an optimal control sequence of the current control period, and based on a first control parameter in the optimal control sequence, a second control parameter in the current control period is obtained; and cooperatively regulating the hydrogen-oxygen side pressure difference of the alkaline electrolyzed water system to a target value, and meanwhile, controlling the hydrogen concentration in oxygen of the alkaline electrolyzed water system within a safety threshold value. According to the scheme, the input is controlled based on rolling optimization of the multivariable dynamic prediction model, the dual targets of pressure difference stabilization and inhibition of the hydrogen content in oxygen are achieved, the technical problem that dynamic balance and the HTO risk are difficult to consider in traditional single parameter adjustment is solved, and the hydrogen production efficiency and safety are remarkably improved in the scene of wind and light fluctuation.

The invention discloses a rolling manufacturing method of low-decarburization medium-chromium round steel for a caterpillar track link and a product of the rolling manufacturing method, and belongs to the technical field of alloy steel rolling. The method comprises the following steps: smelting molten steel, wherein the molten steel comprises the following components in percentage by mass: 0.28-0.34% of C, 0.15-0.35% of Si, 0.50-0.85% of Mn, less than or equal to 0.030% of P, less than or equal to 0.030% of S, 0.80-1.10% of Cr, less than or equal to 0.30% of Ni, 0.10-0.30% of Mo, less than or equal to 0.30% of Cu, 0.010-0.060% of Al and the balance of Fe and impurities; lF refining, RH vacuum degassing (the time is longer than or equal to 20 min, and the hydrogen content is smaller than or equal to 1.5 ppm), electromagnetic stirring continuous casting (the superheat degree is 15-25 DEG C), slow cooling (longer than or equal to 12 h), segmented heating (the total time is shorter than or equal to 200 min, and the residual oxygen content is lt, 3%), multi-stage high-pressure water descaling (the pressure before finish rolling is 30-35 MPa) and hot continuous rolling (the compression ratio is larger than or equal to 6) are conducted. The total decarburized layer depth of the obtained round steel is smaller than or equal to 0.30 mm, and the round steel has high hardenability, excellent mechanical property and low surface defect rate and is suitable for heavy-load components such as a hydraulic excavator caterpillar track link.

The invention discloses a compact tensile sample dynamic hydrogen charging test device and a test method. The compact tensile sample dynamic hydrogen charging test device comprises an electrochemical hydrogen charging device, a liquid carrying table, a compact tensile sample and a clamp, a CT sample penetrates through the liquid carrying table through the clamp and is fixed, and the electrochemical hydrogen charging device is connected with the liquid carrying table; and the whole CT sample and the clamp head are positioned in the columnar container and are immersed in the electrolyte of the columnar container. The problems of potential safety hazards, limited hydrogen filling content and hydrogen escape during hydrogen filling of the CT sample are solved; electrochemical hydrogen charging can be carried out while a fracture toughness test or a fatigue test is carried out, so that hydrogen overflow caused from hydrogen pre-charging to an experiment is effectively avoided, and potential safety hazards of experiment problems caused by a conventional hydrogen pre-charging experiment are also avoided; any hydrogen charging current density can be taken, after the surface area of a sample is measured, the hydrogen flux in the experiment process can be strictly controlled by adjusting the current of the direct-current power supply, the gradient hydrogen concentration is obtained by controlling the current and the hydrogen charging time, research is facilitated, and experiment parameters are accurate.

The application provides a method, an apparatus and a device for evaluating a dynamic diffusion of natural hydrogen in rock pores. The method includes: performing, at a target pressure and a target temperature, a simulation calculation of a natural hydrogen adsorption based on a pre-constructed pore model of a rock to be evaluated, and determining an average number of hydrogen molecules adsorbed in the rock pores when the natural hydrogen is saturated at the target pressure and the target temperature; determining a natural hydrogen content, based on lithologic parameters, the average number of hydrogen molecules, the target pressure and the target temperature; adding one or more preset gases to the pre-constructed pore model, determining a loss content of the natural hydrogen, and determining a diffusion coefficient of the natural hydrogen; determining a diffusion evaluation parameter, based on the natural hydrogen content, the loss content and the diffusion coefficient.

The invention relates to a preparation method of a molybdenum-titanium alloy target material, which comprises the following steps: mixing molybdenum powder and titanium powder in a protective gas atmosphere to obtain mixed powder; the mixed powder is subjected to cold isostatic pressing, sheath degassing, hot isostatic pressing and vacuum annealing in sequence, and then the molybdenum-titanium alloy target material is obtained; the average particle size of the molybdenum powder is 3-5 [mu] m, and the average particle size of the titanium powder is 100-150 [mu] m; according to the preparation method, the molybdenum-titanium alloy target material which only contains a pure molybdenum phase and a molybdenum-titanium alloy phase and is high in density and low in content of gas impurity elements is prepared by selecting raw materials with specific particle sizes and matching specific procedures; wherein the proportion of the molybdenum-titanium alloy phase is preferably as high as 50% or above, the density is preferably as high as 99.9% or above, the hydrogen content is preferably as low as 3 ppm or below, the oxygen content is preferably as low as 576 ppm or below, and the problem that the product yield is low due to the fact that an existing molybdenum-titanium target is likely to be abnormal in the sputtering process is effectively solved.

