13305 results about "Slag" patented technology

The invention provides a solid waste filling material ratio optimization method of a magnesium slag-steel slag composite cementing material, and relates to the technical field of solid waste filling. The method comprises the following steps: mixing magnesium slag, steel slag, desulfurized gypsum and mineral slag to prepare a cementing material, and carrying out pretreatment and physicochemical property analysis on raw materials by taking tailings and waste rocks as filling aggregates; then designing a cementing material proportioning scheme and carrying out strength test to obtain an optimal ratio of the cementing material; then considering different slurry concentrations and plastic-to-bone ratios, and carrying out an all-solid waste filling slurry rheological test and an all-solid waste cementitious body strength test; and finally, according to the two test results, establishing a multi-objective optimization model taking the on-way resistance and the filling material cost as optimization objectives and taking the strengths of cementitious bodies at different ages as constraint conditions, and determining optimal parameters of the full-solid waste filling material. According to the invention, resource utilization of the metallurgical solid waste and the mine solid waste is realized, the bottlenecks of high carbon emission and high cost of a cement-based filling material are broken through, and a solution is provided for co-processing of the mine solid waste.

The present invention relates to the technical field of waste heat recovery equipment, and specifically discloses a waste heat recovery device for flue gas in a thermal power plant. It includes a box body with an upper smoke chamber, a heat exchange chamber and a lower smoke chamber inside. A number of smoke pipes connecting the upper smoke chamber and the lower smoke chamber are fixed in the heat exchange chamber; above the smoke pipes, there is a piston cylinder fixed by the box body; the upper end of the piston cylinder is connected to a high-pressure gas supply pipe, and a piston is arranged inside. The piston is connected with a scraping head through a push rod; side holes are provided on the push rod; when the high-pressure gas drives the piston to move downward, the scraping head moves along the inner wall of the smoke pipe to scrape off the ash slag. The waste heat recovery device for flue gas in this thermal power plant has a cleaning function and a better cleaning effect, high heat exchange efficiency and good waste heat recovery effect. The waste heat recovery device for flue gas in this thermal power plant can be automatically cleaned without disassembling components, is fast and efficient, and can be operated online. The ash slag scraped off during the cleaning process can be centrally recovered, avoiding re-mixing into the flue gas again, reducing the workload in the flue gas dust treatment link, and saving the subsequent environmental protection treatment cost.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The present invention belongs to the field of resource utilization of building materials and solid waste, and relates to a red-mud-based cementing material based on efficient drying, component homogenization and activity improvement, and a preparation method therefor. The preparation method comprises: adding a filter aid to red mud to carry out sedimentation, then subjecting same to filter pressing until the water content is 14-16%, then drying the solid material, which has been subjected to filter pressing, until the water content is 4% or below, and finally grinding same to obtain the product. The filter aid comprises the following raw materials: 10-30 parts of polyaluminum chloride, 5-15 parts of polyaluminum sulfate, 1000-1200 parts of blast furnace slag or fly ash, 700-900 parts of steel slag, 400-600 parts of carbide slag or alkaline residues, and 300-400 parts of desulfurized gypsum or phosphogypsum or fluorgypsum. By means of the present invention, the dehydration efficiency of red mud can be improved, the red-mud-based cementing material can also be prepared in one step; the preparation process for the red-mud-based cementing material is simplified; and the prepared red-mud-based cementing material has the advantages of a high mechanical strength, high durability and erosion resistance.

The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.