The invention relates to a method for monitoring the ventilation of a crankcase (120) of a hydrogen internal combustion engine (100) and to a hydrogen internal combustion engine (100), which has combustion chambers (110) and a gas sensor (140) that is provided in the exhaust tract (130) of the hydrogen internal combustion engine (100) and is designed to generate a gas signal that is representative of the hydrogen content or oxygen content in the exhaust gas of the hydrogen internal combustion engine (100). The method according to the invention has the steps of: determining a specified operating mode of the hydrogen internal combustion engine (100) during which substantially no combustion processes of an air-hydrogen mixture take place within the combustion chambers (110); receiving a gas signal from the gas sensor (140) in the specified operating mode of the hydrogen internal combustion engine (100); determining the hydrogen content in the exhaust gas of the hydrogen internal combustion engine (100) at least partly on the basis of the received gas signal; and determining a functional ventilation of the crankcase (120) if the determined hydrogen content in the exhaust gas of the hydrogen internal combustion engine (100) exceeds a specified hydrogen content threshold value.

This invention discloses a rapid assessment method for hydrogen damage in ultra-long-life structures under alternating loads, relating to the field of materials performance evaluation. The method includes the following steps: S1: Analyzing the service conditions of typical ultra-long-life structures and key components to determine the service environment of key component materials; S2: Conducting ultra-high cycle fatigue tests under different stress ratios to obtain stress-life data for different lifespans; S3: Observing the fracture morphology of high-cycle fatigue and ultra-high cycle fatigue samples using scanning electron microscopy; S4: Performing hydrogen element detection to obtain the hydrogen content distribution around micro-defects; S5: Using the Basquin formula, piecewise linearly fitting the S-N data for the high-cycle fatigue and ultra-high cycle fatigue stages to obtain the slopes of two fitted lines; S6: Using the ratio of the slopes of the two fitted lines as the hydrogen damage factor. The method disclosed in this invention can achieve rapid assessment of hydrogen damage in long-life structures under alternating loads while ensuring the reliability of the assessment results.

The invention relates to the technical field of titanium alloy preparation and machining, and particularly discloses a method for preparing a titanium alloy workpiece through near-net forming of titanium hydride powder. The method comprises the steps that after titanium hydride powder and intermediate alloy powder are mixed, cold press molding is conducted under 200-800 MPa, and a pressed blank is obtained; sintering the pressed blank and the mold for the first time at the temperature of 500-1200 DEG C, preserving heat for 10-30 minutes, and then cooling; and the pressed blank is taken out of the mold, secondary sintering is carried out at the temperature of 1200-1400 DEG C, cooling is carried out after heat preservation is carried out for 2-4 hours, and a titanium alloy workpiece is obtained. The method does not include the step of partially dehydrogenating the titanium hydride powder before cold press molding. According to the method, the problem that the titanium hydride pressed blank is easy to crack during demolding is fundamentally solved through the first sintering with the mold by utilizing the volume shrinkage effect in the dehydrogenation process, so that the product percent of pass is greatly improved, and meanwhile, the low hydrogen content (llt of a workpiece is ensured; 0.015%), high density (greater than or equal to 99%) and uniform components.

Provided herein are examples of methods and related apparatus for depositing an ashable hardmask (AHM) on a substrate using a process gas including hydrocarbons and halide-containing species and pulsed low frequency (LF) power. Halide-containing species may decrease the hydrogen content of the AHM, and a plasma using pulsed LF power may improve mechanical properties of the AHM. Also provided herein are examples of annealed hardmasks and examples of processes for annealing hardmasks.

The invention discloses an alloy aluminum bar containing rare elements and a preparation technology of the alloy aluminum bar. The alloy aluminum bar comprises, by mass, 1.5%-3.3% of Mg, 0.7%-1.1% of Si, 1.0%-1.7% of Cu, 0.15%-0.3% of Y, 0.07%-0.1% of Er, 0.05%-0.11% of Gd, 0.07%-0.24% of La, 0.08%-0.15% of Zr, 0.07%-0.12% of Ti, 0.05%-0.1% of Sc, smaller than or equal to 0.1% of Fe, 0.35%-0.7% of Mn, 0.2%-0.6% of Ni, smaller than or equal to 0.5% of total impurities and the balance aluminum. The preparation process comprises the following steps: burdening: accurately weighing a high-purity aluminum ingot, Al-Y, Al-Zr, Al-Ti intermediate alloy and pure metal according to the components; smelting: melting at 720-750 DEG C, preserving heat, and protecting by argon; cooling to 740-720 DEG C, and adding an intermediate alloy; a refining agent is added for degassing and deslagging, and slagging-off is conducted after standing is conducted for 30 min; casting: the temperature is 720-740 DEG C, the casting speed is 120-200mm / min, the strength of cooling water is 0.06-0.15 MPa, the water temperature is 10-30 DEG C, and online degassing is performed outside the furnace so that the hydrogen content is less than or equal to 0.15 cm / 100g Al; through scientific proportioning of conventional alloy elements such as Mg, Si, Cu and Mn and various rare elements such as Y, Er, Gd, La, Sc, Zr and Ti, the synergistic strengthening effect of the conventional elements and the rare elements is achieved, and the performance bottleneck of a traditional aluminum alloy is effectively broken through.

To provide a piezoelectric element with excellent displacement characteristics, and a liquid dispensing head including such piezoelectric element. [Solution] The piezoelectric element comprises a piezoelectric layer consisting of multiple layers and a pair of electrodes arranged on either side of the piezoelectric layer, wherein the piezoelectric layer is made of lead zirconate titanate, and when the average value H(Ave), maximum value H(max), and minimum value H(min) of the hydrogen content contained in the multiple layers in the center of the piezoelectric layer are defined as follows, and ΔH is the larger of the absolute values ​​of (H(max)-H(ave)) / H(ave)) or (H(min)-H(ave)) / H(ave)) as the rate of change of hydrogen content, ΔH is 24% or less.

The utility model relates to the field of electrolyzed water, and provides a catalyst coated membrane structure, a membrane electrode and a device for producing hydrogen by electrolyzing water, the catalyst coated membrane structure comprises a proton exchange membrane, a cathode catalyst layer and an anode catalyst layer, the cathode catalyst layer and the anode catalyst layer are respectively arranged on two sides of the proton exchange membrane, and the anode catalyst layer is arranged on the proton exchange membrane. And a hydrophobic hydrogen-resistant layer is arranged between the proton exchange membrane and the cathode catalyst layer. The method has the advantages that the hydrogen transmittance is reduced, so that the concentration of hydrogen in anode side oxygen is reduced, the explosion risk is reduced, and the safety coefficient during operation of the electrolytic cell is improved. In addition, expensive metal and metal oxide catalysts are not used in the scheme, so that the cost of the catalyst coating film is reduced while the hydrogen resistance effect is achieved. And when the hydrogen passing ability is reduced, normal proceeding of other mass transfer is guaranteed, the water electrolysis hydrogen production device still has high performance under the condition that the hydrogen content in the anode side oxygen is low, and the safety of an electrolytic cell during operation is improved.

The present application and invention relate to a method for the production and further processing of semi-finished products made of a metal, comprising the steps: -Casting of semi-finished products from a molten metal using a casting device; -If necessary, splitting a casting strand into semi-finished products of defined length using a cutting device; -Transporting the semi-finished products using a transport device; -Cooling of the semi-finished products in at least one cooling process; -Verification of the microstructure quality of the individual semi-finished products by calculating at least one process parameter relevant to the microstructure quality; -Decision on the steps for further processing of the respective semi-finished product in a cooling process based on at least this one process parameter; -where this process parameter is the hydrogen concentration in the semi-finished product and / or in the melt. Knowing the hydrogen content of the semi-finished products allows for a reduction in their dwell time during various cooling processes. The inventive method enables optimization of dwell times during stacking in the cooling process and an improvement in the quality of the semi-finished products.

The application provides a hydrogen deep removal and moisture removal method. High-concentration raw gas is dynamically mixed with dry low-concentration reflux gas in a mixer to form mixed gas, so as to reduce the hydrogen content and reduce the reaction risk. After pressurized heating, oxygen with a precisely matched hydrogen concentration is injected into a reactor for reaction. The reactor is provided with an alternating fixed and rotatable cylinder, and the inner wall of the flow channel is coated with a catalyst; the corresponding cylinder speed is automatically adjusted based on real-time hydrogen concentration detection downstream, and the speed is accelerated when the concentration exceeds the standard to strengthen turbulent contact and prolong the reaction time, combined with the concentration threshold setting decreasing along the flow direction, so that the hydrogen is deeply removed to an ultralow level. The reaction generates moisture, most of which is separated by two-stage water cooling, and then is deeply adsorbed and dried to be completely removed to an ultralow content. Finally, the gas is divided into two parts, one part is output as product gas, and the other part is completely dried reflux gas which is recycled to the initial mixing step to reduce the reaction risk of high hydrogen content.