The invention discloses a cementing material for a solid waste-based road of a coal-fired power plant and a preparation method of the cementing material. The cementing material mainly comprises a cementing component, an alkali-activated component and a reinforcing component, the gelling component is a mixture of coal-fired power plant fly ash and furnace slag; the alkali-activated component is a mixture of alkali residues, red mud, blast furnace slag and coal-fired power plant desulfurized gypsum; the reinforcing component is rice hull ash or peanut hull ash. The mass ratio of the gelling component to the alkali-activated component is (4 / 1)-(10 / 1); and the addition amount of the reinforcing component is 1-3% of that of the main body material. The coal-fired power plant solid waste fly ash, the furnace slag and the desulfurized gypsum are used as main bodies, a small amount of other industrial solid waste is added, and the cementing material belongs to a full-solid-waste low-carbon cementing material and can be applied to a road base, a subbase or a base layer. The invention has the characteristics of low carbon emission, high solid waste consumption, simple production process and strong pavement performance, and in addition, the invention has a good stabilization effect on the problem that part of solid waste heavy metals and sulfate ions in a coal-fired power plant exceed the standard.

The invention provides a tunnel drilling and blasting slag removal vehicle autonomous path planning method and device based on a Naligation 2 behavior tree scheduling framework, and the method comprises the following steps: S1, carrying out the data collection and map construction of a tunnel scene after drilling and blasting; s2, identifying a blasting residue area and generating a target point; s3, constructing a behavior tree scheduling structure and planning a path; and S4, performing path search, execution and feedback evaluation based on a path planning algorithm. According to the method, multi-source sensor mapping and deep learning semantic segmentation technologies are combined, high-precision recognition and traffic area extraction of residual obstacles in an unstructured tunnel environment after drilling and blasting are performed are performed, complex scenes faced by slag removal path planning are fully considered, a behavior tree scheduling mechanism is adopted to fuse path planning, target scheduling and an anomaly recovery strategy, and the path planning efficiency is improved. And a path execution system of real-time response and fault-tolerant capability is further constructed, and the operation continuity and robustness of the robot in a complex operation environment are improved.

The invention belongs to the technical field of tungsten smelting, and particularly discloses a method for recycling tungsten from tungsten smelting soda boiling slag through reselection, tungsten in the slag is recycled through a physical mineral separation method, a large number of acid-base reagents are not introduced, acid-base wastewater is not generated, and high-energy-consumption roasting or high-temperature acid-base leaching is not needed. The process is simple, large-scale treatment can be achieved, reagent consumption is low, energy consumption is low, closed-loop circulation of mineral separation water can be achieved, no wastewater is discharged, the process is environmentally friendly and free of pollution risks, meanwhile, indexes of the soda boiling residues subjected to innocent treatment can reach industrial solid waste, hazardous waste is converted into common solid waste, and the economic benefit is high. The environment-friendly treatment cost is low.

The invention discloses a blast furnace cooling wall damage probability prediction method, which relates to the field of industrial equipment maintenance, and comprises the following steps: arranging a temperature sensor array, a vibration sensor and an acoustic emission sensor, and collecting temperature gradient data, mechanical vibration frequency and high-frequency stress wave signals in real time; calculating the slag crust thickness of the hot surface of the cooling wall based on an unsteady state heat transfer equation, introducing an in-furnace gas flow parameter correction model, and generating a dynamic slag crust thickness distribution cloud picture; establishing temperature and vibration reference threshold values under different working conditions according to historical operation data of the cooling wall, and detecting temperature over-limit accumulated duration and a vibration energy spectrum abnormal frequency band in real time; taking the temperature gradient range, the slag skin thickness variation coefficient and the vibration dominant frequency offset as input characteristics, training a multi-dimensional coupled damage probability prediction model through a random forest algorithm, and outputting a recent dynamic damage probability value of each section of cooling wall; and dividing risk grades according to the damage probability value, dynamically adjusting a threshold interval in combination with the real-time smelting strength of the blast furnace, and generating a differentiated maintenance suggestion set.

The invention discloses an anti-jamming coal mining drilling machine with drilling and multidirectional impacting functions and a using method thereof.The anti-jamming coal mining drilling machine comprises a drilling machine body, a high-pressure driving mechanism is arranged on the drilling machine body through a multidirectional guide rail mechanism, and a drilling assembly is connected with the high-pressure driving mechanism; when the drilling machine works, the high-pressure driving mechanism drives the drill rod and the drill bit to conduct rotary drilling, the high-frequency transverse vibration mechanism synchronously generates transverse high-frequency vibration, the high-pressure driving mechanism drives the drill rod and the drill bit to conduct rotary drilling, and the high-frequency transverse vibration mechanism drives the drill rod and the drill bit to conduct rotary drilling. The friction force between the drill bit and rock is reduced, debris accumulation is prevented, efficient deslagging is achieved, when hard rock or drill jamming occurs, the longitudinal vibration impact mechanism triggers longitudinal vibration, impact and drill jamming prevention functions are achieved through cooperative work of transverse vibration and longitudinal vibration, the drill jamming problem under the complex geological condition is effectively solved, the drilling efficiency and equipment reliability are improved, and the drilling cost is reduced. The device is suitable for drilling operation of mining roofs and baseplates, sides and the like.

The invention relates to the technical field of cementing materials, in particular to an early-strength type freeze-thaw cycle-resistant cementing material and a preparation method thereof. The cementing material comprises the following raw materials in parts by mass: 50 parts of steel slag, 32-42 parts of blast furnace slag, 11-17 parts of desulfurized gypsum, 22-30 parts of fly ash, 3-5 parts of calcium chloride, 4-7 parts of a composite alkali activator and 11-17 parts of an interface treating agent. Through the combined action of the composite alkali activator and the interface treating agent, the mechanical strength and the freeze-thaw cycle resistance of the cementing material are improved at the same time, and particularly, the early strength and the freeze-thaw cycle resistance are improved at the same time, so that the cementing material can be applied to high-humidity and cold regions.

The present invention provides a device and method for the resource utilization of urban waste incineration slag, which relates to the technical field of slag waste recycling. The device for the resource utilization of urban waste incineration slag includes an equipment frame and a crusher installed on the equipment frame. It further includes a flow and precipitation component, a water addition component, and a resource recovery component installed on the equipment frame. The crusher transfers the crushed slag to the water addition component. The water addition component is used to add water to the ash slag and make it flow into the flow and precipitation component. After operation and precipitation, it is then discharged onto the resource recovery component. It also includes multiple groups of stirring components for stirring the slurry in the flow and precipitation component. The device and method for the resource utilization of urban waste incineration slag, by setting the flow and precipitation component, can obtain precipitation within the operation time compared with a fixed sedimentation tank, and can be flipped and dumped, and flushed with high-pressure water, making it easier to clean the internal slurry and preventing blockage.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention discloses a slurry shield short screw and rear crusher collaborative deslagging working parameter optimization method based on CFD-DEM coupling modeling, and relates to the technical field of civil engineering and tunnel engineering.The slurry shield short screw and rear crusher collaborative deslagging working parameter optimization method comprises the steps that rheological behaviors of slurry are simulated through a rheological model; establishing a three-dimensional calculation model, and optimizing short spiral rotating speed setting; based on a coupling technology, establishing a crushing cabin three-dimensional coupling model; performing coupling simulation; the working parameters of the crusher are optimized; obtaining the crushing mass per second of rock slag particles under each group of simulation and the mass flow rate of slag discharged from an outlet of the crushing cabin; and optimizing each decision variable by using a multi-objective particle swarm optimization algorithm, and determining an optimal solution by using an approximation ideal solution. The method can quickly and accurately calculate the optimal combination of the working parameters of the short screw and the working parameters of the crusher at different shield tunneling speeds, alleviates the difficult problem of stagnant discharge of the actual engineering muddy water cabin, and has the advantages of low cost, wide applicability, high practicability and high popularization value.

According to the technical scheme, the efficient hot-dip galvanizing method based on the zinc liquid purification technology comprises the following steps of incoming material inspection, degreasing, acid pickling, rinsing, plating assisting, drying, hot-dip galvanizing, zinc draining and cooling, and the hot-dip galvanizing process is dynamically matched with electromagnetic stirring strength through gradual temperature control; based on a temperature-iron content response curve, parameters of all procedures are accurately controlled, temperature dynamic adjustment is achieved, collaborative optimization of the zinc liquid purification and slag salvaging process is achieved, and the method has the advantages that zinc slag is reduced, the coating uniformity is improved, and energy consumption is reduced.