This invention provides a high-end vacuum argon-oxygen refining apparatus (VODC furnace) for special metal materials and its refining method, belonging to the technical field of metallurgical refining equipment. It solves the problems of complex structure and high manufacturing and production costs associated with existing VOD furnace vacuum systems. This invention separates the vacuum system from the blowing system through modular design, employs a movable vacuum sealing structure and optimized furnace design, achieving a significant reduction in equipment and production costs. The refining method, by controlling the vacuum degree, oxygen blowing parameters, and stirring intensity, reduces non-metallic inclusions in the steel, achieving a hydrogen content of less than 1.5 × 10⁻⁶. ‑6 Oxygen content less than 2.0 × 10 ‑5 The chromium recovery rate in stainless steel reaches 98%-99%, and the refined steel possesses superior properties. Production efficiency is significantly improved while ensuring product quality. Compared with traditional equipment, this invention reduces equipment investment costs by more than 30%, shortens the refining cycle by 25%, and reduces energy consumption by 20%, making it particularly suitable for small-batch, multi-variety production of high-end specialty metal materials.

This invention discloses a method for preparing high creep-resistant and high-temperature resistant titanium alloy powder, relating to the field of titanium-based alloy technology. The titanium alloy powder composition includes 4%–8% aluminum, 1%–6% tin, 2%–8% zirconium, 1%–10% niobium, 0.5%–5% molybdenum, 0.05%–0.8% silicon, 0.01%–0.5% yttrium, and 0.5%–5% hafnium, with the balance being titanium and impurities. The titanium alloy melt is obtained by vacuum melting, cooled into alloy ingots, remelted, and then conveyed to an atomization system under high pressure under inert argon protection. Spherical titanium alloy powder is obtained by gas atomization; after multi-stage sieving and deep purification, impurities are removed and the oxygen, nitrogen and hydrogen content is reduced. The purified titanium alloy powders of different particle sizes are mixed and stored in an inert atmosphere; the atomization pressure is 3MPa to 10MPa, the powder particle size is 15μm to 53μm or 45μm to 105μm, the sphericity is not less than 95%, and the oxygen content is ≤0.15wt%, nitrogen content is ≤0.03wt%, and hydrogen content is ≤0.01wt%. This invention has excellent high-temperature stability, high creep resistance and good formability.

An apparatus and process for parahydrogen concentration analysis can include forming a synthetic gas that can mimic a hydrogen fluid (e.g. gas or liquid) having 0 mole percent (mol %) parahydrogen. An analyzer may then be calibrated via use of a reference hydrogen gas having a first pre-selected parahydrogen concentration (e.g. a 25 mol % parahydrogen content) and the synthetic gas to identify multiple calibration points for the analyzer for calibration of the analyzer. After the analyzer is calibrated, it can subsequently be utilized to determine a parahydrogen concentration of one or more samples of hydrogen fluid. Some embodiments can be utilized to help ensure that a liquid hydrogen that is produced via liquefaction or other liquid hydrogen production process has a content of at least 95 mol % parahydrogen.

The invention discloses a liquid hydrogen production device and a working method thereof.The liquid hydrogen production device comprises a first heat exchanger, a pipe mechanism, a conversion mechanism, a cooling mechanism and a valve bank, a second cooling medium inlet, a first inlet and a first outlet are formed in the first heat exchanger, and the pipe mechanism comprises a first cooling pipe; and the first cooling pipes are connected with the first heat exchanger. The valve set comprises a second throttling valve, the second throttling valve is installed on a first cooling pipe, the first cooling pipe is communicated with a first outlet and a second cooling medium inlet, and circulating hydrogen entering the first heat exchanger from the first inlet exchanges heat with circulating hydrogen cooled and depressurized through the cooling mechanism. And the first cooling medium flows into the first cooling pipe from the first outlet, is throttled by the second throttling valve and enters the first heat exchanger from the second cooling medium inlet. The raw material hydrogen is cooled through the mode that expansion continuous refrigeration of the cooling mechanism cooperates with high-pressure throttling refrigeration, energy is saved, and meanwhile the product hydrogen with the parahydrogen content reaching 97% is produced.

The present application relates to a kind of nano platinum colloids and its preparation method and its application, the average particle size of the nano platinum colloids is 50-100nm, D90 is 100-150nm, D10 is 30-70nm, zeta potential is-25mV to-40mV, pd I is 0.2-0.5, sphericity is 0.85-0.97.The nano platinum colloids prepared by the present application has small particle size, as catalyst has higher catalytic efficiency, can quickly capture hydrogen to occur reaction, is not influenced by hydrogen escape, is used in the detection reagent for determining the dissolved hydrogen concentration in water, reaction rate is fast, titration result is more accurate.