The invention relates to a magnesia-carbon refractory material with high thermal shock resistance and erosion resistance and a preparation method thereof. The magnesia-carbon refractory material with high thermal shock resistance and erosion resistance is prepared from fused magnesia aggregate, fused magnesia fine powder, silicon powder, crystalline flake graphite, Al2O3-MgO-CaO core-shell structure raw materials and phenolic resin. The Al2O3-MgO-CaO core-shell structure raw materials are prepared by the following steps: uniformly mixing calcium carbonate, magnesium hydroxide and alumina micro powder by adopting a planetary ball mill, and then carrying out granulation treatment by adopting a disc granulator by taking polyvinyl alcohol as a binding agent, so as to obtain core particles; and mixing the inner core particles and the alumina micro powder by taking alumina sol as a binding agent, and further sintering to obtain the core-shell structure raw material. The Al2O3-MgO-CaO core-shell structure raw material is utilized to improve the comprehensive performance of the magnesia-carbon refractory material, and the prepared magnesia-carbon refractory material has excellent thermal shock resistance and slag corrosion resistance and can meet the requirements of the current steel industry for the magnesia-carbon refractory material.

The invention belongs to the technical field of asphalt mixtures, and relates to a high-dosage RAP low-temperature hot mix plant recycled SMA-13 asphalt mixture and a preparation process thereof, and the low-temperature hot mix plant recycled SMA-13 asphalt mixture comprises the following components by weight: 50-60 parts of an asphalt mixture reclaimed material; 30-40 parts of modified steel slag aggregate; 3-5 parts of SBS modified asphalt; 0.02 to 0.06 part of a low-temperature asphalt modifier; 3-8 parts of superfine slag powder; 0.2 to 0.5 part of lignin fiber; and 1-2 parts of a self-made asphalt regenerant. The limitation of the traditional RAP doping amount is broken through, the highest doping amount reaches 70%, the steel slag recycled aggregate replaces natural aggregate, the consumption of raw materials and the emission of waste are remarkably reduced, and the steel slag recycled aggregate meets the target requirements of the new era of dual-carbon strategy and sustainable development; and the method is particularly suitable for winter construction, heavy traffic roads and green road construction in iron and steel industry areas, and has technical advancement and engineering practicability.

The invention relates to the technical field of cement materials, in particular to a red-mud-containing steel slag composite cementing material and a preparation method thereof.The method comprises the steps that red mud, slag, steel slag, desulfurized gypsum and sulphoaluminate cement clinker are subjected to dry mixing to obtain an initial mixture; determining whether the excitation capability of the potential hydration activity reaches the standard or not based on the alkaline matching index, and adjusting the weight part of the sulphoaluminate cement clinker; adding a composite exciting agent to obtain activated slurry; determining whether the dispersion effect of the flocculation structure of the initial mixture is qualified or not based on the dispersion index of the flocculation structure, and adjusting the ball milling rotating speed; adding a polymer emulsion to obtain an initial composite cementing material; determining whether the synergistic enhancement effect of the polymer emulsion and the activated slurry is qualified or not based on the synergistic enhancement index, and adjusting the dripping rate of the polymer emulsion; the steel slag composite cementing material containing the red mud is obtained. The preparation stability of the red mud-containing steel slag composite cementing material is improved.

The invention provides a method for recycling lithium iron phosphate, which comprises the following steps: S1, obtaining lithium iron phosphate black powder, and washing the lithium iron phosphate black powder by using alkali liquor to obtain aluminum-removed black powder and aluminum-containing lithium filtrate; s2, the aluminum-removed black powder is subjected to acid leaching treatment with acid liquor, and acid leaching liquor is obtained; s3, carrying out reduction precipitation treatment on the acid leaching solution by using a composite reducing agent to obtain a copper-removed leaching solution and solid-phase copper-containing slag; s4, adding a phosphorus source and an oxidizing agent into the copper-removed leaching solution, adding alkali to adjust the pH value, and carrying out oxidation precipitation treatment to obtain iron phosphate precipitate and a first lithium-containing solution; and S5, adjusting the pH value of the aluminum-lithium-containing filtrate in the step S1 by using an acid solution to obtain aluminum filter residues and a second lithium-containing solution. According to the method, iron phosphate with relatively high purity can be obtained; meanwhile, the obtained first lithium-containing solution and the second lithium-containing solution are relatively low in impurity ion content and can be used for obtaining a lithium salt product with relatively high purity.

The invention relates to the technical field of steel pipe hot galvanizing, in particular to steel pipe hot galvanizing automation equipment and a galvanizing technology.The steel pipe hot galvanizing automation equipment comprises a zinc liquid pool, a second horizontal moving part is fixedly arranged on one side of the zinc liquid pool, placing tables are arranged on one side of the second horizontal moving part at intervals, and the upper ends of the placing tables are in threaded connection with blocking strips through bolts; a moving assembly is arranged above the molten zinc pool, a stirring assembly is arranged on the outer surface of the moving assembly, a deslagging assembly is arranged at the upper end of the molten zinc pool, first electric telescopic rods are detachably connected to the two sides of the molten zinc pool through supports, push plates are fixedly arranged at one ends of the first electric telescopic rods, and an air blowing part is arranged on one side of the molten zinc pool in a penetrating mode. Through the arrangement of the moving assembly and the slag removal assembly, automatic hot galvanizing of the special-shaped steel pipe is achieved, automatic removal of zinc slag on the surface of zinc liquid can be achieved, through the arrangement of the moving assembly, the stirring assembly and the first electric telescopic rod, residues of the zinc liquid can be reduced, and the possibility of zinc tumor occurrence is reduced.

The invention relates to the field of building material preparation, in particular to a high-strength concrete material and a preparation method thereof.According to the high-strength concrete material, through the synergistic effect of core-shell type temperature-sensitive resin particles, a pH response type expanding agent and industrial solid waste composite micro powder, multi-environment self-adaptive crack resistance and mechanical property breakthrough are achieved. The core component is prepared from 180 to 240 parts of cement, industrial solid waste composite micro powder (30 to 50 parts of fly ash-based nano SiO2 and 50 to 70 parts of steel slag micro powder), 10 to 15 parts of core-shell resin particles and 8 to 12 parts of pH response type expanding agent. According to the preparation process, multi-section intelligent stirring (ultra-high-speed shearing and dispersing of the nanometer material) and dynamic maintenance of the internet of things are adopted, the hydration process is precisely regulated and controlled, and the finally prepared material has excellent compressive strength and anti-cracking performance. The method is suitable for severe scenes such as ocean engineering and plateau buildings, and has wide application prospects.

The invention relates to the technical field of mine solid waste treatment and carbon dioxide sealing and storage, and particularly discloses a system and a method for sealing and storing carbon dioxide by utilizing coal-based solid waste and mine water to prepare slurry. The system comprises a cement bin, a gangue bin, a coal ash bin, a gasified slag bin, a mine water storage tank, a stirring reaction kettle, a carbon dioxide storage tank, a slurry temporary storage tank, a vacuum pump and a slurry pump, and the stability and adsorption efficiency of carbon dioxide fixation are improved in the mode that coal-based solid waste, mine water and carbon dioxide are subjected to chemical reaction and physical adsorption; meanwhile, the prepared backfill slurry has high-strength anti-pressure ability, the stability of the backfilled underground goaf is better improved, further, coal-based solid waste and mine water are utilized for waste recycling, and the carbon dioxide storage cost is reduced.

The invention discloses an intelligent control system and method for a shield muck treatment site, and relates to the technical field of shield engineering muck treatment. In order to solve the problems of low efficiency and high pollution of the existing muck treatment mode, the invention provides the following technical scheme: the muck treatment system comprises a sensing layer, a transmission layer, a control layer and an application layer, and the sensing layer is mounted around a muck treatment site and is used for monitoring muck components, equipment operation states and environmental parameters in real time; the transmission layer transmits the data collected by the sensing layer to the control layer; the control layer processes data of the sensing layer and automatically adjusts equipment operation parameters according to a preset control logic and an optimization algorithm; and the application layer analyzes and decides the data processed by the control layer. According to the system, intelligent monitoring and control are achieved, equipment faults are early warned in advance, the downtime is shortened, meanwhile, resource recovery and cyclic utilization are achieved, the construction cost and the environmental influence can be reduced, and the shield muck treatment efficiency, the resource recovery rate and the environmental protection performance are remarkably improved.

The invention provides a high-performance shield intelligent synchronous grouting control system based on solid waste residue soil resource utilization, a grouting material and a preparation method, and relates to the technical field of shield engineering, the high-performance shield intelligent synchronous grouting control system comprises a parameter obtaining module used for obtaining key parameters, the actual grouting amount and the actual grouting pressure; the error calculation module is used for calculating a grouting amount error and a grouting pressure error; the error fuzzy classification module is used for fuzzy grade classification; the membership calculation module is used for calculating the membership of the grouting amount error and the grouting pressure error to each fuzzy grade category; the fuzzy rule base construction module is used for establishing an initial fuzzy rule base and adjusting and optimizing the initial fuzzy rule base to obtain a final fuzzy rule base; and a grouting process adjusting module. The solid waste muck is used for replacing bentonite and part of sand aggregate, so that the material cost is remarkably reduced, outward transportation and landfill of waste are reduced, and the burden on the environment is reduced.

The invention provides a treatment method for low-grade multi-metal gold concentrate, and relates to the technical field of comprehensive utilization of minerals. According to the treatment method of the low-grade multi-metal gold concentrate, most of iron and copper form iron-copper matte through pyrogenic smelting, meanwhile, gold is captured into the iron-copper matte, then iron-copper matte powder is obtained after water quenching and ball milling, the iron-copper matte powder is subjected to oxidation ammonia leaching, copper in the iron-copper matte is extracted, and the iron-copper matte powder is subjected to oxidation ammonia leaching to obtain the low-grade multi-metal gold concentrate. The obtained copper-containing ammonia leaching liquid is subjected to a traditional extraction-reverse extraction-electrodeposition process to obtain an electrodeposited copper product, ammonia leaching residues obtained after copper extraction are subjected to cyanidation leaching, gold in the ammonia leaching residues is extracted, cyanidation liquid is subjected to a traditional gold extraction process to obtain a gold product, the cyanidation tailings mainly comprise iron sulfide, the content of iron and sulfur in the tailings is high, and the content of sulfur in the tailings is high. And the subsequent cinder can be directly sold as an iron-making raw material. The amount of iron-silicon slag generated by the method is extremely low, and compared with a traditional molten pool smelting method, the comprehensive utilization rate of iron in the multi-metal gold concentrate is greatly increased.

The invention discloses high-strength corrosion-resistant pervious concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete is prepared from the following raw materials in parts by weight: 200-300 parts of cement, 1000-1300 parts of coarse aggregate, 20-30 parts of a composite admixture, 10-20 parts of a reinforcing agent, 1-1.5 parts of a water reducing agent, 3-5 parts of an additive and 100-130 parts of water, the reinforcing agent is prepared from modified basalt fiber and styrene-acrylic emulsion according to the mass ratio of (8 to 10): 1; the additive is a SiO2 (at) PDA (at) zeolite composite material; the composite admixture is composed of fly ash and modified steel slag powder according to a mass ratio of 2: 1. According to the invention, by optimizing the proportion of a plurality of composite materials, the interface bonding property with a gel material matrix is improved, the mechanical property and durability are remarkably improved while the water permeability is maintained, and the corrosion resistance of the concrete matrix is enhanced.

The invention discloses a preparation method of a green high-performance industrial solid waste-based grouting material, and belongs to the field of industrial solid waste treatment and grouting reinforcement, and the preparation method comprises the following steps: performing dry mixing on red mud, slag, fly ash and cement which are dried and ground to specified fineness according to a preset proportion to obtain a uniform dry material; preparing a composite alkali activator from water glass and sodium hydroxide according to a molar ratio of 3: 1, premixing the composite alkali activator with water, and adding the dry material in batches to form wet slurry; and carrying out high-speed shearing and stirring on the wet slurry, and standing and curing to obtain the solid waste-based slurry which can be directly used for grouting. The method obviously improves the solid waste utilization rate, relieves the environmental pressure, and is suitable for related projects such as stratum settlement control, gushing water blocking, mine roadway broken rock mass supporting and underground cavity concrete lining crack repairing in tunnel and subway projects.

The invention relates to an anorthite material and a preparation method thereof. The adopted technical proposal comprises the following steps of: according to (ZL200510019664.3) patent technology, namely a method for preparing titanium and a titanium alloy by utilizing titanium-containing furnace slag, taking molten tailings which is extracted with the titanium alloy as a raw material, adding 20 to 50 weight percent of silica, 0 to 60 weight percent of clay and 0 to 40 percent aedelforsite, and cooling a melt to obtain the anorthite material after the mixture is completely molten and a bath composition is uniform; or taking cold tailings extracted with the titanium alloy as the raw material, adding 20 to 50 weight percent of the silica, 0 to 60 weight percent of the clay and 0 to 40 percent the aedelforsite, carrying out mix grinding on the raw material and the admixture until the particle size is less than 0.1 mm, performing blank compression, and calcining the mixture at a temperature of between 1,200 and 1,400 DEG C to obtain the anorthite material. The method takes the tailings extracted with the titanium as the raw material, saves precious bauxite resources, has low cost, ensures that industrial residue is utilized with high added value, is environment-friendly and has simple process.

The invention relates to the technical field of plasma generator protection, and discloses a plasma generator protection device which comprises a plasma generator provided with a mounting seat and a spray gun extending into a combustion chamber; the sleeve sleeves the spray gun and is used for replacing the spray gun to bear the scouring of primary air pulverized coal airflow in the combustion chamber; the powder slag cleaning part comprises a scraping plate, the length direction of the scraping plate is consistent with the length direction of the spray gun, and the scraping plate is attached to the periphery of the sleeve; the scraping plate is driven by an annular driving mechanism to rotate along the circumferential track of the outer surface of the sleeve, the movement path of the scraping plate is tightly attached to the outer circumferential face of the sleeve, and the rotation axis of the scraping plate coincides with the geometric axis of the sleeve, so that powder slag generated after hot melting of the surface of the sleeve is removed. Pulverized coal airflow scouring is blocked through the sleeve, powder slag is cleaned in combination with the annular driving scraper, the heat dissipation performance of the spray gun is guaranteed, the service life of the spray gun is remarkably prolonged, the maintenance cost is reduced, and the operation stability and economical efficiency of equipment are improved.

The invention relates to the technical field of sludge reduction and resource utilization, in particular to a method for resource utilization of sludge gasification slag. According to the method, municipal sludge gasification slag is smashed and then subjected to acid leaching, acid leaching liquid and acid leaching slag are obtained, iron in the acid leaching liquid is recycled, meanwhile, the acid leaching slag is subjected to alkaline leaching, under the strong alkaline condition, a calcium source is added into alkaline leaching liquid, then calcium phosphate sediment can be obtained, and iron in alkaline leaching separation liquid is recycled; a calcium ion solution can be generated in the processes of recovering iron in the pickle liquor and refining calcium phosphate, and the obtained calcium ion solution can be used as a calcium source for comprehensive utilization. The method disclosed by the invention can be used for realizing extraction and resource utilization of phosphorus, iron, aluminum and calcium in the sludge gasification slag, and has important significance on environmental protection and resource saving.